{"id":14216,"date":"2016-05-18T17:00:47","date_gmt":"2016-05-18T09:00:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=14216"},"modified":"2016-05-18T14:09:00","modified_gmt":"2016-05-18T06:09:00","slug":"nature-chemistry%ef%bc%9a%e5%8d%95%e5%a3%81%e7%a2%b3%e7%ba%b3%e7%b1%b3%e7%ae%a1%e5%bc%82%e8%b4%a8%e7%bb%93%e4%b8%ad%e6%bf%80%e5%ad%90%e5%88%86%e7%a6%bb%e7%9a%84%e9%a9%b1%e5%8a%a8%e5%8a%9b%e8%b0%83","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=14216","title":{"rendered":"Nature Chemistry\uff1a\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u5f02\u8d28\u7ed3\u4e2d\u6fc0\u5b50\u5206\u79bb\u7684\u9a71\u52a8\u529b\u8c03\u63a7"},"content":{"rendered":"

\u7406\u89e3\u5206\u5b50\u4f53\u7cfb\u4e2d\u754c\u9762\u7535\u5b50\u4f20\u8f93\u52a8\u529b\u5b66\u548c\u80fd\u91cf\u5b66\u5bf9\u4e8e\u5149\u7535\u3001\u592a\u9633\u80fd\u4f53\u7cfb\u548c\u80fd\u91cf\u5b58\u50a8\u6280\u672f\u7684\u53d1\u5c55\u81f3\u5173\u91cd\u8981\u3002\u63cf\u8ff0\u7535\u5b50\u8f6c\u79fb\u7684\u9a6c\u5e93\u65af\u65b9\u7a0b\u628a\u7ed9\u5b9a\u65bd\u4e3b\/\u53d7\u4e3b\u5bf9\u4e4b\u95f4\u7684\u7535\u8377\u8f6c\u79fb\u7684\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u548c\u91cd\u7ec4\u80fd\u4e0e\u5176\u52a8\u529b\u5b66\u548c\u7535\u5b50\u8fc1\u79fb\u7387\u8054\u7cfb\u8d77\u6765\u3002<\/p>\n

\u8fd1\u671f\uff0c\u7f8e\u56fd\u518d\u751f\u80fd\u6e90\u5b9e\u9a8c\u5ba4Jeffrey L. Blackburn\u8bfe\u9898\u7ec4<\/strong>\u91c7\u7528\u65f6\u95f4\u5206\u8fa8\u7684\u5fae\u6ce2\u7535\u5bfc\u7387\uff08TRMC\uff09\u4f5c\u4e3a\u754c\u9762\u6fc0\u5b50\u5206\u79bb\u7684\u4e00\u79cd\u7075\u654f\u63a2\u9488\uff0c\u53d1\u73b0\u4e86\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u5bf9\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08SWCNTs\uff09\u548c\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7684\u5149\u5f15\u53d1\u7535\u5b50\u8f6c\u79fb\uff08PET\uff09\u7684\u5f71\u54cd\u3002\u7814\u7a76\u4eba\u5458\u9996\u6b21\u89c2\u5bdf\u4e86\u9a6c\u5e93\u65af\u53cd\u8f6c\u533a\uff08\u5728\u8be5\u533a\u57df\u5185\u9a71\u52a8\u529b\u5927\u4e8e\u91cd\u7ec4\u80fd\uff09\uff0c\u5e76\u5b9a\u91cf\u63cf\u8ff0\u4e86\u4e00\u4e2a\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\/\u53d7\u4e3b\u7cfb\u7edf\u6a21\u578b\u7684\u5149\u5f15\u53d1\u7535\u5b50\u8f6c\u79fb\uff08PET\uff09\u7684\u91cd\u7ec4\u80fd\u3002\u8fd9\u79cd\u5fae\u5c0f\u7684\u91cd\u7ec4\u80fd\uff08\u5927\u7ea6130meV\uff0c\u5927\u90e8\u5206\u7531\u5bcc\u52d2\u70ef\u53d7\u4e3b\u5f15\u53d1\uff09\u6709\u5229\u4e8e\u4f7f\u5149\u8f6c\u79fb\u65b9\u6848\u7684\u80fd\u91cf\u635f\u5931\u8fbe\u5230\u6700\u5c0f\u5316\u3002<\/p>\n

