{"id":141691,"date":"2018-06-09T06:30:36","date_gmt":"2018-06-08T22:30:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=141691"},"modified":"2018-06-08T08:49:15","modified_gmt":"2018-06-08T00:49:15","slug":"%e5%ae%9e%e9%aa%8c%e7%90%86%e8%ae%ba%e8%a7%a3%e9%87%8a%e7%9a%84%e5%a5%bd%e5%b8%ae%e6%89%8b-%e9%94%82%e7%94%b5%e9%a2%86%e5%9f%9f%e5%b8%b8%e7%94%a8%e6%a8%a1%e6%8b%9f%e8%ae%a1%e7%ae%97%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=141691","title":{"rendered":"\u5b9e\u9a8c\u7406\u8bba\u89e3\u91ca\u7684\u597d\u5e2e\u624b \u9502\u7535\u9886\u57df\u5e38\u7528\u6a21\u62df\u8ba1\u7b97\u65b9\u6cd5\u5927\u8d77\u5e95\uff01"},"content":{"rendered":"
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<\/em>\u662f\u7535\u6c60\u53cd\u5e94\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\uff0c\u5047\u8bbe\u7531\u7535\u6c60\u5d4c\u5165\u53cd\u5e94\u5f15\u8d77\u7684\u4f53\u79ef\u548c\u71b5\u7684\u53d8\u5316\u53ef\u5ffd\u7565\u4e0d\u8ba1\uff0c\u5219<\/p>\n \u0394<\/strong>G<\/em><\/strong>\u2248\u0394<\/strong>E <\/em><\/strong><\/p>\n \u6545\uff1aV<\/em><\/strong>AVE=<\/strong>\u0394<\/strong>E\/F <\/em><\/strong><\/p>\n \u5bf9\u4e8e\u6b63\u6781\u4e3aLiA\uff0c\u8d1f\u6781\u4e3aB \u7684\u7535\u6c60\u4f53\u7cfb\uff0c\u5047\u8bbe\u5145\u7535\u540e\u6709x <\/em>\u4e2a\u9502\u4eceLiA \u4e2d\u8131\u51fa\u5e76\u5d4c\u5165\u5230B \u4e2d\uff08\u6b63\u6781\u5145\u7535\u8fc7\u7a0b\uff09\uff0c\u5176\u53cd\u5e94\u5f0f\u4e3a\uff1a<\/p>\n LiA+B<\/strong>\u2192<\/strong> Li1<\/sub><\/strong>\u2212<\/sub><\/strong>x<\/sub><\/em><\/strong>A+Lix<\/sub><\/em>B <\/strong><\/p>\n 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<\/strong>\u8ba1\u7b97\u5f97\u5230\u5404\u79cd\u9502\u79bb\u5b50<\/strong><\/p>\n 2.<\/strong>\u5206\u5b50\u52a8\u529b\u5b66\u65b9\u6cd5<\/strong><\/p>\n \u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u80fd\u591f\u5f97\u5230\u6750\u6599\u5904\u4e8e\u96f6\u6e29\u57fa\u6001\u65f6\u7684\u6027\u8d28\uff0c\u5728\u6709\u9650\u6e29\u5ea6\u4e0b\u6750\u6599\u4e2d\u539f\u5b50\u3001\u79bb\u5b50\u7684\u8f93\u8fd0\u53ef\u901a\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u8fdb\u884c\u7814\u7a76\u3002\u5206\u5b50\u52a8\u529b\u5b66\u8ba1\u7b97\u4f5c\u4e3a\u91c7\u7528\u7ecf\u9a8c\u52bf\u51fd\u6570\u7684\u539f\u5b50\u7ea7\u6a21\u62df\u624b\u6bb5\uff0c\u4e0e\u7b2c\u4e00\u6027\u539f\u7406\u65b9\u6cd5\u76f8\u6bd4\uff0c\u53ef\u8fdb\u884c\u66f4\u5927\u89c4\u6a21\u7684\u6a21\u62df\uff0c\u80fd\u8f83\u597d\u5730\u5c55\u73b0\u9502\u79bb\u5b50\u52a8\u6001\u6269\u6563\u8fc7\u7a0b\u5e76\u8fdb\u884c\u5206\u6790\u3002<\/p>\n \u56fe<\/strong>2<\/strong>\uff1a\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n 