{"id":142667,"date":"2018-06-21T06:30:40","date_gmt":"2018-06-20T22:30:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=142667"},"modified":"2018-06-21T13:32:31","modified_gmt":"2018-06-21T05:32:31","slug":"energy-environ-sci-%ef%bc%9a%e9%9b%86%e6%88%90%e6%9d%90%e6%96%99%e5%92%8c%e4%b8%a4%e4%b8%aa%e4%ba%8c%e5%85%83%e7%94%b5%e6%b1%a0%e7%9a%84%e4%bc%98%e5%8a%bf-%e4%b8%89%e5%85%83%e9%9d%9e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=142667","title":{"rendered":"Energy Environ. Sci.\uff1a\u96c6\u6210\u6750\u6599\u548c\u4e24\u4e2a\u4e8c\u5143\u7535\u6c60\u7684\u4f18\u52bf\u2014\u2014\u4e09\u5143\u975e\u5bcc\u52d2\u70ef\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u9ad8\u4e8e13.7 %"},"content":{"rendered":"

\u3010\u524d\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u6eb6\u6db2\u5904\u7406\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60(PSCs)\u5f97\u5230\u4e86\u5feb\u901f\u53d1\u5c55\uff0c\u57fa\u4e8e\u9ad8\u6548\u7a84\u5e26\u4f9b\u4f53\u548c\u975e\u560c\u5464\u53d7\u4f53\uff0cPSCs\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387(PCE)\u5df2\u7ecf\u8d85\u8fc713 %\u3002\u589e\u5f3a\u5149\u5b50\u6536\u96c6\u548c\u6709\u6e90\u5c42\u7684\u4f18\u5316\u76f8\u4f4d\u5206\u79bb\u662f\u5b9e\u73b0\u9ad8\u6548PSCs\u7684\u5148\u51b3\u6761\u4ef6\u3002\u4e09\u5143\u7b56\u7565\u5df2\u88ab\u8bc1\u660e\u662f\u901a\u8fc7\u5728\u4f9b\u4f53\u4e2d\u5f15\u5165\u7b2c\u4e09\u7ec4\u5206:\u53d7\u4f53\u4f53\u7cfb\u4f5c\u4e3a\u6d3b\u6027\u5c42\u6765\u5b9e\u73b0\u6027\u80fd\u6539\u8fdb\u7684\u6709\u6548\u4e14\u7b80\u5355\u7684\u65b9\u6cd5\u3002\u5927\u90e8\u5206\u4e09\u5143PSCs\u662f\u6839\u636e\u6240\u7528\u6750\u6599\u7684\u4e92\u8865\u5438\u6536\u5149\u8c31\u8bbe\u8ba1\u7684\u3002\u4e8b\u5b9e\u4e0a\uff0c\u7531\u4e8e\u6240\u7528\u6750\u6599\u7684\u80fd\u7ea7\u4e0d\u540c\uff0c\u4e09\u5143\u6d3b\u6027\u5c42\u4e2d\u5fc5\u7136\u4f1a\u5f62\u6210\u4e00\u4e9b\u7535\u8377\u9677\u9631\u3002\u5982\u679c\u7b2c\u4e09\u7ec4\u5206\u5728\u4e09\u5143\u6d3b\u6027\u5c42\u4e2d\u5145\u5f53\u9677\u9631\u4e2d\u5fc3\uff0c\u4e09\u5143\u7b56\u7565\u5c06\u5931\u6548\u3002\u6fc0\u5b50\u89e3\u79bb\u548c\u7535\u8377\u4f20\u8f93\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u9664\u4e86\u5bf9\u6d3b\u6027\u5c42\u8fdb\u884c\u5145\u5206\u7684\u5149\u5b50\u6536\u96c6\u4e4b\u5916\uff0c\u8fd8\u5e94\u8be5\u5728\u51b3\u5b9aPSCs\u7684\u6027\u80fd\u65b9\u9762\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u3002\u6240\u7528\u6750\u6599\u7684\u76f8\u5bb9\u6027\u51b3\u5b9a\u4e86\u6d3b\u6027\u5c42\u7684\u76f8\u5206\u79bb\u7a0b\u5ea6\u548c\u52a8\u6001\u8fc7\u7a0b\uff0c\u5bfc\u81f4PSCs\u7684\u5149\u4f0f\u53c2\u6570\u660e\u663e\u4e0d\u540c\u3002\u56e0\u6b64\uff0c\u5728\u9009\u62e9\u7b2c\u4e09\u7ec4\u5206\u65f6\uff0c\u9664\u4e86\u8003\u8651\u6240\u7528\u6750\u6599\u7684\u5149\u5b66\u6027\u80fd\u5916\uff0c\u8fd8\u5e94\u8003\u8651\u4e8c\u5143PSCs\u7684\u5149\u4f0f\u53c2\u6570\u3002\u591a\u7528\u9014\u7684\u975e\u560c\u5464\u53d7\u4f53\u5177\u6709\u8f83\u9ad8\u7684\u5149\u5b50\u6536\u96c6\u80fd\u529b\u548c\u6613