{"id":140463,"date":"2018-05-31T14:00:54","date_gmt":"2018-05-31T06:00:54","guid":{"rendered":"\/\/m.iemloyee.com\/?p=140463"},"modified":"2018-05-29T19:24:24","modified_gmt":"2018-05-29T11:24:24","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%e5%af%8cpd-o-sn%e7%95%8c%e9%9d%a2%e7%9a%84%e5%a4%9a%e7%ba%a7pdsno2-%e7%ba%b3%e7%b1%b3%e7%89%87%e7%94%b5%e5%82%ac%e5%8c%96%e8%bf%98%e5%8e%9fc","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=140463","title":{"rendered":"\u53a6\u95e8\u5927\u5b66Angew. Chem. Int. Ed. \u5bccPd-O-Sn\u754c\u9762\u7684\u591a\u7ea7Pd\/SnO2 \u7eb3\u7c73\u7247\u7535\u50ac\u5316\u8fd8\u539fCO2\u5236CH3OH"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5c06\u4e8c\u6c27\u5316\u78b3(CO2<\/sub>)\u901a\u8fc7\u7535\u5316\u5b66\u8f6c\u5316\u4e3a\u6709\u7528\u7684\u78b3\u57fa\u71c3\u6599\u662f\u7f13\u89e3\u73af\u5883\u548c\u80fd\u6e90\u5371\u673a\u7684\u6709\u6548\u9014\u5f84\u3002\u5728\u8fc7\u53bb\u51e0\u5341\u5e74\u4e2d\uff0c\u5305\u62ec\u91d1\u5c5e\u3001\u5408\u91d1\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u91d1\u5c5e\u786b\u5316\u7269\u5728\u5185\u7684\u4f17\u591a\u7eb3\u7c73\u50ac\u5316\u5242\u88ab\u5e94\u7528\u4e8e\u4e8c\u6c27\u5316\u78b3\u7535\u8fd8\u539f(CO2<\/sub>RR)\u4e2d\u3002\u5728\u8fd9\u4e9b\u7eb3\u7c73\u50ac\u5316\u5242\u4e2d\uff0c\u94af(Pd)\u57fa\u7eb3\u7c73\u6750\u6599\u56e0\u5176\u9ad8\u8d28\u91cf\u6d3b\u6027\u5728CO2<\/sub>RR\u4e2d\u5c55\u73b0\u51fa\u4e86\u5f3a\u5927\u7684\u4f18\u52bf\u3002\u5f53\u91c7\u7528\u7eafPd\u7eb3\u7c73\u50ac\u5316\u5242\u65f6\uff0c\u7531\u4e8ePd\u5bf9CO (CO2<\/sub>RR\u4e2d\u95f4\u4f53)\u6709\u5f88\u5f3a\u7684\u5316\u5b66\u4eb2\u548c\u6027\uff0c\u6240\u4ee5Pd\u6781\u6613\u88abCO\u6bd2\u5316\u800c\u5931\u6d3b\u3002\u800c\u4e14\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5927\u591a\u6570Pd\u57fa\u7eb3\u7c73\u6750\u6599\u5728CO2<\/sub>RR\u8fc7\u7a0b\u4e2d\u53ea\u80fd\u901a\u8fc7\u4e24\u7535\u5b50\u8f6c\u79fb\u8fd8\u539f\u5f97\u5230CO\u6216HCOO–<\/sup>\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5e73\u8861CO\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u5438\u9644\u4e0e\u6d3b\u5316\uff0c\u5e76\u8fdb\u4e00\u6b65\u901a\u8fc7\u591a\u7535\u5b50\u8f6c\u79fb\u8fd8\u539f\u5f97\u5230\u9ad8\u9644\u52a0\u503c\u4ea7\u7269\u5982CH3<\/sub>OH\uff0c\u8fd9\u4e3a\u65b0\u578bPd\u57fa\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u5236\u5907\u63d0\u51fa\u4e86\u65b0\u7684\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u53a6\u95e8\u5927\u5b66\u7684\u5434\u70b3\u8f89\u526f\u6559\u6388\u548c\u90d1\u5357\u5cf0\u6559\u6388<\/strong>(<\/strong>\u5171\u540c\u901a\u8baf<\/strong>)<\/strong>\u5728Angew. Chem. Int. Ed.<\/em><\/strong>\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\uff1aElectrochemical Reduction of CO2<\/sub> to CH3<\/sub>OH on hierarchical Pd\/SnO2<\/sub> nanosheets with abundant Pd-O-Sn interfaces<\/strong>\u3002\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u79cd\u8d85\u8584Pd\u7eb3\u7c73\u7247\u90e8\u5206\u88abSnO2<\/sub>\u7eb3\u7c73\u9897\u7c92\u8986\u76d6\u7684\u591a\u7ea7Pd\/SnO2<\/sub>\u7eb3\u7c73\u7247(Pd\/SnO2<\/sub> NSs)\uff0c\u4ee5\u6b64\u6765\u4fc3\u8fdb\u754c\u9762\u591a\u7535\u5b50\u8f6c\u79fb\uff0c\u5b9e\u73b0\u7535\u5316\u5b66\u8fd8\u539fCO2<\/sub>\u4e3aCH3<\/sub>OH\u3002\u8fd9\u79cd\u7ed3\u6784\u4e0d\u4ec5\u80fd\u591f\u6709\u6548\u589e\u5f3aCO2<\/sub>\u5728SnO2<\/sub>\u4e0a\u7684\u5438\u9644\uff0c\u800c\u4e14\u80fd\u591f\u524a\u5f31CO\u5728Pd\u4e0a\u7684\u5f3a\u5438\u9644\u3002\u5e76\u4e14\u6df1\u5165\u7814\u7a76\u8868\u660e\uff0c\u4ee5\u6b64\u6750\u6599\u6784\u5efa\u7684Pd-O-Sn\u91d1\u5c5e-\u6c27\u5316\u7269\u754c\u9762\u5728CO2<\/sub>\u591a\u7535\u5b50\u8fd8\u539f\u7684\u8fc7\u7a0b\u4e2d\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. Pd NSs\u548c\u591a\u7ea7Pd\/SnO2<\/sub> NSs\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) Pd\/SnO2<\/sub> NSs\u7684\u5408\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

