{"id":140453,"date":"2018-05-31T14:00:58","date_gmt":"2018-05-31T06:00:58","guid":{"rendered":"\/\/m.iemloyee.com\/?p=140453"},"modified":"2018-05-27T21:37:40","modified_gmt":"2018-05-27T13:37:40","slug":"energy-environmental-science%ef%bc%9a%e8%b6%85%e8%96%84%e9%9d%9e%e6%99%b6%e6%80%81%e9%92%b4%e9%92%92%e6%b0%a2%e6%b0%a7%e6%b0%a7%e5%8c%96%e7%89%a9%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88oer","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=140453","title":{"rendered":"Energy & Environmental Science\uff1a\u8d85\u8584\u975e\u6676\u6001\u94b4\u9492\u6c22(\u6c27)\u6c27\u5316\u7269\u7528\u4e8e\u9ad8\u6548OER"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u80fd\u6e90\u56f0\u5883\u548c\u5168\u7403\u53d8\u6696\u7684\u6311\u6218\u4fc3\u4f7f\u4eba\u4eec\u5bf9\u6c34\u5206\u89e3\u8fc7\u7a0b\u8fdb\u884c\u79d1\u5b66\u63a2\u7d22\uff0c\u5176\u4e2d\u6c27\u5316\u534a\u53cd\u5e94\uff0c\u5373\u4ea7\u6c27\u53cd\u5e94(OER)\u8d77\u7740\u7279\u522b\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5f00\u53d1\u5177\u6709\u4f18\u5f02\u6027\u80fd\u7684\u4f4e\u6210\u672c\u7535\u50ac\u5316\u5242\u4ee5\u964d\u4f4eOER\u8fc7\u7a0b\u4e2d\u7684\u9ad8\u8fc7\u7535\u4f4d\u548c\u76f8\u5173\u80fd\u91cf\u635f\u5931\u4e00\u76f4\u662f\u5176\u5728\u5b9e\u9645\u5e94\u7528\u9053\u8def\u4e2d\u7684\u6311\u6218\u3002\u4f4e\u6210\u672c\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f3d\u91d1\u5c5e(V, Mn, Fe, Co, Ni) \u5316\u5408\u7269\u7684\u4f7f\u7528\u5df2\u7ecf\u663e\u793a\u51fa\u66ff\u4ee3\u9ad8\u6d3b\u6027\u4f46\u7a00\u6709\u7684\u8d35\u91d1\u5c5e\u6c27\u5316\u7269(\u4f8b\u5982IrO2<\/sub>\u548cRuO2<\/sub>)\u7684\u5de8\u5927\u6f5c\u529b\u3002\u8fd1\u5e74\u6765\uff0c\u5177\u6709\u72ec\u7279\u5206\u5b50\u5f0f\u548c\u56fa\u6709\u4e30\u5bcc\u7f3a\u9677\u7684\u975e\u6676\u6001\u6750\u6599\u7531\u4e8e\u5177\u6709\u9ad8\u6548\u50ac\u5316\u7684\u80fd\u529b\u800c\u5907\u53d7\u5173\u6ce8\u3002Kanan\u548cNocera\u5173\u4e8e\u81ea\u4fee\u590d\u65e0\u5b9a\u5f62\u78f7\u9178\u94b4\u7684\u62a5\u544a\u4fc3\u8fdb\u4e86\u6613\u4e8e\u5236\u5907\u3001\u5bcc\u542b\u5730\u7403\u7684\u50ac\u5316\u5242\u7684\u5f00\u53d1\u3002Indra\u7b49\u4eba\u8868\u660e\u65e0\u5b9a\u5f62\u94b4\u94c1\u6c27\u5316\u7269\u5bf9OER\u7684\u6027\u80fd\u751a\u81f3\u4f18\u4e8e\u5b83\u4eec\u5bf9\u5e94\u7684\u6676\u4f53\u3002\u5bf9\u4e8e\u975e\u6676\u6001\u6c22\u6c27\u5316\u94b4\u548c\u6c22\u6c27\u5316\u954d\u7eb3\u7c73\u7247\u4ee5\u53ca\u57fa\u4e8e\u975e\u6676\u6001\u7ed3\u6784\u7684\u5176\u5b83\u9ad8\u7ea7\u50ac\u5316\u5242\u4e5f\u83b7\u5f97\u7c7b\u4f3c\u7684\u7ed3\u679c\u3002<\/p>\n

