{"id":136195,"date":"2018-04-30T14:00:10","date_gmt":"2018-04-30T06:00:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=136195"},"modified":"2018-04-27T22:14:46","modified_gmt":"2018-04-27T14:14:46","slug":"%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e4%ba%8e%e6%b5%b7%e5%b3%b0%e5%8c%97%e4%ba%ac%e5%8c%96%e5%b7%a5%e5%a4%a7%e5%ad%a6%e6%9d%a8%e4%b8%87%e6%b3%b0macromolecules%ef%bc%9a%e5%b8%a6%e7%94%b5%e8%8d%b7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=136195","title":{"rendered":"\u5317\u4eac\u5927\u5b66\u4e8e\u6d77\u5cf0&\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6768\u4e07\u6cf0Macromolecules\uff1a\u5e26\u7535\u8377\u7aef\u57fa\u7684\u5076\u6c2e\u7fa7\u9178\u5d4c\u6bb5\u805a\u5408\u7269\u5177\u6709\u7279\u6b8a\u7684\u70ed\u54cd\u5e94\u884c\u4e3a"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n

\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u6750\u6599\u79d1\u5b66\u5bb6\u4eec\u90fd\u5ffd\u7565\u4e86\u805a\u5408\u7269\u7684\u7aef\u57fa\u6548\u5e94\uff0c\u6bd4\u5982\u5929\u7136\u6a61\u80f6\u56e0\u4e3a\u7aef\u57fa\u7684\u6548\u5e94\uff0c\u76f8\u5bf9\u4e8e\u5408\u6210\u6a61\u80f6\u62e5\u6709\u66f4\u597d\u7684\u6027\u80fd\u3002\u5728\u4e8c\u5341\u4e16\u7eaa\u516b\u5341\u5e74\u4ee3\u548c\u4e5d\u5341\u5e74\u4ee3\uff0c\u9634\u79bb\u5b50\u548c\u4e0d\u540c\u91d1\u5c5e\u5bf9\u9065\u722a\u805a\u5408\u7269\u7269\u7406\u6027\u8d28\u7684\u5f71\u54cd\u88abTeyssie\u548cJerome\u8bfe\u9898\u7ec4\u53d1\u73b0\u3002\u9664\u4e86\u805a\u5408\u7269\u56fa\u4f53\uff0c\u8fd9\u7c7b\u7aef\u57fa\u6548\u5e94\u5728\u805a\u5408\u7269\u6eb6\u6db2\u9886\u57df\u4e5f\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u6ce8\u610f\u3002\u6bd4\u5982\uff0c\u62e5\u6709\u4e0d\u540c\u7aef\u57fa\u7684ABA\u578b\u4e09\u5d4c\u6bb5\u5171\u805a\u7269\u5177\u6709\u4e0d\u540c\u7684\u6eb6\u6db2-\u51dd\u80f6\u8f6c\u6362\u884c\u4e3a\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n

