{"id":136045,"date":"2018-04-29T06:30:37","date_gmt":"2018-04-28T22:30:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=136045"},"modified":"2018-04-29T17:47:33","modified_gmt":"2018-04-29T09:47:33","slug":"jacs-%e5%8d%95%e9%93%be%e7%ba%b3%e7%b1%b3%e7%b2%92%e5%ad%90%e4%bd%9c%e4%b8%ba%e7%ba%b3%e7%b1%b3%e5%82%ac%e5%8c%96%e5%8f%8d%e5%ba%94%e5%99%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=136045","title":{"rendered":"JACS : \u5355\u94fe\u7eb3\u7c73\u7c92\u5b50\u4f5c\u4e3a\u7eb3\u7c73\u50ac\u5316\u53cd\u5e94\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u65e0\u8bba\u662f\u5de5\u4e1a\u751f\u4ea7\u8fd8\u662f\u5b9e\u9a8c\u5ba4\u79d1\u5b66\u7814\u7a76\u4f7f\u7528\uff0c\u5316\u5b66\u50ac\u5316\u4f53\u7cfb\uff0c\u5728\u6211\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u4e2d\u90fd\u662f\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002\u50ac\u5316\u5242\u4e0d\u4ec5\u80fd\u6fc0\u6d3b\u60f0\u6027\u53cd\u5e94\u6750\u6599\uff0c\u8fd8\u80fd\u964d\u4f4e\u53cd\u5e94\u6761\u4ef6\uff0c\u63d0\u9ad8\u4ea7\u7269\u7684\u9009\u62e9\u6027\u3002\u7136\u800c\uff0c\u7531\u4e8e\u73b0\u4ee3\u50ac\u5316\u5242\u7ecf\u5e38\u8868\u73b0\u51fa\u5404\u79cd\u5404\u6837\u7684\u7f3a\u70b9\uff0c\u56e0\u6b64\u9700\u8981\u8fdb\u4e00\u6b65\u5f00\u53d1\u548c\u6539\u8fdb\u50ac\u5316\u4f53\u7cfb\u3002\u73b0\u5b9e\u793e\u4f1a\u5bf9\u9ad8\u6548\u3001\u7279\u5236\u7684\u50ac\u5316\u5242\u7684\u9700\u6c42\uff0c\u6fc0\u53d1\u4e86\u5316\u5b66\u5bb6\u4eec\u5c06\u5929\u7136\u9176\u7684\u8bbe\u8ba1\u539f\u7406\u4e0e\u5408\u6210\u5927\u5206\u5b50\u7ed3\u6784\u7ed3\u5408\u8d77\u6765\uff0c\u5236\u5907\u51fa\u4eff\u9176\u50ac\u5316\u5242\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6fb3\u5927\u5229\u4e9a\u7684\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66\u7684Christopher Barner-Kowollik\u6559\u6388\u548c\u5361\u5c14\u65af\u9c81\u5384\u6280\u672f\u7814\u7a76\u6240\u7684Peter W. Roesky\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u91c7\u7528\u4e86\u9ad8\u5206\u5b50\u805a\u5408\u7269\u5236\u5907\u4e86\u5355\u94fe\u7eb3\u7c73\u7c92\u5b50\uff08SCNPs\uff09\uff0c\u8d1f\u8f7d\u91d1\u5c5e\u79bb\u5b50\u4eff\u7167\u751f\u7269\u4f53\u5185\u7684\u9176\u50ac\u5316\u5242\u3002\u5c06\u91d1\u5c5e\u6709\u673a\u548c\u5927\u5206\u5b50\u5316\u5b66\u7ed3\u5408\u8d77\u6765\uff0c\u5728\u5206\u5b50\u5c42\u9762\u5236\u5907\u7684\u5404\u79cd\u5404\u6837\u7684\u5355\u4f53\u51e0\u4e4e\u662f\u65e0\u9650\u7684\uff0c\u5e76\u4f7f\u5206\u5b50\u73af\u5883\u7684\u591a\u7528\u9014\u8c03\u6574\u4e3a\u7279\u5b9a\u7684\u53cd\u5e94\u6761\u4ef6\uff0c\u4e14\u5728\u5206\u5b50\u5c42\u9762\u7814\u7a76\u5b8f\u89c2\u81ea\u7136\u7684\u590d\u6742\u56fd\u4ea7\uff0c\u540c\u65f6\u5c06\u8fd9\u4e9b\u7406\u89e3\u5e94\u7528\u5230\u65b0\u7684\u50ac\u5316\u53d1\u5c55\u4e2d\u53bb\u3002\u4e3a\u8fdb\u4e00\u6b65\u53d1\u5c55\u548c\u63a8\u52a8\u50ac\u5316\u5316\u5b66\uff0c\u63d0\u4f9b\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u548c\u601d\u8003\u6a21\u5f0f\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cSingle-Chain Nanoparticles as Catalytic Nanoreactors\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aJACS<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001SCNPs\u914d\u4f4d\u91d1\u5c5e\u79bb\u5b50\u8fc7\u7a0b\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09 \u5728\u805a\u5408\u7269\u94fe\u4e2d\u5f15\u5165\u4f18\u826f\u7684\u914d\u4f53\u529f\u80fd-\u91d1\u5c5e\u7edc\u5408-\u4f7f\u5355\u94fe\u6298\u53e0\u548c\u50ac\u5316\u529f\u80fd\u5316\u6210\u4e3a\u4e00\u4e2a\u6b65\u9aa4\uff1b<\/p>\n

