{"id":138011,"date":"2018-05-10T06:30:09","date_gmt":"2018-05-09T22:30:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=138011"},"modified":"2018-05-09T15:09:26","modified_gmt":"2018-05-09T07:09:26","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e6%8a%80%e6%9c%af%e5%a4%a7%e5%ad%a6nano-energy%ef%bc%9a%e9%93%81%e7%94%b5bi3tinbo9%e7%ba%b3%e7%b1%b3%e7%89%87%e4%b8%8a%e5%ae%9e%e7%8e%b0%e9%80%89%e6%8b%a9%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=138011","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66Nano energy\uff1a\u94c1\u7535Bi3TiNbO9\u7eb3\u7c73\u7247\u4e0a\u5b9e\u73b0\u9009\u62e9\u6027\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22\u6216\u4ea7\u6c27"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138012\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/0.png\" alt=\"\" width=\"600\" height=\"247\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/0.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/0-300x124.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\u4eae\u70b9<\/strong><\/p>\n<p><strong>\uff081<\/strong><strong>\uff09\u94c1\u7535Bi<sub>3<\/sub>TiNbO<sub>9<\/sub><\/strong><strong>\u7eb3\u7c73\u7247\u5177\u6709\u826f\u597d\u7684\u5149\u9a71\u52a8\u5206\u89e3\u6c34\u4ea7\u6c22\u548c\u4ea7\u6c27\u80fd\u529b\uff1b<\/strong><\/p>\n<p>\uff082\uff09<strong>\u6c22\u88ab\u8bc1\u660e\u662f\u5728<\/strong><strong>{001}<\/strong><strong>\u9762\u751f\u6210\u7684\uff0c\u800c\u6c27\u662f\u5728{110}<\/strong><strong>\u9762\u751f\u6210\u7684\uff1b<\/strong><\/p>\n<p><strong>\uff083<\/strong><strong>\uff09\u6539\u53d8{001}<\/strong><strong>\u9762\u4e0e{110}<\/strong><strong>\u9762\u7684\u6bd4\u4f8b\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u4ea7\u6c22\u6216\u4ea7\u6c27\u7684\u8c03\u63a7\u3002<\/strong><\/p>\n<p><strong>\u5f15\u8a00<\/strong><\/p>\n<p>\u5229\u7528\u5149\u50ac\u5316\u6280\u672f\u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u5316\u5b66\u80fd\uff0c\u662f\u89e3\u51b3\u5168\u7403\u80fd\u6e90\u548c\u73af\u5883\u5371\u673a\u7684\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002\u8981\u63d0\u9ad8\u5149\u9a71\u52a8\u5206\u89e3\u6c34\u4ea7\u751f\u6c22\u6c14\u548c\u6c27\u6c14\u7684\u6548\u7387\uff0c\u6709\u4e24\u4e2a\u5173\u952e\u7684\u8fc7\u7a0b\uff0c\u4e00\u662f\u5149\u6fc0\u53d1\u4ea7\u751f\u7684\u7535\u5b50\u548c\u7a7a\u7a74\u80fd\u6709\u6548\u5206\u79bb\uff0c\u53e6\u5916\u4ea7\u6c22\u53cd\u5e94\u548c\u4ea7\u6c27\u53cd\u5e94\u9700\u8981\u5728\u7a7a\u95f4\u4e0a\u5206\u79bb\uff0c\u4ece\u800c\u907f\u514d\u6c34\u5206\u89e3\u53cd\u5e94\u7684\u9006\u53cd\u5e942 H<sub>2<\/sub>+ O<sub>2<\/sub>\u21922H<sub>2<\/sub>O\u3002\u5b9e\u73b0\u8fd9\u4e9b\u76ee\u6807\u7684\u4e00\u4e2a\u5f88\u597d\u7684\u7b56\u7565\u662f\u6676\u4f53\u8868\u9762\u5de5\u7a0b\uff0c\u5373\u91c7\u7528\u5408\u9002\u7684\u5408\u6210\u65b9\u6cd5\u5236\u5907\u51fa\u5177\u6709\u4e0d\u540c\u6781\u6027\u7684\u534a\u5bfc\u4f53\u50ac\u5316\u5242\u3002\u7535\u5b50\u548c\u7a7a\u7a74\u503e\u5411\u4e8e\u8fc1\u79fb\u5230\u4e0d\u540c\u7684\u66b4\u9732\u9762\uff0c\u4ece\u800c\u5b9e\u73b0\u6709\u6548\u7684\u7a7a\u95f4\u5206\u79bb\u3002\u4e4b\u524d\u6240\u7814\u7a76\u7684\u6750\u6599\uff0c\u8981\u4e48\u53ea\u5177\u6709\u4ea7\u6c22\u529f\u80fd\uff0c\u8981\u4e48\u53ea\u5177\u6709\u4ea7\u6c27\u529f\u80fd\uff0c\u5f88\u5c11\u6709\u5355\u4e00\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u5242\u80fd\u517c\u5177\u597d\u7684\u4ea7\u6c22\u548c\u4ea7\u6c27\u529f\u80fd\u3002\u94c1\u7535\u534a\u5bfc\u4f53\u662f\u6781\u5177\u5438\u5f15\u529b\u7684\u4e00\u79cd\u5149\u50ac\u5316\u5242\u3002\u9996\u5148\uff0c\u5185\u6781\u5316\u53ef\u80fd\u4f1a\u6709\u6548\u964d\u4f4e\u4ea7\u6c22\u548c\u4ea7\u6c27\u53cd\u5e94\u5bf9\u5149\u50ac\u5316\u5242\u80fd\u5e26\u7ed3\u6784\u7684\u8981\u6c42\uff0c\u56e0\u6b64\u53ef\u5728\u5355\u76f8\u5149\u50ac\u5316\u5242\u4e2d\u5b9e\u73b0\u9ad8\u6548\u3001\u9009\u62e9\u6027\u7684\u4ea7\u6c22\u548c\u4ea7\u6c27\u3002\u5176\u6b21\uff0c\u94c1\u7535\u4f53\u81ea\u53d1\u6781\u5316\u4ea7\u751f\u7684\u5185\u5efa\u7535\u573a\u53ef\u6781\u5927\u5730\u6291\u5236\u5149\u751f\u7535\u5b50\u7a7a\u7a74\u5bf9\u7684\u590d\u5408\u3002\u7b2c\u4e09\uff0c\u5185\u5efa\u7535\u573a\u5c06\u5f15\u5bfc\u5149\u751f\u7535\u5b50\u7a7a\u7a74\u8fc1\u79fb\u5230\u4e0d\u540c\u7684\u8868\u9762\uff0c\u4ece\u800c\u6291\u5236\u6c34\u5206\u89e3\u7684\u9006\u53cd\u5e94\u3002\u6700\u540e\uff0c\u94c1\u7535\u4f53\u7684\u4f4e\u5bf9\u79f0\u6027\u4f7f\u5f97\u7528\u7b80\u5355\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u5c31\u53ef\u4ee5\u83b7\u5f97\u4e0d\u540c\u7684\u6781\u6027\u66b4\u9732\u9762\u3002<\/p>\n<p><strong>\u6210\u679c\u53ca\u7b80\u4ecb<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u9646\u4e9a\u6797\u8bfe\u9898\u7ec4<\/strong>\u00a0\u91c7\u7528\u6539\u8fdb\u7194\u76d0\u6cd5\u548c\u56fa\u6001\u6cd5\u5408\u6210\u4e86\u4e00\u79cd\u5c42\u72b6\u94c1\u7535\u6750\u6599Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u3002\u7528\u6539\u8fdb\u7194\u76d0\u6cd5\u5408\u6210\u7684\u7eb3\u7c73\u8584\u7247\u7684\u66b4\u9732\u9762\u662f{001}\u548c{110}\uff0c\u66b4\u9732\u9762\u7684\u6bd4\u4f8b\u53ef\u901a\u8fc7\u6539\u53d8\u5408\u6210\u6e29\u5ea6\u8fdb\u884c\u8c03\u8282\u3002Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u7eb3\u7c73\u7247\u5728\u5149\u7167\u4e0b\u65e2\u80fd\u5206\u89e3\u6c34\u4ea7\u6c22\uff0c\u4e5f\u80fd\u4ea7\u6c27\uff0c\u901a\u8fc7