(b) Pd NSs\u7684TEM\u56fe\uff1b<\/p>\n

(c) Pd\/SnO2<\/sub> NSs\u7684TEM\u56fe\uff1b<\/p>\n

(d) Pd\/SnO2<\/sub> NSs\u7684HAADF-STEM\u548cEDX\u56fe\uff1b<\/p>\n

(e) Pd\/SnO2<\/sub> NSs\u7684HRTEM\u56fe\u3002<\/p>\n

\u56fe2. Pd\/SnO2<\/sub> NSs (Pd:Sn=1:1)\u7684CO2<\/sub>RR\u7535\u5316\u5b66\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u00a0LSV\u66f2\u7ebf\u56fe\uff1b<\/p>\n

(b) \u5728\u4e0d\u540c\u504f\u538b\u4e0bCH3<\/sub>OH \u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u56fe\uff1b<\/p>\n

(c) \u7535\u6d41\u5bc6\u5ea6-\u626b\u901f\u7ebf\u6027\u62df\u5408\u56fe\uff1b<\/p>\n

(d) \u8ba1\u65f6\u7535\u6d41\u7a33\u5b9a\u6027\u6d4b\u8bd5\u56fe\u3002<\/p>\n

\u56fe3. Pd\/SnO2<\/sub> NSs\u4e0a\u7684CO2<\/sub>\/CO\u5438\u9644\u548cPd\/Sn\u6bd4\u4f8b\u5bf9\u7532\u9187\u6cd5\u62c9\u7b2c\u6548\u7387\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u9971\u548cCO2<\/sub>\u5438\u9644\u539f\u4f4d\u7ea2\u5916\u6f2b\u53cd\u5c04\u56fe\uff1b<\/p>\n

(b) CO stripping\u6d4b\u8bd5\u56fe\uff1b<\/p>\n

(c) \u4e0d\u540c\u65bd\u52a0\u7535\u538b\u4e0bCH3<\/sub>OH\u3001HCOO–<\/sup>\u548cH2<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u56fe\u3002<\/p>\n

