{"id":140227,"date":"2018-05-29T06:30:42","date_gmt":"2018-05-28T22:30:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=140227"},"modified":"2018-05-27T16:47:29","modified_gmt":"2018-05-27T08:47:29","slug":"%e5%89%91%e6%a1%a5%e5%a4%a7%e5%ad%a6jacs%ef%bc%9a%e8%87%aa%e4%b8%8b%e8%80%8c%e4%b8%8a%e5%bd%a2%e6%88%90mof-%e5%a4%9a%e9%9d%a2%e4%bd%93%e7%9a%84%e5%a4%9a%e5%b1%82%e6%ac%a1%e7%a2%b3%e7%bb%93%e6%9e%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=140227","title":{"rendered":"\u5251\u6865\u5927\u5b66JACS\uff1a\u81ea\u4e0b\u800c\u4e0a\u5f62\u6210MOF-\u591a\u9762\u4f53\u7684\u591a\u5c42\u6b21\u78b3\u7ed3\u6784"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

MOF\u662f\u91d1\u5c5e\u548c\u6709\u673a\u914d\u4f53\u901a\u8fc7\u5316\u5b66\u952e\u914d\u4f4d\uff0c\u5f62\u6210\u7684\u591a\u5b54\u7ed3\u6784\u6750\u6599\u3002\u5b83\u5177\u6709\u5927\u7684\u6bd4\u8868\u9762\u79ef\u3001\u5171\u4ef7\u952e\u548c\u914d\u4f4d\u952e\u7684\u7279\u70b9\uff0c\u5176\u50a8\u80fd\u56f0\u96be\u8f83\u591a\uff0c\u6750\u6599\u7ed3\u6784\u4e0d\u7a33\u5b9a\uff0c\u56e0\u6b64\u5f00\u53d1MOF\u884d\u751f\u7269\u6750\u6599\u662f\u975e\u5e38\u6709\u610f\u4e49\u7684\u3002\u4e09\u7ef4\u78b3\u57fa\u7ed3\u6784\u5177\u6709\u7279\u5b9a\u673a\u68b0\u548c\u80fd\u91cf\u5b58\u50a8\u7279\u6027\uff0c\u5e38\u7528\u7684\u65b9\u6cd5\u662f\u5c06\u9009\u5b9a\u7684\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u4e0e\u50ac\u5316\u91d1\u5c5e\u7ed3\u5408\u540e\u78b3\u5316\u3002\u8fd9\u79cd\u65b9\u6cd5\u6b65\u9aa4\u8f83\u591a\uff0c\u7a0b\u5e8f\u590d\u6742\uff0c\u800c\u4e14MOF\u78b3\u6750\u6599\u7684\u5f62\u8c8c\u6ca1\u6709\u660e\u663e\u53d8\u5316\u3002\u81ea\u4e0b\u800c\u4e0a\u7684\u5408\u6210\u65b9\u6cd5\u5236\u5907MOF\u78b3\u6750\u6599\uff0c\u5177\u6709\u5236\u5907\u65b9\u6cd5\u7b80\u5355\u3001\u6210\u5206\u53ef\u8c03\u548c\u591a\u5c42\u6b21\u5316\u7684\u7ed3\u6784\u7279\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u82f1\u56fd\u5251\u6865\u5927\u5b66\u7684Stoyan K. Smoukov<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u7b56\u7565\uff0c\u901a\u8fc7\u5ba2\u4f53\u5305\u88f9\u4f53\u548c\u9ad8\u6e29MOF-\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\uff0c\u5c06\u5e38\u89c1\u7684MOF\u8f6c\u53d8\u6210\u590d\u6742\u7684\u78b3\u57fa\u7845\u85fb\u72b6\u7b49\u7ea7\u7ed3\u6784\u3002\u5c06\u5ba2\u4f53\u91d1\u5c5e\u76d0\u5f15\u5165HKUST-1\u578bMOF\u4e2d\uff0c\u4ee5\u4ea7\u751f\u5177\u6709\u4e8c\u5230\u56db\u7ea7\u7ed3\u6784\u5c42\u6b21\u7684\u78b3\u57fa\u7eb3\u7c73\u7845\u85fb\u65cf\u3002\u4f5c\u8005\u901a\u8fc7\u63a7\u5236MOF\u548c\u5ba2\u4f53\u7684\u5316\u5b66\u53d8\u5316\uff0c\u8fdb\u884c\u5f62\u8c8c\u8c03\u63a7\uff0c\u8fdb\u800c\u6539\u53d8\u5176\u5f62\u6210\u673a\u5236\u3002\u4f5c\u8005\u901a\u8fc7\u63a7\u5236MOF\u548c\u5ba2\u4f53\u5316\u5b66\u5f62\u8c8c\u7684\u6539\u53d8\uff0c\u8fdb\u800c\u5206\u6790\u5176\u5f62\u6210\u673a\u5236\u3002\u8bc1\u660e\u8fd9\u4e9b\u7ed3\u6784\u5177\u6709\u4f5c\u4e3a\u5feb\u901f\u5145\u7535\u7684\u9502\u79bb\u5b50\u7535\u6c60\u9633\u6781\u7684\u72ec\u7279\u4f18\u52bf\u3002\u5176\u53ef\u8c03\u7ec4\u5206\u7684\u7279\u70b9\uff0c\u6709\u52a9\u4e8e\u8fdb\u4e00\u6b65\u7814\u7a76\u53cd\u5e94\u673a\u5236\uff0c\u4fc3\u8fdb\u7531MOF-\u5ba2\u4f53\u5f62\u6210\u78b3\u57fa\u7ed3\u6784\u7684\u591a\u6837\u6027\u53d1\u5c55\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Bottom-up Formation of Carbon-Based Structures with Multilevel Hierarchy from MOF\u2212Guest Polyhedra<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Journal of the American Chemical Society<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 <\/strong>\u663e\u5fae\u7ed3\u6784\u53ca\u5176\u5236\u5907\u793a\u610f\u56fe<\/strong><\/p>\n

