{"id":136413,"date":"2018-04-27T06:30:23","date_gmt":"2018-04-26T22:30:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=136413"},"modified":"2018-04-26T10:07:39","modified_gmt":"2018-04-26T02:07:39","slug":"%e8%b4%9f%e8%bd%bd%e5%be%ae%e9%87%8fco%e7%9a%84%e6%b0%ae%e6%8e%ba%e6%9d%82%e7%bc%ba%e9%99%b7%e7%a2%b3%e7%94%a8%e4%ba%8e%e5%85%a8%e5%9b%ba%e6%80%81%e9%94%8c-%e7%a9%ba%e6%b0%94%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=136413","title":{"rendered":"\u8d1f\u8f7d\u5fae\u91cfCo\u7684\u6c2e\u63ba\u6742\u7f3a\u9677\u78b3\u7528\u4e8e\u5168\u56fa\u6001\u950c-\u7a7a\u6c14\u7535\u6c60"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7535\u50ac\u5316\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u548c\u6c27\u6790\u51fa\u53cd\u5e94\uff08OER\uff09\u662f\u7535\u5316\u5b66\u80fd\u91cf\u8f6c\u6362\u88c5\u7f6e\uff08\u5982\u71c3\u6599\u7535\u6c60\u548c\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\uff09\u7684\u5173\u952e\uff0cOER&amp;ORR\u7684\u591a\u6b65\u9aa4\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u548c\u7f13\u6162\u52a8\u529b\u5b66\u4f1a\u4ea7\u751f\u8f83\u5927\u7684\u8fc7\u7535\u4f4d\uff0c\u4e25\u91cd\u964d\u4f4e\u4e86\u53cd\u5e94\u6548\u7387\u3002\u76ee\u524d\uff0c\u8d35\u91d1\u5c5eRu\uff08Ir\uff09\u57fa\u548cPt\u57fa\u50ac\u5316\u5242\u662f\u76ee\u524d\u9ad8\u6548\u7684OER\u548cORR\u7535\u50ac\u5316\u5242\uff0c\u4f46\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7a00\u7f3a\u6027\u3001\u4e0d\u83f2\u7684\u4ef7\u683c\u4ee5\u53ca\u5dee\u5f3a\u4eba\u610f\u7684\u7a33\u5b9a\u6027\u963b\u788d\u4e86\u5176\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5728\u4fdd\u8bc1\u9ad8\u6027\u80fd\u7684\u524d\u63d0\u4e0b\uff0c\u5f00\u53d1\u5ec9\u4ef7\u3001\u9ad8\u6548\u7684\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5176\u91cd\u8981\u6027\u4e0d\u8a00\u800c\u55bb\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u4e2d\u5357\u5927\u5b66\u96f7\u6c38\u9e4f\u6559\u6388<\/strong>\u548c<strong>\u4e2d\u79d1\u9662<\/strong>\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240<strong>\u738b\u8981\u5175\u6559\u6388<\/strong>\u56e2\u961f\u7b49\u901a\u8fc7\u201c\u4e00\u9505\u201d\u70ed\u89e3\u6cd5\u5236\u5907\u542b\u5fae\u91cfCo\uff081.5 wt.\uff05\uff09\u7684N\u63ba\u6742\u7f3a\u9677\u78b3\uff0c\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u9ad8\u6548\u7684\u53cc\u529f\u80fd\u6c27\u6790\u51fa\/\u6c27\u8fd8\u539f\u53cd\u5e94\u6d3b\u6027\uff0c\u9ad8\u6d3b\u6027\u4e3b\u8981\u5f52\u56e0\u4e8e\u72ec\u7279\u7684\u5fae-\u4ecb\u5b54\u7ed3\u6784\uff081~3 nm\uff09\u3001\u77f3\u58a8-N\u63ba\u6742\uff08\u9ad8\u8fbe49.0\uff05\uff09\u3001\u4e30\u5bcc\u7684\u7f3a\u9677\u548c\u77f3\u58a8\u78b3\u5305\u8986\u7684\u94b4\u7eb3\u7c73\u9897\u7c92\u3002\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781\u7ec4\u88c5\u5230\u950c-\u7a7a\u6c14\u7535\u6c60\uff0c\u53ef\u5145\u5f0f\u6db2\u6001\u950c\u7a7a\u6c14\u7535\u6c60\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6d3b\u6027\uff08\u6700\u5927\u529f\u7387\u5bc6\u5ea6\u4e3a154.0 mW cm-2\uff1b\u57285 mA cm-2\u65f6\u7684\u80fd\u91cf\u5bc6\u5ea6\u4e3a773 Wh kg-1\u548c\u8d85\u8fc7100\u5708\u7684\u4f18\u79c0\u5faa\u73af\u5145\u653e\u7535\u7a33\u5b9a\u6027\uff09\u3002\u7ee7\u800c\u7ec4\u88c5\u4e86\u67d4\u6027\u3001\u53ef\u5145\u5f0f\u5168\u56fa\u6001\u950c\u7a7a\u6c14\u7535\u6c60\uff0c\u7535\u6c60\u7684\u6700\u9ad8\u529f\u7387\u5bc6\u5ea6\u9ad8\u8fbe45.9 mW