\u4e8e\u8c03\u8282\u7684\u80fd\u7ea7\uff0c\u8fd9\u4e3a\u5236\u5907\u9ad8\u6548\u7684\u4e09\u5143PSCs\u63d0\u4f9b\u4e86\u66f4\u591a\u7684\u673a\u4f1a\u3002\u540c\u65f6\uff0c\u5177\u6709\u76f8\u4f3c\u5316\u5b66\u7ed3\u6784\u7684\u975e\u6108\u6765\u6108\u591a\u7684\u53d7\u4f53\uff0c\u7531\u4e8e\u5176\u7565\u5fae\u5b9a\u5236\u7684\u5b98\u80fd\u56e2\uff0c\u53ef\u80fd\u8868\u73b0\u51fa\u826f\u597d\u7684\u76f8\u5bb9\u6027\uff0c\u4ee5\u53ca\u4e0d\u540c\u7684\u5149\u7269\u7406\u548c\u5149\u5316\u5b66\u6027\u8d28\u3002\u4e3a\u4e86\u83b7\u5f97\u9ad8\u6548\u7684\u4e09\u5143PSCs\uff0c\u5e94\u9009\u62e9\u76f8\u5bb9\u6027\u597d\u7684\u975e\u6108\u6765\u6108\u591a\u7684\u53d7\u4f53\uff0c\u534f\u540c\u4f18\u5316\u4e09\u5143\u6d3b\u6027\u5c42\u7684\u5149\u5b50\u6536\u96c6\u548c\u76f8\u5206\u79bb\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u5317\u4eac\u4ea4\u901a\u5927\u5b66\u7684\u5f20\u798f\u4fca\u6559\u6388\u3001<\/b>\u6b66\u6c49\u5927\u5b66\u53ca\u6df1\u5733\u5927\u5b66\u7684\u6768\u695a\u7f57\u6559\u6388\uff0c<\/b>\u548c<\/b>\u5357\u4eac\u7406\u5de5\u5927\u5b66\u7684\u5510\u536b\u534e\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/b>\u8054\u5408\u5728Energy Environ. Sci.\u53d1\u6587\uff0c\u9898\u4e3a\uff1aTernary nonfullerene polymer solar cells with efficiency \uff1e13.7% by integrating the advantages of the materials and two binary cells\u3002\u7814\u7a76\u4eba\u5458\u7528\u4e24\u79cd\u76f8\u5bb9\u6027\u597d\u7684\u5c0f\u5206\u5b50\u975e\u6838\u53d7\u4f53(INPIC-4F\u548cMeIC1)\u548c\u4e00\u79cd\u805a\u5408\u7269\u4f9b\u4f53PBDB-T.\u5236\u5907\u4e86\u9ad8\u6548\u4e09\u5143\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60(PSCs)\uff0cINPIC-4F\u6216MeIC1\u57fa\u4e8c\u5143PSCs\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387(PCE)\u5206\u522b\u8fbe\u523012.55 %\u548c11.53 %\u3002\u5728\u8fd9\u4e9b\u9ad8\u6548\u7684\u4e8c\u5143PSC\u7684\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u4eba\u5458\u5728\u53d7\u4f53\u4e2d\u542b\u670950 wt%\u7684MeIC1\u7684\u4e09\u5143PSC\u4e2d\u5b9e\u73b0\u4e8613.73 %\u7684\u9ad8PCE\uff0c\u540c\u65f6\u6539\u5584\u4e8621.86 mA cm\u2212<\/sup>2<\/sup>\u7684\u77ed\u8def\u7535\u6d41(JSC<\/sub>)\u30010.88 V\u7684\u5f00\u8def\u7535\u538b(VOC<\/sub>)\u548c71.39 %\u7684\u586b\u5145\u56e0\u5b50(FF)\u3002\u4e09\u5143PSCs\u7684PCE\u6539\u5584\u5e94\u4e3b\u8981\u5f52\u529f\u4e8e\u4e09\u5143\u6d3b\u6027\u5c42\u4f18\u5316\u7684\u5149\u5b50\u6536\u96c6\u548c\u819c\u5f62\u6001\u3002\u8fd9\u4e00\u7ed3\u679c\u53ef\u4e3a\u5236\u5907\u9ad8\u6548\u4e09\u5143PSCs\u63d0\u4f9b\u66f4\u6df1\u5165\u7684\u6750\u6599\u9009\u62e9\u6807\u51c6: (i)\u6240\u7528\u6750\u6599\u7684\u4e92\u8865\u5438\u6536\u5149\u8c31\u548c\u826f\u597d\u7684\u76f8\u5bb9\u6027\uff1b(ii)\u5bf9\u5e94\u7684\u4e24\u4e2a\u4e8c\u5143PSC\u7684\u4e92\u8865\u5149\u4f0f\u53c2\u6570\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe. 1 \u5668\u4ef6\u7ed3\u6784\u548c\u5438\u6536\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u6240\u7528\u6750\u6599\u7684\u5316\u5b66\u7ed3\u6784\uff1b<\/p>\n

