{"id":142076,"date":"2018-06-22T14:00:08","date_gmt":"2018-06-22T06:00:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=142076"},"modified":"2018-06-22T13:13:05","modified_gmt":"2018-06-22T05:13:05","slug":"angew-chem-int-ed-%e7%94%a8%e4%ba%8e%e7%94%b5%e5%8c%96%e5%ad%a6%e7%94%b5%e6%b1%a0%e7%9a%84%e9%9d%9e%e5%85%b1%e8%bd%ad%e4%ba%8c%e7%be%a7%e9%85%b8%e9%98%b3%e6%9e%81%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=142076","title":{"rendered":"Angew. Chem. Int. Ed.: \u7528\u4e8e\u7535\u5316\u5b66\u7535\u6c60\u7684\u975e\u5171\u8f6d\u4e8c\u7fa7\u9178\u9633\u6781\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u53ef\u5145\u7535\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIB\uff09\u5728\u5927\u89c4\u6a21\u7535\u5316\u5b66\u80fd\u91cf\u50a8\u5b58\u9886\u57df\u5177\u6709\u76f8\u5f53\u5927\u7684\u5173\u6ce8\u5ea6\uff0c\u4e14\u8bb8\u591a\u6709\u673a\u5171\u8f6d\u5316\u5408\u7269\u5df2\u88ab\u8bc1\u660e\u5176\u5728Na\u79bb\u5b50\u5b58\u50a8\u4e2d\u5177\u6709\u7535\u5316\u5b66\u6d3b\u6027\u3002\u7136\u800c\uff0c\u7531\u4e8e\u6709\u9650\u7684\u6d3b\u6027\u6c27\u5316\u8fd8\u539f\u57fa\u56e2\u548c\u975e\u5b9a\u91cf\u7684\u79bb\u57df\u4f5c\u7528\uff0c\u8fd9\u4e9b\u6709\u673a\u5171\u8f6d\u6750\u6599\u901a\u5e38\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u6bd4\u5bb9\u91cf\u548c\u4e0d\u53d7\u63a7\u5236\u7684\u7535\u538b\u3002\u82e5\u5c06\u5171\u8f6d\u5316\u5408\u7269\u6269\u5c55\u5230\u975e\u5171\u8f6d\u5316\u5408\u7269\uff0c\u65e2\u53ef\u62d3\u5c55\u6709\u673a\u7535\u6781\u6750\u6599\u79cd\u7c7b\uff0c\u53c8\u53ef\u4ee5\u63d0\u9ad8\u6709\u673a\u7535\u6781\u6750\u6599\u6d3b\u6027\u3001\u4e30\u5bcc\u94a0\u79bb\u5b50\u5b58\u50a8\u673a\u5236\uff0c\u7136\u800c\u975e\u5171\u8f6d\u7535\u6781\u6750\u6599\u7684\u7814\u7a76\u8fd8\u662f\u7a7a\u767d\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u00a0\u8fd1\u65e5\uff0c<\/strong>\u4e2d\u79d1\u9662\u4e0a\u6d77\u7845\u9178\u76d0\u7814\u7a76\u6240\u5218\u5efa\u519b\u3001\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u738b\u5f00\u5b66<\/strong>\u7b49\u4eba\u5408\u4f5c\u62a5\u9053\u4e861,4-\u73af\u5df1\u70f7\u4e8c\u7fa7\u9178\uff08C8<\/sub>H12<\/sub>O4<\/sub>\uff0cCHDA\uff09\uff0c\u5b83\u662f\u7fa7\u9178\u4e0e\u975e\u5171\u8f6d\u73af\uff08-C6<\/sub>H10<\/sub>-\uff09\u8fde\u63a5\u7684\u6709\u673a\u975e\u5171\u8f6d\u7fa7\u9178\u7c7b\u5316\u5408\u7269\uff0c\u53ef\u4ee5\u4e0e\u4e24\u4e2aNa\u79bb\u5b50\u53d1\u751f\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u4ea7\u751f\u4e86\u9ad8\u6bd4\u5bb9\u91cf284 mA h\/g\uff08100\u6b21\u5faa\u73af\u540e249 mA h\/g\uff09\u548c\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\u3002\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u8868\u660e\uff0c\u6c22\u8f6c\u79fb\u8bf1\u5bfc\u7684\u4ece\u03c0*\u53cd\u952e\u5230\u03c3\u952e\u7684\u8f68\u9053\u8f6c\u6362\u80fd\u591f\u7a33\u5b9a\u5d4c\u5165\u7684\u4e24\u4e2a\u7535\u5b50\uff0c\u4e14\u5177\u6709\u672a\u914d\u5bf9\u7535\u5b50\u7684\u6d3b\u6027\u4e2d\u95f4\u4f53\u53ef\u4ee5\u88ab\u5c40\u57df\u7684\u03c3\u952e\u548c\u7a7a\u95f4\u4f4d\u963b\u6240\u7a33\u5b9a\u3002CHDA\u4f5c\u4e3a\u9633\u6781\u6750\u6599\u7684\u4e00\u4e2a\u663e\u8457\u4f18\u70b9\u662f\u5177\u6709\u826f\u597d\u7684\u53ef\u9006\u6027\u548c\u76f8\u5bf9\u6052\u5b9a\u7684\u7535\u538b\uff0c\u56e0\u800c\u4ed6\u4eec\u9884\u8ba1\u5c06\u4f1a\u6709\u5927\u91cf\u7684\u6709\u673a\u975e\u5171\u8f6d\u5316\u5408\u7269\u53ef\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u6709\u524d\u666f\u7684\u9633\u6781\u6750\u6599\uff0c\u540c\u65f6\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5f00\u53d1\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u65b0\u578b\u6709\u673a\u9633\u6781\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u7ebf\u7d22\u3002\u8be5\u7814\u7a76\u53d1\u8868\u4e8eAngewandte Chemie International Edition<\/strong>\uff0c\u9898\u4e3a\u201cNon-Conjugated Dicarboxylate Anode Materials for Electrochemical Cells<\/strong>\u201d<\/strong>\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u9a6c\u8d85\uff0c\u4e0a\u6d77\u7845\u9178\u76d0\u7814\u7a76\u6240\u548c\u592a\u539f\u7406\u5de5\u5927\u5b66\u8054\u5408\u57f9\u517b\u751f\u8d75\u6653\u7433\u662f\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\u00a0<\/strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. CHDA<\/strong>\u7535\u5316\u5b66\u6d3b\u6027\u7684\u5b9e\u9a8c\u8bc4\u4f30<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u57280.5mV\/s\u7684\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n

