{"id":135607,"date":"2018-04-20T06:30:15","date_gmt":"2018-04-19T22:30:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=135607"},"modified":"2018-04-19T15:50:48","modified_gmt":"2018-04-19T07:50:48","slug":"%e4%b8%8a%e6%b5%b7%e4%ba%a4%e9%80%9a%e5%a4%a7%e5%ad%a6-angew-chem-%e8%9c%82%e7%aa%9d%e7%85%a4%e7%8a%b6%e7%a2%b3%e8%86%9c%e6%8e%a2%e7%a9%b6%e9%94%82%e7%a9%ba%e6%b0%94%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=135607","title":{"rendered":"\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66 Angew. Chem.: \u201c\u8702\u7a9d\u7164\u201d\u72b6\u78b3\u819c\u63a2\u7a76\u9502\u7a7a\u6c14\u7535\u6c60\u5927\u5b54\u7684\u52a8\u529b\u5b66\u8fc7\u7535\u4f4d\u884c\u4e3a"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u975e\u6c34\u9502\u7a7a\u6c14\u7535\u6c60\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u7eff\u8272\u73af\u4fdd\u7b49\u4f18\u70b9\uff0c\u662f\u76ee\u524d\u5907\u53d7\u5173\u6ce8\u7684\u7535\u5316\u5b66\u80fd\u91cf\u5b58\u50a8\u4f53\u7cfb\u3002 \u7136\u800c\u9502\u7a7a\u6c14\u7535\u6c60\u5b58\u5728\u7740\u500d\u7387\u6027\u80fd\u4f4e\u3001\u8fc7\u7535\u4f4d\u9ad8\u548c\u5faa\u73af\u6027\u80fd\u5dee\u7b49\u4e00\u7cfb\u5217\u95ee\u9898\u3002\u5145\u7535\u65f6\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6c27\u6790\u51fa\u8fc7\u7a0b\u4f1a\u5f62\u6210\u8f83\u591a\u7684\u526f\u4ea7\u7269\u3002\u653e\u7535\u8fc7\u7a0b\u4e3b\u8981\u5148\u751f\u6210\u4e2d\u95f4\u4ea7\u7269\u8d85\u6c27\u5316\u9502\u3002\u7136\u540e\uff0c\u4e2d\u95f4\u4ea7\u7269\u8d85\u6c27\u5316\u9502\u518d\u7ecf\u8fc7\u8868\u9762\u53cd\u5e94\u673a\u5236\u5f62\u6210\u819c\u72b6\u7684\u8fc7\u6c27\u5316\u9502\u6216\u8005\u7ecf\u8fc7\u6eb6\u6db2\u53cd\u5e94\u673a\u5236\u5f62\u6210\u7b97\u73e0\u72b6\u7684\u8fc7\u6c27\u5316\u9502\u3002\u7406\u8bba\u4e0a\u8bb2\uff0c\u9ad8\u6548\u7684\u9502\u7a7a\u6c14\u7535\u6c60\u9634\u6781\u50ac\u5316\u5242\u9996\u5148\u9700\u8981\u6709\u5927\u91cf\u7684\u6c27\u8fd8\u539f\u6216\u6c27\u6790\u51fa\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u540c\u65f6\uff0c\u8fd8\u8981\u6709\u8db3\u591f\u7684\u7a7a\u95f4\u6765\u5bb9\u7eb3\u5927\u91cf\u5fae\u7c73\u5c3a\u5bf8\u653e\u7535\u4ea7\u7269\u8fc7\u6c27\u5316\u9502\u7684\u6c89\u79ef\u3002\u4f20\u7edf\u7684\u9634\u6781\u50ac\u5316\u5242\u5f80\u5f80\u88ab\u8bbe\u8ba1\u6210\u4ecb\u5b54\u7ed3\u6784\u4ee5\u63d0\u4f9b\u6c27\u8fd8\u539f\u6216\u6c27\u6790\u51fa\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u7136\u800c\uff0c\u751f\u6210\u7684\u5fae\u7c73\u5c3a\u5bf8\u7684\u653e\u7535\u4ea7\u7269\u5f80\u5f80\u4f1a\u5835\u4f4f\u9634\u6781\u50ac\u5316\u5242\u7684\u4ecb\u5b54\u5b54\u9053\uff0c\u4e0d\u4ec5\u5f71\u54cd\u5145\u653e\u7535\u8fc7\u7a0b\u7684\u7535\u89e3\u6db2\u7684\u8f93\u8fd0\u548c\u7a7a\u6c14\u7684\u6269\u6563