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\uff08b\uff09\u7145\u70e7800\u2103\u540e\uff0cHKUST\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09(NH4<\/sub>)2<\/sub>MoS4<\/sub>\/DMF@HKUST-1\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09\u7ea4\u7ef4\/\u7f51\u72b6\u7269\u7684\u3001\u9ad8\u5ea6\u626d\u66f2\u7684\u78b3\u57fa\u7eb3\u7c73\u7845\u85fb\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 2 <\/strong>\u78b3\u57fa\u7eb3\u7c73\u7845\u85fb\u7684\u663e\u5fae\u7ed3\u6784\u8868\u5f81\u56fe<\/strong><\/p>\n

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\uff08a\uff0cb\uff09\u7f51\u7edc\u72b6\u8868\u9762\u7684SE-SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09\u6837\u54c1\u8868\u9762\u7684DF-STEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff0ce\uff09\u6837\u54c1\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

\uff08f\uff0cg\uff09\u7ea4\u7ef4\u72b6\u7ed3\u6784\u7684SE-SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08h\uff09\u7ea4\u7ef4\u72b6\u7ed3\u6784\u7684DF-STEM\u56fe\u50cf\uff1b<\/p>\n

\uff08i\uff0cj\uff09\u7ea4\u7ef4\u72b6\u7ed3\u6784\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

\uff08k\uff09\u7f51\u7edc\u72b6\u548c\u7ea4\u7ef4\u72b6\u7ed3\u6784\u8fde\u63a5\u5904\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08l\uff09C 1s\u7684XPS\u56fe\u8c31\uff1b<\/p>\n

\uff08m\uff09Mo 3d+S 2s\u7684XPS\u56fe\u8c31\uff1b<\/p>\n

\uff08n\uff09S 2P1\/2<\/sub>\u7684XPS\u56fe\u8c31\u3002<\/p>\n

\u56fe<\/strong> 3 MOF<\/strong>\u53ca<\/strong>MOF-<\/strong>\u5ba2\u4f53\u78b3\u5316\u540e\u7684\u7eb3\u7c73\u7845\u85fb\u7684<\/strong>SEM<\/strong>\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09HKUST-1\uff08Cu\uff09\u548c\uff08NH4<\/sub>\uff092<\/sub>WS4<\/sub>\/DMF@HKUST\uff08Cu\uff09\u78b3\u5316\u540e\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b\uff09HKUST-1\uff08Zn\uff09\u548c\uff08NH4<\/sub>\uff092<\/sub>WS4<\/sub>\/DMF@HKUST\uff08Zn\uff09\u78b3\u5316\u540e\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 4 <\/strong>\u7eb3\u7c73\u7845\u85fb\u5206\u7ea7\u7ed3\u6784\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u6027\u80fd\u56fe<\/strong><\/p>\n

