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\u8fd1\u65e5\uff0c\u5728\u590d\u65e6<\/b><\/strong>\u5927\u5b66<\/b><\/strong>\u90d1\u803f\u950b<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u548c\u6e56\u5357\u5927\u5b66\u9a6c\u5efa\u6c11<\/b><\/strong>\uff08<\/b><\/strong>\u5171\u540c<\/b><\/strong>\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u5c55\u793a\u4e86\u787c\u63ba\u6742\u77f3\u58a8\u70ef\u4f5c\u4e3a\u9ad8\u6548\u65e0\u91d1\u5c5eN2<\/sub>\u8fd8\u539f\u7535\u50ac\u5316\u5242\u3002\u787c\u5728\u77f3\u58a8\u70ef\u6846\u67b6\u4e2d\u7684\u63ba\u6742\u5bfc\u81f4\u7535\u5b50\u5bc6\u5ea6\u7684\u91cd\u65b0\u5206\u5e03\uff0c\u5176\u4e2d\u7f3a\u7535\u5b50\u787c\u4f4d\u7f6e\u63d0\u4f9b\u589e\u5f3a\u7684\u4e0eN2<\/sub>\u5206\u5b50\u7684\u7ed3\u5408\u80fd\u529b\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u63ed\u793a\u4e86\u4e0d\u540c\u787c\u63ba\u6742\u78b3\u7ed3\u6784\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5176\u4e2dBC3<\/sub>\u7ed3\u6784\u4f7f\u5f97N2<\/sub>\u7535\u8fd8\u539f\u6210NH3<\/sub>\u7684\u80fd\u91cf\u52bf\u5792\u6700\u4f4e\u3002\u5728\u63ba\u6742\u6c34\u5e73\u4e3a6.2\uff05\u65f6\uff0c\u787c\u63ba\u6742\u77f3\u58a8\u70ef\u7684NH3<\/sub>\u751f\u6210\u901f\u7387\u8fbe\u52309.8\u03bcg\u00b7hr-1<\/sup>\u00b7cm-2<\/sup>\uff0c\u5e76\u4e14\u5728-0.5V\u4e0b\u76f8\u5bf9\u4e8e\u53ef\u9006\u6c22\u7535\u6781\u7684\u6700\u9ad8\u62a5\u544a\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a10.8\uff05\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u7684\u6c34\u6eb6\u6db2\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\u539f\u5b50\u7ea7\u8bbe\u8ba1\u4e3a\u6709\u6548\u7684\u7535\u50ac\u5316\u5242\u51cf\u5c11N2<\/sub>\u7684\u6f5c\u529b\u5f88\u5927\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cBoron-Doped Graphene for Electrocatalytic N<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0Reduction<\/b><\/strong>\u201d\u53d1\u8868\u5728Joule<\/b><\/strong>\u4e0a\uff0c\u8bba\u6587\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u4e3a\uff1a\u4e8e\u6653\u654f\u3001\u5371\u589e\u66e6\u3001\u97e9\u9e4f\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n \u56fe1.<\/b><\/strong>\u00a0<\/b><\/strong>BG\u7684\u7535\u5b50\u5bc6\u5ea6<\/b><\/strong><\/p>\n \uff08A\uff09BC3<\/sub>\u7684\u539f\u5b50\u8f68\u9053\u7ed3\u5408N2\u7684\u793a\u610f\u56fe\u3002<\/p>\n \uff08B\uff09\u672a\u63ba\u6742G\uff08G\uff09\u548cBG\uff08\u53f3\uff09\u7684LUMO\uff08\u84dd\u8272\uff09\u548cHOMO\uff08\u7ea2\u8272\uff09\u3002\u5355\u4e2a\u63ba\u6742\u787c\u539f\u5b50\u7684\u4f4d\u7f6e\u88ab\u6807\u8bb0\u3002<\/p>\n \u56fe2.<\/b><\/strong>\u00a0<\/b><\/strong>BG\u7684\u8868\u5f81<\/b><\/strong><\/p>\n \uff08A\uff09BG-1\u7684TEM\u56fe\u50cf\u3002<\/p>\n \uff08B\uff09B\uff08\u7eff\u8272\uff09\uff0cC\uff08\u7ea2\u8272\uff09\u548cO\uff08\u7d2b\u8272\uff09\u7684BG-1\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n \uff08C\uff09BG-1\uff0cBOG\uff0cBG-2\u548cG\u7684\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n \uff08D\uff09BG-1\uff0cBOG\uff0cBG-2\u548cG\u7684FT-IR\u5149\u8c31\u3002<\/p>\n \u56fe3.<\/b><\/strong>\u00a0<\/b><\/strong>BG\u7684\u7ed3\u6784\u5206\u6790<\/b><\/strong><\/p>\n \uff08A\uff09BG-1\u7684C 1s XPS\u8c31\u3002<\/p>\n \uff08B\uff09BG-1\u7684B 1s XPS\u8c31\u3002<\/p>\n \uff08C\uff09BOG\u7684B 1s XPS\u8c31\u3002<\/p>\n \uff08D\uff09BG-2\u7684B 1s XPS\u8c31\u3002<\/p>\n \uff08E\uff09\u4e09\u4e2aBG\u6837\u672c\u4e2d\u4e0d\u540cB\u7c7b\u578b\u7684\u767e\u5206\u6bd4\u3002<\/p>\n \uff08F\uff09BG-1\uff0cBOG\uff0cBG-2\u548cG\u7684N2<\/sub>TPD\u66f2\u7ebf\u3002<\/p>\n \u56fe4. <\/b><\/strong>BG\u6837\u54c1\u7684\u7535\u50ac\u5316NRR\u6d3b\u6027<\/b><\/strong><\/p>\n \uff08A\uff09\u57281mV\u00b7s -1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\uff0cBG-1\u5728Ar\u548cN2<\/sub>\u9971\u548c\u6eb6\u6db2\u4e2d\u7684LSV\u66f2\u7ebf\u3002<\/p>\n \uff08B\uff09BG-1 \u7684NH3<\/sub>\u4ea7\u751f\u901f\u7387\uff08\u5de6y\u8f74\uff09\u548cNH3<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff08\u53f3y\u8f74\uff09\u3002\u8bef\u5dee\u7ebf\u8868\u793a\u4e09\u6b21\u72ec\u7acb\u6d4b\u91cf\u7684\u5e73\u5747\u503c\u3002<\/p>\n \uff08C\uff09\u4e0d\u540c\u7535\u4f4d\u4e0bBG-1\uff0cBOG\uff0cBG-2\u548cG \u7684NH3<\/sub>\u751f\u6210\u901f\u7387\u3002<\/p>\n \uff08D\uff09\u4e0d\u540c\u65bd\u52a0\u7535\u4f4d\u4e0bBG-1\uff0cBOG\uff0cBG-2\u548cG \u7684NH3<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u503c\u3002<\/p>\n \uff08E\uff09BG-1\u5728\u4e0d\u540c\u65bd\u52a0\u7535\u4f4d\u4e0b\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\u3002<\/p>\n \uff08F\uff09BG-1\u5728-0.5V\u00a0vs.RHE\u7684NRR\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n \u56fe<\/b><\/strong>5<\/b><\/strong>. <\/b><\/strong>BG\u6837\u54c1NRR\u7684\u7406\u8bba\u8ba1\u7b97<\/b><\/strong><\/p>\n \uff08A\uff09BG\u7684NRR\u7684\u793a\u610f\u56fe\u3002<\/p>\n \uff08B\uff09\u5206\u522b\u5728BC3<\/sub>\uff0cBC2<\/sub>O\uff0cBCO2<\/sub>\u548cC\u4e0a\u7684NRR\u7684\u53cd\u5e94\u8def\u5f84\u548c\u76f8\u5e94\u7684\u80fd\u91cf\u53d8\u5316\u3002\u70b9\u7f00\u7684\u77e9\u5f62\u6846\u8868\u793a\u4e0d\u80fd\u53d1\u751f\u7684\u6b65\u9aa4\u3002<\/p>\n \uff08C\uff09\u5206\u522b\u4e3aBC3<\/sub>\uff0cBC2<\/sub>O\uff0cBCO2<\/sub>\u548cC\u7684NRR\u7684\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n \u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n \u603b\u4e4b\uff0c\u56e2\u961f\u901a\u8fc7\u6c27\u5316\u77f3\u58a8\u70ef\u548c\u787c\u9178\u7684\u70ed\u9000\u706b\u6210\u529f\u5f00\u53d1\u4e86BG\uff0c\u5176\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u5728\u6c34\u6eb6\u6db2\u4e2d\u5177\u6709\u7528\u4e8e\u7535\u5316\u5b66NRR\u7684\u65e0\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u3002\u4e0e\u672a\u63ba\u6742\u7684\u77f3\u58a8\u70ef\u76f8\u6bd4\uff0c\u8be5BG\u663e\u793a\u51fa\u663e\u7740\u7684\u589e\u5f3a\uff0c\u5177\u6709\u4f18\u5f02\u7684NH3<\/sub>\u4ea7\u751f\u901f\u73879.8\u03bcg\u00b7hr-1<\/sup>\u00b7cm-2<\/sup>\u548c\u6700\u9ad8\u62a5\u9053\u7684FE NH3<\/sub>\uff08\u5728-0.5V\u00a0vs.RHE\u4e3a10.8\uff05\uff09\u5728\u73af\u5883\u6c34\u6eb6\u6db2\u4e2d\u6761\u4ef6\u3002\u5c06\u5b9e\u9a8c\u89c2\u5bdf\u4e0e\u7406\u8bba\u7814\u7a76\u76f8\u7ed3\u5408\uff0c\u7c7b\u77f3\u58a8\u70ef\u6837BC3<\/sub>\u578b\u952e\u5728\u589e\u5f3a\u51e0\u79cd\u7c7b\u578b\u7684\u63ba\u6742\u787c\u7684\u78b3\u7ed3\u6784\uff08\u5373BC3<\/sub>\uff0cBC2<\/sub>O\uff0cBCO2<\/sub>\uff09\u4e2d\u589e\u5f3aN2<\/sub>\u56fa\u5b9a\u4e2d\u8d77\u5173\u952e\u4f5c\u7528\uff0c\u8fd9\u5bf9N2<\/sub>\u5438\u9644\u548c\u6c28\u751f\u4ea7\u90fd\u6709\u597d\u5904\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3aNRR\u548c\u5176\u4ed6\u7535\u50ac\u5316\u53cd\u5e94\u5f00\u53d1\u9ad8\u6548\u65e0\u91d1\u5c5e\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u8bb8\u591a\u65b0\u7684\u673a\u4f1a\u3002<\/p>\n \u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1a<\/b><\/strong>Boron-Doped Graphene for Electrocatalytic N<\/u>2<\/sub><\/u>\u00a0Reduction<\/u><\/a>\uff08Joule, 2018, DOI\uff1a10.1016\/j.joule.2018.06.007\uff09<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u590d\u65e6\u5927\u5b66\u90d1\u803f\u950b\u6559\u6388<\/strong>\u4fee\u6b63\u6821\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/u><\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n
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