{"id":134139,"date":"2018-04-10T06:30:59","date_gmt":"2018-04-09T22:30:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=134139"},"modified":"2018-04-10T18:46:49","modified_gmt":"2018-04-10T10:46:49","slug":"%e8%af%ba%e5%a5%96%e5%be%97%e4%b8%bb%e5%9c%a8jacs%e4%b8%80%e5%a4%a9%e8%bf%9e%e5%8f%917%e7%af%87%e6%96%87%e7%ab%a0%ef%bc%8c%e5%8f%82%e5%8a%a0%e8%bf%87%e9%ab%98%e8%80%83%e7%9a%84%e4%bd%a0%e4%b8%80","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=134139","title":{"rendered":"\u8bfa\u5956\u5f97\u4e3b\u5728JACS\u4e00\u5929\u8fde\u53d17\u7bc7\u6587\u7ae0\uff0c\u53c2\u52a0\u8fc7\u9ad8\u8003\u7684\u4f60\u4e00\u5b9a\u89c1\u8fc7"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134149\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/001omVKngy6Wbj0D3wl09690.jpg\" alt=\"\" width=\"552\" height=\"332\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/001omVKngy6Wbj0D3wl09690.jpg 552w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/001omVKngy6Wbj0D3wl09690-300x180.jpg 300w\" sizes=\"(max-width: 552px) 100vw, 552px\" \/><\/p>\n<p>Richard F. Heck\u6700\u51fa\u540d\u7684\u5c31\u662f\u5f53\u5e74\u5728JACS\u4e0a\u540c\u4e00\u5929\u53d1\u8868\u4e867\u7bc7\u8fde\u53f7\u6587\u7ae0\uff0c\u8be6\u7ec6\u9610\u8ff0\u4e86\u6709\u673a\u5408\u6210\u9886\u57df\u4e2d\u94af\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7684\u4e00\u4e9b\u65b0\u89c2\u70b9\uff0c\u540e\u88ab\u547d\u540d\u4e3a\u201c\u8d6b\u514b\u53cd\u5e94\u201d\uff0c\u6210\u4e3a\u5176\u4ed6\u65e5\u540e\u53d1\u73b0\u7684\u4f17\u591a\u94af\u50ac\u5316\u5076\u8054\u53cd\u5e94\u7684\u57fa\u7840\uff0c\u8fd9\u4e9b\u53cd\u5e94\u5305\u62ec\u82b3\u5364\u4e0e\u70f7\u57fa\u787c\u9178\u95f4\u7684Suzuki-Miyaura\u5076\u8054\u53cd\u5e94\u3001\u4f7f\u7528\u6709\u673a\u9521\u7684Stille\u5076\u8054\u53cd\u5e94\u3001\u4f7f\u7528\u6709\u673a\u9541\u7684Kumada-Corriu\u5076\u8054\u53cd\u5e94\u3001\u4f7f\u7528\u7845\u70f7\u7684Hiyama\u5076\u8054\u53cd\u5e94\u3001\u5229\u7528\u6709\u673a\u950c\u7684Negishi\u5076\u8054\u53cd\u5e94\uff0c\u4ee5\u53ca\u4ee5\u9187\u548c\u80fa\u4e3a\u5e95\u7269\u7684\u53cd\u5e94\u7b49\u3002\u8fd9\u4e9b\u94af\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\u662f\u76ee\u524d\u6709\u673a\u5408\u6210\u548c\u5de5\u4e1a\u751f\u4ea7\u4e2d\u5e38\u7528\u7684\u5408\u6210\u7b56\u7565\u3002\u4e5f\u6b63\u662f\u56e0\u4e3a\u6b64\u6210\u679c\uff0c\u4ed6\u548c\u65e5\u672c\u79d1\u5b66\u5bb6\u6839\u5cb8\u8363\u4e00\u548c\u94c3\u6728\u7ae0\u5171\u540c\u83b7\u5f972010\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u3002\u8fd9\u4e00\u6210\u679c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5236\u836