{"id":13644,"date":"2016-05-15T21:00:24","date_gmt":"2016-05-15T13:00:24","guid":{"rendered":"\/\/m.iemloyee.com\/?p=13644"},"modified":"2016-05-16T10:41:12","modified_gmt":"2016-05-16T02:41:12","slug":"%e6%9b%b4%e5%a5%bd%e7%9a%84%e9%94%82%e7%a1%ab%e7%94%b5%e6%b1%a0%ef%bc%9a%e5%8d%97%e5%bc%80%e9%99%88%e5%86%9b%e8%af%be%e9%a2%98%e7%bb%84%e5%bc%80%e5%8f%91%e5%87%ba%e6%96%b0%e5%9e%8b%e9%98%b4%e6%9e%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=13644","title":{"rendered":"\u66f4\u597d\u7684\u9502\u786b\u7535\u6c60\uff1a\u5357\u5f00\u9648\u519b\u8bfe\u9898\u7ec4\u5f00\u53d1\u51fa\u65b0\u578b\u9634\u6781\u6750\u6599\u4e0e\u591a\u529f\u80fd\u7c98\u7ed3\u5242\u3010\u65b0\u80fd\u6e90160515\u671f\u3011"},"content":{"rendered":"<p>\u4f5c\u4e3a\u7535\u6c60\u7684\u7535\u6781\u6d3b\u6027\u6750\u6599\uff0c\u6709\u673a\u5316\u5408\u7269\u7531\u4e8e\u5176\u7ed3\u6784\u7684\u591a\u6837\u6027\u3001\u53ef\u518d\u751f\u6027\u9ad8\u3001\u4f4e\u6210\u672c\u3001\u73af\u5883\u53cb\u597d\u7b49\u7279\u70b9\u53d7\u5230\u4e86\u79d1\u7814\u4eba\u5458\u7684\u5173\u6ce8\u3002\u7fb0\u57fa\u5316\u5408\u7269\uff08\u7279\u522b\u662f\u918c\uff09\uff0c\u7531\u4e8e\u5176\u9ad8\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u548c\u5feb\u901f\u53cd\u5e94\u52a8\u529b\u5b66\u8868\u73b0\uff0c\u88ab\u8a89\u4e3a\u662f\u6700\u6709\u53d1\u5c55\u524d\u666f\u7684\u6750\u6599\u4e4b\u4e00\u3002<\/p>\n<p>\u7136\u800c\uff0c\u8981\u5c06\u918c\u7c7b\u5e94\u7528\u4e8e\u7535\u6781\u6750\u6599\u4f9d\u65e7\u5b58\u5728\u8bf8\u591a\u95ee\u9898\uff0c\u6bd4\u5982\u5176\u8fd8\u539f\u7535\u4f4d\u8f83\u4f4e\u3001\u5728\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u6709\u8f83\u9ad8\u7684\u6eb6\u89e3\u5ea6\u4ee5\u53ca\u8f83\u4f4e\u7684\u7535\u5b50\u5bfc\u7535\u7387\u7b49\u3002\u786b\u6742\u73af\u7684\u5f15\u5165\u53ef\u8c03\u8282\u6709\u673a\u5316\u5408\u7269\u7684\u6700\u4f4e\u672a\u5360\u636e\u5206\u5b50\u8f68\u9053\uff08LUMO\uff09\u80fd\u7ea7\u4ece\u800c\u5f71\u54cd\u5176\u8fd8\u539f\u7535\u4f4d\u3002\u4f8b\u5982\uff0c\u84bd\u918c\u7684LUMO\u80fd\u7ea7\u4e3a3.2 eV\uff0c\u76f8\u5bf9\u4e8eLi<sup>+<\/sup>\/Li\u8fd8\u539f\u7535\u4f4d\u4e3a2.27 V\u3002\u901a\u8fc7\u5f15\u5165S\u5143\u7d20benzo [1,2-b:4,5`]dithiophene-4,8-dione\uff08BDTD\uff09\uff0c\u5176LUMO\u80fd\u7ea7\u51cf\u5c0f\u5230\u4e863.5 eV\uff0c\u5bf9\u5e94\u8fd8\u539f\u7535\u4f4d\u4e3a2.52 V\u3002\u6b64\u5916\uff0c\u53e6\u4e00\u79cd\u7fb0\u57fa\u5e26\u6709\u03c0\u5171\u8f6d\u7ed3\u6784\u6709\u673a\u5206\u5b50PT\uff0c\u5176\u521d\u59cb\u8fd8\u539f\u7535\u4f4d\u662f2.6 