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\uff08a\uff09\u6750\u6599\u7684\u5206\u7ea7\u7ed3\u6784\u5bf9\u7535\u6c60\u5feb\u901f\u5145\u653e\u7535\u7684\u5f71\u54cd\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u57282 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08c\uff09\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u56fe\uff1b<\/p>\n

\uff08d\uff09\u57282 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4f5c\u8005\u91c7\u7528\u4e00\u79cd\u7b80\u5355\u7684\u81ea\u4e0b\u800c\u4e0a\u7684\u70ed\u5316\u5b66\u5904\u7406\u65b9\u6cd5\uff0c\u83b7\u5f97\u4e86\u5177\u6709\u591a\u7ea7\u5c42\u6b21\u7ed3\u6784\u7684\u78b3\u57fa\u7ed3\u6784\u3002\u8fd9\u79cd\u7ed3\u6784\u901a\u5e38\u7531MOF\u524d\u4f53\u7684\u5ba2\u4f53-MOF\u914d\u5408\u7269\u7ec4\u6210\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0c\u5c11\u91cf\u7684\u5ba2\u4f53\u4f7fMOF\u4e3b\u4f53\u7ecf\u5386\u5f62\u6001\u8f6c\u53d8\uff0c\u5f62\u6210\u5ba2\u4f53\/\u4e3b\u4f53\u7684\u78b3\u8d28\u6750\u6599\u3002\u5c3d\u7ba1\u4f5c\u8005\u4ec5\u4ec5\u63a2\u7d22\u4e86\u90e8\u5206Cu\/Zn-MOF\u4e3b\u4f53\uff0c\u4f46\u662fMOF\u5ba2\u4f53\u7cfb\u7edf\u4e30\u5bcc\uff0c\u53ef\u4ee5\u83b7\u5f97\u79cd\u7c7b\u7e41\u591a\u7684\u78b3\u57fa\u7ed3\u6784\u3002\u672c\u6587\u5bf9\u8fd9\u79cd\u9ad8\u6e29\u5ba2\u4f53\u8bf1\u5bfc\u7684\u73b0\u8c61\u8fdb\u884c\u4e86\u521d\u6b65\u89c2\u5bdf\uff0c\u6750\u6599\u7684\u5f62\u6210\u673a\u5236\u4ecd\u9700\u8981\u8fdb\u4e00\u6b65\u7814\u7a76\u3002\u4f8b\u5982\uff0cMOF\u7684\u62d3\u6251\u7ed3\u6784\u548c\u5b54\u9053\u5f15\u8d77\u7684\u5206\u5b50\u9650\u5236\uff0c\u5728\u6750\u6599\u5236\u5907\u8fc7\u7a0b\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u6750\u6599\u7684\u83b7\u5f97\u6210\u672c\u8f83\u4f4e\uff0c\u5177\u6709\u5546\u4e1a\u5e94\u7528\u524d\u666f\uff0c\u6709\u5229\u4e8eMOFs\u78b3\u6750\u6599\u7684\u4ea7\u4e1a\u5316\u53d1\u5c55\u3002\u672c\u6587\u4f5c\u8005\u540c\u65f6\u8bc1\u660e\u4e86\u5206\u5c42\u78b3\u8d28\u7ed3\u6784\uff0c\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u5177\u6709\u5feb\u901f\u5145\u7535\u80fd\u529b\u3002\u56e0\u6b64\uff0cMOF-\u5ba2\u4f53\u884d\u751f\u7684\u529f\u80fd\u6750\u6599\u7684\u5206\u5c42\u7ed3\u6784\uff0c\u80fd\u591f\u7ed3\u5408\u5404\u79cd\u65e0\u673a\u5143\u7d20\/\u5316\u5408\u7269\uff0c\u5728\u672a\u6765\u7684\u50a8\u80fd\uff0c\u80fd\u91cf\u8f6c\u6362\u548c\u4f20\u611f\u4e2d\u5177\u6709\u5f88\u9ad8\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Bottom-up Formation of Carbon-Based Structures with Multilevel Hierarchy from MOF\u2212Guest Polyhedra<\/strong><\/a>\uff08JACS, 2018, DOI: 10.1021\/jacs.8b02411\uff09\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/p>\n

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\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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