{"id":137721,"date":"2018-05-09T06:30:33","date_gmt":"2018-05-08T22:30:33","guid":{"rendered":"\/\/m.iemloyee.com\/?p=137721"},"modified":"2018-06-05T23:16:24","modified_gmt":"2018-06-05T15:16:24","slug":"%e6%a2%b3%e7%90%86%ef%bc%9a%e7%83%ad%e5%8a%9b%e5%ad%a6%e8%ae%a1%e7%ae%97%e5%9c%a8%e6%9d%90%e6%96%99%e7%a7%91%e5%ad%a6%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=137721","title":{"rendered":"\u70ed\u529b\u5b66\u8ba1\u7b97\u5728\u6750\u6599\u79d1\u7814\u4e2d\u53ef\u4ee5\u6709\u54ea\u4e9b\u7528\u9014 \u4e86\u89e3\u4e00\u4e0b\uff1f"},"content":{"rendered":"

\"\"<\/p>\n

\u70ed\u529b\u5b66\u662f\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u9886\u57df\u4e0d\u53ef\u6216\u7f3a\u7684\u7ec4\u6210\u90e8\u5206\u4e4b\u4e00\u3002\u6210\u529f\u7684\u6750\u6599\u4e0e\u52a0\u5de5\u5de5\u827a\u8bbe\u8ba1\u90fd\u9700\u8981\u53ef\u9760\u7684\u70ed\u529b\u5b66\u6570\u636e\u3002\u4ee5\u5f80\uff0c\u6750\u6599\u7684\u70ed\u529b\u5b66\u6027\u80fd\u4e3b\u8981\u901a\u8fc7\u5b9e\u9a8c\u624b\u6bb5\u83b7\u5f97\uff0c\u4f8b\u5982 \u5dee\u70ed\u5206\u6790\uff0c\u5316\u5b66\u5206\u6790\uff0cX\u5c04\u7ebf\u884d\u5c04\u548c\u80fd\u8c31\u5206\u6790\u3002\u4f46\u662f\u968f\u7740\u79d1\u5b66\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u6750\u6599\u4e2d\u7684\u7ec4\u5143\u6570\u8d8a\u6765\u8d8a\u591a\uff0c\u5b9e\u9a8c\u6d4b\u5b9a\u70ed\u529b\u5b66\u6570\u636e\u4e5f\u8d8a\u6765\u8d8a\u56f0\u96be\uff0c\u5e76\u4e14\u96be\u4ee5\u5728\u6709\u9650\u7684\u65f6\u95f4\u91cc\u83b7\u5f97\u8db3\u591f\u7684\u6570\u636e\u3002\u57fa\u4e8eCALPHAD\u65b9\u6cd5\u7684\u70ed\u529b\u5b66\u8ba1\u7b97\u6b63\u662f\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\u7684\u6700\u597d\u529e\u6cd5\u3002\u5b83\u53ef\u4ee5\u4ece\u4f4e\u7ec4\u5206\u6750\u6599\u4f53\u7cfb\u7684\u70ed\u529b\u5b66\u6570\u636e\u6765\u8ba1\u7b97\u591a\u7ec4\u5206\u4f53\u7cfb\u7684\u70ed\u529b\u5b66\u6027\u80fd\u4ee5\u8282\u7ea6\u65f6\u95f4\u548c\u6210\u672c\uff0c\u6216\u8005\u901a\u8fc7\u5b9e\u9a8c\u5bb9\u6613\u51c6\u786e\u6d4b\u5b9a\u7684\u5b9e\u9a8c\u6570\u636e\u6765\u63a8\u6d4b\u6781\u7aef\u6761\u4ef6\u4e0b\uff08\u9ad8\u6e29\u3001\u9ad8\u538b\u548c\u653e\u5c04\u6027\u7b49\uff09\u6216\u8005\u5b9e\u9a8c\u96be\u4ee5\u51c6\u786e\u6d4b\u5b9a\u7684\u70ed\u529b\u5b66\u6570\u636e\u3002<\/p>\n