cm-2\uff0c\u662f\u4ee5\u524d\u62a5\u9053\u7684\u6700\u9ad8\u6c34\u5e73\u4e4b\u4e00\u3002\u8be5\u7814\u7a76\u6210\u679c\u5df2\u4e8e\u8fd1\u671f\u53d1\u8868\u5728\u8457\u540d\u671f\u520a<strong>Science Bulletin<\/strong>\uff0c\uff08<a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2095927318301592\" target=\"_blank\" rel=\"noopener\"><strong>N-doped defective carbon with trace Co for efficient rechargeable liquid electrolyte- \/all-solid-state Zn-air batteries<\/strong><\/a>\uff09<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p> <strong>\u56fe1.\u00a0Co-NDC\u7684\u5f62\u8c8c\u7ed3\u6784\u56fe<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-136427\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/1-65.jpg\" alt=\"\" width=\"700\" height=\"888\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/1-65.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/1-65-236x300.jpg 236w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/>(a) SEM\u56fe\uff1b<\/p>\n<p style=\"text-align: left;\">(b) TEM\u56fe\uff1b<\/p>\n<p style=\"text-align: left;\">(c) \u5143\u7d20mapping\u56fe\uff1b<\/p>\n<p style=\"text-align: left;\">(d) HRTEM\u56fe\uff1b<\/p>\n<p style=\"text-align: left;\">(e) Co-NDC\u7684Co K-edge\u7684K\u7a7a\u95f4\u8c31\u56fe\uff1b<\/p>\n<p style=\"text-align: left;\">(f) Co-NDC\u548cCo\u7b94\u7684Co K-edge\u7684R\u7a7a\u95f4\u8c31\u56fe\u3002<\/p>\n<p><strong>\u56fe2. Co-NDC\u7684\u7ec4\u7ec7\u7ed3\u6784\u56fe<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-136428\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/2-63.jpg\" alt=\"\" width=\"700\" height=\"618\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/2-63.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/2-63-300x265.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/>(a) BET\u56fe\uff1b<\/p>\n<p>(b) CA, NDC\u548cCo-NDC\u7684Raman\u8c31\u56fe\uff1b<\/p>\n<p>(c) Co-NDC\u7684\u62df\u5408Raman\u8c31\u56fe\uff1b<\/p>\n<p>(d) \u9ad8\u500dN 1s\u8c31\u56fe(d) \u9ad8\u500dN 1s\u8c31\u56fe<\/p>\n<p> <strong>\u56fe3.\u00a0Co-NDC\u7684\u7535\u5316\u5b66OER \/ ORR\u53d8\u5316<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-136429\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/3-61.jpg\" alt=\"\" width=\"700\" height=\"866\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/3-61.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/3-61-242x300.jpg 242w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/>(a) NDC,Co-NDC,Pt\/C\u548cRuO2\/C\u7684OER\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n<p>(b) \u5854\u83f2\u5c14\u659c\u7387\uff1b<\/p>\n<p>(c) NDC,Co-NDC\u548cPt\/C\u7684ORR\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n<p>(d) Co-NDC\u5728\u4e0d\u540c\u8f6c\u901f\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n<p>(e) Co-NDC\u5728\u4e0d\u540c\u626b\u901f\u4e0bCV\u66f2\u7ebf\uff1b<\/p>\n<p>(f) NDC\u548cCo-NDC\u7684\u53cc\u7535\u5c42\u7535\u5bb9\u6bd4\u8f83\u3002<\/p>\n<p><strong>\u56fe4.\u00a0\u5177\u6709Co-NDC\u7684\u6db2\u6001\u7535\u89e3\u8d28Zn-\u7a7a\u6c14\u7535\u6c60\u7684\u6027\u80fd<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-136430\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/4-59.jpg\" alt=\"\" width=\"700\" height=\"563\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/4-59.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/4-59-300x241.