(b)\u5668\u4ef6\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

(c)\u8584\u819c\u4e2d\u6240\u7528\u6750\u6599\u7684\u5438\u6536\u7cfb\u6570\uff1b<\/p>\n

(d)\u4e0d\u540cMeIC1\u542b\u91cf\u5171\u6df7\u819c\u7684\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

\u56fe. 2 PSCs\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u4e0d\u540cMeIC1\u542b\u91cf\u7684PSCs\u5728AM 1.5G\u5149\u7167\u4e0b\u7684J-V\u66f2\u7ebf\uff0c\u5149\u7167\u5f3a\u5ea6\u4e3a100 mW cm\u22122<\/sup>\uff1b<\/p>\n

(b)\u76f8\u5e94PSCs\u7684EQE\u8c31\uff1b<\/p>\n

(c)\u5206\u6bb5\u8ba1\u7b97\u7684JSC<\/sub>\u4e0eMeIC1\u542b\u91cf\u7684\u5173\u7cfb\uff1b<\/p>\n

(d) PSCs\u7684VOC<\/sub>\u4e0e\u4e09\u5143\u6d3b\u6027\u5c42\u4e2d\u7684MeIC1\u542b\u91cf\u3001\u6240\u7528\u6750\u6599\u7684\u80fd\u7ea7\u548c\u793a\u610f\u6027\u52a8\u6001\u8fc7\u7a0b\u5173\u7cfb\uff1b<\/p>\n

\u56fe. 3 PSCs\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u4e8c\u5143\u548c\u4f18\u5316\u7684\u4e09\u5143PSCs\u7684Jph<\/sub>\u2013Veff<\/sub>\u66f2\u7ebf;<\/p>\n

(b) JSC<\/sub>\u4e0e\u5149\u5f3a\u7684\u5173\u7cfb\uff1b<\/p>\n

(c)\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\u4e0e\u5149\u5f3a\u7684\u5173\u7cfb\uff1b<\/p>\n

(d)\u7a7a\u7a74\u548c\u7535\u5b50\u8fc1\u79fb\u7387\u4e0eMeIC1\u542b\u91cf\u7684\u5173\u7cfb\uff1b<\/p>\n

\u56fe. 4 \u5171\u6df7\u819cGIXD\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\u4e0d\u540c\u7ec4\u5206\u7684MeIC1\u5171\u6df7\u819c\u9762\u5916(a)\u548c\u9762\u5185 (b)\u7684GIXD\u66f2\u7ebf\uff1b<\/p>\n

\u56fe. 5 \u5171\u6df7\u819c\u7ed3\u6784\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\u4e0d\u540c\u7ec4\u5206\u7684MeIC1\u5171\u6df7\u819cTEM\u56fe\uff1b<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u7528\u4e0d\u540c\u7684\u53d7\u4f53\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u9ad8\u6548\u7684PBDB-T\u57faPSC\uff0c\u4ee5MeIC1\u6216INPIC-4F\u4e3a\u53d7\u4f53\u7684\u4e8c\u5143PSC\u7684PCEs\u5206\u522b\u8fbe\u523011.53 %\u548c12.55 %\u3002\u5728\u4f18\u5316\u540e\u7684\u4e09\u5143PSC\u4e2d\uff0c\u5176\u4e0d\u4ec5\u7ee7\u627f\u4e86\u4e24\u79cd\u4e8c\u5143PSC\u7684\u4f18\u70b9\uff0c\u800c\u4e14PCE\u8fbe\u5230\u4e8613.73 %\uff0c\u662f\u4e09\u5143PSC\u4e2d\u6700\u9ad8\u7684\u3002\u4e09\u5143PSCs\u6027\u80fd\u7684\u63d0\u9ad8\u5e94\u5f52\u529f\u4e8e\u589e\u5f3a\u7684\u5149\u5b50\u6536\u96c6\u3001\u4f18\u5316\u7684\u76f8\u5206\u79bb\u548cPBDB-T\u5206\u5b50\u6392\u5217\uff0c\u4ee5\u53ca\u901a\u8fc7\u5728\u53d7\u4f53\u4e2d\u63ba\u516550wt %\u7684MeIC1\uff0c\u5bfc\u81f4\u4e09\u5143\u6d3b\u6027\u5c42\u4e2d\u66f4\u5e73\u8861\u7684\u7535\u8377\u4f20\u8f93\u3002\u540c\u65f6\u4e5f\u5e94\u8003\u8651\u76f8\u5e94\u4e8c\u5143PSCs\u7684\u5149\u5e26\u9699\u3001\u80fd\u7ea7\u3001\u6240\u7528\u6750\u6599\u7684\u76f8\u5bb9\u6027\u548c\u5149\u4f0f\u53c2\u6570\uff0c\u4f5c\u4e3a\u5236\u5907\u9ad8\u6548\u4e09\u5143PSCs\u7684\u5173\u952e\u51c6\u5219\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aTernary nonfullerene polymer solar cells with efficiency >13.7% by integrating the advantages of the materials and two binary cells<\/a>\u00a0<\/strong>(2018, Energy Environ. Sci., DOI: DOI: 10.1039\/c8ee01107a)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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