\uff0c\u8fd8\u4f1a\u5f15\u8d77\u50ac\u5316\u5242\u7684\u5931\u6d3b\uff0c\u5bfc\u81f4\u5145\u653e\u7535\u8fc7\u7535\u52bf\u8fc7\u9ad8\u3002\u4e00\u822c\u8ba4\u4e3a\uff0c\u5927\u5b54\u7ed3\u6784\u53ea\u662f\u4fc3\u8fdb\u7535\u89e3\u6db2\u6216\u53cd\u5e94\u7269\u5728\u6d3b\u6027\u4f4d\u70b9\u4e0a\u7684\u4f20\u8f93\uff0c\u800c\u4e0d\u4f1a\u589e\u5927\u50ac\u5316\u5242\u7684\u6d3b\u6027\u8868\u9762\u3002\u7136\u800c\uff0c\u4f5c\u4e3a\u5fae\u7c73\u5c3a\u5bf8\u653e\u7535\u4ea7\u7269\u7684\u4e3b\u8981\u50a8\u5b58\u7a7a\u95f4\uff0c\u5927\u5b54\u5230\u5e95\u5bf9\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6027\u80fd\u6709\u7740\u600e\u6837\u7684\u5f71\u54cd\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\u8fc7\u7535\u4f4d\u9ad8\u53c8\u5177\u4f53\u548c\u54ea\u4e9b\u56e0\u7d20\u76f8\u5173\u662f\u7814\u7a76\u4eba\u5458\u5e7f\u6cdb\u5173\u6ce8\u7684\u95ee\u9898\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u9648\u63a5\u80dc\u6559\u6388\u3001\u738b\u5f00\u5b66\u6559\u6388\u56e2\u961f<\/strong>\u901a\u8fc7\u4ee5\u6c27\u5316\u950c\u7eb3\u7c73\u68d2\u9635\u5217\u4e3a\u786c\u6a21\u677f\uff0c\u901a\u8fc7\u53cd\u76f8\u9014\u5f84\u5f15\u5165\u4e86\u8702\u7a9d\u7164\u72b6\u5927\u5b54\u5b54\u9053\uff0c\u83b7\u5f97\u4e86\u591a\u7ea7\u5b54\u7ed3\u6784\u7684\u81ea\u652f\u6491\u78b3\u819c\uff1b\u901a\u8fc7\u8c03\u8282\u524d\u9a71\u4f53\u6eb6\u80f6\u5728\u6c27\u5316\u950c\u6a21\u677f\u4e2d\u7684\u6d78\u6e0d\u9ad8\u5ea6\uff0c\u5236\u5907\u4e86\u5177\u6709\u5bfc\u901a\u5927\u5b54\u7ed3\u6784\u7684\u591a\u7ea7\u5b54\u78b3\u819c\u548c\u4e00\u9762\u95ed\u5b54\u3001\u4e00\u9762\u901a\u5b54\u7684\u78b3\u819c\uff0c\u7528\u4f5c\u9502\u7a7a\u6c14\u7535\u6c60\u65e0\u7c98\u7ed3\u5242\u81ea\u652f\u6491\u7684\u9634\u6781\uff0c\u83b7\u5f97\u4e86\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u3002\u53d1\u73b0\u5927\u5b54\u7684\u6a2a\u622a\u9762\u79ef\u5bf9\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6027\u80fd\u6709\u7740\u8f83\u5927\u7684\u5f71\u54cd\uff0c\u968f\u7740\u7535\u6781\u8868\u9762\u5927\u5b54\u7684\u6a2a\u622a\u9762\u79ef\u7684\u589e\u52a0\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\u66f2\u7ebf\u4e0a\u7535\u538b\u6ede\u540e\u7684\u73b0\u8c61\u6108\u660e\u663e\u3002<\/p>\n<p>\u8be5\u6210\u679c\u201cFree-Standing Li-O2 Battery Air Cathode Based on 3D Hierarchically Porous Carbon Membranes: the Kinetic Overpotential of Through Macropores\u201d\u53d1\u8868\u5728\u6700\u8fd1\u7684\u5fb7\u56fd\u5e94\u7528\u5316\u5b66(Angew. Chem. Int. Ed.)