{"id":134928,"date":"2018-04-15T06:30:31","date_gmt":"2018-04-14T22:30:31","guid":{"rendered":"\/\/m.iemloyee.com\/?p=134928"},"modified":"2018-04-14T20:10:46","modified_gmt":"2018-04-14T12:10:46","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6-%e4%bd%99%e6%9e%97%e8%94%9a%e5%90%88%e8%82%a5%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6-%e8%92%8b%e9%98%b3nano-energy-%e5%8f%a0%e5%b1%82%e8%b0%83%e6%8e%a7%e7%89%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=134928","title":{"rendered":"\u5357\u4eac\u5927\u5b66 \u4f59\u6797\u851a&\u5408\u80a5\u5de5\u4e1a\u5927\u5b66 \u848b\u9633Nano Energy: \u53e0\u5c42\u8c03\u63a7\u7269\u7406\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u5236\u5907\u6df7\u5408\u9633\u79bb\u5b50\u9499\u949b\u77ff\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u8584\u819c\u5728\u53ef\u89c1\u5149\u8303\u56f4\u5177\u6709\u4f18\u5f02\u7684\u5149\u5438\u6536\u548c\u80fd\u5e26\u8c03\u63a7\u7279\u6027\uff0c\u4ee5\u53ca\u8f83\u957f\u7684\u8f7d\u6d41\u5b50\u5bff\u547d\uff0c\u8fd1\u5e74\u6765\u4e00\u76f4\u662f\u7814\u7a76\u5173\u6ce8\u7684\u70ed\u70b9\u3002\u7136\u800c\uff0c\u901a\u5e38\u7684\u9499\u949b\u77ff\u6750\u6599\uff08CH3<\/sub>NH3<\/sub>PbI3<\/sub>\uff09\u70ed\u7a33\u5b9a\u6027\u5dee\uff0c\u4e14\u5bf9\u6e7f\u5ea6\u654f\u611f\uff0c\u4e5f\u5927\u5927\u9650\u5236\u4e86\u5176\u89c4\u6a21\u5316\u5149\u4f0f\u5668\u4ef6\u5e94\u7528\u3002\u5982\u4f55\u63d0\u9ad8\u5176\u7a33\u5b9a\u6027\u5e76\u4fdd\u6301\u8f83\u9ad8\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u4e00\u76f4\u662f\u56f0\u6270\u9499\u949b\u77ff\u6750\u6599\u8fdb\u4e00\u6b65\u53d1\u5c55\u7684\u95ee\u9898\u3002\u800c\u57fa\u4e8eCsPbBr3<\/sub>\u7b49\u7684\u65e0\u673a\u9499\u949b\u77ff\u6750\u6599\uff0c\u5176\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u4e5f\u53d7\u5230\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u4eba\u5458\u7684\u9752\u7750\u3002\u4f46\u662f\u76f8\u6bd4\u6709\u673a\u6742\u5316\u9499\u949b\u77ff\u7406\u60f3\u7684\u5149\u5b66\u5e26\u9699\u800c\u8a00\uff0c\u65e0\u673a\u9499\u949b\u77ff\u5176\u5e26\u9699\u8f83\u5bbd\uff0c\u5149\u5438\u6536\u8303\u56f4\u8f83\u7a84\uff0c\u96be\u4ee5\u5145\u5206\u5438\u6536\u53ef\u89c1\u5149\uff0c\u56e0\u6b64\uff0c\u8f83\u4f4e\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u5236\u7ea6\u7740\u65e0\u673a\u9499\u949b\u77ff\u5728\u5546\u4e1a\u5316\u7684\u5e94\u7528\u3002\u5982\u4f55\u63d0\u9ad8\u6709\u673a\u9499\u949b\u77ff\u7684\u7a33\u5b9a\u6027\u7684\u540c\u65f6\uff0c\u5b9e\u73b0\u9ad8\u7684\u8f6c\u6362\u6548\u7387\uff0c\u4e00\u76f4\u662f\u56f0\u6270\u9499\u949b\u77ff\u6750