\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08SWCNTs\uff09\u534a\u5bfc\u4f53\u8584\u819c\u662f\u8bb8\u591a\u5149\u7535\u5e94\u7528\u4e2d\u5f15\u4eba\u6ce8\u76ee\u7684\u5149\u5438\u6536\u5242\u3002\u5b83\u542b\u6709\u79bb\u57df\u03c0\u7535\u5b50\u4f53\u7cfb\uff0c\u56e0\u800c\u5177\u6709\u5927\u8303\u56f4\u80fd\u91cf\u53ef\u8c03\u7684\u5149\u5438\u6536\u7387\u548c\u9ad8\u7684\u7535\u8377\u8fc1\u79fb\u7387\u3002\u8fd1\u671f\u7814\u7a76\u81f4\u529b\u4e8e\u5229\u7528SWCNTs\u534a\u5bfc\u4f53\u7684\u4f18\u5f02\u6027\u80fd\u5408\u6210\u592a\u9633\u80fd\u7535\u6c60\u548c\u5177\u6709\u9ad8\u7ea2\u5916\u91cf\u5b50\u6548\u7387\u7684\u5149\u7535\u63a2\u6d4b\u5668\u3002\u8fd9\u4e9b\u5668\u4ef6\u4e2d\u7684\u5149\u7535\u6d41\u7531\u5149\u751fSWCNT\uff08\u65bd\u4e3b\uff09\u4e0e\u5408\u9002\u7684\u53d7\u4e3b\uff08\u5982\u5bcc\u52d2\u70ef\uff09\u4e4b\u95f4\u7684\u754c\u9762\u6fc0\u5b50\u5206\u79bb\u800c\u9a71\u52a8\u3002SWCNTs\u548c\u5176\u4ed6\u6709\u673a\u534a\u5bfc\u4f53\u4e4b\u95f4\u7684\u2161\u578b\u5f02\u8d28\u7ed3\u4e0a\u81ea\u7531\u7535\u8377\u8f7d\u6d41\u5b50\u7684\u5f62\u6210\u7531\u6fc0\u5b50\u5206\u79bb\u7684\u653e\u80fd\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u800c\u9884\u6d4b\uff08\u5982\u56fe1\uff09\u3002\u4e3a\u4e86\u4f7fSWCNT\u592a\u9633\u80fd\u7535\u6c60\u7684\u5f00\u8def\u7535\u538b\uff08VOC\uff09\u8fbe\u5230\u6700\u5927\uff0c\u754c\u9762\u4e0a\u4e0e\u5149\u751f\u7535\u5b50\u8f6c\u79fb\uff08PET\uff09\u76f8\u5173\u7684\u80fd\u91cf\u635f\u8017\u5e94\u8be5\u8fbe\u5230\u6700\u5c0f\u5316\u3002<\/p>\n

