{"id":134254,"date":"2018-04-11T06:30:02","date_gmt":"2018-04-10T22:30:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=134254"},"modified":"2018-04-10T21:02:07","modified_gmt":"2018-04-10T13:02:07","slug":"%e4%b8%9c%e5%8d%8e%e5%a4%a7%e5%ad%a6%e7%8e%8b%e5%ae%8f%e5%bf%97%e5%9b%a2%e9%98%9facs-nano%e9%ab%98%e6%80%a7%e8%83%bdna%e7%a6%bb%e5%ad%90%e7%94%b5%e8%87%b4%e5%8f%98%e8%89%b2%e5%8a%a9%e5%8a%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=134254","title":{"rendered":"\u4e1c\u534e\u5927\u5b66\u738b\u5b8f\u5fd7\u56e2\u961fACS Nano:\u9ad8\u6027\u80fdNa+\u79bb\u5b50\u7535\u81f4\u53d8\u8272\u52a9\u529b\u5ec9\u4ef7\u663e\u793a\u7535\u5b50\u53ca\u7269\u8054\u7f51\u5668\u4ef6"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u4e8e\u94a0\u5143\u7d20\u8d44\u6e90\u76f8\u5bf9\u4e30\u5bcc\u4e14\u6210\u672c\u4f4e\u5ec9\uff0c\u57fa\u4e8e\u94a0\u79bb\u5b50(Na+<\/sup>)\u7684\u7535\u5316\u5b66\u4f53\u7cfb\u5728\u80fd\u6e90\u5b58\u50a8\u9886\u57df\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4e5f\u6b63\u662f\u57fa\u4e8e\u94a0\u79bb\u5b50\u7684\u591a\u65b9\u9762\u4f18\u52bf\uff0c\u7814\u7a76\u4eba\u5458\u4e5f\u5e0c\u671b\u5c06\u94a0\u79bb\u5b50\u5e94\u7528\u5230\u540c\u6837\u57fa\u4e8e\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u4e2d\u53bb\u3002\u987e\u540d\u601d\u4e49\uff0c\u7535\u81f4\u53d8\u8272\u662f\u6307\u6750\u6599\u5149\u5b66\u5c5e\u6027\u5728\u5916\u52a0\u7535\u573a\u7684\u4f5c\u7528\u4e0b\u53d1\u751f\u53ef\u9006\u7684\u53d8\u5316\u7684\u73b0\u8c61\uff0c\u5b8f\u89c2\u8868\u73b0\u4e3a\u989c\u8272\u548c\u900f\u660e\u5ea6\u7684\u53ef\u9006\u53d8\u5316\uff0c\u5df2\u7ecf\u5e7f\u6cdb\u5e94\u7528\u4e8e\u667a\u80fd\u7a97\u3001\u6c7d\u8f66\u540e\u89c6\u955c\u3001\u667a\u80fd\u663e\u793a\u7b49\u9886\u57df\u3002\u4f46\u662f\u7531\u4e8eNa+<\/sup>\u79bb\u5b50\u534a\u5f84\u660e\u663e\u5927\u4e8e\u901a\u7528\u7684Li+<\/sup>\u79bb\u5b50\uff0c\u5bfc\u81f4\u5176\u5728\u4f20\u7edf\u7535\u81f4\u53d8\u8272\u7535\u6781\u5982\u6c27\u5316\u94a8\u4e2d\u4f20\u8f93\u53d8\u5f97\u7f13\u6162\uff0c\u4ece\u800c\u6781\u5927\u5730\u964d\u4f4e\u4e86\u7535\u81f4\u53d8\u8272\u6750\u6599\u7684\u6027\u80fd\u548c\u5faa\u73af\u5bff\u547d\uff0c\u9650\u5236\u4e86\u94a0\u79bb\u5b50\u7535\u5316\u5b66\u4f53\u7cfb\u5728\u7535\u81f4\u53d8\u8272\u9886\u57df\u7684\u5e94\u7528\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e1c\u534e\u5927\u5b66\u738b\u5b8f\u5fd7\u7814\u7a76\u56e2\u961f<\/strong>\u4e0e\u7f8e\u56fd\u4f50\u6cbb\u4e9a\u7406\u5de5\u738b\u521a\u535a\u58eb(\u73b0\u7f8e\u56fd\u897f\u5317\u5927\u5b66\u535a\u58eb\u540e)\u5408\u4f5c<\/strong>\uff0c\u5c06\u542b\u6709\u53d8\u8272\u57fa\u56e2\u7684\u6709\u673a\u914d\u4f53\u7ec4\u88c5\u6210MOF\u7535\u6781\uff0c\u5229\u7528\u8be5\u7c7b<\/strong>MOF<\/strong>\u7ed3\u6784\u4e2d\u5177\u6709\u8f83\u5927\u5c3a\u5bf8\u7684\u4e00\u7ef4\u79bb\u5b50\u901a\u9053\uff0c\u5b9e\u73b0\u4e86\u94a0\u79bb\u5b50\u7684\u5feb\u901f\u8131\u5d4c\uff0c<\/strong>\u4ece\u800c\u4f7f\u5f97\u7535\u81f4\u53d8\u8272\u7535\u6781\u5728Na+<\/sup>\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u8fbe\u5230\u4e86\u6781\u9ad8\u7684\u53d8\u8272\u901f\u5ea6\u548c\u53d8\u8272\u6548\u7387\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cIon-Transport Design for High-Performance Na+<\/sup>-Based Electrochromics<\/strong>\u201d\u53d1\u8868\u5728ACS Nano<\/strong>\u4e0a\u3002\u6587\u7ae0\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u4e1c\u534e\u5927\u5b66\u674e\u7136<\/strong>\u535a\u58eb\u751f\u548c\u674e\u514b\u777f<\/strong>\u535a\u58eb(\u73b0\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u535a\u58eb\u540e)<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00<\/strong>. <\/strong>\u4e24\u79cd<\/strong>MOF<\/strong>\u7684\u7ed3\u6784\u5206\u6790\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a, b, c, d)\u4e24\u79cdMOF\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(e)\u4e24\u79cdMOF\u7684XRD\u56fe\uff1b<\/p>\n