f\u3001\u7535\u5b50\u5de5\u4e1a\u548c\u5148\u8fdb\u6750\u6599\u7b49\u9886\u57df\uff0c\u53ef\u4ee5\u4f7f\u4eba\u7c7b\u9020\u51fa\u590d\u6742\u7684\u6709\u673a\u5206\u5b50\u3002\u66fe\u7ecf\u8f70\u52a8\u5b66\u672f\u5708\u76847\u7bc7\u540c\u82b1\u987a\u4e00\u6837\u7684\u6587\u7ae0\u662f\u600e\u4e48\u7684\uff0c\u4e0b\u9762\u5c0f\u7f16\u5e26\u4f60\u8d70\u8fdb\u79d1\u5b66\u7684\u4e16\u754c\uff1a<\/p>\n<p><strong>1\u3001JACS\uff1a\u7b2cVIII\u65cf\u91d1\u5c5e\u884d\u751f\u7269\u5bf9\u70ef\u70c3\u7684\u9170\u5316\uff0c\u7532\u57fa\u5316\u548c\u7fa7\u70f7\u57fa\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134140\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72471-8.png\" alt=\"\" width=\"561\" height=\"315\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72471-8.png 561w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72471-8-300x168.png 300w\" sizes=\"(max-width: 561px) 100vw, 561px\" \/>\u975e\u8fc7\u6e21\u91d1\u5c5e\u70f7\u57fa\u548c\u82b3\u57fa\u4e0e\u70ef\u70c3\u7684\u52a0\u6210\u53cd\u5e94\u662f\u4f17\u6240\u5468\u77e5\u7684\uff0c\u4f46\u5f53\u65f6\u5bf9\u4e8e\u70f7\u57fa\u548c\u82b3\u57fa\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u7684\u52a0\u6210\u53cd\u5e94\u77e5\u4e4b\u751a\u5c11\u3002Richard F. Heck\u63a8\u6d4b\u8fd9\u79cd\u53cd\u5e94\u662f\u7531\u70f7\u57fa\u5316\u5242\u6216\u82b3\u57fa\u5316\u5242\u4e0e\u949b\uff0c\u9492\u6216\u94ec\u76d0\u7684\u7ec4\u5408\u5f15\u8d77\u7684\u70ef\u70c3\u805a\u5408\u53cd\u5e94\u7684\u539f\u56e0\u3002\u5e76\u4e14\u53d1\u73b0\u2164\u2162\u65cf\u91d1\u5c5e\u76d0\u7684\u82b3\u57fa\uff0c\u7532\u57fa\u548c\u7fa7\u57fa\u70f7\u57fa\u884d\u751f\u7269\uff0c\u7279\u522b\u662f\u94af\uff0c\u94d1\u548c\u948c\u76d0\u4e0e\u70ef\u70c3\u53cd\u5e94\u751f\u6210\u82b3\u57fa\uff0c\u7532\u57fa\u6216\u7fa7\u57fa\u70f7\u57fa\u53d6\u4ee3\u7684\u70ef\u70c3\uff0c\u8fd8\u539f\u91d1\u5c5e\u76d0\u6216\u91d1\u5c5e\u3002\u901a\u8fc7\u4f7f\u7528\u6c2f\u5316\u94dc\u6216\u6c2f\u5316\u94dc\uff0c\u7a7a\u6c14\u548c\u6c2f\u5316\u6c22\u4f5c\u4e3a\u518d\u6c27\u5316\u5242\uff0c\u53ef\u4f7f\u53cd\u5e94\u5bf9\u91d1\u5c5e\u76d0\u5177\u6709\u50ac\u5316\u6027\u3002\u8be5\u53cd\u5e94\u5bf9\u6c27\u6c14\u548c\u6c34\u4e0d\u654f\u611f\uff0c\u56e0\u6b64\u4e3a\u5408\u6210\u5404\u79cd\u5404\u6837\u7684\u70ef\u70c3\u5316\u5408\u7269\u63d0\u4f9b\u4e86\u975e\u5e38\u65b9\u4fbf\u7684\u65b9\u6cd5\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja01022a034\" target=\"_blank\" rel=\"noopener\">Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives<\/a>\uff08JACS,1968,DOI:10.1021\/ja01022a034\uff09<\/p>\n<p><strong>2\u3001JACS\uff1a\u70ef\u4e19\u9187\u4e0