\u4e0a\uff0c\u535a\u58eb\u751f\u8bb8\u6811\u8302\u662f\u7b2c\u4e00\u4f5c\u8005\uff0c\u738b\u5f00\u5b66\u6559\u6388\u4e3a\u901a\u8baf\u4f5c\u8005\u3002\u8be5\u7814\u7a76\u6210\u679c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u548c\u56fd\u5bb6\u91cd\u5927\u79d1\u5b66\u7814\u7a76\u8ba1\u5212\u7684\u652f\u6301\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135608\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe1-14.jpg\" alt=\"\" width=\"600\" height=\"462\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe1-14.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe1-14-300x231.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>1<\/strong>. \u5cf0\u7a9d\u7164\u72b6\u5927\u5b54\u78b3\u819c\u7684\u5408\u6210\u793a\u610f\u56fe.<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135609\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe2-9.jpg\" alt=\"\" width=\"600\" height=\"649\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe2-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe2-9-277x300.jpg 277w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>2.<\/strong> \u5cf0\u7a9d\u7164\u72b6\u5927\u5b54\u78b3\u819c\u7684\u8868\u5f81. (a) ZnO\u7eb3\u7c73\u68d2\u6a21\u677f\u7684\u626b\u63cf\u7535\u955c\u56fe; (b)\u5bfc\u901a\u5b54\u78b3\u819c(HPCM)\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1b(c)\u76f2\u5b54\u78b3\u819c(HPCM\/C)\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1b(d)HPCM\u548cHPCM\/C\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b(e,f) HPCM\u7684\u4ecb\u5b54\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135610\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe3-9.jpg\" alt=\"\" width=\"600\" height=\"426\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe3-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe3-9-300x213.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>3<\/strong>. (a,b)\u5bfc\u901a\u5b54\u78b3\u819c(HPCM)\u6b63\u53cd\u9762\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1b(c,d)\u76f2\u5b54\u78b3\u819c(HPCM\/C)\u7684\u6b63\u53cd\u9762\u626b\u63cf\u7535\u955c\u56fe\u3002\u6b63\u9762\u6307\u7535\u6c60\u7ec4\u88c5\u65f6\uff0c\u6b63\u5bf9\u7740\u9502\u7247\u7684\u78b3\u819c\u8868\u9762\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135611\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe4-9.jpg\" alt=\"\" width=\"600\" height=\"494\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe4-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe4-9-300x247.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>4<\/strong>. (a)\u4e0d\u540c\u5927\u5b54\u7ed3\u6784\u7684\u78b3\u819c\u7ec4\u88c5\u9502\u7a7a\u6c14\u7535\u6c60\u793a\u610f\u56fe\uff1b(b) \u4e0d\u540c\u5927\u5b54\u7ed3\u6784\u78b3\u819c\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002(c) \u4e0d\u540c\u5927\u5b54\u7ed3\u6784\u78b3\u819c\u7684\u500d\u7387\u6027\u80fd\u3002(d) \u4e0d\u540c\u5927\u5b54\u7ed3\u6784\u78b3\u819c\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