{"id":140616,"date":"2018-06-01T14:00:03","date_gmt":"2018-06-01T06:00:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=140616"},"modified":"2018-05-31T17:32:38","modified_gmt":"2018-05-31T09:32:38","slug":"angew-chem-int-ed-%ef%bc%9a%e5%85%b7%e6%9c%89%e9%80%89%e6%8b%a9%e6%80%a7%e9%98%b3%e7%a6%bb%e5%ad%90%e7%a9%ba%e4%bd%8d%e7%9a%84%e9%92%99%e9%92%9b%e7%9f%bf%e5%9e%8b%e6%b0%a2%e6%b0%a7%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=140616","title":{"rendered":"Angew. Chem. Int. Ed.\uff1a\u5177\u6709\u9009\u62e9\u6027\u9633\u79bb\u5b50\u7a7a\u4f4d\u7684\u9499\u949b\u77ff\u578b\u6c22\u6c27\u5316\u7269\u5e76\u7528\u4e8e\u50ac\u5316OER"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u50ac\u5316\u6c27\u6790\u51fa\u53cd\u5e94\uff08OER\uff09\u662f\u7535\u89e3\u6c34\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u7b49\u80fd\u91cf\u8f6c\u6362\u88c5\u7f6e\u7684\u5173\u952e\u53cd\u5e94\u3002\u4f46\u662fOER\u662f\u4e2a\u56db\u7535\u5b50\u53cd\u5e94\uff0c\u53cd\u5e94\u52a8\u529b\u5b66\u6162\uff0c\u6240\u4ee5\u9700\u8981\u5916\u754c\u63d0\u4f9b\u9ad8\u7684\u8fc7\u7535\u4f4d\uff0c\u80fd\u91cf\u635f\u5931\u5927\u3002\u56e0\u6b64\uff0c\u5bfb\u6c42\u9ad8\u6548OER\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u4f4e\u8fc7\u7535\u52bf\u4e0b\u6790\u6c27\uff0c\u662f\u76ee\u524d\u79d1\u5b66\u5de5\u4f5c\u8005\u7684\u91cd\u70b9\u7814\u7a76\u65b9\u5411\u4e4b\u4e00\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u53d1\u73b0\u7a7a\u4f4d\u80fd\u591f\u6709\u6548\u6539\u5584OER\u50ac\u5316\u5242\u7684\u6027\u80fd\u3002\u4f46\u662f\uff0c\u66f4\u591a\u96c6\u4e2d\u4e8e\u9634\u79bb\u5b50\u7a7a\u4f4d\uff0c\u7f3a\u4e4f\u5bf9OER\u50ac\u5316\u5242\u6750\u6599\u4e2d\u9009\u62e9\u6027\u5236\u5907\u7684\u9633\u79bb\u5b50\u7a7a\u4f4d\u4e0e\u5176\u6027\u80fd\u4e4b\u95f4\u5173\u7cfb\u7684\u7814\u7a76\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u6e56\u5357\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u7684\u738b\u53cc\u5370\u6559\u6388\u4e0e\u5357\u4eac\u5e08\u8303\u5927\u5b66\u7684\u674e\u4e9a\u98de\u6559\u6388\u3001\u53f0\u6e7e\u6de1\u6c5f\u5927\u5b66\u7684\u8463\u5d07\u793c\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\uff0c\u91c7\u7528\u5171\u6c89\u6dc0\u7684\u65b9\u6cd5\u5f97\u5230\u4e86\u5177\u6709\u7eb3\u7c73\u7acb\u65b9\u4f53\u7ed3\u6784\u7684SnCo0.9<\/sub>Fe0.1<\/sub>(OH)6<\/sub>\uff0c\u518d\u91c7\u7528Ar\u7b49\u79bb\u5b50\u4f53\u6280\u672f\u5bf9\u6b64\u524