V\u3002\u5f53\u628aS\u5f15\u5165PT\u540e\u5176LUMO\u80fd\u7ea7\u964d\u4f4e\u3002<\/p>\n<p>\u5357\u5f00\u5927\u5b66\u7684\u9648\u519b\u6559\u6388\u8bfe\u9898\u7ec4\u6700\u8fd1\u5236\u5907\u4e86\u4e00\u79cd\u5c06\u786b\u6742\u73af\u918c\uff08DTT\uff09\u4f5c\u4e3a\u9634\u6781\uff0c poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate )\uff08PEDOT:PSS\uff09\u4f5c\u4e3a\u7c98\u7ed3\u5242\u7684\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u3002\u7531\u4e8eDTT\u548cPEDOT:PSS\u4e4b\u95f4\u5b58\u5728\u7740\u975e\u5171\u4ef7\u952e\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8fd9\u5c06\u6709\u52a9\u4e8e\u6291\u5236DTT\u6eb6\u89e3\uff0c\u540c\u65f6\u4f1a\u589e\u52a0DTT\u7684\u5bfc\u7535\u80fd\u529b\uff0c\u4ece\u800c\u4f7f\u7535\u5316\u5b66\u6027\u80fd\u5f97\u5230\u6781\u5927\u7684\u6539\u5584\u3002\u5c06DTT\u4f5c\u4e3a\u9634\u6781\uff0cPEDOT:PSS\u4f5c\u4e3a\u7c98\u7ed3\u5242\u8868\u73b0\u51fa\u4e86\u6781\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u9996\u6b21\u5faa\u73af292 mAh g<sup>-1<\/sup>\uff0c0.1 C\u4e0b200\u5faa\u73af\u540e\u4e3a266 mAh g<sup>-1<\/sup>\uff09\u548c\u9ad8\u500d\u7387\u6027\u80fd\uff081C\u4e0b220 mAh g<sup>-1<\/sup>\uff09\u3002<\/p>\n<p>\u918c\u7684\u4f4e\u7535\u5bfc\u7387\u548c\u96be\u6eb6\u6027\u95ee\u9898\u901a\u5e38\u53ef\u4ee5\u901a\u8fc7\u6dfb\u52a0\u5404\u79cd\u5bfc\u7535\u6dfb\u52a0\u5242\u6765\u89e3\u51b3\uff08\u5982\u78b3\u6750\u6599\uff09\u3002\u7136\u800c\uff0c\u4f5c\u4e3a\u7535\u6781\u7684\u53e6\u4e00\u4e2a\u4e3b\u8981\u6784\u6210\u90e8\u5206&#8212;\u7c98\u5408\u5242\uff0c\u901a\u5e38\u662f\u5728\u8fd9\u4e2a\u95ee\u9898\u4e0a\u5f88\u5c11\u88ab\u8003\u8651\u5230\u3002\u805a\u504f\u6c1f\u4e59\u70ef\uff08PVDF\uff09\u4f5c\u4e3a\u4e00\u79cd\u6700\u53d7\u6b22\u8fce\u7684\u7c98\u7ed3\u5242\uff0c\u5176\u672c\u8eab\u662f\u4e00\u79cd\u7535\u5b50\u9694\u79bb\u805a\u5408\u7269\uff0c\u5b83\u7684\u7279\u70b9\u662f\u53ef\u4ee5\u964d\u4f4e\u7535\u6781\u7684\u5bfc\u7535\u6027\u3002\u5bfc\u7535\u805a\u5408\u7269\uff08\u5982\u805a\u82ef\u80fa\u3001\u805a\u5421\u54af\u3001\u805a\u567b\u5429\u53ca\u5176\u884d\u751f\u7269\uff09\u7531\u4e8e\u5176\u4f18\u826f\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u9ad8\u7684\u7535\u5bfc\u7387\u76ee\u524d\u5df2\u5e7f\u6cdb\u5e94\u7528\u5728\u5404\u79cd\u5bfc\u7535\u8bbe\u5907\u4e0a\u3002\u4e00\u4e9b\u5bfc\u7535\u805a\u5408\u7269\u5982PEDOT\uff1aPSS\u5df2\u7ecf\u8bc1\u5b9e\u53ef\u4ee5\u4f5c\u4e3a\u65e0\u673a\u7535\u6781\u7c98\u7ed3\u5242\u3002\uff08PEDOT\u7531\u4e8e\u5177\u6709\u03c0\u5171\u8f6d\u567b\u5429\u73af\u6240\u4ee5\u643a\u5e26\u9633\u79bb\u5b50\uff0c