{"id":137672,"date":"2018-05-09T14:00:59","date_gmt":"2018-05-09T06:00:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=137672"},"modified":"2018-05-07T21:33:00","modified_gmt":"2018-05-07T13:33:00","slug":"%e5%8c%97%e5%a4%a7%e6%b7%b1%e5%9c%b3%e7%a0%94%e7%a9%b6%e9%99%a2%e6%bd%98%e9%94%8bnano-energy%ef%bc%9a%e5%9b%ba%e6%80%81%e7%94%b5%e6%b1%a0%e4%b8%ad%ef%bc%8cmof%e5%8d%b3%e7%a6%bb%e5%ad%90%e5%af%bc","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=137672","title":{"rendered":"\u5317\u5927\u6df1\u5733\u7814\u7a76\u9662\u6f58\u950bNano Energy\uff1a\u56fa\u6001\u7535\u6c60\u4e2d\uff0cMOF\u5373\u79bb\u5b50\u5bfc\u4f53\u4fc3\u8fdb\u754c\u9762Li+\u4f20\u8f93"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u662f\u76ee\u524d\u7814\u7a76\u548c\u5e94\u7528\u8f83\u5e7f\u7684\u7eff\u8272\u50a8\u80fd\u6750\u6599\u3002\u4f46\u662f\u76ee\u524d\u5173\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b89\u5168\u6027\u3001\u5bb9\u91cf\u7684\u5927\u5c0f\u548c\u50a8\u80fd\u673a\u5236\u7684\u7814\u7a76\uff0c\u8fd8\u4e0d\u5b8c\u5584\u3002\u56fa\u6001\u7535\u6c60\u80fd\u591f\u89e3\u51b3\u9502\u79bb\u5b50\u7535\u6c60\u5728\u5e94\u7528\u8fc7\u7a0b\u4e2d\uff0c\u9762\u4e34\u7684\u4e00\u90e8\u5206\u5b89\u5168\u95ee\u9898\u3002\u7136\u800c\uff0c\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u7535\u5bfc\u7387\u95ee\u9898\u4e00\u76f4\u56f0\u6270\u7740\u5176\u53d1\u5c55\u3002\u4e3b\u8981\u539f\u56e0\u662f\u56fa\u6001\u9897\u7c92\u4e4b\u95f4\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4f4e\uff0c\u754c\u9762\u7535\u963b\u8f83\u9ad8\uff0c\u663e\u8457\u5f71\u54cd\u4e86\u56fa\u6001\u7535\u6c60\u7684\u53d1\u5c55\u548c\u5e94\u7528\u3002\u672c\u6587\u627e\u5230\u4e86\u4e00\u79cd\u65b0\u7684\u3001\u7535\u5316\u5b66\u7a33\u5b9a\u7684MOF\u79bb\u5b50\u5bfc\u4f53\uff0c\u6781\u5927\u7684\u63d0\u9ad8\u4e86\u56fa\u6001\u7535\u6c60\u7684\u79bb\u5b50\u4f20\u8f93\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 <\/strong>\u56fa\u6001\u7535\u6c60\u4e2d\uff0c<\/strong>LIM<\/strong>\u79bb\u5b50\u5bfc\u4f53\u7684\u7ed3\u6784\u53ca\u5176\u5de5\u4f5c\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong> 2 UIO-67<\/strong>\u548c<\/strong>LIM<\/strong>\u79bb\u5b50\u5bfc\u4f53\u663e\u5fae\u7ed3\u6784\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09UIO-67 MOF\u7684\u5b9e\u9a8c\u548c\u6a21\u62dfXRD\u56fe\u8c31\uff1b<\/p>\n

\uff08b\uff09\u9676\u74f7LLZO\u7c89\u672b\u548c\u6807\u51c6Li5<\/sub>La3<\/sub>Nb2<\/sub>O12<\/sub>\u5361\u7247\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

\uff08c\uff09UIO-67 MOF\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09LIM\u79bb\u5b50\u5bfc\u4f53\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 3 LIMs<\/strong>\u79bb\u5b50\u5bfc\u4f53\u7684<\/strong>Arrhenius<\/strong>\u548c\u963b\u6297\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u79bb\u5b50\u6db2\u4f53\u542b\u91cf\u7684LIMs\u79bb\u5b50\u5bfc\u4f53\u7684Arrhenius\u56fe\uff1b<\/p>\n

\uff08b\uff09\u572830-100\u2103\u4e0b\uff0cLIM\u6837\u54c1\u7684EIS\u66f2\u7ebf\uff08\u63d2\u5165\u56fe\u662f\u9ad8\u9891\u653e\u5927\u56fe\uff09\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540cLIM\u542b\u91cf\u7684LIM-L\u3001\u70e7\u7ed3\u540eLLZO\u9676\u74f7\u7247\u548cLLZO\u7c89\u672b\u538b\u7247\u79bb\u5b50\u5bfc\u7535\u6027\u7684Arrhenius\u56fe\uff1b<\/p>\n

