{"id":140851,"date":"2018-06-01T14:00:54","date_gmt":"2018-06-01T06:00:54","guid":{"rendered":"\/\/m.iemloyee.com\/?p=140851"},"modified":"2018-05-31T17:33:57","modified_gmt":"2018-05-31T09:33:57","slug":"%e7%a6%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%e5%90%b8%e5%85%89%e8%8c%83%e5%9b%b4%e5%8f%af%e8%be%be%e7%ba%a2%e5%85%89%e5%8c%ba%e7%9a%84%e7%a2%b3%e6%b0%ae%e7%bb%93%e6%9e%84%e5%85%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=140851","title":{"rendered":"\u798f\u5dde\u5927\u5b66Angew. Chem. Int. Ed.: \u5438\u5149\u8303\u56f4\u53ef\u8fbe\u7ea2\u5149\u533a\u7684\u78b3\u6c2e\u7ed3\u6784\u5149\u50ac\u5316\u5242\u7528\u4e8e\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u53cd\u5e94"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u592a\u9633\u80fd\u662f\u53ef\u518d\u751f\u3001\u53ef\u6301\u7eed\u7684\u6e05\u6d01\u80fd\u6e90\uff0c\u4e3a\u4e86\u89e3\u51b3\u5168\u7403\u80fd\u6e90\u4e0e\u73af\u5883\u95ee\u9898\uff0c\u5229\u7528\u592a\u9633\u80fd\u8fdb\u884c\u5149\u50ac\u5316\u53cd\u5e94\u5c06\u53cd\u5e94\u5e95\u7269\u8f6c\u5316\u4e3a\u80fd\u6e90\u4ea7\u54c1\u5df2\u7ecf\u5f15\u8d77\u4e86\u79d1\u7814\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u800c\u5bfb\u627e\u4e00\u7cfb\u5217\u5ec9\u4ef7\u3001\u7a33\u5b9a\u548c\u9ad8\u6548\u7684\u5149\u50ac\u5316\u5242\u6210\u4e3a\u8be5\u7814\u7a76\u7684\u5173\u952e\u3002\u78b3\u6c2e\u805a\u5408\u7ed3\u6784\u5149\u50ac\u5316\u5242\u7531\u4e8e\u5236\u5907\u65b9\u6cd5\u7b80\u5355\u4ee5\u53ca\u62e5\u6709\u5408\u9002\u7684\u5e26\u9699\uff0c\u56e0\u6b64\u8fd1\u5e74\u6765\u88ab\u5927\u91cf\u7814\u7a76\uff08\u5c24\u5176\u662f\u6c2e\u5316\u78b3\u5149\u50ac\u5316\u5242\uff09\u3002\u5728\u592a\u9633\u5149\u8c31\u4e2d\uff0c\u53ef\u89c1\u5149\u548c\u8fd1\u7ea2\u5916\u5149\u5206\u522b\u5360\u5168\u5149\u8c31\u768445%\u548c50%\u3002\u4e3a\u4e86\u66f4\u5145\u5206\u5730\u5229\u7528\u592a\u9633\u5149\uff0c\u6269\u5927\u50ac\u5316\u5242\u7684\u5438\u5149\u8303\u56f4\u6210\u4e3a\u5f53\u524d\u7814\u7a76\u70ed\u70b9\u4e4b\u4e00\uff0c\u76ee\u524d\u4e3b\u8981\u7684\u65b9\u6cd5\u5305\u62ec\u8868\u9762\u7b49\u79bb\u6fc0\u5143\u4fee\u9970\u4ee5\u53ca\u63ba\u6742\u6539\u6027\u534a\u5bfc\u4f53\u7b49\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u6c2e\u5316\u78b3\u805a\u5408\u7269\u5149\u50ac\u5316\u5242\u53ea\u80fd\u5438\u6536\u5230\u53ef\u89c1\u5149\u533a\uff08460 