\u6599\u8fdb\u4e00\u6b65\u53d1\u5c55\u7684\u95ee\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5927\u5b66\u7535\u5b50\u5b66\u9662\u4f59\u6797\u851a\u6559\u6388\u8bfe\u9898\u7ec4\u4e0e\u5408\u80a5\u5de5\u4e1a\u5927\u5b66\u6750\u6599\u5b66\u9662\u848b\u9633\u6559\u6388\u56e2\u961f\u5408\u4f5c<\/strong>\uff0c\u63d0\u51fa\u91c7\u7528\u7cbe\u786e\u53ef\u63a7\u7684\u53e0\u5c42\u8c03\u63a7\u7269\u7406\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6280\u672f\uff08stack-sequence physical-chemical vapor deposition\uff09\u5236\u5907\u6df7\u5408\u9633\u79bb\u5b50\u63ba\u6742\u3001\u80fd\u5e26\u6e10\u53d8\u7684\u65b0\u578b\u9499\u949b\u77ff\u8584\u819c\u6750\u6599\u3002\u6b64\u6df7\u5408\u9633\u79bb\u5b50\u63ba\u6742\u6709\u673a\u6742\u5316\u9499\u949b\u77ff\u8584\u819c\uff0c\u5229\u7528\u53ef\u89c4\u6a21\u5316\u5236\u5907\u7684\u6c14\u76f8\u6dc0\u79ef\u5de5\u827a\uff0c\u9996\u5148\u5236\u5907\u5bcc\u96c6Cs\u3001Br\u5143\u7d20\u7684\u8868\u5c42\u9499\u949b\u77ff\u548c\u5bcc\u96c6FA\u3001I\u7684\u5185\u5c42\u53e0\u5c42\u7ed3\u6784\uff0c\u7136\u540e\u7ecf\u8fc7\u4f4e\u6e29\u9000\u706b\u76f8\u4e92\u6269\u6563\u6784\u5efa\u51fa\u5177\u6709\u80fd\u5e26\u68af\u5ea6\u7684\u9499\u949b\u77ff\u8584\u819c\uff0c\u4f7f\u5176\u80fd\u5145\u5206\u5e76\u5206\u5e03\u5f0f\u5438\u6536\u4e0d\u540c\u6ce2\u6bb5\u7684\u5165\u5c04\u5149\uff0c\u4ece\u800c\u5b9e\u73b018.22%\u7684\u8f6c\u6362\u6548\u7387\u3002\u4ee4\u4eba\u5174\u594b\u7684\u662f\uff0c\u6df7\u5408\u65e0\u673a\u9633\u79bb\u5b50\u63ba\u6742\u5927\u5927\u63d0\u9ad8\u4e86\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\uff1a\u5668\u4ef6\u653e\u7f6e\u5728\u7a7a\u6c14\u4e2d\u4e24\u4e2a\u6708\u540e\uff0c\u9633\u79bb\u5b50\u63ba\u6742\u9499\u949b\u77ff\u4f9d\u65e7\u80fd\u591f\u4fdd\u6301\u8f83\u9ad8\u7684\u8f6c\u6362\u6548\u7387\uff0c\u8fd9\u4e3a\u5b9e\u73b0\u89c4\u6a21\u5316\u5236\u5907\u9ad8\u6027\u80fd\u7a33\u5b9a\u7684\u63ba\u6742\u9499\u949b\u77ff\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u4e00\u9898\u4e3a\u201cMixed cation perovskite solar cells by stack-sequence chemical vapor deposition with self-passivation and gradient absorption layer\u201d\u53d1\u8868\u5728\u8fd1\u671f\u7684Nano Energy<\/strong>\u4e0a\u3002\u7ae5\u56fd\u5e86\u535a\u58eb<\/strong>\u4e3a\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\uff0c\u90e8\u5206\u5de5\u4f5c\u5f97\u5230\u5408\u80a5\u5de5\u4e1a\u5927\u5b66\u7855\u58eb\u751f\u674e\u6b22<\/strong>\u540c\u5b66\u7684\u91cd\u8981\u5e2e\u52a9\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1<\/strong>\uff1a\u5b9e\u9a8c\u6d41\u7a0b\u56fe
\n \"\"<\/strong><\/p>\n