\uff08b\uff09 \u901a\u8fc7\u4e00\u4e2a\u5916\u90e8\u89e6\u53d1\u5668\u548c\u968f\u540e\u7684\u91d1\u5c5e\u8d1f\u8f7d\u7684\u4e00\u4e2a\u9884\u5148\u6298\u53e0\u7684\u652f\u67b6\u5f62\u6210\u7eb3\u7c73\u7c92\u5b50\u3002<\/p>\n

\u56fe\u4e8c\u3001\u5206\u5b50\u50ac\u5316\u5242\u4e0eSCNPs\u50ac\u5316\u6d3b\u6027\u4e4b\u95f4\u7684\u6982\u5ff5\u5dee\u5f02\u00a0<\/strong><\/p>\n

\"\"
\n \uff08a\uff09 \u5f53\u5206\u5b50\u50ac\u5316\u5242[Rh(cod)Cl]2<\/sub>\u88abRh(I)-SCNPs\u53d6\u4ee3\u65f6\uff0c\u5728\u4ea4\u53c9\u8026\u5408\u53cd\u5e94\u4e2d\u5bf9\u4ea7\u7269\u6bd4\u7684\u663e\u8457\u5f71\u54cd\uff1b\uff08b\uff09 \u5f53\u7528Cu(II)-SCNPs\u800c\u4e0d\u662fCuCl2<\/sub>\u4f5c\u4e3a\u50ac\u5316\u5242\u65f6\uff0c\u5728\u672b\u7aef\u4e59\u7094\u7684\u6c27\u5316\u5076\u8054\u4e2d\u72ec\u7279\u7684\u5e95\u7269\u7279\u5f02\u6027\u3002<\/p>\n

\u56fe\u4e09\u3001\u9009\u62e9\u6027\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684SCNP\u7279\u6027\u7684\u4fee\u9970\u00a0<\/strong><\/p>\n

\"\"
\n \uff08a\uff09 \u5728\u805a\u5408\u7269\u94fe\u4e2d\u78f7\u5316\u6c22\u4e0e\u5916\u90e8\u6dfb\u52a0\u7684Pt(II)\u76d0\u4e4b\u95f4\u5f62\u62102:1\u7684\u590d\u5408\u7269\u8d1f\u8f7d\u5728SCNPs\u4e0a\uff1b<\/p>\n

\uff08b\uff09 Pt(II)- SCNPs\u5e94\u7528\u4e8e\u70ef\u4e19\u9187\u7684\u6c28\u57fa\u5316\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e\u6eb6\u5242\u6781\u6027\u7684\u53d8\u5316\uff0c\u4f7f\u5176\u6eb6\u89e3\u6027\u884c\u4e3a\u548c\u50ac\u5316\u6d3b\u6027\u53d1\u751f\u4e86\u53d8\u5316\uff0c\u4ece\u800c\u7ed3\u5408\u4e86\u540c\u8d28\u6027\u548c\u5f02\u8d28\u6027\uff0c\u5e76\u4f7f\u50ac\u5316\u5242\u5177\u6709\u53ef\u56de\u6536\u6027\u3002\uff1b<\/p>\n

\u56fe\u56db\u3001SCNPs\u7684\u7b2c\u4e8c\u53cd\u5e94\u4f4d\u70b9\u5bf9\u50ac\u5316\u6548\u679c\u7684\u5f71\u54cd\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09 \u7b2c\u4e8c\u534f\u8c03\u70b9\u5bf9\u50ac\u5316\u5e94\u7528\u7684\u5f71\u54cd\u662f\u7531\u87ba\u65cb\u72b6\u7684\u805a\u5408\u7269\u50ac\u5316L-\u812f\u6c28\u9178\u6765\u8bf4\u660e\u7684:\u73af\u5df1\u916e\u548c\u5bf9\u785d\u57fa\u82ef\u7532\u919b\u7684\u919b\u9187\u7f29\u5408\u53cd\u5e94\u53ea\u6709\u5728\u805a\u5408\u7269\u5904\u4e8e\u6298\u53e0\u6784\u8c61\u4e2d\u624d\u80fd\u88ab\u50ac\u5316\uff0c\u4ece\u800c\u5728\u50ac\u5316\u7684L-\u812f\u6c28\u9178\u4e2d\u5fc3\u5468\u56f4\u5f62\u6210\u758f\u6c34\u56ca\uff1b<\/p>\n