nm\u5de6\u53f3\uff09\uff0c\u8fdc\u8fdc\u65e0\u6cd5\u6ee1\u8db3\u5bf9\u592a\u9633\u5149\u5145\u5206\u5229\u7528\u7684\u8981\u6c42\u3002\u5f53\u524d\uff0c\u4ec5\u6709\u51e0\u7bc7\u6587\u7ae0\u62a5\u9053\u4e86\u53ef\u4ee5\u5c06\u6c2e\u5316\u78b3\u805a\u5408\u7269\u50ac\u5316\u5242\u7684\u5438\u5149\u8303\u56f4\u6269\u5927\u5230\u63a5\u8fd1\u7ea2\u5916\u533a\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66\u80fd\u6e90\u4e0e\u73af\u5883\u5149\u50ac\u5316\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4<\/strong>\u5728Angewandte Chemie International Edition<\/strong>\u4e0a\u53d1\u8868\u6700\u65b0\u7814\u7a76\u6210\u679c\u201cPhotochemical Construction of Carbonitride Superstructures for Red-Light Redox Catalysis<\/strong>\u201d\u3002\u672c\u6587\u901a\u8fc7\u4e00\u79cd\u5149\u5316\u5b66\u805a\u5408\u65b9\u6cd5\u5236\u5907\u4e86\u5177\u6709\u51c6\u4e8c\u7ef4\u7ed3\u6784\u7684\u65b0\u578b\u78b3\u6c2e\u805a\u5408\u7269\u50ac\u5316\u5242\u3002\u901a\u8fc7\u56fa\u4f53\u6838\u78c1\u548cX\u5c04\u7ebf\u8fd1\u8fb9\u5438\u6536\u8c31\u8bc1\u5b9e\u8be5\u50ac\u5316\u5242\u662f\u4e00\u79cd\u4e09\u55ea\u57fa\u805a\u5408\u7269\u3002\u8fd9\u79cd\u65b0\u578b\u78b3\u6c2e\u50ac\u5316\u5242\u5438\u5149\u8303\u56f4\u53ef\u4ee5\u8fbe\u5230735 nm\u7684\u7ea2\u5149\u533a\uff0c\u662f\u76ee\u524d\u4e3a\u6b62\u6240\u62a5\u9053\u7684\u78b3\u6c2e\u57fa\u50ac\u5316\u5242\u4e2d\u5438\u5149\u8303\u56f4\u6700\u5bbd\u7684\u3002\u5728\u7ea2\u5149\u533a\uff0c\u8be5\u50ac\u5316\u5242\u53ef\u4ee5\u6709\u6548\u53d1\u6325\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u4f5c\u7528\uff0c\u6bd4\u5982\u9187\u7684\u6c27\u5316\u548c\u4e8c\u6c27\u5316\u78b3\u7684\u8fd8\u539f\u50ac\u5316\u53cd\u5e94\u3002\u53e6\u5916\uff0c\u672c\u6587\u4e5f\u656c\u8d3a\u798f\u5dde\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6821\u53cb\u5434\u65b0\u6d9b\u9662\u58eb\u516b\u5341\u5927\u5bff<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00 \u5149\u5316\u5b66\u65b9\u6cd5\u5408\u6210\u50ac\u5316\u5242\u56fe\u793a<\/strong><\/p>\n