\u53e0\u5c42\u8c03\u63a7\u7269\u7406\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6d41\u7a0b\u56fe<\/p>\n

\u56fe<\/strong>2<\/strong>\uff1a\u4e0d\u540c\u6bd4\u4f8b\u65e0\u673a<\/strong>CsBr<\/strong>\u63ba\u6742\u8868\u5f81\u5206\u6790
\n \"\"
\n <\/strong>(a\u3001b) \u4e0d\u540c\u6bd4\u4f8b\u65e0\u673aCsBr\u63ba\u6742\u6709\u673a\u9499\u949b\u77ffXRD\uff1b<\/p>\n

(c) \u4e0d\u540c\u6bd4\u4f8b\u65e0\u673aCsBr\u63ba\u6742\u6709\u673a\u9499\u949b\u77ff\u5438\u6536\u56fe\u8c31(d)\u5bf9\u5e94\u7684\u5149\u5b66\u5e26\u9699\u3002<\/p>\n

\u56fe<\/strong>3<\/strong>\uff1a\u53e0\u5c42\u8c03\u63a7\u7269\u7406\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u5236\u5907\u6709\u673a\u9499\u949b\u77ff\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe\u548c\u80fd\u5e26\u7ed3\u6784
\n \"\"<\/strong><\/p>\n

(a)\u65e0\u673a\u9499\u949b\u77ff\u884d\u751f\u76f8CsPb2Br5\u949d\u5316\u673a\u5236\uff1b<\/p>\n

(b)\u6df7\u5408\u9633\u79bb\u5b50\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

(c)\u80fd\u5e26\u7ed3\u6784\u56fe\u53ca\u5149\u5438\u6536\u8fc7\u7a0b\u3002<\/p>\n

\u56fe<\/strong>4<\/strong>\uff1a<\/strong>\u6df7\u5408\u9633\u79bb\u5b50\u9499\u949b\u77ff\u7535\u6c60\u5149\u4f0f\u6027\u80fd
\n \"\"<\/strong><\/p>\n

(a) \u4e0d\u540c\u6bd4\u4f8b\u65e0\u673aCsBr\u63ba\u6742\u6709\u673a\u9499\u949b\u77ff\u7535\u6c60J-V\u66f2\u7ebf\uff1b<\/p>\n

(b) \u6df7\u5408\u9633\u79bb\u5b50\u9499\u949b\u77ff\u7535\u6c60\u6b63\u53cd\u626bJ-V\u66f2\u7ebf\uff1b<\/p>\n

(c) \u5bf9\u5e94\u7684IPCE\u53ca\u79ef\u5206\u7535\u6d41\uff1b<\/p>\n

(d) \u4e09\u79cd\u6709\u673a\u6742\u5316\u9499\u949b\u77ff\u7a33\u5b9a\u6027\u5bf9\u6bd4\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Mixed cation perovskite solar cells by stack-sequence chemical vapor deposition with self-passivation and gradient absorption laye<\/a> (Nano Energy, 2018, DOI: 10.1016\/j.nanoen.2018.04.012)<\/p>\n

\u3010\u56e2\u961f\u8fd1\u671f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b\u3011<\/strong><\/p>\n

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\n \"\"<\/p>\n

\u56fe<\/strong>5<\/strong> \u6c14\u76f8\u6c89\u79ef\u4e24\u76f8\u65e0\u673a\u9499\u949b\u77ff\u67d4\u6027\u5149\u7535\u63a2\u6d4b\u5668<\/p>\n