d\u9a71\u4f53\u8fdb\u884c\u540e\u5904\u7406\u3002\u523b\u8680\u540e\u7684\u7eb3\u7c73\u7acb\u65b9\u4f53\u8868\u9762\u53ef\u4ee5\u5f62\u6210\u591a\u79cd\u7c7b\u578b\u7a7a\u4f4d\uff0c\u5982\u6c27\u7a7a\u4f4d\uff0c\u9521\u7a7a\u4f4d\uff0c\u94b4\u7a7a\u4f4d\u548c\u94c1\u7a7a\u4f4d\u3002\u7136\u800c\uff0c\u7531\u4e8e\u6c22\u6c27\u5316\u9521\u6676\u683c\u80fd\u8fdc\u6bd4\u94b4\u6216\u94c1\u7684\u6c22\u6c27\u5316\u7269\u7684\u4f4e\uff0c\u56e0\u6b64\u5728\u5f62\u6210\u591a\u79cd\u9633\u79bb\u5b50\u7a7a\u4f4d\u7684\u8fc7\u7a0b\u4e2d\uff0cSn\u7a7a\u4f4d\u9009\u62e9\u6027\u5730\u4f18\u5148\u5f62\u6210\uff0c\u4ece\u800c\u5f00\u53d1\u4e86\u4e00\u79cd\u5177\u6709\u4e30\u5bccSn\u7a7a\u4f4d\u7684\u9499\u949b\u77ff\u578b\u6c22\u6c27\u5316\u7269OER\u50ac\u5316\u5242\u6750\u6599\uff0c\u547d\u540d\u4e3aSnCoFe-Ar\u3002\u4e30\u5bcc\u7684Sn\u7a7a\u4f4d\u4f7f\u50ac\u5316\u5242\u6750\u6599\u5177\u6709\u4e86\u66f4\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u8d85\u4eb2\u6c34\u6027\uff0c\u66b4\u9732\u51fa\u66f4\u591a\u7684CoFe\u6d3b\u6027\u4f4d\u70b9\uff0c\u6539\u5584\u6750\u6599\u7684\u7535\u5b50\u7ed3\u6784\u548c\u7269\u8d28\u4f20\u8f93\u80fd\u529b\u3002 \u6b64\u5916\uff0cDFT\u8ba1\u7b97\u8868\u660e\uff0cSn-O\u7a7a\u4f4d\u7684\u751f\u6210\u4f18\u5316\u4e86\u5bf9\u53cd\u5e94\u7269\u7684\u5438\u9644\uff0c\u56e0\u6b64\uff0cSnCoFe-Ar\u7684OER\u6027\u80fd\u4f18\u4e8eSnCoFe\u3002\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA\/cm2<\/sup>\u4e0b\uff0c\u524d\u8005\u8fc7\u7535\u52bf\u4e3a300 mV\uff0c\u800c\u540e\u8005\u4e3a420 mV\u3002\u6b64\u5916\uff0c\u524d\u8005\u5854\u83f2\u5c14\u659c\u7387\u4e3a42.3 mV\/decade\uff0c\u540e\u8005\u662f77.0mV\/decade\u3002\u76f8\u5173\u6210\u679c\u88ab\u53d1\u8868\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\uff0c\u9898\u4e3a\u201cPreferential Cation Vacancies in Perovskite Hydroxide for Oxygen Evolution Reaction<\/strong>\u201d\u3002\u7b2c\u4e00\u4f5c\u8005\u4e3a\u6e56\u5357\u5927\u5b66\u7684\u535a\u58eb\u540e\u9648\u5927\u4f1f\uff0c\u5357\u4eac\u5e08\u8303\u5927\u5b66\u7684\u535a\u58eb\u751f\u4e54\u66fc\u548c\u53f0\u6e7e\u6de1\u6c5f\u5927\u5b66\u7684\u5362\u82f1\u777f\u535a\u58eb\uff08\u5171\u540c\u4e00\u4f5c\uff09\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. SnCoFe<\/strong>\u548c<\/strong>SnCoFe-Ar<\/strong>\u4e24\u79cd\u6750\u6599\u7684\u5f62\u8c8c\u3001\u6676\u4f53\u7ed3\u6784\u548c\u5143\u7d20\u5206\u5e03\u56fe<\/strong><\/p>\n