\u8c03\u8282{001}\/{110}\u9762\u7684\u6bd4\u4f8b\uff0c\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u4f18\u5316\u4ea7\u6c22\u6216\u4ea7\u6c27\u3002{001}\u66b4\u9732\u9762\u6bd4\u4f8b\u6700\u9ad8\u7684\u6837\u54c1\u5177\u6709\u6700\u597d\u7684\u4ea7\u6c22\u80fd\u529b(342.6\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>)\uff0c\u800c{110}\u66b4\u9732\u9762\u6bd4\u4f8b\u6700\u9ad8\u7684\u6837\u54c1\u5177\u6709\u6700\u597d\u7684\u4ea7\u6c27\u6027\u80fd(275.2\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>)\uff0c\u8868\u660e{001}\u9762\u4e3a\u4ea7\u6c22\u6d3b\u6027\u9762\uff0c\u800c{110}\u4e3a\u4ea7\u6c27\u6d3b\u6027\u9762\u3002\u672c\u7814\u7a76\u5bf9\u7c7b\u4f3c\u7684\u5149\u50ac\u5316\u5242\u4e2d\u5408\u7406\u8bbe\u8ba1\u5e76\u9ad8\u6548\u4ea7\u6c22\u6216\u4ea7\u6c27\u751f\u5177\u6709\u6307\u5bfc\u610f\u4e49\u3002<strong>\u9646\u4e9a\u6797\u6559\u6388\u548c\u5085\u6b63\u5e73\u526f\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff0c\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\u4e3a\u6bb7\u5c0f\u4e30\u535a\u58eb<\/strong>\u3002\u8be5\u6587\u7ae0\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a<strong>Nano Energy<\/strong><strong>\u4e0a<\/strong>\uff08\u5f71\u54cd\u56e0\u5b50\uff1a12.343\uff09\u3002<\/p>\n<p><strong>\u56fe\u6587\u89e3\u8bfb<\/strong><\/p>\n<p><strong>\u56fe1 Bi<sub>3<\/sub>TiNbO<sub>9<\/sub><\/strong><strong>\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff0cDFT<\/strong><strong>\u8ba1\u7b97\uff0cXRD<\/strong><strong>\u53caXPS<\/strong><strong>\u7ed3\u679c<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138013\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/1-12.jpg\" alt=\"\" width=\"600\" height=\"508\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/1-12.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/1-12-300x254.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe;<\/p>\n<p>(b)\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u7684Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u603b\u5bc6\u5ea6(TDOS) ;<\/p>\n<p>(c)\u7194\u76d0\u6cd5\u548c\u56fa\u6001\u6cd5\u5408\u6210\u6837\u54c1\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31(XRD);<\/p>\n<p>(d)O1s\u7684\u9ad8\u5206\u8fa8\u7387\u5149\u7535\u5b50\u80fd\u8c31(XPS)\u3002<\/p>\n<p><strong>\u56fe2<\/strong> B<strong>TNO-SS<\/strong><strong>\u548cBTNO-M800<\/strong><strong>\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138014\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/2-15.jpg\" alt=\"\" width=\"600\" height=\"751\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/2-15.