\u7136\u800c\uff0c\u5982\u4f55\u5408\u7406\u8bbe\u8ba1\u5177\u6709\u4f18\u5316\u7684\u6574\u4f53\u6027\u80fd\uff0c\u5373\u4f4e\u8fc7\u7535\u4f4d\u548c\u957f\u671f\u7a33\u5b9a\u6027\u7684\u975e\u6676\u6001\u7535\u50ac\u5316\u5242\u4ecd\u7136\u662f\u4e00\u4e2a\u91cd\u5927\u6311\u6218\u3002\u76ee\u524d\uff0c\u6709\u4e24\u79cd\u8bbe\u8ba1\u7b56\u7565\u53ef\u7528\u4e8e\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u4e00\u79cd\u662f\u5229\u7528\u53ef\u63a7\u5408\u91d1\u5316\u5408\u7269\u5f62\u6210\u6709\u5229\u7684\u5c40\u90e8\u914d\u4f4d\u548c\u80fd\u91cf\u5b66\uff0c\u800c\u53e6\u4e00\u79cd\u662f\u5229\u7528\u8d85\u8584\u6837\u54c1\u7684\u6709\u76ca\u754c\u9762\u6548\u5e94\u6765\u589e\u52a0\u6d3b\u6027\u91d1\u5c5e\u4f4d\u70b9\u7684\u66b4\u9732\u5e76\u5b9e\u73b0\u66f4\u5feb\u7684\u79bb\u5b50\u8fc1\u79fb\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\u3002\u6765\u81ea\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u7684\u90ed\u6797\u6559\u6388\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u7684\u6768\u4e16\u6cb3\u6559\u6388\u4ee5\u53ca\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7684\u7f57\u6bc5\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u5728Energy & Environmental Science<\/strong>\u8054\u5408\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\uff1aUltrathin amorphous cobalt\u2013vanadium hydr(oxy)oxide catalysts for the oxygen evolution reaction<\/strong>\u3002\u7814\u7a76\u4eba\u5458\u5408\u6210\u7684\u8d85\u8584\u975e\u6676\u6001\u94b4\u9492\u6c22(\u6c27)\u6c27\u5316\u7269\u662f\u4e00\u79cd\u975e\u5e38\u6709\u524d\u9014\u7684\u7528\u4e8eOER\u7684\u7535\u50ac\u5316\u6750\u6599\uff0c\u572810 mA cm\u22122<\/sup>\u4e0b\u5177\u67090.250 V\u7684\u4f4e\u8fc7\u7535\u4f4d(\u5f53\u8d1f\u8f7d\u5728Au\u6ce1\u6cab\u4e0a\u65f6\u751a\u81f3\u66f4\u4f4e\u81f30.215 V )\uff0c\u5e76\u4e14\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u5177\u6709\u957f\u7684\u7a33\u5b9a\u53cd\u5e94\u65f6\u95f4(170 h)\u3002\u7ed3\u5408\u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u8868\u5f81\u548c\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u62df\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u8d85\u8584\u3001\u65e0\u5b9a\u5f62\u548c\u5408\u91d1\u5316\u7684\u7ed3\u6784\u7279\u5f81\u4f7f\u5176\u6613\u4e8e\u8f6c\u53d8\u4e3a\u7406\u60f3\u7684\u6d3b\u6027\u76f8\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4e86\u50ac\u5316\u6d3b\u6027\u3002\u7814\u7a76\u4eba\u5458\u7684\u53d1\u73b0\u7a81\u51fa\u4e86\u4e8c\u7ef4\u975e\u6676\u6750\u6599\u7684\u663e\u8457\u4f18\u52bf\uff0c\u4e3a\u9ad8\u6027\u80fd\u7535\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. \u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a\u548cb) CoV-UAH\u7684TEM\u56fe,\u63d2\u56fe\u662f\u5176SAED\u56fe\uff1b<\/p>\n