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\u7684\u81ea\u6269\u6563\u8fc7\u7a0b\uff0c\u53d1\u73b0\u8be5\u6750\u6599\u4e2dLi+\u7684\u8fc1\u79fb\u5e76\u4e0d\u662f\u8fde\u7eed\u53d1\u751f\u7684\uff0c\u800c\u662f\u901a\u8fc7\u76f8\u90bb\u6676\u683c\u4f4d\u7f6e\u4e4b\u95f4\u9010\u6e10\u63a8\u8fdb\u7684\u8dc3\u8fc1\u53d1\u751f\u7684\u30022014\u5e74\u4e0a\u6d77\u5927\u5b66\u5f20\u4fca\u4e7e\u7b49\u4eba\u91c7\u7528\u5206\u5b50\u52a8\u529b\u5b66\u65b9\u6cd5\uff0c\u6a21\u62df\u5145\u7535\u8fc7\u7a0b\u4e2d\u9502\u79bb\u5b50\u5728\u77f3\u58a8\u5c42\u95f4\u7684\u6269\u6563\u884c\u4e3a\u3002\u7814\u7a76\u4e86300 K\u6e29\u5ea6\u4e0b\u77f3\u58a8\u9633\u6781\u6750\u6599\u7684\u9502\u79bb\u5b50\u6269\u6563\u6027\u8d28\uff0c\u5b9e\u9a8c\u7ed3\u679c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u53d8\u5f62\u7684\u8fde\u7eed\u5c3a\u5ea6\u6a21\u578b\u7814\u7a76\u63d0\u4f9b\u4e86\u57fa\u7840\u6570\u636e\u3002<\/p>\n \u56fe<\/strong>3<\/strong>\uff1a\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u5f97\u5230\uff08<\/strong>a<\/strong>\uff09<\/strong>Li <\/strong>\u79bb\u5b50\u5728<\/strong>LiFePO4 <\/sub><\/strong>\u4e2d\u7684\u8fd0\u52a8\u8f68\u8ff9\uff1b\uff08<\/strong>b<\/strong>\uff09<\/strong>Li <\/strong>\u79bb\u5b50\u901a\u8fc7<\/strong>Li\/Fe <\/strong>\u4e92\u5360\u4f4d\u7f3a\u9677\u5728\u901a\u9053\u4e4b\u95f4\u7684\u8fc1\u79fb 3.\u76f8\u573a\u6a21\u578b<\/strong><\/p>\n \u76f8\u573a\u6cd5(Phase field method) \u662f\u4ee5Ginzburg-Landau\u7406\u8bba\u4e3a\u7269\u7406\u57fa\u7840\uff0c\u901a\u8fc7\u5fae\u5206\u65b9\u7a0b\u6765\u4f53\u73b0\u5177\u6709\u7279\u5b9a\u7269\u7406\u673a\u5236\u7684\u6269\u6563\u3001\u6709\u5e8f\u5316\u52bf\u548c\u70ed\u529b\u5b66\u9a71\u52a8\u7684\u7efc\u5408\u4f5c\u7528\uff0c\u901a\u8fc7\u8ba1\u7b97\u673a\u7f16\u7a0b\u6c42\u89e3\u4e0a\u8ff0\u65b9\u7a0b\uff0c\u4ece\u800c\u83b7\u53d6\u7814\u7a76\u4f53\u7cfb\u5728\u65f6\u95f4\u548c\u7a7a\u95f4\u4e0a\u7684\u77ac\u65f6\u72b6\u6001\u3002\u76f8\u573a\u6a21\u578b\u662f\u4ee5\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u57fa\u672c\u539f\u7406\u4e3a\u57fa\u7840\u800c\u5efa\u7acb\u8d77\u6765\u7684\u4e00\u4e2a\u7528\u4e8e\u9884\u6d4b\u56fa\u6001\u76f8\u53d8\u8fc7\u7a0b\u4e2d\u5fae\u7ed3\u6784\u6f14\u5316\u7684\u6709\u529b\u5de5\u5177\u3002<\/p>\n \u901a\u8fc7\u76f8\u573a\u6a21\u578b\u80fd\u591f\u6a21\u62df\u6676\u4f53\u751f\u957f\u3001\u56fa\u6001\u76f8\u53d8\u3001\u88c2\u7eb9\u6f14\u5316\u3001\u8584\u819c\u76f8\u53d8\u3001\u79bb\u5b50\u5728\u754c\u9762\u5904\u8fc1\u79fb\u7b49\uff0c\u4f46\u662f\u6a21\u62df\u7ed3\u679c\u7f3a\u5c11\u548c\u65f6\u95f4\u89c2\u6d4b\u91cf\u7684\u5b9a\u91cf\u6bd4\u8f83\uff0c\u8ba1\u7b97\u65f6\u754c\u9762\u539a\u5ea6\u7684\u8bbe\u5b9a\u901a\u5e38\u5927\u4e8e\u5b9e\u9645\u60c5\u51b5\uff0c\u5bfc\u81f4\u7ec6\u8282\u7684\u7f3a\u5931\u3002\u8377\u5170\u4ee3\u5c14\u592b\u7279\u7406\u5de5\u5927\u5b66\u7684Marnix Wagemaker\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u57282018\u5e74Adv.Funct.Mater.