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/2-15-240x300.jpg 240w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a\uff0cb) BTNO-SS\u548cBTNO-M800\u7684\u626b\u63cf\u7535\u955c(SEM)\u56fe\u50cf;<\/p>\n<p>(c) BTNO-M800\u7684\u900f\u5c04\u7535\u955cTEM\u56fe\u50cf;<\/p>\n<p>(d) \u56fe2c\u7684\u767d\u8272\u6807\u8bb0\u533a\u57df\u7684\u6676\u683c\u6761\u7eb9\u50cf;<\/p>\n<p>(e) \u5165\u5c04\u65b9\u5411\u5782\u76f4\u4e8eBTNO-M800\u7eb3\u7c73\u7247\u4e0a\u8868\u9762\u6240\u5f97\u5230\u7684\u9009\u533a\u57df\u7535\u5b50\u884d\u5c04\u82b1\u6837(SAED);<\/p>\n<p>(f) BTNO-M800\u7eb3\u7c73\u7247\u6676\u4f53\u53d6\u5411\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u56fe3. BTNO-SS<\/strong><strong>\u548cBTNO-M800<\/strong><strong>\u7684UV-vis<\/strong><strong>\uff0c\u6c34\u5206\u89e3\u53ca\u7535\u5316\u5b66\u6d4b\u8bd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138015\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/3-12.jpg\" alt=\"\" width=\"600\" height=\"465\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/3-12.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/3-12-300x233.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) BTNO-SS\u548cBTNO-M800\u7684\u7d2b\u5916-\u53ef\u89c1\u6f2b\u53cd\u5c04\u8c31;<\/p>\n<p>(b) BTNO-SS\u548cBTNO-M800\u7684\u5206\u89e3\u6c34\u4ea7\u6c22\u548c\u4ea7\u6c27\u6027\u80fd\uff1b<\/p>\n<p>(c) \u5149\u7535\u6d41-\u65f6\u95f4\u66f2\u7ebf;<\/p>\n<p>(d) \u6bd4\u8868\u9762\u79ef\u5f52\u4e00\u5316\u540e\u7684\u4ea7\u6c22\u548c\u4ea7\u6c27\u6027\u80fd\u3002<\/p>\n<p><strong>\u56fe4<\/strong><strong>\u4e0d\u540c\u7194\u76d0\u6e29\u5ea6\u4e0b\u5236\u5907\u7684Bi<sub>3<\/sub>TiNbO<sub>9<\/sub><\/strong><strong>\u7684SEM<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138016\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/4-12.jpg\" alt=\"\" width=\"600\" height=\"486\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/4-12.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/4-12-300x243.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) BTNO-M900;<\/p>\n<p>(b)BTNO-M800;<\/p>\n<p>(c)BTNO-M750;<\/p>\n<p>(d)BTNO-M700.<\/p>\n<p><strong>\u56fe5 BTNO-M700<\/strong><strong>\u3001BTNO-M750<\/strong><strong>\u3001BTNO-M800<\/strong><strong>\u548cBTNO-M900<\/strong><strong>\u7684UV-vis<\/strong><strong>\u53ca\u76f8\u5173\u6d4b\u8bd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138017\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/5-8.jpg\" alt=\"\" width=\"600\" height=\"360\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/5-8.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/5-8-300x180.