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/>\u00a0(a) Co-NDC\u548cPt\/C\u7684\u653e\u7535\u66f2\u7ebf\u548c\u5bf9\u5e94\u7684\u529f\u7387\u5bc6\u5ea6\u66f2\u7ebf\uff1b<\/p>\n<p>(b) Co-NDC\u7684\u6052\u6d41\u653e\u7535\u7a33\u5b9a\u6027\uff1b<\/p>\n<p>(c) Co-NDC\u548cPt\/C + Ir\/C\u572810 mA cm-2\u6761\u4ef6\u4e0b\u7684\u5145\u653e\u7535\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u56fe5.\u00a0\u5177\u6709Co-NDC\u7684\u5168\u56fa\u6001Zn-\u7a7a\u6c14\u7535\u6c60\u7684\u6027\u80fd<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-136431\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/5-48.jpg\" alt=\"\" width=\"700\" height=\"574\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/5-48.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/5-48-300x246.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/>(a) \u5168\u56fa\u6001\u7535\u6c60\u793a\u610f\u56fe\uff1b<\/p>\n<p>(b) Co-NDC\u7684\u5145\u653e\u7535\u66f2\u7ebf\u548c\u5bf9\u5e94\u7684\u529f\u7387\u5bc6\u5ea6\u66f2\u7ebf\uff1b<\/p>\n<p>(b) Co-NDC\u4e0e\u5df2\u62a5\u9053\u50ac\u5316\u5242\u7684\u6700\u5927\u529f\u7387\u5bc6\u5ea6\u503c\u6bd4\u8f83\uff1b<\/p>\n<p>Co-NDC\u57282 mA cm-2\u6761\u4ef6\u4e0b\u7684\u5145\u653e\u7535\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u63d2\u56fe\u4e3a\u67d4\u6027\u5168\u56fa\u6001\u7535\u6c60\u70b9\u706f\u7167\u7247\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u672c\u6587\u4ecb\u7ecd\u4e86\u4e00\u79cd\u57fa\u4e8e\u201c\u56fa\u6001\u88c2\u89e3\u201d\u7b56\u7565\u5236\u5907\u7684\u542b\u5fae\u91cfCo\u7684N\u63ba\u6742\u7f3a\u9677\u78b3\u53cc\u529f\u80fd\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u5ec9\u4ef7\u3001\u9ad8\u6548\u3002\u7ec4\u88c5\u7684\u67d4\u6027\u3001\u53ef\u9006\u5168\u56fa\u6001\u950c\u7a7a\u6c14\u7535\u6c60\u5728\u5404\u79cd\u5f2f\u6298\u60c5\u51b5\u4e0b\u4f9d\u7136\u5177\u6709\u7a33\u5b9a\u7684\u5145\u653e\u7535\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p style=\"text-align: center;\"><strong>TOC<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-136432\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/6-32.jpg\" alt=\"\" width=\"700\" height=\"298\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/6-32.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/6-32-300x128.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u96f7\u6c38\u9e4f\u7b80\u4ecb\uff1a<\/strong><\/p>\n<p>\u96f7\u6c38\u9e4f\uff0c\u7537\uff0c1982\u5e74\u751f\u30022011\u5e74\u6bd5\u4e1a\u4e8e\u56fd\u9632\u79d1\u6280\u5927\u5b66\uff0c\u83b7\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u4e13\u4e1a\u535a\u58eb\u5b66\u4f4d\uff0c\u535a\u58eb\u8bba\u6587\u88ab\u8bc4\u4e3a\u6e56\u5357\u7701\u4f18\u79c0\u535a\u58eb\u5b66\u4f4d\u8bba\u6587\uff082014\uff09\u3002\u7814\u7a76\u65b9\u5411\u4e3a\u7ed3\u6784\/\u529f\u80fd\u7ea4\u7ef4\u53ca\u5176\u590d\u5408\u6750\u6599\u3001\u5149\/\u7535\u80fd\u6e90\u50ac\u5316\u6750\u6599\u3002\u5148\u540e\u4e3b\u6301\u56fd\u5bb6\u81ea\u79d1\u57fa\u91d1\u7b49\u9879\u76ee\uff0c\u5df2\u53d1\u8868SCI\u8bba\u658750\u4f59\u7bc7\uff0c\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u52295\u9879\u3002\u5171\u540c\u6307\u5bfc\u5168\u519b\u4f18\u79c0\u7855\u58eb\u5b66\u4f4d\u8bba\u65872\u7bc7\uff0c\u6307\u5bfc\u7acb\u9879\u56fd\u5bb6\u7ea7\u5927\u5b66\u751f\u521b\u65b0\u9879\u76ee8\u9879\u3002<\/p>\n<p>\u611f\u8c22\u738b\u542f\u6668\u4f9b\u7a3f\uff01<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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