n<p>\u5bfc\u901a\u5b54\u819c\u7684\u653e\u7535\u5bb9\u91cf\u548c\u500d\u7387\u6027\u80fd\u8fdc\u5927\u4e8e\u76f2\u5b54\u78b3\u819c\u548c\u6ca1\u6709\u5927\u5b54\u53ea\u6709\u4ecb\u5b54\u7ed3\u6784\u7684\u78b3\u819c\u3002\u5e76\u4e14\uff0c\u5927\u5b54\u7684\u6a2a\u622a\u9762\u79ef\u5bf9\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6027\u80fd\u6709\u7740\u8f83\u5927\u7684\u5f71\u54cd\uff0c\u968f\u7740\u7535\u6781\u8868\u9762\u5927\u5b54\u7684\u6a2a\u622a\u9762\u79ef\u7684\u589e\u52a0\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\u66f2\u7ebf\u4e0a\u7535\u538b\u6ede\u540e\u7684\u73b0\u8c61\u6108\u660e\u663e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135612\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe5-9.jpg\" alt=\"\" width=\"600\" height=\"621\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe5-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe5-9-290x300.jpg 290w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>5<\/strong>. \u9502\u7a7a\u6c14\u7535\u6c60\u6052\u7535\u6d41\u653e\u7535\u66f2\u7ebf\u4e2d\u5b58\u5728\u7684\u7535\u4f4d\u6ede\u540e\u548c\u6df1\u653e\u7535\u659c\u7ebf\u884c\u4e3a\u3002<\/p>\n<p>\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u6587\u732e\u8c03\u7814\u53d1\u73b0\u8fd9\u79cd\u7535\u538b\u6ede\u540e\u73b0\u8c61\u5e7f\u6cdb\u5b58\u5728\u5728\u4e00\u4e9b\u9502\u7a7a\u6c14\u7535\u6781\u9634\u6781\u50ac\u5316\u5242\u540e\u7eed\u7684\u653e\u7535\u66f2\u7ebf\u4e2d\uff0c\u7279\u522b\u662f\u5728\u4f4e\u7684DN\u503c\u6eb6\u5242\u4e2d\u6216\u4f4e\u7684\u6c27\u538b\u4e0b\u6216\u8005\u662f\u5728\u4f4e\u7684\u50ac\u5316\u5242\u4e0e\u7c98\u7ed3\u5242\u6bd4\u7684\u9634\u6781\u4e2d\u3002\u6df1\u653e\u7535\u659c\u7ebf\u884c\u4e3a\u5728\u67d0\u4e9b\u9502\u7a7a\u6c14\u7535\u6781\u7684\u9634\u6781\u50ac\u5316\u5242\uff0c\u50cf\u94df\u6c27\u5316\u77f3\u58a8\u70ef\u590d\u5408\u50ac\u5316\u5242\uff0c\u5806\u79ef\u78b3\u7ea4\u7ef4\u7684\u653e\u7535\u66f2\u7ebf\u4e2d\u5c24\u4e3a\u660e\u663e\u3002\u4f4e\u7684DN\u503c\u6eb6\u5242\u4e2d\uff0c\u4e2d\u95f4\u4ea7\u7269\u8d85\u6c27\u5316\u9502\u6613\u4e8e\u5438\u9644\u5728\u50ac\u5316\u5242\u8868\u9762\uff0c\u800c\u4e0d\u662f\u503e\u5411\u4e8e\u6eb6\u6db2\u53cd\u5e94\u673a\u5236\u3002\u4f4e\u7684\u6c27\u538b\u4ee3\u8868\u7535\u89e3\u6db2\u4e2d\u6eb6\u89e3\u6c27\u7684\u503c\u6216\u8005\u50ac\u5316\u5242\u8868\u9762\u8d85\u6c27\u5316\u9502\u6216\u8fc7\u6c27\u5316\u9502\u7684\u8986\u76d6\u5ea6\u6bd4\u8f83\u4f4e\u3002\u7814\u7a76\u4eba\u5458\u63a8\u6d4b\u8fd9\u79cd\u7535\u538b\u6ede\u540e\u548c\u6df1\u653e\u7535\u659c\u7ebf\u884c\u4e3a\u548c\u7535\u6781\u7684\u5927\u5b54\u7ed3\u6784\u548c\u7535\u6781\u8868\u9762\u8986\u76d6\u7684\u56fa\u76f8\u6216\u8fd1\u56fa\u76f8\u7684\u653e\u7535\u4ea7\u7269