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) BTNO-M700\u3001BTNO-M750\u3001BTNO-M800\u548cBTNO-M900\u7684Uv-vis;<\/p>\n<p>(b) (\u03b1hv)<sup>2<\/sup>\u4e0e\u5149\u5b50\u80fd\u91cf\u5173\u7cfb;<\/p>\n<p>(c\uff0cd)\u56db\u4e2a\u6837\u54c1\u7684XRD\u56fe\u8c31\u7684\u5c40\u90e8\u653e\u5927;<\/p>\n<p>(e)\u4e0a\u8ff0\u6837\u54c1\u7684\u5206\u89e3\u6c34\u4ea7\u6c22\u548c\u4ea7\u6c27\u7ed3\u679c;<\/p>\n<p>(f)\u5f52\u4e00\u5316\u4ea7\u6c22\u6027\u80fd\u4e0e\u5bf9\u5e94{001}\/{110}\u6bd4\u7684\u5173\u7cfb\u56fe;<\/p>\n<p>(g)\u5f52\u4e00\u5316\u4ea7\u6c27\u6027\u80fd\u4e0e\u5bf9\u5e94{001}\/{110}\u6bd4\u7684\u5173\u7cfb\u56fe\u3002<\/p>\n<p>\u56fe5a\u663e\u793a\u4e86\u7194\u76d0\u6cd5\u6837\u54c1\u7684\u7d2b\u5916-\u53ef\u89c1\u6f2b\u53cd\u5c04\u5149\u8c31\uff0c\u53ef\u4ee5\u770b\u51faBTNO-M700\u3001BTNO-M750\u3001BTNO-M800\u548cBTNO-M900\u7684\u5e26\u9699\u5206\u522b\u4e3a3.323 eV\u30013.330 eV\u30013.334 eV\u548c3.313 eV\u3002\u56db\u4e2a\u6837\u54c1\u7684\u5f52\u4e00\u5316XRD\u56fe\u8c31\u5982\u56fe5\u6240\u793a\uff0c\u8fd9\u4e9b\u6837\u54c1\u7684(004)\u548c(220)\u884d\u5c04\u5cf0\u7684\u76f8\u5bf9\u5f3a\u5ea6\u662f\u4e0d\u540c\u7684\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u9610\u660e\u56db\u4e2a\u6837\u54c1\u4e2d(004)\/(220)\u7684\u5dee\u5f02\uff0c\u5728\u56fe5c\u548cd\u4e2d\u5206\u522b\u7ed9\u51fa\u4e86\u653e\u5927\u7684XRD\u884d\u5c04\u5cf0\uff0c\u8fd9\u4e0eSEM\u56fe\u50cf\u6240\u5f97\u5230\u7684\u5f62\u8c8c\u4e00\u81f4\u3002\u6b64\u5916\uff0c\u56fe5c\u4e2d\u53ef\u770b\u51fa(200\/020)\u548c(220)\u884d\u5c04\u5cf0\u5f3a\u5ea6\u968f\u5236\u5907\u6e29\u5ea6\u7684\u63d0\u9ad8\u800c\u663e\u8457\u964d\u4f4e\uff0c\u800c(004)\u884d\u5c04\u5cf0\u7684\u5f3a\u5ea6\u5219\u5448\u73b0\u76f8\u53cd\u7684\u8d8b\u52bf\u3002\u5982\u4e0a\u6240\u8ff0\uff0c\u9ad8\u6bd4\u4f8b\u7684(004)\/(220)\u5f3a\u5ea6\u6bd4\u610f\u5473\u7740\u9ad8\u6bd4\u4f8b\u7684{001}\u66b4\u9732\u9762\u548c\u4f4e\u6bd4\u4f8b\u7684{110}\u66b4\u9732\u9762\uff0c\u800c\u9ad8\u6bd4\u4f8b(220)\/(004)\u8868\u660e\u4e86\u9ad8\u6bd4\u4f8b{110}\u66b4\u9732\u9762\u548c\u4f4e\u6bd4\u4f8b\u7684{001}\u66b4\u9732\u9762\u3002\u663e\u7136\u968f\u7740\u70e7\u7ed3\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c{001}\u66b4\u9732\u9762\u7684\u6bd4\u4f8b\u4ece0.41 (BTNO-M700)\u589e\u52a0\u52301.08 (BTNO-M900)\uff0c\u800c{110}\u66b4\u9732\u9762\u7684\u6bd4\u4f8b\u4ece2.43 (BTNO-M700)\u4e0b\u964d\u52300.92 (BTNO-M900)\uff0c\u3002\u56fe5e\u663e\u793a\u7194\u76d0\u6cd5\u6837\u54c1\u7684\u5149\u7167\u5206\u89e3\u6c34\u4ea7\u6c22\u548c\u4ea7\u6c27\u7ed3\u679c\u3002\u867d\u7136\u6837\u54c1\u7684\u6bd4\u8868\u9762\u79ef\u51cf\u5c11\uff0c\u6c22\u6c14\u4ea7\u91cf\u4eceBTNO-M700\u768490.1 \u00a0\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>\u00a0\u589e\u52a0\u5230BTNO-M900\u7684342.6\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>\uff0c\u63ed\u793a\u4e86\u6837\u54c1\u4e2d\u4ea7\u751f\u7684\u6c22\u91cf\u4e0e{001}\u66b4\u9732\u9762\u7684\u6bd4\u4f8b\u4e4b\u95f4\u7684\u6b63\u76f8\u5173\u5173\u7cfb\u3002\u4e0e\u4e4b\u5bf9\u6bd4\u7684\u662f\uff0c\u968f\u7740{110}\u66b4\u9732\u9762\u6bd4\u4f8b\u7684\u589e\u52a0\uff0c\u6c27\u6c14\u4ea7\u91cfBTNO-M900\u768425.5\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>\u00a0 \u589e\u52a0\u5230\u4e86BTNO-M750\u7684275.2\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>\u3002BTNO-M700\u6837\u54c1\u662f\u7531\u4e8e\u6742\u8d28\u7684\u5f71\u54cd\u5bfc\u81f4\u4ea7\u6c27\u6d3b\u6027\u5927\u5927\u964d\u4f4e\u7684\u539f\u56e0\u3002\u8003\u8651\u5230\u8fd9\u56db\u4e2a\u6837\u54c1\u7684\u5149\u5438\u6536\u975e\u5e38\u76f8\u4f3c\uff0c\u5982\u679c\u5c06\u6837\u54c1\u7684\u4ea7\u6c22\u548c\u4ea7\u6c27\u80fd\u529b\u7528\u6bd4\u8868\u9762\u79ef\u6765\u5f52\u4e00\u5316\uff0c\u90a3\u4e48\u6211\u4eec\u5c31\u53ef\u4ee5\u66f4\u51c6\u786e\u5730\u63ed\u793a\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22\u548c\u4ea7\u6c27\u4e0e\u66b4\u9732\u9762\u7684\u5173\u7cfb\u3002\u9664\u4e0d\u7eaf\u6837\u54c1BTNO-M700\u5916\uff0c\u5176\u5b83\u6837\u54c1\u7684\u5f52\u4e00\u5316\u4ea7\u6c22\u5173\u7cfb\u56fe\u53ca\u5176\u5bf9\u5e94\u7684\u66b4\u9732\u9762\u6bd4({001}\/{110})\u5982\u56fe5f\u6240\u793a\u3002\u4eceBTNO-M750\u5230BTNO-M900\uff0c\u5f52\u4e00\u5316\u4ea7\u6c22\u548c\u66b4\u9732\u9762\u6bd4\u503c({001}\/{110})\u7684\u589e\u52a0\u8d8b\u52bf\u662f\u76f8\u540c\u7684\uff0c\u8868\u660e\u6709\u66f4\u591a{001}\u66b4\u9732\u9762\u7684\u6837\u54c1\u66f4\u6709\u5229\u4e8e\u4ea7\u6c22\u3002\u56fe5g\u663e\u793a\u5f52\u4e00\u5316\u4ea7\u6c27\u548c\u66b4\u9732\u9762\u6bd4({110}\/{001})\u7684\u8d8b\u52bf(\u51cf\u5c11)\u4e5f\u662f\u76f8\u540c\u7684\uff0c\u8868\u660e\u5177\u6709\u66f4\u591a{110}\u66b4\u9732\u9762\u7684\u6837\u54c1\u66f4\u6709\u5229\u4e8e\u4ea7\u6c27\u3002\u4e5f\u5c31\u662f\u8bf4\uff0cBi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u7684{001}\u548c{110}\u5e73\u9762\u5206\u522b\u4e3a\u6c22\u751f\u6210\u6d3b\u6027\u9762\u548c\u6c27\u751f\u6210\u6d3b\u6027\u9762\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4f5c\u8005\u901a\u8fc7\u7b80\u5355\u7684\u8c03\u8282\u7194\u76d0\u6cd5\u5408\u6210\u6e29\u5ea6\uff0c\u9009\u62e9\u6027\u5730\u5b9e\u73b0Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u7eb3\u7c73\u7247\u4e2d\u7684\u6700\u5927\u4ea7\u6c22(342.6\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>\u00a0)\u6216\u6700\u5927\u4ea7\u6c27(275.2\u03bcmol