{"id":138402,"date":"2018-05-14T06:30:58","date_gmt":"2018-05-13T22:30:58","guid":{"rendered":"\/\/m.iemloyee.com\/?p=138402"},"modified":"2018-05-13T21:36:36","modified_gmt":"2018-05-13T13:36:36","slug":"%e9%83%91%e5%a4%a7%e9%82%b5%e5%9b%bd%e8%83%9c%e5%9b%a2%e9%98%9fj-mater-chem-a%e6%b0%af%e5%8c%96%e7%89%a9%e6%8f%92%e5%b1%82mos2%e7%a0%94%e7%a9%b6%e9%95%81%e9%94%82%e6%b0%af%e4%b8%89%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=138402","title":{"rendered":"\u90d1\u5927\u90b5\u56fd\u80dc\u56e2\u961fJ Mater Chem A:\u6c2f\u5316\u7269\u63d2\u5c42MoS2\u7814\u7a76\u9541\u9502\u6c2f\u4e09\u79bb\u5b50\u534f\u540c\u8f93\u8fd0\u7684\u9ad8\u5bb9\u91cf\u9541\u7535\u6c60\u6b63\u6781\u6750\u6599"},"content":{"rendered":"<p><span style=\"color: #0000ff;\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u7531\u4e8e\u5730\u7403\u4e0a\u9502\u8d44\u6e90\u7684\u50a8\u91cf\u5e76\u4e0d\u4e30\u5bcc\uff0c\u7814\u7a76\u4e0b\u4e00\u4ee3\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u5e76\u63d0\u524d\u50a8\u5907\u5176\u76f8\u5173\u6280\u672f\uff0c\u5bf9\u4e8e\u9884\u9632\u672a\u6765\u53ef\u80fd\u5230\u6765\u7684\u50a8\u80fd\u5371\u673a\uff0c\u5177\u6709\u975e\u5e38\u91cd\u8981\u7684\u79d1\u5b66\u610f\u4e49\u3002\u91d1\u5c5e\u9541\u8d44\u6e90\u4e30\u5bcc\uff08\u50a8\u5b58\u91cf\u662f\u9502\u76841000\u500d\uff09\uff0c\u5e02\u573a\u4ef7\u683c\u4f4e\u5ec9\uff08\u4ec5\u4e3a\u91d1\u5c5e\u9502\u76847%\uff09\uff0c\u4ee5\u53ca\u5c0f\u7684\u79bb\u5b50\u534a\u5f84\uff080.66\u00c5\uff09\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u9541\u79bb\u5b50\u5e26\u6709\u4e24\u4e2a\u6b63\u7535\u8377\uff0c\u56e0\u6b64\u9541\u5177\u6709\u6781\u9ad8\u7684\u91cd\u91cf\u6bd4\u5bb9\u91cf\uff082205 mA h g<sup>-1<\/sup>\uff09\uff0c\u548c\u4f53\u79ef\u6bd4\u5bb9\u91cf\uff083833 mA h cm<sup>-1<\/sup>\uff09\uff0c\u540c\u65f6\u91d1\u5c5e\u9541\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u4e0e\u5b89\u5168\u6027\u5747\u4f18\u4e8e\u9502\u548c\u94a0\uff0c\u6240\u4ee5\u9541\u7535\u6c60\u88ab\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f46\u662f\uff0c\u7531\u4e8e\u9541\u79bb\u5b50\u5e26\u4e8c\u4ef7\u6b63\u7535\u8377\uff0c\u5b83\u4e0e\u7535\u6781\u6750\u6599\u4e2d\u7684\u975e\u91d1\u5c5e\u5143\u7d20\u6709\u5f88\u5f3a\u7684\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u3002\u4f8b\u5982\uff0c\u76f8\u5173\u7814\u7a76\u8bc1\u660e\u9541\u79bb\u5b50\u5728\u6c27\u5143\u7d20\u73af\u5883\u4e0b\u96be\u4ee5\u53d1\u751f\u63d2\u5c42\u8fc7\u7a0b\uff0c\u7531\u4e8e\u9541\u79bb\u5b50\u4e0e\u7535\u6781\u4e2d\u6c27\u539f\u5b50\u5f3a\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4f1a\u5f15\u8d77\u7535\u6781\u5927\u7684\u4f53\u79ef\u53d8\u5316\u548c\u590d\u6742\u7684\u76f8\u53d8\u8fc7\u7a0b\uff0c\u4ece\u800c\u5bfc\u81f4\u9541\u79bb\u5b50\u5728\u6b63\u6781\u4e2d\u8f93\u8fd0\u56f0\u96be\uff0c\u7535\u