\"\"(a, b). SnCoFe\u7684\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\u56fe\u548c\u76f8\u5e94\u7684SAED\u56fe\uff1b<\/p>\n

(c, d). SnCoFe-Ar\u7684\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\u56fe\u548c\u76f8\u5e94\u7684SAED\u56fe\uff1b<\/p>\n

(e). SnCoFe\u7684\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

(f). SnCoFe-Ar\u7684\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

\u56fe<\/strong>2. SnCoFe<\/strong>\u548c<\/strong>SnCoFe-Ar<\/strong>\u4e2d<\/strong>Co, Fe<\/strong>\u548c<\/strong>Sn<\/strong>\u7684\u540c\u6b65\u8f90\u5c04\u6570\u636e<\/strong><\/p>\n

\"\"(a). SnCoFe\u548cSnCoFe-Ar\u4e2dCo\u7684K\u8fb9\u7684XANES\u6570\u636e\u5bf9\u6bd4\u56fe\uff1b<\/p>\n

(b). SnCoFe\u548cSnCoFe-Ar\u4e2dCo\u7684K\u8fb9\u7684FE-XAFS\u6570\u636e\u5bf9\u6bd4\u56fe\uff1b<\/p>\n

(c). SnCoFe\u548cSnCoFe-Ar\u4e2dFe\u7684K\u8fb9\u7684XANES\u6570\u636e\u5bf9\u6bd4\u56fe;<\/p>\n

(d). SnCoFe\u548cSnCoFe-Ar\u4e2dFe\u7684K\u8fb9\u7684FE-XAFS\u6570\u636e\u5bf9\u6bd4\u56fe;<\/p>\n

(e). SnCoFe\u548cSnCoFe-Ar\u4e2dSn\u7684K\u8fb9\u7684FE-XAFS\u6570\u636e\u5bf9\u6bd4\u56fe(\u63d2\u56fe\u4e3a\u76f8\u5e94\u7684Sn\u7684K\u8fb9\u7684XANES\u6570\u636e\u5bf9\u6bd4\u56fe)\uff1b<\/p>\n

(f). SnCoFe\u548cSnCoFe-Ar\u4e2dCo, Fe\u548cSn\u7684K\u8fb9\u7684EXAFS\u632f\u8361\u56fe\u3002<\/p>\n

\u4eceTEM\u56fe\u53ef\u4ee5\u770b\u51fa\uff0cSnCoFe\u8868\u9762\u5f62\u6210\u4e86\u65e0\u5b9a\u578b\u7ed3\u6784\uff0c\u901a\u8fc7\u5143\u7d20\u5206\u5e03\u56fe\u4e0eCo\/Fe\u5143\u7d20\u76f8\u6bd4\uff0c\u8868\u5c42\u7684Sn\u539f\u5b50\u57fa\u672c\u5df2\u7ecf\u88ab\u9009\u62e9\u6027\u5730\u523b\u8680\u6389\u3002\u5206\u6790\u540c\u6b65\u8f90\u5c04\u7684\u6570\u636e\u548c\u62df\u5408\u6570\u636e\u53ef\u4ee5\u53d1\u73b0\uff0c\u7b49\u79bb\u5b50\u4f53\u5904\u7406\u540e\uff0c\u9664\u4e86\u5f62\u6210\u4e86\u6c27\u7f3a\u9677\uff0c\u4e5f\u5f62\u6210\u4e86\u5927\u91cf\u7684Sn\u7f3a\u9677\u3002\u4f46Sn\u5468\u56f4\u7684\u539f\u5b50\u7ed3\u6784\u57fa\u672c\u6ca1\u6709\u53d1\u751f\u53d8\u5316\uff0c\u56e0\u6b64\u53ef\u4ee5\u5224\u5b9a\u5927\u91cf\u7684Sn\u7a7a\u4f4d\u53ea\u96c6\u4e2d\u5206\u5e03\u5728\u50ac\u5316\u5242\u8868\u9762\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u50ac\u5316\u5242\u6750\u6599\u7684\u7535\u50ac\u5316\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"(a). \u57281.0 mol\/L\u7684KOH\u6eb6\u6db2\u4e2d\uff0c\u8d1f\u8f7d\u5728\u73bb\u78b3\u7535\u6781\u4e0a\u7684SnCoFe\u548cSnCoFe-Ar\u4ee5\u53ca\u8d1f\u8f7d\u5728\u6ce1\u6cab\u954d\u4e0a\u7684SnCoFe-Ar\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