\uff08b\uff09\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u8fc7\u7a0b<\/p>\n

\uff08c\uff09\u57280.1A\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n

\uff08d\uff09\u5728\u4e0d\u540c\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\u56fe<\/strong>2. <\/strong>\u5145\u653e\u7535\u8fc7\u7a0b\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u653e\u7535\u8fc7\u7a0b\u4e2d\u7ed3\u6784\u7684\u6f14\u53d8\uff0c\u6cbf(100)\u65b9\u5411\u7684CHDA\uff0cNaCHDA\u548cNa2<\/sub>CHDA\u5f1b\u8c6b\u540e\u7684\u6676\u4f53\u7ed3\u6784<\/p>\n

\uff08b\uff09\u653e\u7535\u8fc7\u7a0b\u4e2d\u952e\u957f\u7684\u53d8\u5316\uff0c\u8868\u660e\u6c22\u8f6c\u79fb\u8fc7\u7a0b<\/p>\n

\uff08c\uff09\u5bf9CHDA\u7684\u78b3\u548c\u6c27\u539f\u5b50\u8fdb\u884cBader\u7535\u8377\u5206\u6790\uff0c\u8868\u5f81\u7535\u5316\u5b66\u6d3b\u6027\u4f4d\u70b9<\/p>\n

\uff08d\uff09Nax<\/sub>CHDA (x = 0,1,2)\u4e2d-C(OH)2<\/sub>\u57fa\u56e2\u4e2d\u78b3\u539f\u5b50\u548c\u6c27\u539f\u5b50\u7684\u6001\u5bc6\u5ea6\u6295\u5f71\uff08pDOS\uff09<\/p>\n