\u524d\u4eba\u5173\u4e8e\u542b\u591a\u5e26\u9699SWCNT\u7684\u591a\u5206\u6563\u4f53\u7cfb\u7684\u7814\u7a76\u8868\u660e\uff1a\u8f7d\u6d41\u5b50\u7684\u4ea7\u7387\uff08\u03d5\uff09\u548c\u70ed\u529b\u5b66\u9a71\u52a8\u529b\uff08\u0394GPET\uff09\u4e4b\u95f4\u6709\u5f88\u5f3a\u7684\u76f8\u5173\u6027\uff0c\u5373\u5f53SWCNTs\u7684\u76f4\u5f84\uff1e1nm\u65f6\uff0c\u03d5\u5927\u5e45\u4e0b\u964d\u3002\u7136\u800c\uff0c\u4e4b\u524d\u7684\u7814\u7a76\u6ca1\u6709\u8003\u8651\u540c\u6837\u91cd\u8981\u7684\u7535\u8377\u8f6c\u79fb\u91cd\u7ec4\u80fd\uff08\u03bb\uff09\u2014\u2014\u5728\u5149\u5f15\u53d1\u7535\u5b50\u8f6c\u79fb\u65f6\u4e0e\u65bd\u4e3b\u3001\u53d7\u4e3b\u548c\u5468\u56f4\u73af\u5883\u7684\u7535\u8377\u91cd\u6392\u54cd\u5e94\u6709\u5173\u7684\u80fd\u91cf\u6d88\u8017\u2014\u2014\u7684\u5f71\u54cd\u3002SWCNTs\u662f\u72ec\u7279\u7684\u6709\u673a\u534a\u5bfc\u4f53\uff0c\u5728\u4e8e\u5176\u76f8\u5bf9\u60f0\u6027\u7684\u03c0\u5171\u8f6d\u5206\u5b50\u548c\u9ad8\u5ea6\u79bb\u57df\u5316\u7684\u8f7d\u6d41\u5b50\uff08\u8fd9\u4e0e\u5178\u578b\u7684\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684\u805a\u5408\u7269\u7684\u6781\u5316\u5b50\u8fd0\u8f93\u4e0d\u540c\uff09\u3002\u8fd9\u4e9b\u7279\u6027\u8868\u660eSWCNTs\u4e0a\u7684\u7535\u8377\u4f1a\u5bf9\u952e\u957f\u9020\u6210\u5fae\u6270\uff0c\u8fd9\u4f7f\u5f97SWCNTs\u6210\u4e3a\u4e00\u4e2a\u5bfb\u627e\u4f4e\u7684\u5149\u5f15\u53d1\u7535\u5b50\u8f6c\u79fb\u91cd\u7ec4\u80fd\u7684\u6a21\u578b\u7cfb\u7edf\u3002<\/p>\n

\u6b64\u5916\uff0c\u8fd8\u672a\u6709\u7814\u7a76\u8003\u8651\u5230\u6f5c\u5728\u7684\u53ef\u66ff\u4ee3\u7684\u5bcc\u52d2\u70ef\u53d7\u4e3b\uff08\u9664C60\u6216PCBM\uff08\u4e00\u79cd\u5bcc\u52d2\u70ef\u884d\u751f\u7269\uff09\u4ee5\u5916\uff09\u3002\u5728\u8fd9\u4e2a\u6709\u8da3\u7684\u65b0\u65bd\u4e3b\/\u53d7\u4e3b\u4f53\u7cfb\u4e2d\uff0c\u53d7\u4e3b\u6709\u53ef\u8c03\u7684\u7535\u5b50\u4eb2\u5408\u80fd\uff08EAs\uff09\uff0c\u8fd9\u4e0d\u4ec5\u80fd\u4f18\u5316\u6fc0\u5b50\u5206\u79bb\u800c\u4e14\u6709\u5229\u4e8e\u7814\u7a76\u9a71\u52a8\u529b\u548c\u91cd\u7ec4\u80fd\u4e4b\u95f4\u7684\u57fa\u672c\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

\u7406\u89e3\u548c\u6d4b\u91cf\u91cd\u7ec4\u80fd\u5bf9\u7535\u8377\u5206\u79bb\u7387\u7684\u5f71\u54cd\u5c06\u4f7f\u65bd\u4e3b\/\u53d7\u4e3b\u5f02\u8d28\u7ed3\u7684\u7406\u6027\u8bbe\u8ba1\u53d8\u5f97\u53ef\u80fd\uff0c\u5e76\u5c06\u5927\u5927\u51cf\u5c11\u4e0e\u754c\u9762\u6fc0\u5b50\u5206\u79bb\u6709\u5173\u7684\u80fd\u91cf\u635f\u8017\uff0c\u63d0\u9ad8\u5149\u7535\u6548\u7387\u3002\u4ee5\u4e0b\u662f\u8be5\u6587\u732e\u56fe\u6587\u89e3\u8bfb\uff1a<\/p>\n