(b). \u8d1f\u8f7d\u5728\u73bb\u78b3\u7535\u6781\u4e0a\u7684 SnCoFe\u548cSnCoFe-Ar\u76f8\u5bf9\u5e94\u7684Tafel\u66f2\u7ebf\uff1b<\/p>\n

(c). \u8d1f\u8f7d\u5728\u73bb\u78b3\u7535\u6781\u4e0a\u7684 SnCoFe\u548cSnCoFe-Ar\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

(d). \u8d1f\u8f7d\u5728\u73bb\u78b3\u7535\u6781\u4e0a\u7684 SnCoFe\u548cSnCoFe-Ar\u7684EIS\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>4. <\/strong>\u50ac\u5316\u5242\u6750\u6599\u7535\u50ac\u5316<\/strong>OER<\/strong>\u8fc7\u7a0b\u7684\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c<\/strong><\/p>\n

\"\"(a). \u5728\u78b1\u6027\u7535\u89e3\u6db2\u4e2d\uff0c\u5728SnCoFe-Ar\u4e0a\u53d1\u751f\u7684OER\u7684\u56db\u4e2a\u6b65\u9aa4\u793a\u4f8b\u56fe (\u56fe\u4e2d\u84dd\u8272\u73af\u4e2d\u6807\u8bb0\u7684\u662f\u6d3b\u6027\u4f4d\u70b9)\uff1b<\/p>\n

(b). \u7eaf\u7684SnCoFe\uff08\u5305\u62ec\u6d3b\u6027\u4f4d\u70b9Sn\u548cCo\uff09\u4ee5\u53caSnCoFe-Ar\u4e09\u79cd\u6a21\u578b\u7684OER\u53cd\u5e94\u6216\u6027\u80fd\u8ba1\u7b97\u7ed3\u679c\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u4f7f\u7528Ar\u7b49\u79bb\u5b50\u4f53\u5bf9\u9499\u949b\u77ff\u578b\u6c22\u6c27\u5316\u7269SnCo0.9<\/sub>Fe0.1<\/sub>(OH)6<\/sub>\u8fdb\u884c\u5904\u7406\uff0c\u5f97\u5230\u5177\u6709\u4e30\u5bccSn\u7a7a\u4f4d\u7684OER\u7535\u50ac\u5316\u5242\u3002\u901a\u8fc7\u4e00\u7cfb\u5217\u7684\u8868\u5f81\u53d1\u73b0\uff0c\u8be5\u9633\u79bb\u5b50\u7a7a\u4f4d\u4f7f\u50ac\u5316\u5242\u6750\u6599\u66b4\u9732\u51fa\u66f4\u591a\u7684Co\/Fe\u6d3b\u6027\u4f4d\u70b9\uff0c\u5e76\u5728\u6750\u6599\u8868\u9762\u5236\u9020\u66f4\u591a\u76841-2nm\u7684\u5b54\u9053\uff0c\u63d0\u9ad8\u5176\u7269\u8d28\u4f20\u8f93\u80fd\u529b\uff0c\u540c\u65f6\u6539\u5584\u5176\u7535\u5b50\u4f20\u8f93\u80fd\u529b\u3002\u6545\u800c\uff0c\u8be5\u5bcc\u9633\u79bb\u5b50\u7f3a\u9677\u7684SnCoFe-Ar\u8868\u73b0\u51fa\u5f88\u597d\u7684\u50ac\u5316\u6027\u80fd\uff0c\u4e3a\u540e\u6765\u8005\u8bbe\u8ba1\u9ad8\u6548OER\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Preferential Cation Vacancies in Perovskite Hydroxide for Oxygen Evolution Reaction <\/a>(Angew. Chem. Int. Ed., 2018, DOI: 10.1002\/anie.201805520)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4Wenli Lu\u7f16\u8f91\uff0c\u5218\u5b87\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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