{"id":138427,"date":"2018-05-28T06:30:35","date_gmt":"2018-05-27T22:30:35","guid":{"rendered":"\/\/m.iemloyee.com\/?p=138427"},"modified":"2018-05-27T16:33:59","modified_gmt":"2018-05-27T08:33:59","slug":"jacs-%e5%8d%95%e5%b1%82tic3%e7%94%a8%e4%ba%8e%e9%ab%98%e6%af%94%e5%ae%b9%e9%87%8f%e7%9a%84%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=138427","title":{"rendered":"JACS: \u5355\u5c42TiC3\u7528\u4e8e\u9ad8\u6bd4\u5bb9\u91cf\u7684\u94a0\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u6700\u6210\u529f\u7684\u6e05\u6d01\u548c\u9ad8\u6548\u80fd\u91cf\u5b58\u50a8\u8bbe\u5907\u4e4b\u4e00\uff0c\u88ab\u5e7f\u6cdb\u7528\u4e8e\u5404\u79cd\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u3002\u7136\u800c\uff0c\u9502\u5728\u5730\u7403\u4e0a\u7684\u50a8\u5b58\u91cf\u76f8\u5f53\u6709\u9650\u3002\u6309\u76ee\u524d\u6bcf\u5e7421280\u5428\u7684\u6d88\u8017\u7387\uff0c\u73b0\u6709\u7684\u9502\u6e90\u53ea\u80fd\u7ef4\u6301\u7ea665\u5e74\u3002\u94a0\u662f\u5730\u58f3\u4e2d\u7b2c\u56db\u4e30\u5bcc\u7684\u91d1\u5c5e\u5143\u7d20\uff0c\u4e3a\u5f00\u53d1\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u63d0\u4f9b\u4e86\u5927\u91cf\u7684\u94a0\u6e90\u3002\u94a0\u4e0e\u9502\u5177\u6709\u76f8\u4f3c\u7684\u7535\u5316\u5b66\u6027\u8d28\uff0c\u8fd9\u610f\u5473\u7740LIBs\u4e2d\u7684\u4e00\u4e9b\u6210\u719f\u6280\u672f\u53ef\u4ee5\u8fc1\u79fb\u5230SIBs\u3002\u6b64\u5916\uff0cSIBs\u7684\u5b89\u5168\u6027\u8fdc\u4f18\u4e8eLIBs\u3002\u56e0\u6b64\uff0cSIBs\u6210\u4e3a\u80fd\u6e90\u50a8\u5b58\u8bbe\u5907\u7684\u6700\u4f73\u5019\u9009\u8005\u4e4b\u4e00\u3002\u7136\u800c\uff0cSIBs\u4ecd\u5904\u4e8e\u6700\u521d\u7684\u53d1\u5c55\u9636\u6bb5\uff0c\u9762\u4e34\u8bb8\u591a\u95ee\u9898\u3002\u73b0\u6709\u9633\u6781\u6750\u6599\u6027\u80fd\u5df2\u6210\u4e3a\u5236\u7ea6SIBs\u6027\u80fd\u63d0\u9ad8\u7684\u4e3b\u8981\u969c\u788d\u3002\u5df2\u62a5\u9053\u7528\u4e8eSIBs\u7684\u5404\u79cd\u6539\u8fdb\u7684C\u57fa\u9633\u6781\u6750\u6599\uff08\u4f8b\u5982\u81a8\u80c0\u77f3\u58a8\uff0c\u786c\u78b3\uff0c\u5d4c\u5165\u78b3\u4e2d\u7684\u9521\u7eb3\u7c73\u9897\u7c92\u548c\u5206\u5c42\u591a\u5b54\u78b3\/\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\uff09\u3002\u4f46\u662f\uff0c\u5b83\u4eec\u7684\u6bd4\u5bb9\u91cf\u8fdc\u8fdc\u4e0d\u80fd\u4ee4\u4eba\u6ee1\u610f\u3002\u5c3d\u7ba1IV\u65cf\u548cV\u65cf\u5143\u7d20\u6750\u6599\uff08\u5982Ge\uff0cSn\uff0cPb\u548cSb\uff09\u7684\u6bd4\u5bb9\u91cf\u6709\u6240\u63d0\u9ad8\uff0c\u4f46\u5b83\u4eec\u7684\u500d\u7387\u80fd\u529b\u6781\u5927\u5730\u9650\u5236\u4e86SIBs\u7684\