\"\"<\/p>\n

UV light\u5149\u6e90\uff1a125 W\u9ad8\u538b\u6c5e\u706f\uff08\u6ce2\u957f\u5927\u4e8e280 nm\uff09<\/p>\n

\u56fe\u4e8c \u6c2e\u5316\u78b3\u57fa\u50ac\u5316\u5242\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a. \u9ad8\u89d2\u73af\u5f62\u6697\u573a\uff08HAADF\uff09\u548c\u5143\u7d20\u5206\u5e03\u56fe
\n b. 15<\/sup>N NMR \uff08\u9ed1\u7ebf\uff09\u548c15<\/sup>N CPPI NMR(\u53c2\u6bd4\u6db2\u6c28)\u56fe
\n c. C\u7684K\u8fb9X\u5c04\u7ebf\u8fd1\u8fb9\u5438\u6536\u8c31\u56fe\uff08K-edge XANES\uff09
\n d. N \u7684K\u8fb9X\u5c04\u7ebf\u8fd1\u8fb9\u5438\u6536\u8c31\u56fe
\n e. XPS C 1s\u7cbe\u7ec6\u8c31\u56fe
\n f. XPS N 1s\u7cbe\u7ec6\u8c31\u56fe<\/p>\n

\u56fe\u4e09 \u6c2e\u5316\u78b3\u57fa\u50ac\u5316\u5242\u5149\u54cd\u5e94\u6027\u80fd\u548c\u80fd\u5e26\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

a. \u7d2b\u5916\u53ef\u89c1\u6f2b\u53cd\u5c04\u56fe\u53ca\u63d2\u56fe\u4e2d\u5bfc\u51fa\u7684\u5e26\u9699\uff081.68 eV\uff09
\n b. \u5f52\u4e00\u5316\u5149\u81f4\u53d1\u5149\u5149\u8c31\u56fe\uff08PL\u8c31\uff09
\n c. \u5149\u7535\u6d41\u54cd\u5e94\u66f2\u7ebf\u56fe\uff08-0.2 V\u504f\u538b\uff0c50 W LED\u706f\uff09
\n d. \u7535\u5b50\u987a\u78c1\u5171\u632f\u56fe\uff08EPR\uff09
\n e. XPS\u4ef7\u5e26\u8c31\u56fe
\n f. \u78b3\u6c2e\u57fa\u50ac\u5316\u5242\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\u56fe\u56db \u6c2e\u5316\u78b3\u57fa\u50ac\u5316\u5242\u50ac\u5316\u6d3b\u6027\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

a. \u4e0d\u540c\u6ce2\u957f\u7167\u5c04\u4e0b\u82ef\u7532\u9187\u6c27\u5316\u6d3b\u6027\uff0810 h\uff0c333 K\uff09
\n b. \u4e0d\u540c\u5bf9\u4f4d\u53d6\u4ee3\u57fa\u7684\u82ef\u7532\u9187\u8f6c\u6362\u4e3a\u919b\u7684\u9009\u62e9\u6027\uff08420 nm LED\uff0c10 h\uff0c333 K\uff09
\n c. \u4e0d\u540c\u6ce2\u957f\u7167\u5c04\u4e0b\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u6d3b\u6027\uff081 h\uff0c303 K\uff09
\n d. \u4e00\u6c27\u5316\u78b3\u52a8\u529b\u5b66\u66f2\u7ebf\uff08303 K\uff09<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u901a\u8fc7\u4e00\u79cd\u5149\u5316\u5b66\u805a\u5408\u8def\u7ebf\u5408\u6210\u65b0\u578b\u7684\u6c2e\u5316\u78b3\u57fa\u5149\u50ac\u5316\u5242\uff0c\u5176\u5438\u5149\u8303\u56f4\u8fbe\u5230\u4e86\u7ea2\u5149\u533a\uff08735 nm\uff09\uff0c\u5b9e\u73b0\u4e86\u5bf9\u592a\u9633\u5149\u7684\u5145\u5206\u5229\u7528\u3002\u540c\u65f6\uff0c\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5728\u7ea2\u5149\u7167\u5c04\u4e0b\uff08730 nm\uff09\uff0c\u8be5\u50ac\u5316\u5242\u4e5f\u80fd\u6709\u6548\u50ac\u5316\u6c27\u5316\u9187\u548c\u50ac\u5316\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\u3002\u8be5\u7814\u7a76\u4e0d\u4ec5\u4ec5\u5927\u5927\u63d0\u5347\u4e86\u6c2e\u5316\u78b3\u57fa\u5149\u50ac\u5316\u5242\u7684\u5438\u5149\u8303\u56f4\uff0c\u800c\u4e14\u6240\u63d0\u51fa\u7684\u5149\u5316\u5b66\u805a\u5408\u6cd5\u4e5f\u4e3a\u5408\u6210\u78b3\u6c2e\u7c7b\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u5408\u6210\u8def\u5f84\u3002\u8be5\u7814\u7a76\u5bf9\u4e8e\u5145\u5206\u5229\u7528\u592a\u9633\u80fd\u8fdb\u884c\u5149\u50ac\u5316\u53cd\u5e94\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aPhotochemical Construction of Carbonitride Superstructures for Red-Light Redox Catalysis<\/a><\/strong>\uff08Angew. Chem. Int. Ed. 2018, DOI: 10.1002\/anie.201804996\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4\u66f9\u6653\u864e\u7f16\u8bd1\uff0c\u675c\u6210\u6c5f\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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