\"nchem.2496-f1\"
\n\u56fe1<\/strong> \u7528TRMC\u6d4b\u91cfSWCNT\u6fc0\u5b50\u5206\u79bb\u968f\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u7684\u53d8\u5316\u5173\u7cfb.<\/strong> a, \u805a\u5408\u7269\u5305\u88f9\u7684SWCNTs\u548c\u5bcc\u52d2\u70ef(CF3)n\uff08(C60(CF3)4\u7684\u7f29\u5199\uff09\u7684\u793a\u610f\u56fe. b, \u4ece\u5149\u6fc0\u53d1SWCNT\u65bd\u4e3b\uff08D*\uff09\u5230\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u53d7\u4e3b\uff08A\uff09\u7684\u7535\u5b50\u8f6c\u79fb\u7684\u9a6c\u5e93\u65af\u66f2\u7ebf. \u7535\u5b50\u8f6c\u79fb\u7684\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u76f8\u5bf9\u4e8e\u91cd\u7ec4\u80fd\u7684\u5927\u5c0f\uff1a\u5e38\u6001\u65f6\uff08\u2212\u0394GPET < \u03bb)\uff09\uff0c\u53cd\u8f6c\u533a\uff08\u2212\u0394GPET > \u03bb)\uff09. c, PFO\u5305\u8986\u7684\uff087,5\uff09SWCNTs\u8584\u819c\u548cPRH-A\u5305\u8986\u7684LV SWCNTs\u8584\u819c\u7684\u5438\u6536\u5149\u8c31. LV SWCNT\u8584\u819c\u662f\u4e00\u79cd\u591a\u624b\u6027\u6837\u54c1\uff0c\u800c\uff087,5\uff09\u8584\u819c\u662f\u5355\u624b\u6027\u7684.<\/p>\n

d, \u6fc0\u5b50\u5206\u79bb\u7684\u53cc\u5c42\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u6fc0\u5b50\u5206\u79bb\u53d1\u751f\u5728\u77f3\u82f1\u4e0a\u7ea6\uff5e9nm\u7684SWCNT\u8584\u819c\u548c\u76f4\u63a5\u5728SWCNT\u8584\u819c\u8868\u9762\u6c89\u79ef\u7684\u7ea6\uff5e90nm\u539a\u7684\u5bcc\u52d2\u70ef\u8584\u819c\u4e4b\u95f4\u3002\u6bcf\u4e00\u5c42\u90fd\u662f\u5728\u9ad8\u6e29\u4e0b\u55b7\u5c04\u6c89\u79ef\u5f62\u6210\u7684. e, \u7528TRMC\u63a2\u6d4b\u7684\u6fc0\u5b50\u5f62\u6210\u548c\u5206\u79bb\uff0c\u5176\u4e2d\uff087,5\uff09SWCNTs\u8584\u819c\u548cLV SWCNTs\u8584\u819c\u7684S11\u6fc0\u5b50\u8f6c\u53d8\u5206\u522b\u53d1\u751f\u57281045nm\u548c1665nm. f, \u7528TRMC\u63a2\u6d4b\uff08\u6fc0\u5b50\u5206\u79bb\u540e\uff09\u5438\u6536\u5fae\u6ce2\u63a2\u6d4b\u7684\u81ea\u7531\u7535\u8377\u8f7d\u6d41\u5b50.<\/p>\n