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u5bf9\u4e8eSIBs\u6765\u8bf4\uff0c\u5f00\u53d1\u5408\u9002\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u9633\u6781\u6750\u6599\u53d8\u5f97\u76f8\u5f53\u7d27\u8feb\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u7269\u7406\u5b66\u9662\u6768\u56fd\u6625\u6559\u6388\u56e2\u961f<\/strong>\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u7684\u7fa4\u4f53\u667a\u80fd\u7ed3\u6784\u8ba1\u7b97\u53d1\u73b0\u7406\u60f3\u7684\u9633\u6781\u6750\u6599\uff0c\u5373\u91d1\u5c5eTiC3<\/sub>\u5355\u5c42\uff0c\u4e0d\u4ec5\u5177\u67091278 mA h g-1<\/sup>\u7684\u9ad8\u5b58\u50a8\u5bb9\u91cf\uff0c\u800c\u4e14\u5177\u6709\u4f4e\u52bf\u5792\u80fd\u91cf\u548c\u5f00\u8def\u7535\u538b\u3002TiC3<\/sub>\u5438\u9644\u4e24\u5c42Na\u539f\u5b50\u540e\u4ecd\u4fdd\u6301\u91d1\u5c5e\u6027\u8d28\uff0c\u4f7f\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5177\u6709\u826f\u597d\u7684\u5bfc\u7535\u6027\u3002\u6b64\u5916\uff0c\u9ad8\u7194\u70b9\u548c\u4f18\u8d8a\u7684\u52a8\u529b\u5b66\u7a33\u5b9a\u6027\u6709\u5229\u4e8e\u5b9e\u9645\u5e94\u7528\u3002\u5176\u4f18\u5f02\u7684\u6027\u80fd\u4e3b\u8981\u5f52\u56e0\u4e8eTiC3<\/sub>\u5355\u5c42\u4e2d\u5b58\u5728n<\/em>-\u8054\u82ef\u5355\u5143\u3002\u591a\u952e\u5171\u5b58\uff08\u4f8b\u5982\u5171\u4ef7\u952e\uff0c\u79bb\u5b50\u952e\u548c\u91d1\u5c5e\u952e\uff09\u4f7f\u5f97TiC3<\/sub>\u5355\u5c42\u663e\u793a\u51fa\u9ad8\u5185\u805a\u80fd\uff0c\u8fd9\u4e3a\u5b9e\u9a8c\u5408\u6210\u63d0\u4f9b\u53ef\u884c\u6027\u3002\u4e0eTiC3<\/sub>\u76f8\u6bd4\uff0c\u5b98\u80fd\u5316\u7684TiC3<\/sub>O\u663e\u793a\u66f4\u9ad8\u7684\u5b58\u50a8\u5bb9\u91cf; \u540c\u65f6\uff0c\u5b83\u4fdd\u6301\u51e0\u4e4e\u76f8\u540c\u7684\u52bf\u5792\u3002\u8fd9\u4e0e\u5bcc\u542b\u91d1\u5c5e\u7684MXenes\u5f62\u6210\u9c9c\u660e\u5bf9\u6bd4\u3002TiC3<\/sub>\u4e0d\u4ec5\u663e\u793a\u51fa\u4f18\u5f02\u7684\u70ed\u548c\u52a8\u6001\u7a33\u5b9a\u6027\uff0c\u800c\u4e14\u663e\u793a\u51fa\u9ad8\u7535\u5b50\u548c\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u56e0\u6b64\uff0cTiC3<\/sub>\u5355\u5c42\u662fSIBs\u7684\u8f83\u597d\u7684\u9633\u6781\u6750\u6599\uff0c\u7b49\u5f85\u8fdb\u4e00\u6b65\u5b9e\u9a8c\u9a8c\u8bc1\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u201cTiC3<\/sub> Monolayer with High Specific Capacity for Sodium-Ion Batteries\u201d\u4e3a\u9898\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u00a0<\/strong>TiC3<\/sub><\/strong>\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5177\u6709C2\/m\u5bf9\u79f0\u6027\u7684TiC3<\/sub>\u5355\u5c42\u7684\u4f18\u5316\u7ed3\u6784<\/p>\n