\u671f\u520a\u4e0a\u53d1\u8868\u6587\u7ae0\u63d0\u51fa\u4e86\u9502\u79bb\u5b50\u63d2\u5165\u5230\u5c16\u6676\u77f3Li4<\/sub>Ti5<\/sub>O12<\/sub>\u4e2d\u7684\u70ed\u529b\u5b66\u76f8\u573a\u6a21\u578b\uff0c\u6574\u5408\u4e86DFT\u6570\u636e\uff0c\u80fd\u591f\u5bf9\u5305\u542b\u76f8\u5206\u79bb\u9897\u7c92\u7684\u5b8c\u6574\u70ed\u529b\u5b66\u884c\u4e3a\u8fdb\u884c\u63cf\u8ff0\uff0c\u4e3a\u8bbe\u8ba1\u6700\u4f73\u6027\u80fd\u7684Li4<\/sub>Ti5<\/sub>O12<\/sub>\u7535\u6781\u63d0\u4f9b\u4e86\u5177\u4f53\u7684\u65b9\u5411\u3002<\/p>\n 4.<\/strong>\u6709\u9650\u5143\u6cd5<\/strong><\/p>\n \u6709\u9650\u5143\u65b9\u6cd5\uff08finite element method\uff09\u662f\u4e00\u79cd\u6c42\u89e3\u504f\u5fae\u5206\u65b9\u7a0b\u8fb9\u503c\u95ee\u9898\u8fd1\u4f3c\u89e3\u7684\u6570\u503c\u6280\u672f\u3002\u6709\u9650\u5143\u65b9\u6cd5\u6a21\u62df\u7684\u6d41\u7a0b\u4e3a\uff1a1.\u5bf9\u6c42\u89e3\u95ee\u9898\u533a\u57df\u79bb\u6563\u53162.\u786e\u5b9a\u8fd9\u4e2a\u533a\u57df\u7684\u72b6\u6001\u53d8\u91cf\u548c\u53d8\u91cf\u7684\u63a7\u5236\u65b9\u6cd5\uff0c\u5373\u53d8\u91cf\u65f6\u95f4\u7a7a\u95f4\u7684\u6f14\u5316\u65b9\u7a0b\uff1b3.\u5bf9\u5355\u4e2a\u5355\u5143\u8fdb\u884c\u63a8\u5bfc\uff0c\u5bf9\u7531\u5355\u5143\u7ec4\u88c5\u8d77\u6765\u7684\u603b\u4f53\u8fdb\u884c\u6c42\u89e3\uff0c\u6700\u540e\u8054\u7acb\u65b9\u7a0b\u7ec4\u6c42\u89e3\u5e76\u83b7\u5f97\u7ed3\u679c\u3002<\/p>\n \u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3\u7535\u52a8\u8f66\u7528\u7684\u5927\u5bb9\u91cf\u548c\u5927\u529f\u7387\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8fc7\u70ed\u884c\u4e3a\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66f9\u79c9\u521a\u7b49\u5728\u8003\u8651\u5185\u963b\u3001\u5bf9\u6d41\u3001\u5916\u90e8\u8017\u6563\u7b49\u6761\u4ef6\u4e0b\u5229\u7528\u6709\u9650\u5143\u65b9\u6cd5\u6a21\u62df\u4e86\u7535\u6c60\u5de5\u4f5c\u65f6\u5185\u90e8\u6e29\u5ea6\u7684\u7a7a\u95f4\u5206\u5e03\uff0c155 \u2103\u70ed\u7089\u4e2d\u6d4b\u8bd5\u7535\u6c60\u7684\u6e29\u5ea6\u5206\u5e03\u6a21\u62df\u7ed3\u679c\u548cVLP50\/62\/100S-Fe\uff083.2 V\/55 A\u00b7h\uff09LiFePO4<\/sub>\/\u77f3\u58a8\u7684\u7535\u6c60\u590d\u5408\u3002<\/p>\n<\/a><\/p>\n
<\/a><\/p>\n
<\/a><\/p>\n
\n <\/strong><\/p>\n<\/a>\u56fe4\uff1aLTO\u5355\u7c92\u5b50\u6a21\u62df\uff0c\u591a\u5b54\u7535\u6781\u6a21\u62df\u4e0b\u7684\u7535\u6c60\u5bb9\u91cf\u53ca\u6807\u79f0\u653e\u7535\u5bb9\u91cf\u4e0e\u7535\u6781\u539a\u5ea6\u7684\u5173\u7cfb<\/strong><\/p>\n