\u6709\u5173\u3002<\/p>\n<p>\u5f53\u50ac\u5316\u5242\u8868\u9762\u80fd\u548c\u5438\u9644\u7684\u6216\u7ed3\u6676\u7684\u8d85\u6c27\u5316\u7269\u4e2d\u95f4\u4ea7\u7269\u6216\u4e0d\u5b8c\u5168\u5d4c\u9502\u7684\u8fc7\u6c27\u5316\u7269\u95f4\u5f62\u6210\u7d27\u5bc6\u63a5\u89e6\uff0c\u7535\u5b50\u8f6c\u79fb\u4f34\u968f\u7740\u9502\u79bb\u5b50\u5728\u56fa\u76f8\u4e2d\u8fc1\u79fb\u7684\u7535\u6781\u53cd\u5e94\u52a8\u529b\u5b66\u65b9\u7a0b\uff08LiO<sub>2<\/sub><sup>*<\/sup><sub>(adsorbed) <\/sub>or LiO<sub>2(crystalline)<\/sub> + Li<sup>+<\/sup> + e<sup>&#8211;<\/sup> \u2192 Li<sub>2<\/sub>O<sub>2<\/sub>\uff09\u53ef\u4ee5\u7b80\u5316\u8868\u8fbe\u6210\u5982\u4e0b\u65b9\u7a0b\u5f0f\uff1a<br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135613\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u516c\u5f0f1.jpg\" alt=\"\" width=\"446\" height=\"56\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u516c\u5f0f1.jpg 446w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u516c\u5f0f1-300x38.jpg 300w\" sizes=\"(max-width: 446px) 100vw, 446px\" \/>\uff08\u2206V:\u8fc7\u7535\u4f4d\uff1bt:\u65f6\u95f4\uff1ba, b, c\u4e3a\u5e38\u6570\u3002b\u4e3b\u8981\u548c\u6e29\u5ea6\u76f8\u5173\uff1ba\u7684\u5927\u5c0f\u548c\u7535\u6781\u672c\u8eab\u7ed3\u6784\uff0c\u8868\u9762\u7279\u6027\uff0c\u7535\u6781\u8868\u9762\u8d85\u6c27\u5316\u9502\u6216\u4e0d\u5b8c\u5168\u5d4c\u9502\u7684\u8fc7\u6c27\u5316\u9502\u4ea7\u7269\u7684\u8d77\u521d\u8986\u76d6\u5ea6\uff0c\u6e29\u5ea6\uff0c\u5916\u52a0\u7535\u6d41\uff0c\u5927\u5b54\u6a2a\u622a\u9762\u79ef\u76f8\u5173\u3002c: \u5f53\u653e\u7535\u65f6\u95f4\u4e3aa<sup>2<\/sup>\/4\u65f6\u7684\u8fc7\u7535\u4f4d\u3002c\u7684\u5927\u5c0f\u4e3b\u8981\u548c\u6e29\u5ea6\uff0c\u7535\u6781\u8868\u9762\u8d85\u6c27\u5316\u9502\u6216\u4e0d\u5b8c\u5168\u5d4c\u9502\u7684\u8fc7\u6c27\u5316\u9502\u4ea7\u7269\u4e2d\u95f4\u4ea7\u7269\u5e73\u8861\u6001\u4e0b\u7684\u8986\u76d6\u5ea6\u76f8\u5173\u3002\uff09<\/p>\n<p>\u5f53\u7535\u6781\u6df1\u653e\u7535\u65f6\uff0c\u50ac\u5316\u5242\u6d3b\u6027\u4f4d\u70b9\u8986\u76d6\u4e0a\u8d85\u6c27\u5316\u9502\u6216\u8fc7\u6c27\u5316\u9502\uff0c\u5916\u5c42\u5438\u9644\u7684\u8d85\u6c27\u5316\u9502\u4e2d\u95f4\u4ea7\u7269\u9664\u4e86\u53ef\u4ee5\u53d1\u751f\u8fd8\u539f\u5f62\u6210\u8fc7\u6c27\u5316\u9502\u5916\uff0c\u8fd8\u53ef\u4ee5\u53d1\u751f\u6b67\u5316\u53cd\u5e94\u751f\u6210\u8fc7\u6c27\u5316\u9502\u3002\u76f8\u5173\u53cd\u5e94(2LiO<sub>2<\/sub><sup>*<\/sup><sub>(adsorbed)<\/sub> or LiO<sub>2(crystalline)<\/sub> \u2192 