CALPHAD\u65b9\u6cd5\u57fa\u4e8e\u70ed\u529b\u5b66\u7406\u8bba\uff0c\u6839\u636e\u5404\u4e2a\u7ec4\u6210\u76f8\uff08\u5305\u62ec\u6c14\u76f8\uff0c\u6db2\u76f8\uff0c\u56fa\u6eb6\u4f53\u548c\u5316\u5408\u7269\uff09\u7684\u6676\u4f53\u7ed3\u6784\u5efa\u7acb\u70ed\u529b\u5b66\u6a21\u578b\uff0c\u901a\u8fc7\u8bc4\u4f30\u7b5b\u9009\u4e00\u5b9a\u6e29\u5ea6\u538b\u529b\u4e0b\u7684\u591a\u5143\u6750\u6599\u4f53\u7cfb\u7684\u5b9e\u9a8c\u53ca\u7406\u8bba\u8ba1\u7b97\uff08\u5305\u62ec\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u3001\u7edf\u8ba1\u5b66\u65b9\u6cd5\u548c\u7ecf\u9a8c\u3001\u534a\u7ecf\u9a8c\u516c\u5f0f\uff09\u6570\u636e\uff0c\u62df\u5408\u4f18\u5316\u6a21\u578b\u53c2\u6570\uff0c\u786e\u5b9a\u4f53\u7cfb\u4e2d\u6bcf\u4e00\u4e2a\u76f8\u5409\u5e03\u65af\uff08Gibbs\uff09\u81ea\u7531\u80fd\uff0c\u5e76\u6700\u7ec8\u5efa\u7acb\u591a\u5143\u591a\u7ec4\u5206\u6750\u6599\u4f53\u7cfb\u70ed\u529b\u5b66\u6570\u636e\u5e93\u3002 \u56fe1\u4e3aCALPHAD\u65b9\u6cd5\u6d41\u7a0b\u793a\u610f\u56fe\u3002CALPHAD\u65b9\u6cd5\u662f\u76ee\u524d\u552f\u4e00\u53ef\u4ee5\u8ba1\u7b97\u591a\u5143\u4f53\u7cfb\u70ed\u529b\u5b66\u6027\u8d28\u5e76\u80fd\u6ee1\u8db3\u5b9e\u9645\u5e94\u7528\u7cbe\u5ea6\u8981\u6c42\u7684\u70ed\u529b\u5b66\u8ba1\u7b97\u65b9\u6cd5\u3002\u5b83\u8fd8\u662f\u6750\u6599\u52a8\u529b\u5b66\u3001\u5fae\u89c2\u7ed3\u6784\u6f14\u53d8\u6a21\u62df\u7684\u70ed\u529b\u5b66\u57fa\u7840\u3002\u56e0\u6b64\uff0cCALPHAD\u65b9\u6cd5\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e\u65b0\u6750\u6599\u7814\u5236\u548c\u65b0\u5de5\u827a\u7684\u8bbe\u8ba1\u4e4b\u4e2d\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1\u4e3aCALPHAD\u65b9\u6cd5\u6d41\u7a0b\u793a\u610f\u56fe [1]<\/p>\n

\u672c\u6587\u5c06\u4ecb\u7ecdCALPHAD\u65b9\u6cd5\u5728\u4f20\u7edf\u5408\u91d1\u5408\u91d1\u8bbe\u8ba1\uff0c\u9ad8\u71b5\u5408\u91d1\u7684\u5f00\u53d1, 3D\u6253\u5370\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u7684\u5e94\u7528<\/p>\n

1. \u4f20\u7edf\u5408\u91d1\u5408\u91d1\u5f00\u53d1<\/p>\n

\u91d1\u5c5e\u95f4\u5316\u5408\u7269NiAl\u5728\u9ad8\u6e29\u5408\u91d1\u9886\u57df\u6781\u5177\u5e94\u7528\u524d\u666f\uff0c\u4f46\u662f\u8f83\u5dee\u7684\u5ef6\u5c55\u6027\u6781\u5927\u5730\u9650\u5236\u4e86\u5176\u5e94\u7528\u3002Kainuma\u7b49\u4eba[2]\u5229\u7528CALPHAD\u65b9\u6cd5\u548c\u5b9e\u9a8c\u786e\u5b9a\u7684Ni-Al-Fe\u4f53\u7cfb\u7684\u76f8\u56fe(\u56fe2a)\uff0c\u786e\u5b9a\u4e86NiAl\u3001Ni \u56fa\u6eb6\u4f53\u548cNi3Al\u76f8\u7684\u7ec4\u5206\u533a\u95f4\u3002\u901a\u8fc7\u4f18\u5316\u5408\u91d1\u7ec4\u5206\u70ed\u5904\u7406\u5de5\u827a\u548c\u5408\u91d1\u7ec4\u5206(\u56fe2b)\uff0c\u83b7\u5f97\u4e86\u4e09\u79cd\u7531NiAl\u548cNi3Al\u76f8\u7ec4\u6210\u4f46\u5fae\u89c2\u7ed3\u6784\u622a\u7136\u4e0d\u540c\u7684NiAl\u57fa\u5408\u91d1\u6750\u6599\u3002\u8be5\u6750\u6599\u7684\u5ef6\u5c55\u6027\u4e0eNiAl\u76f8\u6bd4\u5f97\u5230\u4e86\u5927\u5e45\u5ea6\u63d0\u9ad8\uff0c\u8fbe\u5230\u4e8610%\uff0c\u5e76\u4e14\u5f3a\u5ea6\u9ad8\u8fbe750-1000 MPa.<\/p>\n