\uff08b\uff09TiC3<\/sub>\u5355\u5c42\u4e2d\u7684\u201cZ\u201d\u5b57\u5f62Ti\u539f\u5b50\u94fe\u548cn<\/em>-\u8054\u82ef\u7ed3\u6784\u5355\u5143<\/p>\n

\uff08c\uff09TiC3<\/sub>\u5355\u5c42\u7684ELF\u56fe<\/p>\n

\u56fe\u4e8c\u00a0<\/strong>TiC3<\/sub><\/strong>\u5d4c<\/strong>Na<\/strong>\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Na\u5438\u9644\u5728\u4e94\u5143TiC4\u73af\u7684\u4e2d\u5fc3\uff0c\u547d\u540d\u4e3aA1<\/p>\n

\uff08b\uff09Na\u4f4d\u4e8eC6\u73af\u7684\u4e2d\u5fc3\uff0c\u5982A2<\/p>\n

\uff08c\uff09Na\u5728TiC3<\/sub>\u5355\u5c42\u4e0a\u6269\u6563\u7684\u8fc1\u79fb\u9014\u5f84<\/p>\n

\uff08d\uff09\u8def\u5f84I\u548c\u8def\u5f84II\u7684\u76f8\u5e94\u7684\u6269\u6563\u80fd\u91cf\u52bf\u5792\u5206\u5e03<\/p>\n

\u56fe\u4e09\u00a0<\/strong>\u4e0d\u540c<\/strong>Na<\/strong>\u6d53\u5ea6\u4e0b\u7684<\/strong>TiC3<\/sub>Nan<\/sub><\/strong>\u7684\u5404\u79cd\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u57280K\uff0cTiC3<\/sub>Nan<\/sub><\/em>\uff08n<\/em> =1-4\uff09\u76f8\u5bf9\u4e8eNa\u5355\u8d28\u548cTiC3<\/sub>\u5355\u5c42\u7684\u76f8\u5bf9\u7a33\u5b9a\u6027<\/p>\n

\uff08b\uff0ce\uff09\u5728TiC3<\/sub>Nan<\/sub><\/em>\u4e2d\u5177\u6709\u4e0d\u540cNa\u6d53\u5ea6\u7684\u6700\u7a33\u5b9a\u7ed3\u6784<\/p>\n

\u56fe\u56db TiC3<\/sub>O\u5355\u5c42\u7684\u7ed3\u6784\u4ee5\u53ca\u5d4c\u7eb3\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09TiC3<\/sub>O\u5355\u5c42\u7684\u4f18\u5316\u7ed3\u6784\u3002<\/p>\n

\uff08b\uff09TiC3<\/sub>O\u5355\u5206\u5b50\u5c42\u7684\u4e0d\u7b49\u4ef7\u5438\u9644\u4f4d\u70b9\uff0c\u547d\u540d\u4e3aB1\uff0cB2\u548cB3\u3002\u5728TiC3<\/sub>O\u5355\u5c42\u4e0a\u8003\u8651\u7684Na\u6269\u6563\u8def\u5f84\u3002<\/p>\n

\uff08c\uff09\u8def\u5f84I\u548c\u8def\u5f84II\u7684\u76f8\u5e94\u6269\u6563\u80fd\u91cf\u52bf\u5792\u5206\u5e03\u3002<\/p>\n