Li<sub>2<\/sub>O<sub>2<\/sub> + O<sub>2<\/sub>)\u7684\u52a8\u529b\u5b66\u65b9\u7a0b\u53ef\u4ee5\u8868\u793a\u5982\u4e0b\uff1a<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135614\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u516c\u5f0f2.jpg\" alt=\"\" width=\"195\" height=\"70\" \/>\uff08\u2206V:\u8fc7\u7535\u4f4d\uff1bt:\u65f6\u95f4\uff1b\u5e38\u6570k\u548c\u7535\u6781\u8868\u9762\u5438\u9644\u8d85\u6c27\u5316\u9502\u53d1\u751f\u6b67\u5316\u53cd\u5e94\u7684\u4ea4\u6362\u901f\u5ea6\uff0c\u7535\u6781\u8868\u9762\u5e73\u8861\u6001\u548c\u5916\u7535\u6d41i\u7a33\u6001\u4e0b\u5438\u9644\u7684\u8fc7\u6c27\u5316\u9502\u7684\u6469\u5c14\u5206\u6570\u76f8\u5173\u3002\uff09<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135615\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe6-3.jpg\" alt=\"\" width=\"600\" height=\"499\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe6-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe6-3-300x250.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>6<\/strong>. (a) (\u65e0\u5927\u5b54\u78b3\u819c)MCM\uff0c(\u76f2\u5b54\u78b3\u819c)HPCM\/C\uff0c(\u5bfc\u901a\u5b54\u78b3\u819c)HPCM\u7684\u6052\u7535\u6d41\u653e\u7535\u66f2\u7ebf\u52a8\u529b\u5b66\u62df\u5408\u3002\u6a59\u8272\u865a\u7ebf\u4ee3\u8868\u4e8c\u6b21\u7535\u5b50\u8f6c\u79fb\u548cLi<sup>+<\/sup>\u56fa\u76f8\u8fc1\u79fb\u7684\u52a8\u529b\u5b66\u62df\u5408\u66f2\u7ebf\uff1b\u6a44\u6984\u7eff\u865a\u7ebf\u4ee3\u8868\u7531\u6b67\u5316\u53cd\u5e94\u4fee\u6b63\u7684\u52a8\u529b\u5b66\u62df\u5408\u66f2\u7ebf\uff1b\u7ea2\u70b9\u4ee3\u8868\u4e34\u754c\u8fc7\u7535\u4f4dc\u3002(b) \u62df\u5408\u76841\/a\u503c\u548c\u5927\u5b54\u6a2a\u622a\u9762\u79ef\u9664\u4ee5\u7535\u6781\u8868\u89c2\u9762\u79ef\u7684\u5173\u7cfb\u56fe\uff1b(c,d) HPCM\u9996\u5708\u653e\u7535\u540e\u78b3\u7684\u819c\u6b63\u53cd\u9762\u626b\u63cf\u7535\u955c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-135619\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe7-3.jpg\" alt=\"\" width=\"600\" height=\"402\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe7-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe7-3-300x201.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>7<\/strong>. (a) HPCM\u8d77\u521d\u7535\u6781\u548c\u653e\u75352 h, 4 h\u548c 6 h\u7684\u62c9\u66fc\u5149\u8c31\u56fe\u3002(b) HPCM \u7684\u9996\u5708\u653e\u5145\u7535XRD\u56fe\u3002(c-e) HPCM\u653e\u7535\u4ea7\u7269\u7684TEM, HAADF STEM \u548cHRTEM\u56fe\u3002<\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u4ee5ZnO\u7eb3\u7c73\u68d2\u9635\u5217\u4e3a\u786c\u6a21\u677f\u5408\u6210\u4e86\u6709\u5e8f\u8702\u7a9d\u7164\u72b6\u5927\u5b54\u78b3\u819c\u4f5c\u4e3a\u65e0\u7c98\u7ed3\u5242\u548c\u96c6\u6d41\u4f53\u7684\u81ea\u652f\u6491\u9634\u6781, \u5b9e\u73b0\u4e86\u9502\u7a7a\u6c14\u7535\u6c60\u4f18\u8d8a\u7684\u500d\u7387\u6027\u80fd\u3002\u540c\u65f6\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u5927\u5b54\u7684\u6a2a\u622a\u9762\u79ef\u662f\u5f71\u54cd\u