(c)\u80f6\u4f53\u6eb6\u6db2\u7684\u5149\u5b66\u56fe\u50cf\u548cCoV-UAH\u7684\u5f62\u6001\u548c\u7ed3\u6784\u7684\u793a\u610f\u56fe\u3002\u7ea2\u8272\u3001\u84dd\u8272\u548c\u7070\u8272\u539f\u5b50\u5206\u522b\u662fO\u3001Co\u548cV\u539f\u5b50\uff1b<\/p>\n

(d) CoV-UAH\u5927\u89d2\u5ea6\u73af\u5f62\u6697\u573a(HAADF)\u6a21\u5f0f\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(STEM)\u56fe\u50cf\u548c\u76f8\u5173\u7684EDS\u56fe\u50cf\uff1b<\/p>\n

(e) CoV-UAH\u7684\u539f\u5b50\u529b\u663e\u5fae\u955c\u56fe\u50cf\uff0c\u5176\u4e2dP-1\u548cP-II\u6807\u8bb0\u4e86\u7eb3\u7c73\u7247\u4e2d\u7684\u5b54\uff1b<\/p>\n

(f) CoV-UAH\u76f8\u5e94\u9ad8\u5ea6\u5256\u9762\u56fe\uff1b<\/p>\n

(g) Co – UH\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf\uff0c\u63d2\u56fe\u4e3aSAED\u56fe\uff1b<\/p>\n

(h)\u80f6\u4f53\u6eb6\u6db2\u7684\u5149\u5b66\u56fe\u50cf\u548cCo-UH\u7684\u5f62\u6001\u548c\u7ed3\u6784\u7684\u793a\u610f\u56fe\u3002\u7ea2\u8272\u539f\u5b50\u548c\u84dd\u8272\u539f\u5b50\u5206\u522b\u662fO\u539f\u5b50\u548cCo\u539f\u5b50\uff1b<\/p>\n

\u56fe2. CoV-UAH\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a\u548cb) CoV-UAH\u4e2d\u7684Co 2p\u548cV 2p\u7684XPS\u56fe\uff1b<\/p>\n

(c) CoV-UAH, \u548c\u53c2\u8003\u6750\u6599Co(OH)2<\/sub>\u548cCoOOH\u7684Co K-edge XANES\u56fe\uff1b<\/p>\n

(d) CoV-UAH\u548c\u53c2\u8003\u6750\u6599VO2<\/sub>, V2<\/sub>O5<\/sub>\u548cCo3<\/sub>V2<\/sub>O8<\/sub> V K-edge XANES\u56fe\uff1b<\/p>\n

\u56fe3. CoV-UAH OER\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u7ecfIR\u6821\u6b63\u7684CoV-UAH, Co-UH, V2<\/sub>O5<\/sub>, CoV-C\u548cIrO2<\/sub>\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

(b)\u5728N2<\/sub>\u9971\u548c1 M KOH\u4e2d\uff0c\u4f7f\u7528\u65cb\u8f6c\u73af\u5f62\u76d8\u7535\u6781\u6d4b\u91cf(\u793a\u610f\u56fe\u5982\u63d2\u56fe\u6240\u793a)\u5bf9CoV-UAH\u6cd5\u62c9\u7b2c\u6548\u7387\u8fdb\u884c\u6d4b\u8bd5\uff1b<\/p>\n