\uff08d\uff09\u542b\u670920 wt%\u7684LIM-L\u7684LIM-L\u7684EIS\u56fe\uff08\u63d2\u5165\u56fe\u662f\u9ad8\u9891\u653e\u5927\u56fe\uff09\u3002<\/p>\n

\u56fe<\/strong> 4 <\/strong>Li\/LIM\/Li<\/strong>\u5bf9\u79f0\u7535\u6c60\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7eb3\u7c73\u6da6\u6e7f\u754c\u9762\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09Li-IL\uff0cLIM\u79bb\u5b50\u5bfc\u4f53\u548cLIM-L\u6df7\u5408SSEs\u7684Li+<\/sup>\u8fc1\u79fb\u6570\uff1b<\/p>\n

\uff08c\uff09\u6781\u5316\u524d\u540e\uff0cLi\/LIM\/Li\u5bf9\u79f0\u7535\u6c60\u7684\u963b\u6297\u56fe\uff08\u63d2\u5165\u56fe\u662f\u6781\u5316\u8fc7\u7a0b\u4e2d\u7535\u6d41\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff09\uff1b<\/p>\n

\uff08d\uff09Li-IL\uff0cLLZO\uff0cLIM\u79bb\u5b50\u5bfc\u4f53\u548cLIM-L\u6df7\u5408SSE\u7684\u7535\u5316\u5b66\u7a97\u53e3\uff1b<\/p>\n

\uff08e\uff09\u57280.1 mA\/cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cLi\/LIM\/Li\u5bf9\u79f0\u7535\u6c60\u7684\u7535\u9540\u5265\u79bb\u56fe\u3002<\/p>\n

\u56fe<\/strong> 5 <\/strong>LiCoO2<\/sub><\/strong>\u548c<\/strong>LiFePO4<\/sub> SSBs<\/strong>\u7684\u7535\u6c60\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cLiCoO2<\/sub> SSBs\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09LiCoO2<\/sub> SSBs\u7684\u500d\u7387\u56fe\uff1b<\/p>\n

\uff08c\uff09\u57280.1 C\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cLiCoO2<\/sub> SSBs\u7684\u5faa\u73af\u6027\u80fd\u56fe\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cLiFePO4<\/sub> SSBs\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u53d1\u73b0\u6d78\u6da6Li+<\/sup>\u79bb\u5b50\u6db2\u4f53\u7684MOF\u4e3b\u4f53\u7684\u65b0\u578b\u79bb\u5b50\u5bfc\u4f53\uff0c\u53ef\u4ee5\u5728LLZO\u56fa\u6001\u7535\u6c60\u4e2d\u964d\u4f4e\u754c\u9762\u963b\u6297\u3002MOF\u4e3b\u4f53\u5177\u67093 D\u901a\u5b54\u7ed3\u6784\uff0c\u4f7f\u5185\u90e8Li-IL\u79bb\u5b50\u76f4\u63a5\u4e0eLLZO\u548c\u6b63\u6781\u9897\u7c92\u63a5\u89e6\uff0c\u5f62\u6210\u7eb3\u7c73\u6d78\u6da6Li+<\/sup>\u4f20\u8f93\u754c\u9762\u3002\u79bb\u5b50\u5bfc\u4f53\u548cLLZO\u7684\u6df7\u5408SSE\u5177\u6709\u9ad8\u7684\u79bb\u5b50\u5bfc\u7535\u73871.0\u00d710-4 <\/sup>S\u00b7cm-1<\/sup>\uff0c\u5bbd\u7684\u5316\u5b66\u7a97\u53e35.2 V\u3002\u6df7\u5408SSE\u548cLi\u8d1f\u6781\u5177\u6709\u5f88\u597d\u7684\u5339\u914d\u6027\uff0c\u5747\u5300\u7684Li\u6c89\u79ef\u80fd\u591f\u6709\u6548\u5730\u6291\u5236Li\u679d\u6676\u7684\u751f\u957f\u3002\u5f53\u79bb\u5b50\u5bfc\u4f53\u52a0\u5165\u5230LCO\u548cLFP SSBs\uff0c\u6709\u6548\u7684Li+\u4f20\u8f93\u7f51\u7edc\u5728\u7535\u6c60\u5185\u90e8\u5f62\u6210\uff0c\u8fdb\u800c\u63d0\u9ad8\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u80fd\u3002\u5177\u6709\u7eb3\u7c73\u6d78\u6da6\u754c\u9762\u7684\u79bb\u5b50\u5bfc\u4f53\u6709\u52a9\u4e8eLi+<\/sup>\u4f20\u8f93\uff0c\u8fd9\u79cd\u65b9\u6cd5\u5b9e\u73b0\u4e3aSSB\u89c4\u6a21\u5316\u5236\u9020\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Boosting Interfacial Li+ Transport with a MOF-Based Ionic Conductor for Solid-State Batteries<\/a>\uff08Nano Energy, 2018, DOI: 0.1016\/j.nanoen.2018.04.076\uff09\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/p>\n

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