(f, g)\u4e24\u79cdMOF\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

(h)\u4e24\u79cdMOF\u7684N2<\/sub>\u7b49\u6e29\u5438\u8131\u9644\u66f2\u7ebf\uff1b<\/p>\n

\u56fe\u4e8c<\/strong>. MOF<\/strong>\u7535\u6781\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7535\u5316\u5b66\u6027\u80fd\u548c\u79bb\u5b50\u4f20\u8f93\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a)MOF\u7535\u6781\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u963b\u6297\u56fe\uff1b<\/p>\n

(b)MOF\u7535\u6781\u5728Na+<\/sup>\u7535\u89e3\u6db2\u4e2d\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

(c)\u4e0d\u540c\u79bb\u5b50\u5728MOF\u7535\u6781\u4e2d\u7684\u79bb\u5b50\u4f20\u8f93\u6548\u7387\uff1b<\/p>\n

(d) MOF\u7535\u6781\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u79bb\u5b50\u4f20\u8f93\u673a\u5236\u56fe\uff1b<\/p>\n

\u56fe3. MOF\u7535\u6781\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u81f4\u53d8\u8272\u6027\u80fd\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a)MOF\u7535\u6781\u5728Na+<\/sup>\u7535\u89e3\u6db2\u4e2d\u4e0d\u540c\u7535\u538b\u4e0b\u7684\u7d2b\u5916\u5438\u6536\u8c31\u56fe\uff1b<\/p>\n

(b)MOF\u7535\u6781\u5728\u4e0d\u540c\u7535\u538b\u4e0b\u7684\u989c\u8272\u793a\u610f\u56fe\uff1b<\/p>\n

(c)MOF\u7535\u6781\u5728\u4e0d\u540c\u79bb\u5b50\u7535\u89e3\u6db2\u4e2d\u7684\u53d8\u8272\u901f\u7387\uff1b<\/p>\n

(d)\u4e24\u79cdMOF\u7535\u6781\u5728Na+<\/sup>\u7535\u89e3\u6db2\u4e2d\u7684\u53d8\u8272\u901f\u7387\uff1b<\/p>\n

(e)\u4e24\u79cdMOF\u7535\u6781\u5728\u4e0d\u540c\u79bb\u5b50\u7535\u89e3\u6db2\u4e2d\u7684\u53d8\u8272\u6548\u7387\uff1b<\/p>\n

(f)\u4e24\u79cdMOF\u7535\u6781\u5728Na+<\/sup>\u7535\u89e3\u6db2\u4e2d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

\u56fe4. \u57fa\u4e0eMOF\u7535\u6781\u7684\u591a\u5f69\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u548c\u5e94\u7528\u4e8e\u5171\u4eab\u5355\u8f66\u7684\u667a\u80fd\u4e8c\u7ef4\u7801\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u00a0<\/strong>(a) MOF\u7535\u6781\u6fc0\u5149\u523b\u8680\u5236\u5907\u6d41\u7a0b\u56fe\uff1b<\/p>\n

(b)\u57fa\u4e8e\u523b\u8680MOF\u7535\u6781\u7684\u591a\u8272\u7535\u81f4\u53d8\u8272\u5668\u4ef6\uff1b<\/p>\n

(c)\u57fa\u4e8eMOF\u7535\u6781\u4e2d\u667a\u80fd\u4e8c\u7ef4\u7801\u5668\u4ef6\uff1b<\/p>\n