\"nchem.2496-f2\"
\n\u56fe2 SWCNT\u53cc\u5206\u5b50\u819c\uff08\u542bC60\u548cC60(CF3)4\uff09\u548c (7,5) SWCNTs\u548cLV SWCNTs\u8584\u819c\u5728IOFA = 2\u00d71012 cm\u22122 \u65f6\u7684TRMC\u77ac\u65f6\u5149\u7535\u5bfc\u7387.<\/strong> a,b, \u53cc\u5206\u5b50\u819c\u548c\u8584\u819c\u7531\u4e00\u675f4 ns\u7684\u6fc0\u5149\u8109\u51b2\u6fc0\u53d1\u8c03\u8282\u5230SWCNT\u7684S11\u5438\u6536\u5cf0\uff0c\uff08a\uff09\u4e3a\uff087,5\uff09\u7c07\u5355\u624b\u6027\u819c\uff0c\uff08b\uff09\u4e3a\uff0811,9\uff09\u7c07\u591a\u624b\u6027LV\u819c\u3002\u8fd9\u4e9b\u6837\u54c1\u7684\u805a\u5408\u7269\u548c\u5bcc\u52d2\u70ef\u5728\u8fd9\u4e9b\u6ce2\u957f\u8303\u56f4\u90fd\u4e0d\u80fd\u88ab\u6fc0\u53d1\u3002\u6b64\u5916\uff0c\u5728\u5206\u79bb\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684SWCNTs\u65f6\uff0c\u65e0\u8bba\u662fSWCNTs\u4e2d\u8fd8\u662f\u805a\u5408\u7269\uff08PFO\u6216PFH-A\uff09\u4e2d\u7684\u7a7a\u7a74\u548c\u7535\u5b50\u8f6c\u79fb\u90fd\u4f1a\u51cf\u5c11\u80fd\u91cf\uff0c\u8fd9\u662f\u7531\u5728SWCNT\u548c\u805a\u5408\u7269\u4e4b\u95f4\u5f62\u6210\u7684\u2160\u578b\u5f02\u8d28\u7ed3\u51b3\u5b9a\u3002\u6709\u5f3a\u800c\u957f\u65f6\u95f4\u7684\u4fe1\u53f7\u77ac\u65f6\u5149\u7535\u5bfc\u7387\uff0c\u6bd4\u5982 (7,5)\/C60\u548cLV\/C60(CF3)4\u53cc\u5206\u5b50\u819c\uff0c\u5728\u5149\u6fc0\u53d1\u7535\u5b50\u8f6c\u79fb\u65f6\u4eceSWCNT\u5230\u5bcc\u52d2\u70ef\u8868\u73b0\u51fa\u660e\u663e\u7684\u754c\u9762\u6fc0\u5b50\u5206\u79bb\u3002<\/p>\n

\"nchem.2496-f3\"<\/p>\n

\u56fe3 \u4ea7\u7387\u968f\u5438\u6536\u7684\u53d8\u5316\u89c4\u5f8b\u56fe.<\/strong> a,b (a)\u4e3a (7,5)\u53cc\u5206\u5b50\u819c\uff0c(b)\u4e3aLV\u819c. \u5b9e\u7ebf\u662f\u5bf9\u5b9e\u9a8c\u503c\u7684\u4f4e\u901a\u91cf\uff08\uff5e1 \u65e5\u6652\u6761\u4ef6\uff09\u7406\u8bba\u62df\u5408\u03d5\u03bch\uff0c\u8fd9\u5141\u8bb8\u4e86\u4f4e\u901a\u91cf\u7387\u5206\u79bb\uff0c\u514d\u53bb\u4e86\u66f4\u9ad8\u7ea7\u522b\u7684\u91cd\u7ec4\u8fc7\u7a0b\uff0c\u4f8b\u5982\u4fc4\u6b47\u91cd\u7ec4\u52a8\u6001. \u4e3a\u4e86\u907f\u514d\u56fe\u8c31\u6570\u636e\u7684\u62e5\u6324\uff0c\u56fe\u4e2d\u7701\u53bb\u4e86\u8bef\u5dee\u7ebf\uff0c\u76f8\u5bf9\u8bef\u5dee\u5927\u7ea610-16%.<\/p>\n