6c60\u6574\u4f53\u5faa\u73af\u7279\u6027\u5dee\u3002\u6545\u5982\u4f55\u5b9e\u73b0\u9541\u79bb\u5b50\u5728\u6b63\u6781\u6750\u6599\u7684\u5feb\u901f\u8f93\u8fd0\u88ab\u8ba4\u4e3a\u662f\u9541\u79bb\u5b50\u7535\u6c60\u6025\u9700\u89e3\u51b3\u7684\u5173\u952e\u95ee\u9898\u4e4b\u4e00\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p><strong>\u90d1\u5dde\u5927\u5b66\u90b5\u56fd\u80dc\u6559\u6388\u7814\u7a76\u56e2\u961f<\/strong>\u5728<strong>Journal of Materials Chemistry A<\/strong>\u53d1\u8868\u9898\u4e3a<strong>\u201cHigh-capacity cathodes for magnesium lithium chlorine tri-ion batteries through chloride intercalation in layered MoS<sub>2<\/sub>: a computational study\u201d<\/strong>\u7684\u6587\u7ae0\u3002\u00a0\u6587\u4e2d\u91c7\u7528\u6750\u6599\u57fa\u56e0\u7ec4\u65b9\u6cd5\uff0c\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u6c2f\u5316\u7269\u63d2\u5c42MoS<sub>2<\/sub>\u4e2d\u7684\u9541\u3001\u9502\u3001\u6c2f\u4e09\u79bb\u5b50\u534f\u540c\u4f5c\u7528\uff0c\u4ece\u800c\u5b9e\u73b0\u9541\u79bb\u5b50\u5feb\u901f\u8f93\u8fd0\u3002\u57fa\u672c\u8bbe\u8ba1\u601d\u8def\u5982\u4e0b\uff1a\uff081\uff09\u9009\u62e9\u5c42\u72b6\u786b\u5316\u7269\u4e3a\u8f7d\u4f53\uff1a\u786b\u5143\u7d20\u4e0e\u9541\u79bb\u5b50\u7684\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u9002\u4e2d\uff1b\uff082\uff09\u5229\u7528\u91d1\u5c5e\u79bb\u5b50\u95f4\u7684\u65a5\u529b\uff1a\u7528\u5bb9\u6613\u8f93\u8fd0\u7684\u9502\u79bb\u5b50\u9a71\u52a8\u9541\u79bb\u5b50\u7684\u8f93\u8fd0\uff1b\uff083\uff09\u6c2f\u79bb\u5b50\u6269\u5c42\u6280\u672f\uff1a\u6269\u5bbd\u5c42\u72b6\u786b\u5316\u7269\u7684\u5c42\u95f4\u8ddd\u79bb\uff0c\u8fdb\u4e00\u6b65\u5f31\u5316\u9541\u79bb\u5b50\u4e0e\u786b\u7684\u76f8\u4e92\u4f5c\u7528\uff1b\uff084\uff09\u6c2f\u79bb\u5b50\u8f93\u8fd0\uff1a\u5728\u7535\u573a\u4f5c\u7528\u4e0b\uff0c\u5b9e\u73b0\u9541\u3001\u9502\u3001\u6c2f\u4e09\u7c92\u5b50\u534f\u540c\u8f93\u8fd0\uff0c\u5176\u4e2d\u6c2f\u79bb\u5b50\u53d1\u751f\u8f93\u8fd0\uff0c\u80fd\u4e3a\u7535\u6c60\u63d0\u4f9b\u989d\u5916\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u8fd9\u79cd\u6b63\u6781\u6750\u6599\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u4e3a277.4 mA h g<sup>-1<\/sup>\uff0c\u540c\u65f6\u5728\u591a\u79bb\u5b50\u63d2\u5c42\u8fc7\u7a0b\u4e2d\u6b63\u6781\u4f53\u79ef\u53d8\u5316\u5f88\u5c0f\uff0c\u4ee5\u53ca\u5bf9\u5176\u79bb\u5b50\u8f93\u8fd0\u6027\u80fd\u505a\u51fa\u9884\u4f30\uff0c\u4e3a\u540e\u7eed\u5b9e\u9a8c\u7814\u7a76\u63d0\u4f9b\u53ef\u884c\u6027\u65b9\u6848\u3002<\/p>\n<p>\u00a0\u00a0 \u672c\u6587\u91c7\u7528\u7684\u6750\u6599\u57fa\u56e0\u7ec4\u65b9\u6cd5\u5305\u62ec\uff1a\uff081\uff09USPEX\u9057\u4f20\u7b97\u6cd5\uff1a\u641c\u7d22M<sub>x<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u5168\u5c40\u80fd\u91cf\u6700\u4f4e\u7ed3\u6784\uff1b\uff082\uff09\u5f62\u6210\u80fd\u8ba1\u7b97\uff1a\u9488\u5bf9\u76f8\u5173\u5316\u5408\u7269\uff0c\u505a\u51fa\u80fd\u91cf\u7a33\u5b9a\u6027\u4e0a\u7684\u8bc4\u4f30\uff1b\uff083\uff09\u58f0\u5b50\u5e26\u8ba1\u7b97\uff1a\u9488\u5bf9\u76f8\u5173\u5316\u5408\u7269\uff0c\u505a\u51fa\u7ed3\u6784\u7a33\u5b9a\u6027\u4e0a\u7684\u8bc4\u4f30\uff1b\uff084\uff09\u5206\u5b50\u52a8\u529b\u5b66AIMD\u8ba1\u7b97\uff1a\u5bf9\u4e8e\u76f8\u5173\u5316\u5408\u7269\uff0c\u505a\u51fa\u4f20\u8d28\u80fd\u529b\u7684\u8bc4\u4f30\uff1b\uff085\uff09HSE06\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\u8ba1\u7b97\uff1a\u9488\u5bf9\u76f8\u5173\u5316\u5408\u7269\uff0c\u505a\u51fa\u5bfc\u7535\u80fd\u529b\u7684\u8bc4\u4f30\uff1b\uff086\uff09\u5bf9\u7535\u538b\u5e73\u53f0\uff0c\u80fd\u91cf\u5bc6\u5ea6\u548c\u4f53\u79ef\u53d8\u5316\uff0c\u505a\u51fa\u9884\u4f30\u3002<\/p>\n<p>\u8be5\u5de5\u4f5c\u88ab\u9009\u4e3a\u5f53\u671f\u5185\u5c01\u9762\u8fdb\u884c\u62a5\u9053\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138409\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCAab.jpg\" alt=\"\" width=\"600\" height=\"434\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCAab.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCAab-300x217.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p><strong>\u56fe1\uff1a\u91c7\u7528USPEX\u9057\u4f20\u7b97\u6cd5\uff0c\u5168\u5c40\u57df\u641c\u7d22M<sub>x<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u6210\u5206\u7684\u6700\u7a33\u5b9a\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138404\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA1.jpg\" alt=\"\" width=\"600\" height=\"511\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA1-300x256.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u901a\u8fc7USPEX\u8fdb\u884c\u5168\u5c40\u57df\u641c\u7d22\u5f97\u5230M<sub>x<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u76f8\u5e94\u6210\u5206\u7684\u80fd\u91cf\u6700\u7a33\u5b9a\u7ed3\u6784\u3002(a)Mg<sub>0.25<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>, (b)Li<sub>0.25<\/sub>Mg<sub>0.25<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>,(c)Mg<sub>0.5<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>,(d)Li<sub>0.5<\/sub>Mg<sub>0.25<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>, (e) LiMoS<sub>2<\/sub>Cl<sub>0.5<\/sub>, and Li<sub>0.5<\/sub>Mg<sub>0.5<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5\u3002<\/sub><\/p>\n<p><strong>\u56fe2\uff1aM<sub>x<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u7684\u5f62\u6210\u80fd\u3001\u4f53\u79ef\u53d8\u5316\u548c\u7535\u538b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138405\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA2.jpg\" alt=\"\" width=\"600\" height=\"367\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA2-300x184.