PSS\u4e2d\u6e38\u79bb\u7684\u78fa\u9178\u57fa\u56e2\u901a\u8fc7\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\u6765\u5e73\u8861PEDOT\u4e2d\u7684\u9633\u79bb\u5b50\uff09\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u4e0e\u4e00\u4e9b\u6709\u673a\u7535\u5b50\u7ed9\u4f53\uff08\u5982DTT\uff09\u7684\u76f8\u4e92\u4f5c\u7528\uff0cPEDOT\u6709\u671b\u6210\u4e3a\u7535\u5b50\u53d7\u4f53\u3002\u6240\u4ee5\uff0c\u5c06PEDOT\uff1aPSS\u4f5c\u4e3a\u6709\u673a\u7535\u6781\u7c98\u5408\u5242\u662f\u4e00\u4e2a\u4e0d\u9519\u7684\u9009\u62e9\u3002<\/p>\n<p>\u4ee5\u4e0b\u662f\u8be5\u6587\u7ae0\u56fe\u6587\u5bfc\u8bfb\uff1a<\/p>\n<p>\u8981\u7814\u7a76\u67d0\u79cd\u6750\u6599\uff0c\u9996\u5148\u8981\u77e5\u9053\u5176\u5206\u5b50\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-13645 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/FIG1.png\" alt=\"FIG1\" width=\"276\" height=\"151\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u56fea\uff09 DTT\/ Li<sub>4<\/sub>DTT\u7684\u7ed3\u6784\u4ee5\u53ca\u53ef\u9006\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u673a\u5236\uff08DTT \u76f8\u5bf9\u5206\u5b50\u91cf\u4e3a376 g mol<sup>-1<\/sup>\uff0c\u7406\u8bba\u5bb9\u91cf285 mAh g<sup>-1<\/sup> \uff09<\/p>\n<p>\u56feb\uff09\u805a\u5408\u7269PEDOT\uff1aPSS\u7684\u7ed3\u6784\u3002<\/p>\n<p>\u603b\u7ed3\u6765\u770b\uff0cDTT\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u6709\u4ee5\u4e0b\u51e0\u4e2a\u4f18\u70b9\uff1a<\/p>\n<p>1\uff09\u7531\u918c\u5f0f\u7ed3\u6784\u63d0\u4f9b\u7684\u591a\u7535\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u662f\u53ef\u4ee5\u8fdb\u884c\u7684\uff1b<\/p>\n<p>2\uff09\u589e\u52a0\u4e86\u7535\u5b50\u5bfc\u7535\u6027\uff0c\u5e76\u4e14\u7531\u4e8e\u5177\u6709\u03c0\u5171\u8f6d\u7ed3\u6784\uff0cDTT\u6bd4\u5176\u4ed6\u975e\u5171\u8f6d\u6709\u673a\u5206\u5b50\u5728\u7535\u89e3\u8d28\u4e2d\u66f4\u4e0d\u6613\u6eb6\u89e3\uff1b<\/p>\n<p>3\uff09\u786b\u6742\u73af\u7684\u5f15\u5165\u589e\u5f3a\u4e86\u8fd8\u539f\u7535\u4f4d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-13646 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/FIG2.png\" alt=\"FIG2\" width=\"610\" height=\"212\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/FIG2.png 610w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/FIG2-300x104.png 300w\" sizes=\"(max-width: 610px) 100vw, 610px\" \/><\/p>\n<p>\u56fe1. a\uff09DTT\u4e3a\u9634\u6781\uff0c\u626b\u63cf\u901f\u7387\u4e3a0.1 mV s<sup>-1<\/sup>\uff0c CV\u66f2\u7ebf\u7684\u57281.6\u20133.6 V\u7684\u7535\u538b\u8303\u56f4\uff1b