\u56fe4. Pd\/SnO2<\/sub> NSs (Pd:Sn=1:1)\u4e2dPd-O-Sn\u754c\u9762\u91cd\u8981\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a) Pd\/SnO2<\/sub> NSs\u7684FT-EXAFS\u56fe\uff1b<\/p>\n

(b) Pd\/SnO2<\/sub> NSs\u7684XANES\u56fe\uff1b<\/p>\n

(c) Pd\/PdO\u50ac\u5316\u524d\u540eXRD\u56fe\uff1b<\/p>\n

(d) Pd\/PdO\u50ac\u5316\u524d\u540e\u6db2\u6001\u4ea7\u7269\u76841<\/sup>H NMR\u56fe\uff1b<\/p>\n

\u3010\u7ed3\u8bba\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7528SnO2 <\/sub>NPs\u90e8\u5206\u8986\u76d6Pd NSs\uff0c\u6784\u5efa\u4e86\u4e00\u79cd\u4e8c\u7ef4\u591a\u7ea7Pd\/SnO2<\/sub> NSs\u7535\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u7535\u5316\u5b66\u8fd8\u539fCO2<\/sub>\u5230CH3<\/sub>OH\u3002\u901a\u8fc7\u8c03\u6574SnO2<\/sub>\u5728Pd NSs\u4e0a\u7684\u8986\u76d6\u5ea6\uff0c\u53ef\u4ee5\u4f18\u5316\u5f97\u5230\u9ad8\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u7684Pd\/SnO2<\/sub> NSs\u3002\u5176CH3<\/sub>OH\u9ad8\u9009\u62e9\u6027\u53ef\u5f52\u56e0\u4e8e\u4e09\u4e2a\u56e0\u7d20: (1) Pd\/SnO2<\/sub> NSs\u5177\u6709\u4f18\u5f02\u7684CO2<\/sub>\u5438\u9644\u80fd\u529b\uff1b(2) Pd\/SnO2<\/sub> NSs\u4e0a\u90e8\u5206\u66b4\u9732\u7684Pd\u5438\u9644CO*\u4e2d\u95f4\u4f53\uff0c\u4f7f\u4e4b\u6709\u6df1\u5ea6\u8fd8\u539f\u7684\u53ef\u80fd\uff1b(3) Pd-O-Sn\u754c\u9762\u52a9\u529b\u7535\u8377\u4f20\u9012\u7ed9CO*\u4e2d\u95f4\u4f53\uff0c\u8fdb\u4e00\u6b65\u5c06\u5176\u8fd8\u539f\u4e3aCH3<\/sub>OH\u3002\u968f\u7740\u591a\u7ea7\u91d1\u5c5e-\u91d1\u5c5e\u6c27\u5316\u7269\u5f02\u8d28\u7ed3\u6750\u6599\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u8be5\u7b56\u7565\u4e3a\u5b9e\u73b0CO2<\/sub>RR\u4e2d\u7684\u591a\u7535\u5b50\u8f6c\u79fb\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Electrochemical Reduction of CO2<\/sub> to CH3<\/sub>OH on hierarchical Pd\/SnO2<\/sub> nanosheets with abundant Pd-O-Sn interfaces<\/a>, (Angew. Chem. Int. Ed.<\/em>, 2018<\/strong>, DOI: 10.1002\/anie.201804142)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5c06\u4e8c\u6c27\u5316\u78b3(CO2)\u901a\u8fc7\u7535\u5316\u5b66\u8f6c\u5316\u4e3a\u6709\u7528\u7684\u78b3\u57fa\u71c3\u6599\u662f\u7f13\u89e3\u73af\u5883\u548c\u80fd\u6e90\u5371\u673a\u7684\u6709\u6548\u9014\u5f84\u3002\u5728\u8fc7\u53bb\u51e0\u5341\u5e74\u4e2d\uff0c\u5305\u62ec\u91d1\u5c5e\u3001\u5408\u91d1\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u91d1\u5c5e\u786b\u5316\u7269\u5728\u5185\u7684\u4f17\u591a\u7eb3\u7c73…<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2569],"class_list":["post-140463","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2569"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/140463"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=140463"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/140463\/revisions"}],"predecessor-version":[{"id":140858,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/140463\/revisions\/140858"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=140463"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=140463"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=140463"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}