\"\"<\/p>\n

\u56fe2 1) Ni-25Al-xFe\u5782\u76f4\u622a\u9762\uff0c2) \u4e09\u79cd\u4e0d\u540cNiAl\u548cNi3Al\u4e8c\u5143\u7ed3\u6784\u7684\u5fae\u89c2\u7ed3\u6784\u6f14\u53d8, \u4ece\u4e0a\u5230\u4e0b\u7ec4\u5206\u4e3aNi-25Al-(18,15,13)Fe<\/p>\n

2. \u9ad8\u71b5\u5408\u91d1\u7684\u5f00\u53d1<\/p>\n

\u9ad8\u71b5\u5408\u91d1\uff08High entropy alloy, HEA\uff09\u4ee3\u8868\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u5408\u91d1\u8bbe\u8ba1\u7406\u5ff5\u3002HEA\u4e2d\u901a\u5e38\u542b\u67095\u4e2a\u6216\u80055\u4e2a\u4ee5\u4e0a\u7684\u5143\u7d20\u3002\u8fd9\u4e9b\u5143\u7d20\u6709\u4e00\u6837\u7684\u6216\u8005\u8fd1\u4f3c\u7684\u539f\u5b50\u5206\u6570\u3002\u4e0e\u4f20\u7edf\u5408\u91d1\u4e0d\u540c\uff0cHEA\u901a\u5e38\u5f62\u6210\u5177\u6709\u7b80\u5355\u7684\u4f53\u5fc3\u7acb\u65b9(bcc)\u6216\u9762\u5fc3\u7acb\u65b9\u76f8(fcc). \u4e0e\u4f20\u7edf\u5408\u91d1\u76f8\u6bd4\uff0cHEA\u62e5\u6709\u5f88\u591a\u4f18\u5f02\u7279\u6027\uff0c\u901a\u8fc7\u5408\u7406\u7684\u914d\u65b9\u8bbe\u8ba1\uff0c\u53ef\u4ee5\u83b7\u5f97\u9ad8\u5f3a\u5ea6\u3001\u9ad8\u786c\u5ea6\u3001\u9ad8\u52a0\u5de5\u786c\u5316\u3001\u8010\u9ad8\u6e29\u8f6f\u5316\u3001\u8010\u9ad8\u6e29\u6c27\u5316\u3001\u8010\u8150\u8680\u548c\u9ad8\u7535\u963b\u7387\u7b49\u7279\u6027\u7ec4\u5408\uff0c\u56e0\u6b64\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u5e76\u5177\u6709\u5f88\u5927\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u5229\u7528TCHEA1\u6570\u636e\u5e93\u8ba1\u7b97\u5f97\u5230\u7684Co-Cr-Fe-Mn-Ni \u4f53\u7cfb\u4e2d10626\u4e2a\u7ec4\u5206\u76f8\u7ec4\u6210<\/p>\n

Bracq\u7b49\u4eba[3]\u5229\u7528TCHEA1\u9ad8\u71b5\u5408\u91d1\u6570\u636e\u5e93\uff0c\u7814\u7a76\u4e86fcc\u76f8\u5728Co-Cr-Fe-Mn-Ni \u4f53\u7cfb\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u901a\u8fc7\u5bf910626\u4e2a\u7ec4\u5206\u7684\u8ba1\u7b97\uff0c\u786e\u5b9a\u4e86\u5355\u4e00fcc\u76f8\u7684\u7a33\u5b9a\u533a\u95f4 \uff08\u56fe3\uff09\uff0c\u5e76\u5b9e\u9a8c\u9a8c\u8bc1\u4e86\u8be5\u8ba1\u7b97\u7ed3\u679c\u7684\u51c6\u786e\u6027\u3002\u8ba1\u7b97\u8fdb\u4e00\u6b65\u8868\u660eCr\u548cMn\u542b\u91cf\u7684\u5347\u9ad8\u4f1a\u964d\u4f4efcc\u76f8\u7684\u7a33\u5b9a\u76f8\u800cNi\u548cCo\u80fd\u591f\u63d0\u9ad8fcc\u76f8\u7684\u7a33\u5b9a\u6027\u3002\u8be5\u6210\u679c\u4f7f\u5f97\u901a\u8fc7\u4f18\u5316Co-Cr-Fe-Mn-Ni \u57faHEA\u5316\u5b66\u7ec4\u6210\u6765\u4f18\u5316\u5408\u91d1\u6027\u80fd\u6210\u4e3a\u53ef\u80fd\u3002<\/p>\n