\u5076\u6c2e\u7fa7\u9178\u662f\u4e00\u79cd\u7279\u6b8a\u7684\u529f\u80fd\u57fa\u56e2\uff0c\u5b83\u96c6\u6db2\u6676\u7684\u81ea\u7ec4\u88c5\u7279\u6027\u4e0e\u5076\u6c2e\u82ef\u57fa\u56e2\u7684\u5149\u54cd\u5e94\u4e8e\u4e00\u8eab\uff0c\u540c\u65f6\u5176\u805a\u5408\u7269\u53ef\u4ee5\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u53ef\u4ee5\u81ea\u7ec4\u88c5\u6210\u6db2\u6676\u51dd\u80f6\uff08Journal of Materials Chemistry 2010, 20, 3610-3614\uff09\uff0c\u65e0\u8bba\u662f\u5747\u805a\u7269\u8fd8\u662f\u5d4c\u6bb5\u5171\u805a\u7269\u90fd\u5177\u6709\u805a\u96c6\u8bf1\u5bfc\u8367\u5149\u589e\u5f3a\u7684\u7279\u6027\uff08Polymer, 2016, 97,533-542\uff1bPolymer Chemistry 2015, 6(2), 270-277\uff09\u3002\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u4e8e\u6d77\u5cf0\u6559\u6388\u4e0e\u5317\u4eac\u5316\u5de5\u5927\u5b66<\/b><\/strong>\u7684\u6768\u4e07\u6cf0\u9662\u58eb<\/b><\/strong>\u8bfe\u9898\u7ec4\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8ePNIPAm\u3001\u542b\u6709\u7fa7\u57fa\u5076\u6c2e\u57fa\u56e2\u7684\u53cc\u5d4c\u6bb5\u5171\u805a\u7269\uff0c\u7531\u4e8e\u542b\u6709\u5e26\u7535\u8377\u7684\u7aef\u57fa\u800c\u5177\u6709\u7684\u7279\u6b8a\u7684\u70ed\u54cd\u5e94\u884c\u4e3a\u3002\u52a0\u70ed\u65f6\uff0c\u79bb\u5b50\u5316\u7684\u7aef\u57fa\u53ef\u4ee5\u9632\u6b62\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u76f8\u5206\u79bb\uff0c\u5bfc\u81f4\u6d4a\u70b9\u7684\u6d88\u5931\u3002\u5f53\u80f6\u675f\u6eb6\u6db2\u572850\u2103\u4e0b\u4fdd\u5b582h\u540e\uff0c\u80f6\u675f\u6eb6\u6db2\u4ee5\u5e26\u7535\u8377\u7aef\u57fa\u7a33\u5b9a\u7684\u5927\u80f6\u675f\u4e3a\u8f6c\u5316\u6001\uff0c\u8868\u73b0\u51fa\u4ece\u80f6\u675f\u5230\u56ca\u6ce1\u7684\u5f62\u6001\u8f6c\u53d8\u3002\u8fd9\u79cd\u5f62\u6001\u8f6c\u53d8\u53ef\u5f52\u7ed3\u4e8e\u5e26\u7535\u8377\u7aef\u57fa\u7a33\u5b9a\u548cPNIPAm\u4eb2\u758f\u6c34\u5e73\u8861\u53d8\u5316\u7684\u5171\u540c\u4f5c\u7528\u7ed3\u679c\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Charged End-Group Terminated Poly(N-isopropylacrylamide)-b-poly(carboxylic azo) with Unusual Thermoresponsive Behaviors<\/b><\/strong>“\u53d1\u8868\u5728Macromolecules<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>1 <\/b><\/strong>\u5d4c\u6bb5\u5171\u805a\u7269\u5728\u4e0d\u540cpH\u6c34\u6eb6\u6db2\u4e2d\u7684\u70ed\u54cd\u5e94\u6027\u8d28<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>2<\/b><\/strong>\u00a0<\/b><\/strong>\u5d4c\u6bb5\u5171\u805a\u7269BC-CPDB\u548cBC-DDTA\u7684\u5316\u5b66\u4f4d\u79fb\u968f\u6e29\u5ea6\u7684\u53d8\u5316<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>3<\/b><\/strong>\u00a0<\/b><\/strong>\u5316\u5b66\u4f4d\u79fb3.8\u548c1.1ppm\u7684\u6838\u78c1\u5f3a\u5ea6\u968f\u6e29\u5ea6\u7684\u53d8\u5316\u548c\u4e24\u79cd\u5d4c\u6bb5\u5171\u805a\u7269\u5728550nm\u5904\u7684\u5438\u6536\u5f3a\u5ea6\u968f\u6e29\u5ea6\u7684\u53d8\u5316<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>4<\/b><\/strong>\u00a0<\/b><\/strong>BC-DDTA\u5728\u4e0d\u540c\u72b6\u6001\u4e0b\u7684TEM\u56fe\u548c\u80f6\u675f\u5230\u56ca\u6ce1\u8f6c\u6362\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>\u91d1\u5c5e\u79bb\u5b50\u5bf9\u5d4c\u6bb5\u5171\u805a\u7269\u70ed\u54cd\u5e94\u6027\u8d28\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e00\u79cd\u57fa\u4e8ePNIPAm\u3001\u542b\u6709\u7fa7\u57fa\u5076\u6c2e\u57fa\u56e2\u7684\u53cc\u5d4c\u6bb5\u5171\u805a\u7269\uff0c\u7531\u4e8e\u542b\u6709\u5e26\u7535\u8377\u7684\u7aef\u57fa\u800c\u5177\u6709\u7684\u7279\u6b8a\u7684\u70ed\u54cd\u5e94\u884c\u4e3a\u3002\u52a0\u70ed\u65f6\uff0c\u79bb\u5b50\u5316\u7684\u7aef\u57fa\u53ef\u4ee5\u9632\u6b62\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u76f8\u5206\u79bb\uff0c\u5bfc\u81f4\u6d4a\u70b9\u7684\u6d88\u5931\u3002\u5f53\u80f6\u675f\u6eb6\u6db2\u572850\u2103\u4e0b\u4fdd\u5b582h\u540e\uff0c\u80f6\u675f\u6eb6\u6db2\u4ee5\u5e26\u7535\u8377\u7aef\u57fa\u7a33\u5b9a\u7684\u5927\u80f6\u675f\u4e3a\u8f6c\u5316\u6001\uff0c\u8868\u73b0\u51fa\u4ece\u80f6\u675f\u5230\u56ca\u6ce1\u7684\u5f62\u6001\u8f6c\u53d8\u3002\u8fd9\u79cd\u5f62\u6001\u8f6c\u53d8\u53ef\u5f52\u7ed3\u4e8e\u5e26\u7535\u8377\u7aef\u57fa\u7a33\u5b9a\u548cPNIPAm\u4eb2\u758f\u6c34\u5e73\u8861\u53d8\u5316\u7684\u5171\u540c\u4f5c\u7528\u7ed3\u679c\u3002\u8fd9\u4e2a\u5de5\u4f5c\u4e3a\u540e\u7eed\u523a\u6fc0\u54cd\u5e94\u805a\u5408\u7269\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCharged End-Group Terminated Poly(N-isopropylacrylamide)-b-poly(carboxylic azo) with Unusual Thermoresponsive Behaviors<\/a>\u00a0(Macromolecules, 2018, 10.1021\/acs.macromol.7b02640)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002 \u00a0<\/p>\n

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\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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