b\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u663e\u8457\u70b9\u5bf9\u5e94\u7684\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff080.1\u2103\uff0c1 C = 285 mA g<sup>-1<\/sup>\uff09\uff1b c\uff09XRD \u6d4b\u8bd5 d\uff09\u62c9\u66fc\u5149\u8c31 e\uff09DTT\u7684LUMO\u80fd\u7ea7\u56fe\uff1b\u3002f\uff09\u4e0d\u540c\u7684\u9502\u5316\u9636\u6bb5\u4e0bli<sub>x<\/sub>DTT\u6a21\u578b\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff08x = 0-4\uff09\u3002<\/p>\n<p>\u7531\u56fe\u4e2d\u53ef\u4ee5\u770b\u51fa\u6709\u4e09\u4e2a\u8fd8\u539f\u5cf0\uff08\u5206\u522b\u57282.85 V\uff0c2.33 V\u548c1.55 V\uff09\u548c\u56db\u6c27\u5316\u5cf0\uff08\u5206\u522b\u57282.60 V\uff0c2.87 V\uff0c3.17 V\u548c3.52 V\uff09\uff0c\u4e4b\u6240\u4ee5\u4f1a\u51fa\u73b0\u8fd9\u79cd\u73b0\u8c61\u7684\u539f\u56e0\u662f\u56e0\u4e3a\u524a\u51cf\u6b65\u9aa4\uff08LiDTT \/ Li<sub>2<\/sub>DTT \/ Li<sub>3<\/sub>DTT\uff09\u53d1\u751f\u7684\u975e\u5e38\u5feb\uff0c\u6bcf\u4e24\u4e2a\u6b65\u9aa4\u4e4b\u95f4\u7684\u7535\u538b\u95f4\u9699\u592a\u5c0f\u800c\u96be\u4ee5\u533a\u5206\u3002\u5e76\u4e14\u6c27\u5316\u5cf0\u4e0e\u8fd8\u539f\u5cf0\u7684\u9762\u79ef\u5927\u81f4\u76f8\u7b49\uff0c\u53ef\u4ee5\u63a8\u65adDTT\u5177\u6709\u826f\u597d\u7684\u53ef\u9006\u6027\u3002<\/p>\n<p>\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c DTT\u9996\u5148\u51fa\u73b0\u4e00\u4e2aX\u5c04\u7ebf\u884d\u5c04\u5cf0\u968f\u540e\u5cf0\u9010\u6e10\u51cf\u5f31\uff0c\u5728\u5b8c\u5168\u653e\u7535\u7684\u72b6\u6001\u4e0b\u5cf0\u6d88\u5931\u3002\u5728\u968f\u540e\u7684\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u7535\u6781\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u6848\u53c8\u53d8\u56de\u539f\u6765\u7684\u5f62\u5f0f\uff08\u5728\u56fe1c\u66f2\u7ebfC\uff09.\u7531\u4e8e\u7fb0\u57fa\uff08C=O\uff09\u7684\u5b58\u5728\u62c9\u66fc\u5149\u8c31\u57281648 cm<sup>-1 <\/sup>\u548c1580 cm<sup>-1<\/sup>\u5904\u51fa\u73b0\u9707\u52a8\uff0c\u800c\u540e\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u9010\u6e10\u6d88\u5931\uff0c\u5145\u7535\u8fc7\u7a0b\u4e2d\u9010\u6e10\u6062\u590d\u3002<\/p>\n<p>\u4e0a\u8ff0\u7684\u89c2\u5bdf\u8868\u660e\uff0c DTT\u5728\u9502\u5316\/\u8131\u9502\u8fc7\u7a0b\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u662f\u53ef\u9006\u7684,\u8fd9\u5c31\u8fdb\u4e00\u6b65\u652f\u6301\u4e86\u5faa\u73af\u4f0f\u5b89\u6cd5\uff08CV\uff09\u548c\u6052\u6d41\u653e\u7535\/\u5145\u7535\u7684\u8fdb\u4e00\u6b65\u7814\u7a76\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-13647 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/FIG3.png\" alt=\"FIG3\" width=\"299\" height=\"308\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/FIG3.png 