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09M<sub>x<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\uff08M=Li,Mg\u6216\u8005Li\/Mg\u6df7\u5408\uff09\u7684\u5f62\u6210\u80fd\u59cb\u7ec8\u4e3a\u8d1f\u503c\uff0c\u8868\u660e\u76f8\u5e94\u4ea7\u7269\u80fd\u91cf\u7a33\u5b9a\uff1b<\/p>\n<p>\uff08b\uff09\u7531\u4e8eCl\u79bb\u5b50\u63d2\u5c42\uff0c\u80fd\u6709\u6548\u7684\u514b\u670d\u6b63\u6781\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u5982M<sub>x<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u5c42\u95f4\u8ddd\u53d8\u5316\u4ec5\u4ec5\u4e3a2%\u3002\u5c0f\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u6709\u52a9\u4e8e\u63d0\u9ad8\u7535\u6781\u6750\u6599\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n<p>\uff08c\uff09\u7531\u4e8eMg<sup>2+<\/sup>\u548cCl<sup>&#8211;<\/sup>\u79bb\u5b50\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u6709\u52a9\u4e8e\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7535\u6781\u7684\u5de5\u4f5c\u7406\u8bba\u7535\u538b2.4 V v.s. Mg\uff0c\u8fdc\u9ad8\u4e8e\u5df2\u77e5\u7684\u786b\u5316\u7269\u5c42\u72b6\u9541\u7535\u4f53\u7cfb\u7684\u6700\u9ad8\u7535\u538b\u5e73\u53f01.1 V v.s. Mg\u3002<\/p>\n<p><strong>\u56fe3\uff1a<\/strong><strong>M<sub>x<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub><\/strong><strong>\u7684\u58f0\u5b50\u5e26<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138406\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA3.jpg\" alt=\"\" width=\"600\" height=\"829\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA3-217x300.jpg 217w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u901a\u8fc7\u58f0\u5b50\u80fd\u5e26\u7ed3\u6784\u8ba1\u7b97\uff0c\u5bf9\u6c2f\u79bb\u5b50\u63d2\u5c42\u76f8\u5173\u5316\u5408\u7269 (a)Mg<sub>0.25<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>, (b)Li<sub>0.25<\/sub>Mg<sub>0.25<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>, (c)Mg<sub>0.5<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>,(d)Li<sub>0.5<\/sub>Mg<sub>0.25<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>,(e)LiMoS<sub>2<\/sub>Cl<sub>0.5<\/sub>, (f) Li<sub>0.5<\/sub>Mg<sub>0.5<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u8bc4\u4f30\uff0c\u5176\u4e2d\u9ed1\u8272\u865a\u7ebf\u4ee3\u88680 THz\uff0c\u84dd\u8272\u865a\u7ebf\u4ee3\u8868\u53ef\u63a5\u53d7\u7684\u865a\u9891\u8303\u56f4-0.3 THz\u3002\u6c2f\u79bb\u5b50\u63d2\u5c42\u76f8\u5173\u4ea7\u7269\u5747\u8868\u73b0\u51fa\u597d\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u6b64\u539f\u6587\u4e2d\u901a\u8fc7\u4e0e\u65e0Cl<sup>&#8211;<\/sup>\u63d2\u5c42\u76f8\u5173\u5316\u5408\u7269\u7684\u58f0\u5b50\u5e26\u8fdb\u884c\u5bf9\u6bd4\uff0c\u53d1\u73b0\u6c2f\u79bb\u5b50\u63d2\u5c42\u540e\u58f0\u5b50\u5e26\u5f80\u4f4e\u9891\u533a\u57df\u79fb\u52a8\u660e\u663e\uff08\u5982\u7bad\u5934\u4f4d\u7f6e\u6240\u793a\uff09\u3002\u56e0\u6b64\uff0cCl<sup>&#8211;<\/sup>\u63d2\u5c42\u5bf9\u6676\u683c\u8f6f\u5316\u6709\u7740\u660e\u663e\u6548\u679c\uff0c\u53ef\u80fd\u6709\u52a9\u4e8e\u5e26\u7535\u79bb\u5b50\u53d1\u751f\u5feb\u901f\u7684\u8f93\u8fd0\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong><strong>\uff1a\u6269\u6563\u7cfb\u6570\uff08<\/strong><strong>AIMD<\/strong><strong>\uff09\u8ba1\u7b97<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138407\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA4.jpg\" alt=\"\" width=\"600\" height=\"450\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA4-300x225.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u901a\u8fc7AIMD\u5206\u5b50\u52a8\u529b\u5b66\uff0c\u8ba1\u7b97\u4e0d\u540c\u7ec4\u5206\u4e2d\u5404\u7c92\u5b50\u7684\u6269\u6563\u7cfb\u6570\u3002Mg<sub>0.5<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u4e2dCl<sup>&#8211;<\/sup> (\u7ea2\u7ebf)\u7684\u6269\u6563\u6fc0\u6d3b\u80fd\u4e3a0.6 eV\uff0c\u800c Mg<sup>2+<\/sup> \u79bb\u5b50(\u84dd\u7ebf)\u7684\u6269\u6563\u6fc0\u6d3b\u80fd\u4e3a0.86 eV\uff0c\u660e\u663e\u4f18\u4e8eMg<sub>0.5<\/sub>MoS<sub>2<\/sub>\u4e2d\u7684Mg<sup>2+<\/sup>\u79bb\u5b50\u8f93\u8fd0\u60c5\u51b5\uff08Ea=1.8 eV\uff09\u3002\u6b64\u5916\u5728Li\u7684\u9a71\u52a8\u4e0b\uff0cMg<sup>2+<\/sup> \u548cCl<sup>&#8211;<\/sup>\u79bb\u5b50\u80fd\u5b9e\u73b0\u5feb\u901f\u8f93\u8fd0\uff0c\u4f8b\u5982\u5728Li<sub>0.25<\/sub>Mg<sub>0.25<\/sub>MoS<sub>2<\/sub>Cl<sub>0.5<\/sub>\u4e2dLi<sup>+<\/sup> (\u9ed1\u7ebf), Mg<sup>2+<\/sup> (\u84dd\u7ebf) \u548cCl<sup>&#8211;<\/sup> (\u7ea2\u7ebf)\u7684\u6269\u6563\u6fc0\u6d3b\u80fd\u8d8b\u4e8e\u76f8\u7b49\uff0c\u7ea6\u4e3a 0.2 eV\u3002\u56e0\u6b64\uff0c\u6709\u5e0c\u671b\u5f62\u6210\u5982\u56fe5\u6240\u793a\u7684\uff0c\u4e09\u79bb\u5b50\u8f93\u8fd0\u9541\u7535\u6c60\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>5<\/strong><strong>\uff1a<\/strong><strong>Mg-Li-Cl<\/strong><strong>\u4e09\u7c92\u5b50\u7535\u6c60\u7684\u5efa\u7acb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138408\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA5.jpg\" alt=\"\" width=\"600\" height=\"454\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA5.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/JMCA5-300x227.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n<p>\u672c\u6587\u901a\u8fc7\u6750\u6599\u57fa\u56e0\u7ec4\u65b9\u6cd5\uff0c\u7cfb\u7edf\u7406\u8bba\u7814\u7a76\u4ee5\u6c2f\u5316\u7269\u63d2\u5c42MoS<sub>2<\/sub>\u4f5c\u4e3a\u9541\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u7684\u53ef\u80fd\u6027\u4ee5\u53ca\u5bf9\u5176\u5173\u952e\u6027\u80fd\u8fdb\u884c\u8bc4\u4f30\u3002\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u5728\u786b\u5316\u7269\u5c42\u72b6\u7ed3\u6784\u4e2d\uff0c\u80fd\u5b9e\u73b0\u9541\u3001\u9502\u3001\u6c2f\u4e09\u79bb\u5b50\u534f\u540c\u8f93\u8fd0\u3002\u5728\u5c42\u95f4\u63d2Cl<sup>&#8211;<\/sup>\u7684\u5e2e\u52a9\u4e0b\uff0c\u76f8\u5173\u4f53\u7cfb\u80fd\u91cf\u3001\u7ed3\u6784\u7a33\u5b9a\uff0c\u4f53\u79ef\u53d8\u5316\u5c0f\uff0c\u5e26\u7535\u79bb\u5b50\u7684\u6269\u6563\u6fc0\u6d3b\u80fd\u7ea6\u4e3a0.2 