h<sup>\u22121<\/sup>g<sup>\u22121<\/sup>\u00a0)\u3002\u4e3a\u4e86\u7814\u7a76\u4e3a\u4ec0\u4e48{001}\u9762\u662f\u751f\u6210\u6c22\u6c14\u7684\u6d3b\u6027\u9762\uff0c\u800c{110}\u5e73\u9762\u662f\u4ea7\u751f\u6c27\u6c14\u7684\u6d3b\u6027\u9762\uff0c\u4f5c\u8005\u5206\u522b\u7528AgNO3\u548cPb(NO<sub>3<\/sub>)<sub>2<\/sub>\u8fdb\u884c\u4e86\u5149\u6c89\u79ef\u5b9e\u9a8c\u3002\u6c89\u79ef\u6837\u54c1\u7684TEM\u56fe\u50cf\u5982\u56feS7\u6240\u793a\uff0cAg\u7eb3\u7c73\u9897\u7c92\u4e3b\u8981\u6c89\u79ef\u4e8e{001}\u9762\uff0cPbO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\u4e3b\u8981\u6c89\u79ef\u5728{110}\u9762\u4e0a\u3002\u8fd9\u8868\u660e\u7535\u5b50\u503e\u5411\u4e8e\u8fc1\u79fb\u5230{001}\u65b9\u9762\uff0c\u800c\u7a7a\u7a74\u503e\u5411\u4e8e\u8fc1\u79fb\u5230{110}\u65b9\u9762\u3002\u8003\u8651\u4ea7\u6c22\u53cd\u5e94\u548c\u4ea7\u6c27\u53cd\u5e94\uff0c\u53ef\u4ee5\u89e3\u91ca{001}\u662f\u6c22\u751f\u6210\u6d3b\u6027\u9762\uff0c\u56e0\u4e3a\u5b83\u662f\u7535\u5b50\u805a\u96c6\u9762\uff0c\u800c{110}\u662f\u6c27\u6c14\u4ea7\u751f\u6d3b\u6027\u9762\uff0c\u56e0\u4e3a\u5b83\u662f\u4e00\u4e2a\u7a7a\u7a74\u805a\u96c6\u9762\u3002<\/p>\n<p><strong>\u56fe6 Bi<sub>3<\/sub>TiNbO<sub>9<\/sub><\/strong><strong>\u7eb3\u7c73\u7247\u7684\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22\u548c\u4ea7\u6c27\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-138018\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/6-4.jpg\" alt=\"\" width=\"600\" height=\"183\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/6-4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/05\/6-4-300x92.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe6\u7ed9\u51fa\u4e86Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u7eb3\u7c73\u7247\u7684\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22\u548c\u4ea7\u6c27\u8fc7\u7a0b\u793a\u610f\u56fe\u3002\u5f53\u7eb3\u7c73\u8584\u7247\u88ab\u5149\u7167\u5c04\u65f6\uff0c\u5149\u4ea7\u751f\u7684\u7535\u5b50\u503e\u5411\u4e8e\u8fc1\u79fb\u5230{001}\u5e73\u9762\uff0c\u800c\u5149\u4ea7\u751f\u7684\u7a7a\u7a74\u503e\u5411\u4e8e\u8fc1\u79fb\u5230{110}\u5e73\u9762\u3002\u56e0\u6b64\uff0c\u6c22\u7684\u6f14\u5316\u53cd\u5e94\u4e3b\u8981\u53d1\u751f\u5728{001}\u5e73\u9762\u4e0a\uff0c\u6c27\u7684\u6f14\u5316\u53cd\u5e94\u4e3b\u8981\u53d1\u751f\u5728{110}\u5e73\u9762\u4e0a\u3002\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u9009\u62e9\u6027\u8fc1\u79fb\u662f\u94c1\u7535\u6027\u7684Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u7eb3\u7c73\u7247\u4e2d\u5b9e\u73b0\u9ad8\u6548\u548c\u9009\u62e9\u6027\u4ea7\u6c22\u548c\u4ea7\u6c27\u7684\u5185\u5728\u539f\u56e0\u3002<\/p>\n<p><strong>\u603b\u7ed3<\/strong><\/p>\n<p>\u91c7\u7528\u6539\u8fdb\u7684\u7194\u76d0\u6cd5\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u94c1\u7535\u5c42\u72b6\u6750\u6599Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u3002\u7ed3\u679c\u8868\u660e\uff0c800<sup>o<\/sup>C\u7194\u76d0\u6cd5\u5236\u5907\u7684\u6837\u54c1BTNO-M800\u5177\u6709\u66f4\u591a{001}\u66b4\u9732\u9762\uff0c\u5176\u4ea7\u6c22\u80fd\u529b(24.8\u500d)\u548c\u4ea7\u6c27\u80fd\u529b(3.3\u500d)\u4e5f\u6bd4BTNO-SS\u9ad8\u5f97\u591a\u3002\u4e3a\u4e86\u89e3\u91ca\u8fd9\u4e00\u73b0\u8c61\uff0c\u4f5c\u8005\u7528\u7194\u76d0\u6cd5\u5408\u6210\u4e86\u4e0d\u540c\u6bd4\u4f8b{001}\/{110}\u66b4\u9732\u9762\u7684\u6837\u54c1\u3002\u7ed3\u679c\u53d1\u73b0\u5177\u6709\u6700\u9ad8\u6bd4\u4f8b{001}\u66b4\u9732\u9762\u7684BTNO-M900\u5176\u4ea7\u6c22\u80fd\u529b\u4e5f\u6700\u9ad8\uff0c\u76f8\u53cd{110}\u66b4\u9732\u9762\u6bd4\u4f8b\u6700\u9ad8\u7684BTNO-M75\u5177\u6709\u6700\u9ad8\u4ea7\u6c27\u6d3b\u6027\uff0c\u8868\u660e\u94c1\u7535\u6750\u6599Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u7684{001}\u548c{110}\u9762\u5206\u522b\u662f\u4ea7\u6c22\u6d3b\u6027\u9762\u548c\u4ea7\u6c27\u6d3b\u6027\u9762\u3002\u540e\u7eed\u7684\u5149\u6c89\u79ef\u5b9e\u9a8c\u8bc1\u5b9e\uff0c{001}\u66b4\u9732\u9762\u4e3a\u7535\u5b50\u6536\u96c6\u9762\uff0c{110}\u66b4\u9732\u9762\u4e3a\u7a7a\u7a74\u6536\u96c6\u9762\uff0c\u4e0e\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22-\u4ea7\u6c27\u7684\u7ed3\u679c\u4e00\u81f4\u3002Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u7eb3\u7c73\u7247\u4e2d\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u9009\u62e9\u6027\u8fc1\u79fb\u662f\u5176\u4e2d\u5b9e\u73b0\u9ad8\u6548\u548c\u9009\u62e9\u6027\u4ea7\u6c22\u548c\u4ea7\u6c27\u7684\u51b3\u5b9a\u6027\u56e0\u7d20\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong><\/p>\n<p><a href=\"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S2211285518303173\" target=\"_blank\" rel=\"noopener\"><strong>Realizing selective water splitting hydrogen\/oxygen evolution on ferroelectric Bi<sub>3<\/sub>TiNbO<sub>9<\/sub>\u00a0nanosheets<\/strong><\/a>, Xiaofeng Yin, Xiaoning Li, Huan Liu, Wen Gu, Wei Zou, Liuyang Zhu, <strong>Zhengping Fu<\/strong> , <strong>Yalin Lu<\/strong>, Nano energy, 2018, DOI<a href=\"https:\/\/doi.org\/10.1016\/j.nanoen.2018.05.001\">\uff1a10.1016\/j.nanoen.2018.05.001<\/a><\/p>\n<p><strong>\u00a0<\/strong>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8<strong>\u7eb3\u7c73\u6750\u6599\u5b66\u672f\u7ec4<\/strong><strong>Kevin<\/strong><strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406<\/strong>\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u6750\u6599\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08228686798\uff09\uff01<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a 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