\u8fdb\u4e00\u6b65\uff0c\u9488\u5bf9\u65e0\u673a\u9499\u949b\u77ff\u5728\u7d2b\u5916-\u53ef\u89c1\u5149\u533a\u57df\u7684\u5f3a\u5438\u6536\u6027\u80fd\u548c\u5149\u81f4\u53d1\u5149\u6027\u80fd\uff0c\u901a\u8fc7\u5728\u6709\u673a\u9499\u949b\u77ff\u63a2\u6d4b\u5668\u7684FTO\u57fa\u5e95\u5916\u90e8\u84b8\u9540\u4e00\u5c42\u65e0\u673a\u9499\u949b\u77ff\u6750\u6599\u4f5c\u4e3a\u7a97\u53e3\u5c42\uff0c\u53ef\u5c06\u9ad8\u80fd\u91cf\u7684\u7d2b\u5916\u5149\u5438\u6536\u3001\u5e76\u76f4\u63a5\u8f6c\u6362\u6210\u6709\u673a\u9499\u949b\u77ff\u5438\u6536\u6700\u4f73\u7684\uff08400~600 nm\uff09\u53ef\u89c1\u5149\u6ce2\u6bb5\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u6df1\u7d2b\u5916\u5149\u63a2\u6d4b\u3002\u5982\u6b64\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u5b9e\u73b0\u65e0\u673a\u9499\u949b\u77ff\u5c42\u7684\u7cbe\u786e\u8c03\u63a7\uff0c\u53c8\u80fd\u6709\u6548\u7684\u907f\u514d\u540e\u7eed\u65e0\u673a\u9499\u949b\u77ff\u4e2d\u7684\u6eb6\u5242\u5bf9\u6709\u673a\u9499\u949b\u77ff\u5c42\u7684\u7834\u574f\uff0c\u5927\u5927\u63d0\u9ad8\u4e86\u63a2\u6d4b\u5668\u7684\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728\u300a\u7269\u7406\u5316\u5b66\u5feb\u62a5\u300b\u4e0a\uff08Journal of Physical Chemistry Letters, DOI: 10.1021\/acs.jpclett.8b00429\uff09\uff0c\u8be5\u5de5\u4f5c\u4ea6\u53d7\u9080\u4ee5ACS LiveSlides<\/em>\u5f62\u5f0fHighlight\u3002
\n \"\"<\/p>\n

\u56fe<\/strong>6<\/strong> \u590d\u76f8\u65e0\u673a\u9499\u949b\u77ff\u5c42\u4e0b\u8f6c\u6362\u673a\u7406<\/p>\n

\u76f8\u5173\u6587\u7ae0\u53ca\u94fe\u63a5\uff1a<\/strong><\/p>\n

    \n
  1. Mixed cation perovskite solar cells by stack-sequence chemical vapor deposition with self-passivation and gradient absorption layer<\/a>. Guoqing Tong, Huan Li, Guopeng Li, Ting Zhang, Chengdong Li, Linwei Yu<\/strong>*<\/sup>, Jun Xu, Yang Jiang*<\/sup><\/strong>, Yi Shi, Kunji Chen
    \n Nano Energy<\/em><\/strong>, published online, DOI:10.1016\/j.nanoen.2018.04.012. (2018)<\/li>\n
  2. \u00a0Enhancing Hybrid Perovskite Detectability in the Deep Ultraviolet Region with Down-Conversion Dual-Phase (CsPbBr3<\/sub>\u2013Cs4<\/sub>PbBr6<\/sub>) Films<\/a>. G Tong, H Li, Z Zhu, Y Zhang, L Yu<\/strong>*, J Xu, Y Jiang*<\/strong> The Journal of Physical Chemistry Letters<\/em><\/strong> 9, 1592-1599 (2018)<\/li>\n
  3. Dual-Phase CsPbBr3<\/sub>\u2013CsPb2<\/sub>Br5<\/sub> Perovskite Thin Films via Vapor Deposition for High-Performance Rigid and Flexible Photodetectors<\/a>. Guoqing Tong, Huan Li, Danting Li, Zhifeng Zhu, Enze Xu, Guopeng Li, Linwei Yu,* <\/strong>Jun Xu, and Yang Jiang*<\/strong> Small <\/em>14, <\/em><\/strong>1702523 (2018)\u00a0<\/li>\n<\/ol>\n

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