{"id":135221,"date":"2018-04-22T06:30:14","date_gmt":"2018-04-21T22:30:14","guid":{"rendered":"\/\/m.iemloyee.com\/?p=135221"},"modified":"2018-04-22T22:14:35","modified_gmt":"2018-04-22T14:14:35","slug":"%e5%94%90%e6%9c%ac%e5%bf%a0-jacky-w-y-lam-angew-chem-int-ed-%e4%bd%bf%e4%b8%8d%e8%a7%81%e7%9a%84%e5%8f%af%e8%a7%86%e5%8c%96-%e5%8e%9f%e4%bd%8d%e7%9b%91%e6%b5%8b%e5%9b%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=135221","title":{"rendered":"\u5510\u672c\u5fe0 & Jacky W. Y. Lam : \u4f7f\u4e0d\u89c1\u7684\u53ef\u89c6\u5316\u2014\u2014\u539f\u4f4d\u76d1\u6d4b\u56db\u82ef\u4e59\u70ef\u7684RAFT\u805a\u5408\u53cd\u5e94\uff0c\u5176\u542b\u6709\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u7279\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5728\u5b66\u672f\u548c\u5de5\u4e1a\u9886\u57df\u76d1\u6d4b\u548c\u4e86\u89e3\u539f\u4f4d\u805a\u5408\u8fc7\u7a0b\u90fd\u662f\u81f3\u5173\u91cd\u8981\u7684\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u9632\u6b62\u7206\u70b8\u53cd\u5e94\u3002\u5355\u4f53\u3001\u5f15\u53d1\u5242\u548c\u805a\u5408\u7269\u5206\u5b50\u7684\u6269\u6563\u5728\u805a\u5408\u53cd\u5e94\u52a8\u529b\u5b66\u8fc7\u7a0b\u4e2d\u8d77\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u4e5f\u5728\u805a\u5408\u7269\u7684\u6027\u8d28\u4e0a\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002\u5982\u6d41\u53d8\u5b66\u3001\u7c98\u5ea6\u6d4b\u91cf\u6cd5\u6216\u81a8\u80c0\u6cd5\u90fd\u88ab\u4f7f\u7528\u6765\u83b7\u7684\u8fd9\u4e9b\u4fe1\u606f\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u53ea\u80fd\u4ece\u5b8f\u89c2\u7684\u7c98\u5ea6\u83b7\u53d6\u8fd9\u4e9b\u4fe1\u606f\uff0c\u800c\u4e0d\u80fd\u4ece\u5206\u5b50\u6c34\u5e73\u83b7\u5f97\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u7684\u5510\u672c\u5fe0\u6559\u6388\u548cJacky W. Y. Lam\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>\uff09\u91c7\u7528\u4e86\u4e00\u79cd\u7b80\u4fbf\u800c\u6709\u6548\u7684\u65b9\u6cd5\u539f\u4f4d\u5c06\u805a\u5408\u4f5c\u7528\u53ef\u89c6\u5316\u3002\u5408\u6210\u4e86\u4e00\u7ec4\u542b\u6709\u4e8c\u786b\u4ee3\u6c28\u57fa\u7532\u9178\u4e59\u916f\u7684\u4e8c\u786b\u4ee3\u6c28\u57fa\u7532\u9178\u916f\uff08TPE\uff09\uff0c\u5e76\u4f5c\u4e3aRAFT\u805a\u5408\u7684\u8f7d\u4f53\u8fdb\u884c\u4e86\u7b5b\u9009\u3002\u5229\u7528\u4ea4\u66ff\u7684\u53ef\u89c1\u5149\u7167\u5c04\uff0c\u4f7f\u5f97RAFT\u805a\u5408\u5904\u4e8e\u201c\u5f00\u201d\u548c\u201c\u5173\u201d\u7684\u53ef\u63a7\u72b6\u6001\u4e0b\u3002\u7531\u4e8e\u5176\u805a\u96c6\u8bf1\u5bfc\u7684\u6392\u653e\u7279\u6027\uff0cTPE\u7684\u6392\u653e\u5bf9\u5c40\u90e8\u7c98\u5ea6\u53d8\u5316\u5f88\u654f\u611f\u3002\u5728\u4e0d\u7834\u574f\u53cd\u5e94\u4f53\u7cfb\u7684\u524d\u63d0\u4e0b\uff0c\u201c\u88f8\u773c\u201d\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u83b7\u5f97\u5b9a\u91cf\u4fe1\u606f\u3002\u6b64\u5916\uff0c\u5341\u4e8c\u79cd\u4e0d\u540c\u7684\u805a\u5408\u4f53\u7cfb\u4e5f\u5145\u5206\u8bc1\u660e\u4e86\u8fd9\u79cd\u6280\u672f\u7684\u901a\u7528\u6027\u3002\u76ee\u524d\uff0c\u8fd9\u79cd\u65b9\u6cd5\u4e3a\u7406\u89e3\u53d7\u63a7\u7684\u6d3b\u6027\u81ea\u7531\u57fa\u805a\u5408\u8fc7\u7a0b\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5f3a\u6709\u529b\u7684\u5e73\u53f0\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cMaking Invisible Visible: In Situ Monitoring the RAFT Polymerization by Tetraphenylethylene-Containing Agents with Aggregation-Induced Emission Characteristics\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAngew. Chem. Int. Ed.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\"\"<\/p>\n