\uff08d\uff09TiC3<\/sub>ONa5<\/sub>\u7684\u4f18\u5316\u7ed3\u6784<\/p>\n

\u56fe\u4e94 \u5177\u6709\uff08<\/strong>a<\/strong>\uff09\u5355\u5c42\u548c\uff08<\/strong>b<\/strong>\uff09\u4e24\u5c42<\/strong>Na<\/strong>\u539f\u5b50\u7684\u88f8<\/strong>TiC3<\/sub><\/strong>\u7684<\/strong>ELF<\/strong>\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u5728\u7b2c\u4e00\u6027\u539f\u7406\u7684\u7fa4\u4f53\u667a\u80fd\u7ed3\u6784\u8ba1\u7b97\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u4e86TiC3<\/sub>\u5355\u5c42\u7684\u51e0\u4f55\u7ed3\u6784\uff0c\u7535\u5b50\u6027\u8d28\u548c\u94a0\u79bb\u5b50\u7684\u50a8\u5b58\u548c\u8fc1\u79fb\u80fd\u529b\u3002\u72ec\u7279\u7684n<\/em>-\u8054\u82ef\u5355\u5143\u63d0\u4f9b\u8f83\u5927\u7684\u5438\u9644\u9762\u79ef\u548c\u8f83\u5f3a\u7684\u94a0\u79bb\u5b50\u5438\u9644\u80fd\u529b\uff0c\u5bfc\u81f4\u88f8\u9732\u7684\u548c\u5b98\u80fd\u5316\u7684TiC3<\/sub>\u5355\u5c42\u90fd\u5177\u6709\u6781\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\u548c\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\u3002\u5373\u4f7f\u5728\u5806\u79ef\u6781\u9650\u7684\u6761\u4ef6\u4e0b\uff0cTiC3<\/sub>\u4e5f\u8868\u73b0\u51fa\u6bd4Ti3<\/sub>C2<\/sub>\u548cTiC2<\/sub>\u66f4\u597d\u7684\u9633\u6781\u6750\u6599\u6027\u80fd\u3002\u66f4\u6709\u8da3\u7684\u662f\uff0cTiC3<\/sub>\u5355\u5c42\u4e0d\u4ec5\u663e\u793a\u51fa\u9ad8\u7535\u5b50\u548c\u79bb\u5b50\u8fc1\u79fb\u7387\uff0c\u800c\u4e14\u8fd8\u663e\u793a\u8f83\u4f4e\u7684\u7535\u6781\u7535\u4f4d\u3002\u5171\u4ef7\u952e\u3001\u79bb\u5b50\u952e\u548c\u91d1\u5c5e\u952e\u5728TiC3<\/sub>\u4e2d\u7684\u5171\u5b58\u5bfc\u81f4\u9ad8\u5185\u805a\u80fd\uff0c\u8fd9\u5bf9\u4e8e\u5b9e\u9a8c\u5408\u6210\u662f\u6709\u5229\u7684\u3002\u58f0\u5b50\u8ba1\u7b97\u548c\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u6e05\u695a\u5730\u8868\u660eTiC3<\/sub>\u5355\u5c42\u5177\u6709\u826f\u597d\u7684\u52a8\u529b\u5b66\u548c\u70ed\u7a33\u5b9a\u6027\u3002\u603b\u4f53\u6765\u8bf4\uff0cTiC3<\/sub>\u5355\u5c42\u662fSIBs\u9633\u6781\u6750\u6599\u7684\u4f18\u79c0\u5019\u9009\u8005\u3002\u8be5\u53d1\u73b0\u5fc5\u5c06\u4f1a\u4e3a\u8fdb\u4e00\u6b65\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u5b9e\u9a8c\u548c\u7406\u8bba\u7814\u7a76\u6ce8\u5165\u65b0\u7684\u52a8\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong>TiC3 Monolayer with High Specific Capacity for Sodium-Ion Batteries<\/strong><\/a>\u201d(JACS, 2018, DOI: 10.1021\/jacs.8b02016)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u6768\u56fd\u6625\u6559\u6388\u4fee\u6b63\u4f9b\u7a3f\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

PS\uff1a\u6750\u6599\u4eba\u91cd\u78c5\u63a8\u51fa\u6750\u6599\u8ba1\u7b97\u89e3\u51b3\u65b9\u6848\uff0c\u7ec4\u5efa\u4e86\u4e00\u652f\u6765\u81ea\u5168\u56fd\u77e5\u540d\u9ad8\u6821\u8001\u5e08\u53ca\u4f01\u4e1a\u5de5\u7a0b\u5e08\u7684\u79d1\u6280\u987e\u95ee\u56e2\u961f\uff0c\u4e13\u6ce8\u4e8e\u4e3a\u5927\u5bb6\u89e3\u51b3\u5404\u7c7b\u8ba1\u7b97\u6a21\u62df\u9700\u6c42\u3002\u5982\u679c\u60a8\u6709\u9700\u6c42\uff0c\u6b22\u8fce\u626b\u4ee5\u4e0b\u4e8c\u7ef4\u7801\u63d0\u4ea4\u60a8\u7684\u9700\u6c42\u3002\u6216\u70b9\u51fb\u94fe\u63a5\u63d0\u4ea4<\/a>\uff0c\u6216\u76f4\u63a5\u8054\u7cfb\u5fae\u4fe1\u5ba2\u670d\uff08\u5fae\u4fe1\u53f7\uff1acailiaoren001\uff09<\/p>\n

\"\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u6700\u6210\u529f\u7684\u6e05\u6d01\u548c\u9ad8\u6548\u80fd\u91cf\u5b58\u50a8\u8bbe\u5907\u4e4b\u4e00\uff0c\u88ab\u5e7f\u6cdb\u7528\u4e8e\u5404\u79cd\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u3002\u7136\u800c\uff0c\u9502\u5728\u5730\u7403\u4e0a\u7684\u50a8\u5b58\u91cf\u76f8\u5f53\u6709\u9650\u3002\u6309\u76ee\u524d\u6bcf\u5e7421280\u5428\u7684\u6d88…<\/p>\n","protected":false},"author":7084,"featured_media":139500,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[18,97],"class_list":["post-138427","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-xinnengyuan","tag-computation"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/138427"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7084"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=138427"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/138427\/revisions"}],"predecessor-version":[{"id":140476,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/138427\/revisions\/140476"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/139500"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=138427"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=138427"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=138427"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}