(c)\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b<\/p>\n

(d)\u57280.18 V\u65f6\u76f8\u5bf9\u4e8e\u94f6\/\u6c2f\u5316\u94f6 (\u25b3J = Ja – Jc ) \u7684\u5145\u7535\u7535\u6d41\u5bc6\u5ea6\u4e0e\u626b\u63cf\u901f\u7387\u7684\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n

\u56fe4. CoV-UAH\u7684\u539f\u4f4dXAS\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a\u548cb) Co – K – edge XANES\u6536\u96c6\u7684\u521d\u59cb\u72b6\u6001\u3001CoV-UAH\u548cCoV-C\u7684\u539f\u4f4d\u72b6\u6001\u4ee5\u53caCoOOH\u4f5c\u4e3a\u914d\u5bf9\u7269\u7684\u6570\u636e\uff1b<\/p>\n

(c\u548cd) V . K – edge XANES\u6536\u96c6\u7684\u521d\u59cb\u72b6\u6001\u3001CoV-UAH\u548cCoV-C\u7684\u539f\u4f4d\u72b6\u6001\u4ee5\u53caVO2<\/sub>\u4f5c\u4e3a\u5bf9\u5e94\u7269\u7684\u6570\u636e\uff1b<\/p>\n

\u56fe5. DFT\u8ba1\u7b97<\/strong><\/p>\n

\"\"(a) \u5efa\u7acb\u7684\u6a21\u578b\u548c\u5438\u9644\u51e0\u4f55\u5f62\u72b6\uff1b<\/p>\n

(b) \u81ea\u7531\u80fd\u56fe\uff1b<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u91c7\u7528\u7b80\u5355\u7684\u4e00\u6b65\u5171\u6c89\u6dc0\u6cd5\u5236\u5907\u4e86\u8d85\u8584\u975e\u6676\u6001CoV-UAH\uff0c\u8be5\u50ac\u5316\u5242\u5bf9OER\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u5408\u6210\u7684\u975e\u6676\u6001\u50ac\u5316\u5242\u5177\u6709\u4e8c\u7ef4\u8d85\u8584\u7279\u6027\uff0cV\u65cf\u63ba\u6742\u5747\u5300\u3002\u5b83\u5177\u6709\u5c06\u5176\u539f\u59cb\u76f8\u8f6c\u79fb\u5230\u5177\u6709\u4f18\u5316\u6d3b\u6027Co\u72b6\u6001\u7684\u771f\u5b9e\u6d3b\u6027\u76f8\u7684\u80fd\u529b\uff0c\u4e0e\u5177\u6709\u521a\u6027\u6784\u8c61\u7684\u7ed3\u6676\u7ed3\u6784\u5f62\u6210\u9c9c\u660e\u5bf9\u6bd4\u3002\u8fd9\u79cd\u7075\u6d3b\u6027\u786e\u4fdd\u5b9e\u73b0\u9ad8\u6d3b\u6027\u548c\u957f\u671f\u7a33\u5b9a\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u8bbe\u8ba1\u9ad8\u7ea7\u50ac\u5316\u5242\u65f6\uff0c\u5e94\u8003\u8651\u8f6c\u5316\u4e3a\u6d3b\u6027\u76f8\u7684\u80fd\u529b\u548c\u5f62\u6210\u7684\u6d3b\u6027\u76f8\u7684\u50ac\u5316\u80fd\u529b\u3002\u4f5c\u8005\u7684\u5de5\u4f5c\u5c55\u793a\u4e86\u8d85\u8584\u975e\u6676\u50ac\u5316\u6750\u6599\u7684\u5e7f\u9614\u524d\u666f\uff0c\u4e30\u5bcc\u4e86\u5bf9\u7535\u50ac\u5316\u53cd\u5e94\u7ed3\u6784-\u6d3b\u6027\u5173\u7cfb\u7684\u8ba4\u8bc6\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ultrathin amorphous cobalt\u2013vanadium hydr(oxy)oxide catalysts for the oxygen evolution reaction<\/a>\uff0c(Energy & Environmental Science, 2018, DOI: 10.1039\/c8ee00611c)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

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