\u00a0\u56fe\u4e8c\u3001RIM\u539f\u7406\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

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\uff08b\uff09\u5316\u5408\u72692a (Mn = 1.5 \u00d7 104<\/sup> g\/ mol, 20 mg in 1 mL THF) \u7684PMA\u5728\u4e0d\u540cPS(Mw = 2.8 \u00d7 105<\/sup> g\/mol)\u7684\u8367\u5149\u53d8\u5316\u56fe\uff1b<\/p>\n

\uff08c\uff09\u76f8\u5bf9PL\u5f3a\u5ea6(I\/I0<\/sub>)\u4e0ePS\u6d53\u5ea6\u7684\u5173\u7cfb\u56fe\uff0c\u5176\u4e2dI0<\/sub>\u4e3a\u7eafTHF\u4e2d\u7684PL\u5f3a\u5ea6\u3002<\/p>\n

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\"\"
\n \uff08a\uff09 \u53cd\u5e94\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09 \u5728\u624b\u6301\u7d2b\u5916\u706f365 nm\u7167\u5c04\u4e0b\u3002\u805a\u5408\u7269\u6eb6\u6db2\u5728\u4e0d\u540c\u8f6c\u6362\u4e0b\u7684\u8367\u5149\u7167\u7247\uff1b<\/p>\n

\uff08c\uff09 \u4e0d\u540c\u8f6c\u6362\u7684\u805a\u5408\u7269\u6df7\u5408\u7269\u7684PL\u5149\u8c31;<\/p>\n

\uff08d\uff09 \u8f6c\u6362\u548cMn\u4e0ePL\u5f3a\u5ea6\u7684\u6307\u6570\u5173\u7cfb\u3002<\/p>\n

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\"\"<\/p>\n

\uff08a\uff09 \u4e0d\u540cMn\u6d53\u5ea6\u7684MA\u7684PL\u5f3a\u5ea6\u53d8\u5316\uff1b<\/p>\n

\uff08b\uff09 \u4e0d\u540cMn\u6d53\u5ea6\u7684HMA\u7684PL\u5f3a\u5ea6\u53d8\u5316\uff1b<\/p>\n

\uff08c\uff09 \u4e0d\u540cMn\u6d53\u5ea6\u7684tBA\u7684PL\u5f3a\u5ea6\u53d8\u5316;<\/p>\n

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\uff08f\uff09 \u4e0d\u540c\u7684HEA\u7684PL\u5f3a\u5ea6\u53d8\u5316\u3002<\/p>\n

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\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5<\/strong>\uff1aMaking Invisible Visible: In Situ Monitoring the RAFT Polymerization by Tetraphenylethylene-Containing Agents with Aggregation-Induced Emission Characteristics<\/a><\/strong>\uff08Angew. Chem. Int. Ed., 2018, DOI: 10.1002\/anie.201803268\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u7ec4\u5c0f\u80d6\u7eb8\u7f16\u8bd1\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a><\/strong>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

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