\uff08e\uff09CHDA\u7684VBM\u6ce2\u51fd\u6570\u5206\u5e03\u548cNaCHD\u4e0eNa2<\/sub>CHDA\u7684CBM\u6ce2\u51fd\u6570\u5206\u5e03<\/p>\n

\uff08f\uff09\u6c22\u8f6c\u79fb\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u56fe<\/strong>3.<\/strong> \u6c22\u8f6c\u79fb\u673a\u7406\u7684\u5b9e\u9a8c\u8bba\u8bc1<\/strong><\/p>\n

\"\"<\/p>\n

CHDA\u7535\u6781\u3001\u653e\u7535\u81f30.01 V\u3001\u518d\u5145\u7535\u81f33.0 V\u7684\uff08a\uff091 <\/sup>H NMR\u8c31\u548c\uff08b\uff09FTIR\u5149\u8c31\u3002<\/p>\n

\u00a0<\/strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u00a0<\/strong>\u8be5\u9879\u7814\u7a76\u63d0\u51fa\u975e\u5171\u8f6d\u7fa7\u9178\u65cf\u5177\u6709\u66f4\u591a\u7684\u8c03\u8282\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u5bb9\u91cf\u7684\u9009\u62e9\uff0c\u8fd9\u5bf9\u4e8e\u7ecf\u5178\u5171\u8f6d\u7fa7\u9178\u5316\u5408\u7269\u4f5c\u4e3a\u552f\u4e00\u7684\u9633\u6781\u6750\u6599\u7684\u4f9d\u8d56\u6027\u662f\u4e00\u4e2a\u91cd\u5927\u7684\u7a81\u7834\u3002\u4ee51,4-\u73af\u5df1\u70f7\u4e8c\u7fa7\u9178\uff08CHDA\uff0cC8<\/sub>H12<\/sub>O4<\/sub>\uff09\u4e3a\u975e\u5171\u8f6d\u7fa7\u9178\u7684\u4e00\u4e2a\u5178\u4f8b\uff0c\u8be5\u9879\u5de5\u4f5c\u7684\u8ba1\u7b97\u8868\u660e\uff0c\u7fa7\u9178\u5b98\u80fd\u56e2\u5728\u50a8\u94a0\u8fc7\u7a0b\u4e2d\u7684\u7535\u5316\u5b66\u6d3b\u6027\u88ab\u4e24\u4e2a\u76f8\u90bb\u7fa7\u9178\u57fa\u56e2\u4e4b\u95f4\u7684\u6c22\u8f6c\u79fb\u6240\u6fc0\u53d1\u3002\u7535\u5b50\u7a33\u5b9a\u5316\u662f\u901a\u8fc7\u6c22\u952e\u8f6c\u79fb\u4f5c\u4e3a\u4ecb\u8d28\uff0c\u7531\u03c0*\u53cd\u952e\u5230\u03c3\u952e\u7684\u8f68\u9053\u6539\u53d8\u5b9e\u73b0\u7684\uff0c\u5176\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u6291\u5236\u4e86\u53cd\u5e94\u4e2d\u95f4\u4f53\u5e76\u63d0\u9ad8\u4e86\u7535\u5316\u5b66\u53ef\u9006\u6027\u3002\u7814\u7a76\u8005\u5728\u7ed3\u6784\u4e0a\u5bf9\u94a0\u5316\u3001\u8131\u94a0\u548c\u7535\u5316\u5b66\u6027\u80fd\u7684\u63cf\u8ff0\u4e0e\u8ba1\u7b97\u9884\u6d4b\u5b8c\u5168\u4e00\u81f4\uff0c\u4ed6\u4eec\u901a\u8fc7\u6c22\u8f6c\u79fb\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u5236\u5f00\u8f9f\u4e86\u5bfb\u627e\u9ad8\u5bb9\u91cf\u548c\u9ad8\u53ef\u9006\u9633\u6781\u7684\u65b0\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Non\u2010Conjugated Dicarboxylate Anode Materials for Electrochemical Cells<\/a> (Angewandte Chemie International Edition 2018, DOI: 10.1002\/anie.201801654)<\/p>\n