\uff08b\uff09 \u5728\u5468\u56f4\u7684\u805a\u5408\u7269\u4f53\u7cfb\u4e2d\uff0c\u7531\u4e8e\u9644\u52a0\u7684\u529f\u80fd\u7f9f\u57fa\u5355\u5143\u7684\u4f5c\u7528\uff0c\u4f7f\u5f97\u4e00\u4e2aNi-SCNPs\u8154\u7684\u7b80\u5316\u5f62\u6210\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u6e29\u5ea6\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u8fd9\u662f\u7531\u4e8e\u4e8c\u6b21\u534f\u8c03\u6548\u5e94\u5f15\u8d77\u7684\u3002<\/p>\n

\u56fe\u4e94\u3001SCNPs\u5bf9\u5e8f\u5217\u5b9a\u4e49\u805a\u5408\u7269\u7684\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09 SCNP\u6280\u672f\u5b9e\u73b0\u4e86\u5e8f\u5217\u5b9a\u4e49\u805a\u5408\u7269\u7684\u53d7\u63a7\u6298\u53e0\u8fc7\u7a0b\uff1b<\/p>\n

\uff08b\uff09 \u53ef\u9006\u6298\u53e0SCNPs\u7684\u53ef\u89c6\u5316\uff0c\u53ef\u6839\u636e\u9700\u8981\uff0c\u901a\u8fc7\u5916\u573a\u63a7\u5236\u5f00\u5173\u5176\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u91c7\u7528\u4e86\u5c06\u805a\u5408\u7269\u548c\u5927\u5206\u5b50\u5316\u5b66\u7ed3\u5408\uff0c\u5236\u5907\u51fa\u5355\u94fe\u7eb3\u7c73\u9897\u7c92\uff08SCNPs\uff09\u4f5c\u4e3a\u901a\u7528\u8f7d\u4f53\u3002\u7814\u7a76\u4e86\u5728\u5bb9\u6613\u5236\u5f97\u7684\u5408\u6210\u805a\u5408\u7269\u4e0a\u8fdb\u884c\u9176\u6a21\u62df\uff0c\u662f\u4e00\u4e2a\u975e\u5e38\u5438\u5f15\u4eba\u7684\u7814\u7a76\u65b9\u5411\uff0c\u968f\u7740\u7814\u7a76\u7684\u6df1\u5165\uff0c\u5b83\u4e5f\u5c06\u8fdb\u5165\u6210\u719f\u7684\u7814\u7a76\u9886\u57df\u3002\u800c\u5b83\u7684\u5438\u5f15\u529b\u5305\u62ec\u5bf9\u6bcf\u4e2a\u50ac\u5316\u53cd\u5e94\u7cbe\u786e\u5b9a\u5236SCNP\u7cfb\u7edf\u7684\u80fd\u529b\uff0c\u878d\u5408\u9ad8\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u3001\u9009\u62e9\u6027\u548c\u91cd\u590d\u5229\u7528\u6027\u548c\u52a8\u6001\u7279\u6027\uff0c\u4ece\u800c\u4f7f\u50ac\u5316\u80fd\u529b\u7684\u8fdc\u7a0b\u6fc0\u6d3b\u6216\u5931\u6d3b\u3002\u901a\u8fc7\u7814\u7a76\u8bc1\u5b9e\u57fa\u4e8e\u5408\u6210\u805a\u5408\u7269\u7684SCNPs\u5177\u6709\u5b9e\u73b0\u8fd9\u4e9b\u7279\u6027\u7684\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Single-Chain Nanoparticles as Catalytic Nanoreactors<\/strong><\/a>\uff08JACS, 2018, DOI: 10.1021\/jacs.8b02135\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u7ec4\u5c0f\u80d6\u7eb8\u7f16\u8bd1\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u65e0\u8bba\u662f\u5de5\u4e1a\u751f\u4ea7\u8fd8\u662f\u5b9e\u9a8c\u5ba4\u79d1\u5b66\u7814\u7a76\u4f7f\u7528\uff0c\u5316\u5b66\u50ac\u5316\u4f53\u7cfb\uff0c\u5728\u6211\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u4e2d\u90fd\u662f\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002\u50ac\u5316\u5242\u4e0d\u4ec5\u80fd\u6fc0\u6d3b\u60f0\u6027\u53cd\u5e94\u6750\u6599\uff0c\u8fd8\u80fd\u964d\u4f4e\u53cd\u5e94\u6761\u4ef6\uff0c\u63d0\u9ad8\u4ea7…<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3106],"class_list":["post-136045","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-3106"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/136045"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=136045"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/136045\/revisions"}],"predecessor-version":[{"id":136380,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/136045\/revisions\/136380"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=136045"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=136045"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=136045"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}