3. \u589e\u6750\u5236\u9020\uff083D\u6253\u5370\uff09<\/p>\n

\u4eca\u5e74\u6765\uff0c\u7531\u4e8e\u5176\u8fc7\u7a0b\u7684\u7075\u6d3b\u6027\u3001\u53ef\u63a7\u6027\u3001\u80fd\u591f\u5236\u5907\u4f20\u7edf\u5236\u9020\u65b9\u5f0f\u65e0\u6cd5\u5236\u5907\u7684\u590d\u6742\u7ed3\u6784\u4ef6\u7b49\u7279\u70b9\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u591a\u5143\u76f8\u56fe\u88ab\u8ba4\u4e3a3D\u6253\u5370\u5236\u5907\u91d1\u5c5e\u90e8\u4ef6\u7684\u201c\u5730\u56fe\u201d\u3002\u57283D\u6253\u5370\u5236\u5907\u68af\u5ea6\u91d1\u5c5e\u6750\u6599\u4e2d\uff0cHofmann\u7b49\u4eba[4]\u5229\u7528\u70ed\u529b\u5b66\u8ba1\u7b97\u83b7\u5f97\u7684\u76f8\u56fe\uff0c\u786e\u5b9a\u4e86\u6700\u4f18\u7684\u7ec4\u5206\u68af\u5ea6\u8def\u5f84\uff0c\u4ee5\u907f\u514d\u8106\u6027\u76f8\u7684\u751f\u6210\u3002\u8fd0\u7528\u8fd9\u4e00\u7406\u5ff5\uff0c\u6210\u529f\u5236\u5907\u4e86304L\/Inconel626\u3001304L\/Invar36\u3001Ti-6-4\/Nb\u3001Ti-6-4\/V\/420\u4e0d\u9508\u94a2\u3001Ti-6-4\/TiC\u7b49\u4e00\u7cfb\u5217\u68af\u5ea6\u6750\u6599\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 1)\u4e09\u5143\u76f8\u56fe\u4e2d\u4e24\u79cd\u5408\u91d1\u4e4b\u95f4\u53ef\u80fd\u7684\u7ec4\u5206\u68af\u5ea6\u8def\u5f84\uff0c2) 3D\u6253\u5370\u5236\u5907\u7684Ti-6-4\/Nb\u68af\u5ea6\u6750\u6599<\/p>\n

4. \u9502\u79bb\u5b50\u7535\u6c60<\/p>\n

\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u4e2d\uff0c\u5408\u91d1\u9633\u6781\u6750\u6599\u5177\u6709\u9ad8\u7535\u8377\u5bc6\u5ea6\u548c\u4f4e\u5316\u5b66\u7535\u4f4d\uff0c\u56e0\u6b64\u5176\u88ab\u8ba4\u4e3a\u6709\u671b\u53d6\u4ee3\u78b3\u8d28\u9633\u6781\u6750\u6599\uff0c\u5e76\u4e14\u7535\u6c60\u7684\u5b89\u5168\u6027\u4e5f\u4f1a\u5f97\u5230\u63d0\u9ad8\u3002Sn\u57fa\u5408\u91d1\u662f\u6700\u91cd\u8981\u7684\u5408\u91d1\u9633\u6781\u5907\u9009\u6750\u6599\u4e4b\u4e00\uff0c\u7531\u4e8e\u5176\u9ad8\u7684\u7406\u8bba\u7535\u8377\u5bc6\u5ea6\uff08Li22Sn5, 994 mAh\/g\uff09\u548c\u4f4e\u5316\u5b66\u7535\u4f4d\u3002Li\u7b49\u4eba[5]\u5229\u7528CALPHAD\u65b9\u6cd5\u5efa\u7acb\u4e86Li-Sn\u4f53\u7cfb\u7684\u70ed\u529b\u5b66\u6570\u636e\u5e93\uff0c\u5229\u7528\u8be5\u6570\u636e\u5e93\u8ba1\u7b97\u5f97\u5230\u4e86Li-Sn\u4f53\u7cfb\u4e2d\u4e0d\u540c\u5316\u5408\u7269\u7684\u5f00\u8def\u7535\u538b\uff0c\u5982\u56fe5\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 \u8ba1\u7b97\u5f97\u5230\u7684Li\u2013Sn \u5408\u91d1\u76f8\u5bf9\u4e8e\u7eaf\u9502\u7684\u5f00\u8def\u7535\u538b<\/p>\n

\u94dc\u7684\u6c27\u5316\u7269\u88ab\u8ba4\u4e3a\u6709\u671b\u5728\u4e0b\u4e00\u4ee3\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u3002Lepple\u7b49\u4eba[6]\u5229\u7528CALPHAD\u65b9\u6cd5\u5efa\u7acb\u4e86Li-Cu-O\u4f53\u7cfb\u7684\u70ed\u529b\u5b66\u6570\u636e\u5e93. \u5229\u7528\u8be5\u6570\u636e\u5e93\u8ba1\u7b97\u5f97\u5230\u4e86\u5f53CuO\u6216\u8005Cu2O\u4f5c\u4e3a\u9634\u6781\u6750\u6599\u65f6\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u7535\u538b\u4e0e\u9502\u542b\u91cf\u7684\u5173\u7cfb\u3002\u8ba1\u7b97\u8868\u660e<\/p>\n

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\uff082\uff09\u5f53Cu2O\u4f5c\u4e3a\u9634\u6781\u6750\u6599\u65f6\uff0c\u4ec5\u6709\u4e24\u4e2a\u5e73\u53f0\u533a\u95f4\u3002\u7b2c\u4e00\u4e2a\u5e73\u53f0\u533a\u95f4\u7684\u7535\u6c60\u7535\u538b\u4f1a\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\u800c\u7b2c\u4e8c\u4e2a\u5e73\u53f0\u533a\u95f4\u7684\u7535\u538b\u4f1a\u968f\u7740\u6e29\u5ea6\u7684\u589e\u52a0\u800c\u51cf\u5c0f\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6\u8ba1\u7b97\u5f97\u5230\u7684(a) CuO\u548c(b) Cu2O\u4f5c\u4e3a\u9634\u6781\u6750\u6599\u65f6\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u7535\u538b\u4e0e\u9502\u542b\u91cf\u7684\u5173\u7cfb<\/p>\n

CALPHAD\u65b9\u6cd5\u5728\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u4e2d\u7684\u5e94\u7528\u8fd8\u6709\u5f88\u591a\uff0c\u5177\u4f53\u53ef\u4ee5\u53c2\u8003\u4e66\u7c4dCALPHAD (Calculation of Phase Diagrams)\uff1aA Comprehensive Guide [7]\u3002<\/p>\n

\u53c2\u8003\u6587\u732e
\n [1] H.J. Seifert, F. Aldinger, Applied phase studies. Z. Metallkd. 87 (1996) 841-853.<\/p>\n

[2] R. Kainuma, S. Imano, H. Ohtani, K. Ishida, Intermetallics 4 (1996) 37-45.<\/p>\n

[3] G. Bracq, M. Laurent-Brocq, L. Perriere, R. Pires, J. Joubert, I. Guillot, Acta Materialia 128 (2017) 327-336.<\/p>\n

[4] D.C. Hofmann, J. Kolodziejska, S. Roberts, R. Otis, R.P. Dillon, J.-O. Suh, Z.-K. Liu, J.-P. Borgonia, Journal of Materials Research 29 (2014) 1899-1910.<\/p>\n

[5] D. Li, S. F\u00fcrtauer, H. Flandorfer, D.M. Cupid, Calphad 47 (2014) 181-195.<\/p>\n

[6] M. Lepple, R. Adam, D.M. Cupid, P. Franke, T. Bergfeldt, D. Wadewitz, D. Rafaja, H.J. Seifert, J. Mater. Sci. 48 (2013) 5818-5826.<\/p>\n

[7] N.J. Saunders, A.P. Miodownik, CALPHAD (Calculation of Phase Diagrams)\uff1aA Comprehensive Guide, Pergamon Press, Oxford ,1998.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u4e13\u680f\u79d1\u6280\u987e\u95ee\u5f6d\u535a\u58eb\u4f9b\u7a3f\u3002<\/p>\n

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\"\"<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

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