e\u6709\u673a\u94af\u5316\u5408\u7269\u7684\u82b3\u57fa\u5316\u20143-\u82b3\u57fa\u919b\u548c\u916e\u7684\u65b0\u5408\u6210<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134142\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72472-5.png\" alt=\"\" width=\"600\" height=\"201\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72472-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72472-5-300x101.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u70ef\u57fa\u4e0e\u2167\u65cf\u91d1\u5c5e\u7684\u82b3\u57fa\u884d\u751f\u7269\u7684\u82b3\u57fa\u5316\u662f\u57fa\u672c\u53cd\u5e94\u3002\u7531\u4e8e\u70ef\u4e19\u57fa\u53d6\u4ee3\u57fa\uff0c\u67d0\u4e9b\u70ef\u4e19\u57fa\u5316\u5408\u7269\u53d1\u751f\u4e0d\u540c\u4e8e\u7b80\u5355\u70ef\u70c3\u7684\u53cd\u5e94\u3002\u70ef\u4e19\u57fa\u919a\u548c\u916f\u53d1\u751f\u53cd\u5e94\uff0c\u5206\u522b\u751f\u6210\u8089\u6842\u57fa\u919a\u548c\u916f\uff0c\u4f46\u70ef\u4e19\u57fa\u5364\u5316\u7269\u5931\u53bb\u5364\u7d20\uff0c\u5f62\u6210\u70ef\u4e19\u57fa\u82b3\u65cf\u5316\u5408\u7269\u3002Richard F. Heck\u5f53\u65f6\u53d1\u73b0\u4e86\u53e6\u4e00\u4e2a\u4e0d\u5bfb\u5e38\u7684\u82b3\u57fa\u5316\u53cd\u5e94\uff0c\u5373\u70ef\u4e19\u57fa\u9187\u7684\u82b3\u57fa\u5316\u3002\u7531\u82b3\u57fa\u6c5e\u76d0\u548c\u94af\u76d0\u539f\u4f4d\u5236\u5907\u7684\u82b3\u57fa\u94af\u76d0\u4e0e\u4f2f\u6216\u4ef2\u70ef\u4e19\u9187\u53cd\u5e94\uff0c\u6839\u636e\u6240\u7528\u7684\u6c5e\u548c\u70ef\u4e19\u9187\u4ee5\u4f4e\u81f3\u9ad8\u4ea7\u7387\u751f\u62103-\u82b3\u57fa\u919b\u6216\u916e\u3002\u7531\u4e8e\u8be5\u53cd\u5e94\u5bf9\u5927\u591a\u6570\u53d6\u4ee3\u57fa\u5177\u6709\u8010\u53d7\u6027\uff0c\u56e0\u6b64\u5b83\u4e3a\u5236\u5907\u5404\u79cd\u5404\u6837\u76843-\u82b3\u57fa\u919b\u548c\u916e\u63d0\u4f9b\u4e86\u4e00\u79cd\u975e\u5e38\u65b9\u4fbf\u548c\u6709\u7528\u7684\u65b0\u65b9\u6cd5\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja01022a035\" target=\"_blank\" rel=\"noopener\">The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones<\/a>\uff08JACS,1968,DOI:10.1021\/ja01022a035\uff09<\/p>\n<p><strong>3\u3001JACS\uff1a\u82b3\u9999\u65cf\u5316\u5408\u7269\u4e0e\u6709\u673a\u94af\u76d0\u7684\u70ef\u4e19\u57fa\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134143\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72473-5.png\" alt=\"\" width=\"600\" height=\"177\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72473-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72473-5-300x89.