(d)\u53ef\u9690\u85cf\u667a\u80fd\u4e8c\u7ef4\u7801\u5668\u4ef6\u5e94\u7528\u4e8e\u5171\u4eab\u5355\u8f66\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u5c06\u4e24\u79cd\u542b\u6709\u4e0d\u540c\u5c3a\u5bf8\u4e00\u7ef4\u5b54\u9053(10 \u00c5 vs 33 \u00c5)\u7684MOF\u7535\u6781\u5206\u522b\u5728Al3+<\/sup>\u3001Li+<\/sup>\u3001Na+<\/sup>\u548cTBA+<\/sup>\u57fa\u7535\u89e3\u6db2\u4e2d\u8fdb\u884c\u6d4b\u8bd5\uff0c\u53d1\u73b0\u5bf9\u4e8e\u4e24\u79cd\u7535\u6781\uff0c\u65e2\u4e0d\u662f\u79bb\u5b50\u534a\u5f84\u6700\u5c0f\u7684Al3+<\/sup>\u79bb\u5b50\u4e5f\u4e0d\u662f\u534a\u5f84\u6700\u5927\u7684TBA+<\/sup>\u4f20\u8f93\u6700\u4e3a\u8fc5\u901f\u3002\u5c3d\u7ba1Na+<\/sup>\u79bb\u5b50\u534a\u5f84\u8981\u5927\u4e8eLi+<\/sup>\u79bb\u5b50\u548cAl3+<\/sup>\u79bb\u5b50\uff0c\u5374\u6709\u7740\u6700\u9ad8\u7684\u79bb\u5b50\u4f20\u8f93\u6548\u7387\u3002\u7814\u7a76\u56e2\u961f\u8ba4\u4e3a\u540c\u65f6\u6709\u4e24\u4e2a\u91cd\u8981\u7684\u56e0\u7d20\u5f71\u54cd\u7740\u79bb\u5b50\u4f20\u8f93\uff1a\u79bb\u5b50\u4e0e\u4f20\u8f93\u8def\u5f84\u95f4\u7684\u7a7a\u95f4\u4f4d\u963b\u548c\u79bb\u5b50\u4e0eMOF\u6846\u67b6\u4e0a\u8d1f\u7535\u57fa\u56e2\u7684\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u3002\u6b63\u662f\u7531\u4e8eMOFs\u72ec\u7279\u7684\u7ed3\u6784\u5bfc\u81f4\u5176\u5bf9\u4e0d\u540c\u79bb\u5b50\u8131\u5d4c\u5177\u6709\u9009\u62e9\u6027\u3002\u57fa\u4e8e\u8be5\u7c7b\u5177\u6709\u79bb\u5b50\u4f20\u8f93\u9009\u62e9\u6027\u7684MOF\u6750\u6599\uff0c\u7814\u7a76\u56e2\u961f\u5236\u5907\u4e86\u5feb\u901f\u53d8\u8272\uff0c\u4e14\u5177\u6709\u9ad8\u5149\u8c03\u5236\u8303\u56f4\u4e0e\u53d8\u8272\u6548\u7387\u548c\u826f\u597d\u7684\u7a33\u5b9a\u6027\u7684\u94a0\u79bb\u5b50\u7535\u81f4\u53d8\u8272\u7535\u6781\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u901a\u8fc7\u65e0\u6a21\u677f\u7684\u6fc0\u5149\u96d5\u523b\u6cd5\u523b\u8680\u53d8\u8272\u5c42\u548c\u7535\u6781\uff0c\u6210\u529f\u5236\u5907\u4e86\u591a\u5f69\u7535\u81f4\u53d8\u8272\u663e\u793a\u5668\u4ef6\u4e0e\u5e94\u7528\u4e8e\u5171\u4eab\u5355\u8f66\u7684\u53ef\u9690\u85cf\u667a\u80fd\u4e8c\u7ef4\u7801\u5668\u4ef6\uff0c\u8bc1\u660e\u4e86\u5176\u5728\u5ec9\u4ef7\u7535\u81f4\u53d8\u8272\u548c\u7269\u8054\u7f51\u7535\u5b50\u5668\u4ef6\u90bb\u57df\u7684\u53d1\u5c55\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u8fde\u63a5\uff1a<\/strong>Ion-Transport Design for High-Performance Na+<\/sup>-Based Electrochromics<\/a> (ACS Nano, 2018, DOI:10.1021\/acsnano.8b00974)<\/strong><\/p>\n

\u672c\u6587\u7531\u674e\u7136\u535a\u58eb<\/strong>\u64b0\u5199\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406<\/strong>\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u6750\u6599\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08228686798\uff09\uff01
\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH<\/strong>\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\n \u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790<\/strong>\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u94a0\u5143\u7d20\u8d44\u6e90\u76f8\u5bf9\u4e30\u5bcc\u4e14\u6210\u672c\u4f4e\u5ec9\uff0c\u57fa\u4e8e\u94a0\u79bb\u5b50(Na+)\u7684\u7535\u5316\u5b66\u4f53\u7cfb\u5728\u80fd\u6e90\u5b58\u50a8\u9886\u57df\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4e5f\u6b63\u662f\u57fa\u4e8e\u94a0\u79bb\u5b50\u7684\u591a\u65b9\u9762\u4f18\u52bf\uff0c\u7814\u7a76\u4eba\u5458\u4e5f\u5e0c\u671b\u5c06\u94a0\u79bb\u5b50\u5e94…<\/p>\n","protected":false},"author":3440,"featured_media":134263,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[2789],"class_list":["post-134254","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-mofs"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/134254"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3440"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=134254"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/134254\/revisions"}],"predecessor-version":[{"id":134379,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/134254\/revisions\/134379"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/134263"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=134254"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=134254"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=134254"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}