\"nchem.2496-f4\"
\n\u56fe4 \u542b\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7684 (7,5)\u548cLV\u53cc\u5206\u5b50\u5c42\u7684\u76f8\u5bf9\u4ea7\u7387\u968f\u0394GPET\u7684\u53d8\u5316\u56fe.<\/strong> a, \u7528\u7ea2\u8272\u6b63\u65b9\u5f62\u8868\u793a\u7684 (7,5) SWCNT\u53cc\u5206\u5b50\u5c42. \u8fd9\u4e24\u5c42\u4e2d\u7684\u6bcf\u4e00\u5c42\u90fd\u6765\u81ea\u5b8c\u5168\u76f8\u540c\u7684\u6837\u54c1\u5e76\u91c7\u7528\u76f8\u540c\u7684\u6d4b\u8bd5\u3002b, \u7528\u7ea2\u8272\u83f1\u5f62\u8868\u793a\u7684LV SWCNT\u53cc\u5206\u5b50\u5c42\u7684\u76f8\u5bf9\u4ea7\u7387. \u5b9e\u7ebf\u662f\u5bf9\u53cc\u5206\u5b50\u5c42\u7684\u4ea7\u7387\u91c7\u7528\u516c\u5f0f\u62df\u5408\u7684\u7ed3\u679c. \u5bf9 (7,5)\u548cLV SWCNT\u578b\uff0c\u6a21\u62df\u4e86\u9884\u671f\u81ea\u7531\u7535\u8377\u751f\u6210\u7387\uff08\u03d5B\uff09\u4e0eSWCNT\u548c\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u95f4\u9a71\u52a8\u529b\u7684\u76f8\u5173\u6027. \u5782\u76f4\u7684\u865a\u7ebf\u8868\u660e\u4e86\u4ece\u62df\u5408\u66f2\u7ebf\u4e2d\u63d0\u53d6\u51fa\u7684\u91cd\u7ec4\u80fd. \u4e24\u79cd\u624b\u6027\u5206\u5e03\u7684\u6837\u54c1\u90fd\u89c2\u6d4b\u5230\u4e86\u9a6c\u5e93\u65af\u53cd\u8f6c\u533a. \u8be5\u8bef\u5dee\u7ebf\u662f\u56fe3\u4e2d\u5b9e\u9a8c\u66f2\u7ebf\u4e0e\u8bef\u5dee\u7ebf\u4e4b\u95f4\u7684\u6807\u51c6\u504f\u5dee\u3002<\/p>\n

\u603b\u7ed3<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u7528TRMC\u6d4b\u91cf\u4e86\u591a\u7ec4\u542b\u4e0d\u540c\u624b\u6027\u5206\u5e03\u7684SWCNT\u7684\u5bcc\u52d2\u70ef\u5316\u5408\u7269\u7684\u6fc0\u5b50\u5206\u79bb\u7387\uff0c\u4ee5\u7cfb\u7edf\u7814\u7a76\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u5bf9\u5149\u5f15\u53d1\u7535\u5b50\u8f6c\u79fbPET\u7684\u5f71\u54cd\u3002\u5177\u4f53\u7684\u662f\uff0c\u4ed6\u4eec\u89c2\u5bdf\u5230\u4e86\u4e00\u4e2a\u660e\u663e\u7684\u9a6c\u5e93\u65af\u53cd\u8f6c\u533a\uff0c\u5b9a\u91cf\u5206\u6790\u4e86SWCNT\u65bd\u4e3b\/\u5bcc\u52d2\u70ef\u53d7\u4e3b\u7cfb\u7edf\u7684\u4f4e\u7684\u91cd\u7ec4\u80fd\uff08\uff5e130meV\uff09\u3002\u6d4b\u5f97\u7684\u4f4e\u91cd\u7ec4\u80fd\u8868\u660e\u76f8\u5bf9\u4e8e\u4e00\u4e9b\u5177\u6709\u9ad8\u91cd\u7ec4\u80fd\u7684\u805a\u5408\u7269\/\u5bcc\u52d2\u70ef\u7cfb\u7edf\u6765\u8bf4\uff0c\u8be5\u7cfb\u7edf\u53ef\u80fd\u4ee5\u76f8\u5bf9\u4f4e\u7684\u8fd0\u8f7d\u80fd\u91cf\u635f\u8017\u6765\u4f7f\u7535\u8377\u5206\u79bb\u3002\u56e0\u6b64\uff0cSWCNT\u534a\u5bfc\u4f53\u7531\u4e8e\u5176\u56fa\u6709\u7684\u4f4e\u91cd\u7ec4\u80fd\u4ee5\u53ca\u53ef\u8c03\u63a7\u6027\u3001\u8fc1\u79fb\u7387\u3001\u5f3a\u5438\u6536\u7387\u7b49\u7279\u70b9\u800c\u53ef\u80fd\u66f4\u9002\u5408\u4e8ePV\u5e94\u7528\u3002<\/p>\n