299w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/FIG3-291x300.png 291w\" sizes=\"(max-width: 299px) 100vw, 299px\" \/><\/p>\n<p>\u56fe2. DTT\u548cPEDOT\uff1aPSS\u4e4b\u95f4\u7684\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u3002a\uff09TEM\u00a0 b\uff09HRTEM 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Chemie International Edition\u4e0a\uff0c\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201601119\/abstract\" target=\"_blank\">A Sulfur Heterocyclic Quinone Cathode and a Multifunctional Binder for a High-Performance Rechargeable Lithium-Ion Battery<\/a><\/p>\n<p>\u8be5\u6587\u732e\u89e3\u8bfb\u5bfc\u8bfb\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u5c0f\u7ec4 \u5927\u5b8b \u4f9b\u7a3f\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c\u82e5\u60f3\u53c2\u4e0e\u65b0\u80fd\u6e90\u6587\u732e\u89e3\u8bfb\u548c\u6587\u732e\u6c47\u603b\u3001\u65b0\u80fd\u6e90\u77e5\u8bc6\u79d1\u666e\u548c\u6df1\u5ea6\u6316\u6398\u65b0\u80fd\u6e90\u5b66\u672f\u4ea7\u4e1a\u4fe1\u606f\uff0c\u8bf7\u52a0qq 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href=\"mailto:\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\">\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4f5c\u4e3a\u7535\u6c60\u7684\u7535\u6781\u6d3b\u6027\u6750\u6599\uff0c\u6709\u673a\u5316\u5408\u7269\u7531\u4e8e\u5176\u7ed3\u6784\u7684\u591a\u6837\u6027\u3001\u53ef\u518d\u751f\u6027\u9ad8\u3001\u4f4e\u6210\u672c\u3001\u73af\u5883\u53cb\u597d\u7b49\u7279\u70b9\u53d7\u5230\u4e86\u79d1\u7814\u4eba\u5458\u7684\u5173\u6ce8\u3002\u7fb0\u57fa\u5316\u5408\u7269\uff08\u7279\u522b\u662f\u918c\uff09\uff0c\u7531\u4e8e\u5176\u9ad8\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u548c\u5feb&#8230;<\/p>\n","protected":false},"author":90,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[129],"class_list":["post-13644","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-battery"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/13644"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/90"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=13644"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/13644\/revisions"}],"predecessor-version":[{"id":13794,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/13644\/revisions\/13794"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=13644"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=13644"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=13644"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}