\u3010\u76f8\u5173\u5de5\u4f5c\u3011<\/strong><\/p>\n

\u9664\u6b64\u4ee5\u5916\uff0c\u8ba1\u7b97\u6750\u6599\u56e2\u961f\u4e5f\u5f00\u5c55\u4ee5\u73af\u8f9b\u56db\u70ef\u4e3a\u57fa\u7684\u9ad8\u7535\u538b\u9ad8\u6bd4\u5bb9\u91cf\u7684\u7535\u6781\u6750\u6599\u8bbe\u8ba1\uff0c\u8bbe\u8ba1\u7cfb\u5217C4<\/sub>\/C8<\/sub>\u4e0d\u540c\u6bd4\u7387\u7a20\u5408\u7684\u7535\u6781\u6750\u6599\uff0c\u9ad8\u7535\u538b\u4e0e\u9ad8\u6bd4\u5bb9\u91cf\u6765\u81ea\u4e8e\u5355\u53cc\u952e\u91cd\u6784\u548c\u82b3\u9999\u5316\u673a\u5236\u7684\u53cc\u91cd\u53e0\u52a0\uff0c\u8fdb\u4e00\u6b65\u9884\u6d4bC4<\/sub>\u73af\u542b\u91cf\u4e0d\u4ec5\u51b3\u5b9a\u4e86\u6709\u673a\u5206\u5b50\u7ed3\u6784\u7684\u5c3a\u5bf8\u548c\u5f62\u6001\uff0c\u800c\u4e14\u5728\u653e\u7535\u7535\u538b\u4e2d\u8d77\u7740\u51b3\u5b9a\u6027\u7684\u4f5c\u7528\uff0c\u8ba1\u7b97\u7ed3\u679c\u5f97\u5230\u5b9e\u9a8c\u9a8c\u8bc1\uff0c\u8fd9\u4e3a\u8bbe\u8ba1\u9ad8\u7535\u538b\u6709\u673a\u7535\u6781\u6750\u6599\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u7406\u8bba\u57fa\u7840\u3002\u751f\u7269\u6709\u673a\u5206\u5b50\u5c3f\u9178\u662f\u4e00\u79cd\u5177\u6709\u4e09\u4e2a\u7fb0\u57fa\u7684\u7b80\u5355\u6709\u673a\u5316\u5408\u7269\uff0c\u7406\u8bba\u8ba1\u7b97\u548c\u5b9e\u9a8c\u8868\u5f81\u5747\u663e\u793a\u8d1f\u6781\u6750\u6599\u5c3f\u9178\u5728\u88ab\u63d2\u5165\/\u8131\u5d4cNa+<\/sup>\u65f6\u5177\u6709\u7535\u5316\u5b66\u6d3b\u6027\u3002\u8ba1\u7b97\u53d1\u73b0\u5c3f\u9178\u5206\u5b50\u653e\u7535\u65f6\u51fa\u73b0\u78b3\u8d1f\u79bb\u5b50\uff0c\u4f46C=C(NH-)2\u4e2d\u5f3a\u7535\u8d1f\u6027N\u5143\u7d20p\u8f68\u9053\u4e0e\u78b3\u8d1f\u79bb\u5b50\u7684\u5b64\u5bf9\u7535\u5b50p\u8f68\u9053\u7684\u6742\u5316\u7a33\u5b9a\u4e86\u78b3\u8d1f\u79bb\u5b50\uff0c\u5b9e\u73b0\u4e86\u5c3f\u9178\u7684\u50a8\u94a0\uff0c\u4e14\u5b9e\u9a8c\u6d4b\u5f97\u590d\u5408\u6750\u6599UA@CNT\u5728200 mA\/g\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af200\u5708\u4ecd\u7136\u53ef\u4ee5\u4fdd\u6301163 mA h\/g\u7684\u5bb9\u91cf\u3002\u7814\u7a76\u6210\u679c\u5206\u522b\u5728ACS Appl. Mater. Interface<\/em>\uff0c2018<\/strong>, 10<\/em>\uff0c2496\u20132503\u4e0eACS Appl. Mater. Interface,<\/em> 2017<\/strong>, 9<\/em>, 33934\u53d1\u8868\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u8ba1\u7b97\u6750\u6599\u7ec4Annay\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>cailiaokefu<\/strong>\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

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