\u6700\u540e\uff0c\u8be5\u7814\u7a76\u7ed3\u679c\u8868\u660e\u9009\u5b9a\u7684SWCNT\u65bd\u4e3b\u6750\u6599\uff08\u65bd\u4e3b\u76f4\u5f84\/\u5e26\u9699\u5206\u5e03\uff09\u5f97\u76ca\u4e8e\u80fd\u91cf\u53ef\u8c03\u7684\u53d7\u4e3b\uff0c\u4e14\u901a\u5e38\u91c7\u7528\u7684C60\u53d7\u4e3b\u4e5f\u8bb8\u5e76\u4e0d\u80fd\u666e\u904d\u9002\u7528\u4e8e\u6240\u6709\u7684\u534a\u5bfc\u4f53SWCNTs\u3002\u8fd9\u9879\u5de5\u4f5c\u5bf9\u4e8e\u672a\u6765\u4f7f\u7528\u53ef\u53d8\u5e26\u9699\u7684SWCNT\u5438\u6536\u5242\u7684\u5f02\u8d28\u7ed3\u592a\u9633\u80fd\u7535\u6c60\u548c\u8fd1\u7ea2\u5916\u63a2\u6d4b\u5668\u7684\u8bbe\u8ba1\u5177\u6709\u5e7f\u6cdb\u7684\u610f\u4e49\u3002<\/p>\n

\u8be5\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728Nature Chemistry<\/strong>\u4e0a\uff0c\u6587\u732e\u94fe\u63a5\uff1aTuning the driving force for exciton dissociation in single-walled carbon nanotube heterojunctions<\/a>\uff08Nature Chemistry ,\u00a02016,\u00a0doi:10.1038\/nchem.2496\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4 Sea\u00a0\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\uff0c\u4e00\u8d77\u8fdb\u884c\u6750\u6599\u9876\u520a\u5b66\u672f\u52a8\u6001\u7684\u8ddf\u8e2a\u548c\u62a5\u9053\u4ee5\u53caSCI\u76f8\u5173\u77e5\u8bc6\u79d1\u666e\u7b49\u3002\u52a0\u5165\u65b9\u5f0f\uff1a\uff081\uff09\u52a0\u5165\u6750\u6599\u4eba\u6587\u732e\u68c0\u7d22\u7fa4\uff08410109144\uff09\uff0c\u79c1\u4fe1\u7ba1\u7406\u5458\u201c\u6210\u90fd-\u5c0f\u5c0f\uff08QQ:763044722\uff09\u201d\u62a5\u540d\uff1b\uff082\uff09\u70b9\u6b64\u5904\u62a5\u540d<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n","protected":false},"excerpt":{"rendered":"

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