{"id":138260,"date":"2018-05-11T08:42:38","date_gmt":"2018-05-11T00:42:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=138260"},"modified":"2018-05-11T08:42:38","modified_gmt":"2018-05-11T00:42:38","slug":"%e4%bb%8a%e6%97%a5science%e6%b0%a2%e9%94%ae%e7%9b%b8%e8%bd%ac%e7%a7%bb%e5%82%ac%e5%8c%96%e4%b8%ad%e7%9a%84%e9%9d%9e%e5%af%b9%e7%a7%b0%e4%ba%b2%e6%a0%b8%e6%b0%9f%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=138260","title":{"rendered":"\u4eca\u65e5Science:\u6c22\u952e\u76f8\u8f6c\u79fb\u50ac\u5316\u4e2d\u7684\u975e\u5bf9\u79f0\u4eb2\u6838\u6c1f\u5316\u53cd\u5e94"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u4e00\u822c\u6765\u8bf4\uff0c\u7531\u65e0\u673a\u76d0\u884d\u751f\u51fa\u7684\u9634\u79bb\u5b50\u4eb2\u6838\u53cd\u5e94\u9650\u4e8e\u5176\u4e0d\u53ef\u6eb6\u6027\u800c\u4e0d\u80fd\u7528\u4e8e\u5bf9\u6620\u9009\u62e9\u6027\u50ac\u5316\u4f5c\u7528\u3002\u5982\u7b80\u5355\u7684\u6c1f\u5316\u76d0\u7ecf\u8fc7\u7406\u8bba\u7814\u7a76\u88ab\u8ba4\u4e3a\u53ef\u4ee5\u975e\u5e38\u7b80\u4fbf\u5730\u5408\u6210\u78b3-\u6c1f\u952e\uff0c\u7136\u800c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u6c1f\u5316\u76d0\u5e38\u5e38\u4e0d\u80fd\u4e0e\u5176\u4ed6\u53cd\u5e94\u7269\u5171\u6eb6\u4e8e\u6eb6\u5242\u4e2d\uff0c\u8fd9\u6781\u5927\u5730\u9650\u5236\u4e86\u6c1f\u76d0\u5728\u5305\u62ec\u836f\u7269\u79d1\u5b66\u7b49\u9886\u57df\u7684\u53d1\u5c55\u5e94\u7528\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u725b\u6d25\u5927\u5b66\u7684<\/strong><strong>Veronique Gouverneur<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u5b66\u8005\u5728\u63d0\u51fa\u5229\u7528\u57fa\u4e8e\u901a\u8fc7\u6c22\u952e\u5b9e\u73b0\u7684\u9633\u79bb\u5b50\u8bc6\u522b\u6765\u4fc3\u4f7f\u975e\u5bf9\u79f0\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\u548c\u65e0\u673a\u4eb2\u6838\u4f53\u5728\u6709\u673a\u4ecb\u8d28\u4e2d\u53d1\u751f\u50ac\u5316\u4f5c\u7528\uff0c\u4e3a\u975e\u53ef\u6eb6\u6027\u7684\u4eb2\u6838\u8bd5\u5242\u7684\u6d3b\u5316\u63d0\u4f9b\u4e86\u65b0\u578b\u7684\u6a21\u5f0f\u65b9\u6cd5\u3002\u8be5\u7814\u7a76\u4ee5\u6d3b\u5316\u78b1\u91d1\u5c5e\u6c1f\u5316\u7269\u5bf9\u6620\u9009\u62e9\u6027\u5f62\u6210\u78b3\u6c1f\u952e\u4e3a\u4f8b\uff0c\u4ee5\u8132\u57fa\u50ac\u5316\u5242\u4f5c\u4e3a\u6c22\u952e\u4f9b\u4f53\u578b\u56fa\u6db2\u76f8\u8f6c\u79fb\u50ac\u5316\u5242\uff0c\u4e0e\u91d1\u5c5e\u6c1f\u5316\u7269\u5f62\u6210\u5bcc\u542b\u6c22\u952e\u7684\u8132-\u6c1f\u590d\u5408\u7269\uff0c\u4ece\u800c\u589e\u52a0\u6c1f\u5316\u7269\u7684\u6709\u673a\u8bd5\u5242\u53ef\u6eb6\u6027\u3002\u8fd9\u4e00\u7814\u7a76\u6210\u679c\u8bbe\u8ba1\u65b0\u578b\u624b\u6027\u50ac\u5316\u5242\u7528\u4e8e\u5bf9\u6620\u9009\u62e9\u6027\u50ac\u5316\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u9047\u30022018\u5e745\u670811\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Asymmetric nucleophilic fluorination under hydrogen bonding phase-transfer catalysis<\/strong>\u201d\u5728\u7ebf\u53d1\u8868\u5728<strong>Science<\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1 \u50ac\u5316\u53cd\u5e94\u8bbe\u8ba1<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138263\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe1-11.jpg\" alt=\"\" width=\"600\" height=\"522\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe1-11.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe1-11-300x261.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\u53cd\u5e94\u8fdb\u7a0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138262\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe2-6.jpg\" alt=\"\" width=\"488\" height=\"544\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe2-6.jpg 488w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe2-6-269x300.jpg 269w\" sizes=\"(max-width: 488px) 100vw, 488px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u53cd\u5e94\u8303\u56f4\u548c\u673a\u7406\u89e3\u91ca<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138264\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe3-5.jpg\" alt=\"\" width=\"401\" height=\"590\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe3-5.jpg 401w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/\u56fe3-5-204x300.jpg 204w\" sizes=\"(max-width: 401px) 100vw, 401px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/science.sciencemag.org\/content\/360\/6389\/638\">Asymmetric nucleophilic fluorination under hydrogen bonding phase-transfer catalysis<\/a>\uff08Science, 2018, DOI: 10.1126\/science.aar7941\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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