eV\u3002\u56e0\u6b64\uff0c\u8be5\u9541\u7535\u6b63\u6781\u6750\u6599\u6709\u671b\u8868\u73b0\u51fa\u597d\u7684\u5faa\u73af\u7279\u6027\uff0c\u4e3a\u9541\u91d1\u5c5e\u7535\u6c60\u4e43\u81f3\u5176\u4ed6\u91d1\u5c5e\u7535\u6c60\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u89c6\u89d2\u3002<\/p>\n<p><strong><span style=\"color: #0000ff;\">\u3010\u81f4\u8c22\u3011<\/span><\/strong><\/p>\n<p>\u8be5\u8bba\u6587\u7684\u5728\u90d1\u5dde\u5927\u5b66\u5343\u4eba\u6559\u6388\u90b5\u56fd\u80dc\u6307\u5bfc\u4e0b\u5b8c\u6210\uff0c\u8ba1\u7b97\u7ec4\u6210\u5458\u4e3a\u90d1\u5dde\u5927\u5b66\uff1a\u738b\u5353\u3001\u8f69\u654f\u6770\u3001\u5f90\u7ea2\u6770\u3001\u5f20\u5411\u4e39\u3001\u4e8e\u7389\u7136\u3002\u8be5\u5de5\u4f5c\u5728\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u90d1\u5dde\u5927\u5b66\u6750\u6599\u5b66\u9662\u3001\u90d1\u5dde\u65b0\u4e16\u7eaa\u6750\u6599\u57fa\u56e0\u7ec4\u5de5\u7a0b\u7814\u7a76\u9662\u7684\u8d44\u52a9\u4e0b\u5b8c\u6210\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p><strong>\u90b5\u56fd\u80dc<\/strong>\uff0c\u5343\u4eba\u8ba1\u5212\u521b\u65b0A\u7c7b\u6750\u6599\u5b66\u4e13\u5bb6\u3002\u66fe\u4efb\u804c\u82f1\u56fd\u8428\u5229\u5927\u5b66\u8d44\u6df1\u7814\u7a76\u5b98\uff1b\u5e03\u9c81\u5948\u5c14\u5927\u5b66\u6750\u6599\u5b66\u526f\u6559\u6388\uff1b\u82f1\u56fd\u535a\u5c14\u987f\u5927\u5b66\u8ba1\u7b97\u6750\u6599\u5b66\u6559\u6388\u3001\u65b0\u80fd\u6e90\u7814\u7a76\u6240\u6240\u957f\u3001\u5de5\u7a0b\u9662\u9662\u957f\u3001\u7406\u5de5\u53ca\u4f53\u80b2\u5b66\u90e8\u4e3b\u4efb\u7b49\uff1b\u82f1\u56fd\u6750\u6599\u5316\u5b66\u59d4\u5458\u4f1a\u59d4\u5458\u3001\u53ef\u6301\u7eed\u80fd\u6e90\u6750\u6599\u5de5\u4f5c\u7ec4\u6210\u5458\u30022010\u5e74\u5165\u9009\u56fd\u5bb6\u201c\u5343\u4eba\u8ba1\u5212\u201d\uff0c\u670d\u52a1\u4e8e\u90d1\u5dde\u5927\u5b66\uff0c\u521b\u5efa\u4e86\u4e2d\u82f1\u7eb3\u7c73\u591a\u529f\u80fd\u6750\u6599\u7814\u7a76\u4e2d\u5fc3\uff082012\uff09\uff0c\u5e76\u88ab\u8ba4\u5b9a\u4e3a\u6cb3\u5357\u7701\u4f4e\u78b3\u53ca\u73af\u5883\u6750\u6599\u56fd\u9645\u8054\u5408\u5b9e\u9a8c\u5ba4\uff082014\uff0c \u79d1\u6280\u5385\uff09\u3001 \u56fd\u5bb6\u7ea7\u4f4e\u78b3\u53ca\u73af\u4fdd\u6750\u6599\u667a\u80fd\u8bbe\u8ba1\u56fd\u9645\u8054\u5408\u5b9e\u9a8c\u5ba4\uff082015\uff0c \u79d1\u6280\u90e8\uff09\u30022016\u5e74\u4e8e\u201c\u4e2d\u539f\u667a\u8c37\u201d\u521b\u5efa\u90d1\u5dde\u65b0\u4e16\u7eaa\u6750\u6599\u57fa\u56e0\u7ec4\u5de5\u7a0b\u7814\u7a76\u9662\u3002\u521b\u529e\u4e86\u56fd\u9645\u671f\u520a\u300aEnergy &amp; Environmental Materials (EEM)\u300b\uff0c\u7531John Wiley &amp; Sons, Inc\u51fa\u7248\u3002\u56fd\u5bb6\u5343\u4eba\u8ba1\u5212\u3001\u957f\u6c5f\u5b66\u8005\u7b49\u9ad8\u7aef\u4eba\u624d\u9879\u76ee\u8bc4\u5ba1\u4e13\u5bb6\uff1b \u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u4e13\u5bb6\u59d4\u5458\u3002\u56fd\u9645\u80fd\u6e90\u6750\u6599\u4e0e\u7eb3\u7c73\u6280\u672f\u7cfb\u5217\u56fd\u9645\u4f1a\u8bae\u4e3b\u5e2d\u3002\u7814\u7a76\u96c6\u4e2d\u4e8e\u591a\u5c3a\u5ea6\u6750\u6599\u6a21\u62df\u53ca\u667a\u80fd\u6750\u6599\u8bbe\u8ba1\u3001\u7eb3\u7c73\u53ca\u8584\u819c\u6750\u6599\u5236\u5907\u6280\u672f\u3001\u5148\u8fdb\u6750\u6599\u8868\u5f81\u3001\u65b0\u80fd\u6e90\u53ca\u73af\u5883\u6e05\u6d01\u6750\u6599\u6280\u672f\u7b49\u3002\u53d1\u8868\u5305\u62ec\u300aNature\u300b\u5728\u5185\u7684\u56fd\u9645\u8457\u540d\u671f\u520a\u8bba\u6587200\u4f59\u7bc7\uff0c\u7533\u8bf7\u5e76\u83b7\u5f97\u56fd\u5185\u5916\u4e13\u522930\u4f59\u9879\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlehtml\/2018\/ta\/c8ta01050a\">High-capacity cathodes for magnesium lithium chlorine tri-ion batteries through chloride intercalation in layered MoS<sub>2<\/sub>: a computational study<\/a> (J. Mater. Chem. A, 2018, DOI: 10.1039\/c8ta01050a)<\/p>\n<p>\u672c\u6587\u7531<strong>\u90d1\u5dde\u5927\u5b66\u90b5\u56fd\u80dc\u6559\u6388\u56e2\u961f<\/strong>\u4f9b\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/strong><\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u5730\u7403\u4e0a\u9502\u8d44\u6e90\u7684\u50a8\u91cf\u5e76\u4e0d\u4e30\u5bcc\uff0c\u7814\u7a76\u4e0b\u4e00\u4ee3\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u5e76\u63d0\u524d\u50a8\u5907\u5176\u76f8\u5173\u6280\u672f\uff0c\u5bf9\u4e8e\u9884\u9632\u672a\u6765\u53ef\u80fd\u5230\u6765\u7684\u50a8\u80fd\u5371\u673a\uff0c\u5177\u6709\u975e\u5e38\u91cd\u8981\u7684\u79d1\u5b66\u610f\u4e49\u3002\u91d1\u5c5e\u9541\u8d44\u6e90\u4e30\u5bcc\uff08\u50a8&#8230;<\/p>\n","protected":false},"author":3727,"featured_media":138409,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2481,129],"class_list":["post-138402","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-fp","tag-battery"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/138402"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3727"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=138402"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/138402\/revisions"}],"predecessor-version":[{"id":138765,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/138402\/revisions\/138765"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/138409"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=138402"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=138402"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=138402"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}