9502\u7a7a\u6c14\u7535\u6c60\u6052\u7535\u6d41\u653e\u7535\u66f2\u7ebf\u7535\u538b\u6ede\u540e\u7684\u4e00\u4e2a\u4e3b\u8981\u56e0\u7d20\u3002\u5e76\u57fa\u4e8e\u5927\u5b54\u6a2a\u622a\u9762\u79ef\u548c\u9502\u79bb\u5b50\u8fc1\u79fb\u7684\u56fa\u76f8\u53cd\u5e94\u8fc7\u7a0b\uff0c\u5efa\u7acb\u4e86\u9502\u7a7a\u6c14\u7535\u6c60\u8fc7\u7535\u4f4d\u7684\u52a8\u529b\u5b66\u65b9\u7a0b\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/ange.201801399\" target=\"_blank\" rel=\"noopener\">Free-Standing Air Cathodes Based on 3D Hierarchically Porous Carbon Membranes: Kinetic Overpotential of Through Macropores in Li-O<sub>2<\/sub> Battery<\/a> (Angew. Chem. Int. Ed., 2018, DOI10.1002\/ange.201801399)<\/p>\n<p>\u672c\u6587\u7531\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u9648\u63a5\u80dc\u6559\u6388\u3001\u738b\u5f00\u5b66\u6559\u6388\u56e2\u961f\u4f9b\u7a3f\uff0c\u7279\u6b64\u611f\u8c22\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002\u5982\u679c\u4f60\u5bf9\u7535\u5b50\u6750\u6599\u611f\u5174\u8da3\uff0c\u613f\u610f\u4e0e\u7535\u5b50\u7535\u5de5\u9886\u57df\u4eba\u624d\u4ea4\u6d41\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u7535\u5b50\u7535\u5de5\u6750\u6599\u5b66\u4e60\u5c0f\u7ec4\uff08QQ\u7fa4\uff1a482842474\uff09\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH , \u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u975e\u6c34\u9502\u7a7a\u6c14\u7535\u6c60\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u7eff\u8272\u73af\u4fdd\u7b49\u4f18\u70b9\uff0c\u662f\u76ee\u524d\u5907\u53d7\u5173\u6ce8\u7684\u7535\u5316\u5b66\u80fd\u91cf\u5b58\u50a8\u4f53\u7cfb\u3002 \u7136\u800c\u9502\u7a7a\u6c14\u7535\u6c60\u5b58\u5728\u7740\u500d\u7387\u6027\u80fd\u4f4e\u3001\u8fc7\u7535\u4f4d\u9ad8\u548c\u5faa\u73af\u6027\u80fd\u5dee\u7b49\u4e00\u7cfb\u5217\u95ee\u9898\u3002&#8230;<\/p>\n","protected":false},"author":99,"featured_media":135625,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[2966,3095,1441],"class_list":["post-135607","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-2966","tag-3095","tag-1441"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/135607"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/99"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=135607"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/135607\/revisions"}],"predecessor-version":[{"id":135668,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/135607\/revisions\/135668"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/135625"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=135607"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=135607"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=135607"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}