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u82b3\u65cf\u5316\u5408\u7269\u7684\u82b3\u57fa\u884d\u751f\u7269\u5f88\u5bb9\u6613\u901a\u8fc7\u82b3\u65cfGrignard\u8bd5\u5242\u6216\u9502\u5316\u5408\u7269\u4e0e\u70ef\u4e19\u57fa\u5364\u5316\u7269\u7684\u53cd\u5e94\u83b7\u5f97\u3002\u7136\u800c\uff0c\u8be5\u53cd\u5e94\u662f\u6709\u9650\u7684\uff0c\u56e0\u4e3a\u4e0eGrignard\u8bd5\u5242\u6216\u9502\u5316\u5408\u7269\u53cd\u5e94\u7684\u53d6\u4ee3\u57fa\u4e0d\u5b58\u5728\u3002Richard F. Heck\u53d1\u73b0\u4e86\u4e00\u79cd\u4e0d\u5177\u6709\u6b64\u9650\u5236\u7684\u82b3\u65cf\u5316\u5408\u7269\u70ef\u4e19\u57fa\u5316\u65b9\u6cd5\u3002\u7531\u82b3\u57fa\u6c5e\u76d0\u548c\u94af\uff08\u2161\uff09\u5316\u5408\u7269\u539f\u4f4d\u5236\u5907\u7684\u82b3\u57fa\u94af\u76d0\u5728\u5ba4\u6e29\u4e0b\u4e0e\u70ef\u4e19\u57fa\u5364\u5316\u7269\u53cd\u5e94\u4ee5\u4ea7\u751f\u70ef\u4e19\u57fa\u82b3\u9999\u65cf\u884d\u751f\u7269\u3002\u7528\u5404\u79cd\u5404\u6837\u7684\u82b3\u65cf\u5316\u5408\u7269\u90fd\u83b7\u5f97\u9002\u4e2d\u7684\u6548\u679c\uff0c\u751a\u81f3\u785d\u57fa\uff0c\u916f\u548c\u919b\u57fa\u4e5f\u53ef\u4ee5\u5b58\u5728\u4e8e\u82b3\u57fa\u6c5e\u5316\u5408\u7269\u4e2d\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja01022a036\" target=\"_blank\" rel=\"noopener\">Allylation of aromatic compounds with organopalladium salts<\/a>\uff08JACS,1968,DOI:10.1021\/ja01022a036\uff09<\/p>\n<p><strong>4\u3001JACS\uff1a\u94af\u50ac\u5316\u7684\u70ef\u9187\u916f\uff0c\u919a\u548c\u5364\u5316\u7269\u7684\u82b3\u57fa\u5316\u20142-\u82b3\u57fa\u919b\u548c\u916e\u7684\u65b0\u5408\u6210<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134144\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72474-3.png\" alt=\"\" width=\"576\" height=\"441\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72474-3.png 576w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72474-3-300x230.png 300w\" sizes=\"(max-width: 576px) 100vw, 576px\" \/>\u5728Richard F. Heck\u53d1\u8868\u6587\u7ae0\u4e4b\u524d\uff0c\u5df2\u6709\u7814\u7a76\u8bc1\u660e\u4e0d\u9971\u548c\u5316\u5408\u7269\u4e0e\u2167\u65cf\u91d1\u5c5e\u82b3\u57fa\u7684\u82b3\u57fa\u5316\u53cd\u5e94\u662f\u975e\u5e38\u666e\u904d\u7684\u53cd\u5e94\u3002\u51e0\u79cd\u65b0\u7684\u6709\u7528\u7684\u5408\u6210\u6709\u673a\u53cd\u5e94\u90fd\u662f\u57fa\u4e8e\u8fd9\u79cd\u82b3\u57fa\u5316\uff1a\u70ef\u70c3\u82b3\u57fa\u5316\uff0c\u82b3\u65cf\u5364\u4ee3\u4e59\u57fa\u5316\uff0c\u82b3\u65cf\u70ef\u4e19\u57fa\u5316\uff0c\u548c\u901a\u8fc7\u70ef\u4e19\u57fa\u9187\u7684\u82b3\u57fa\u5316\u5408\u62103-\u82b3\u57fa\u919b\u6216\u916e\u5408\u6210\u3002Richard F. Heck\u53d1\u73b0\u4e86\u53e6\u4e00\u79cd\u6709\u7528\u7684\u82b3\u57fa\u5316\u53cd\u5e94 &#8211; \u70ef\u9187\u916f\uff0c\u919a\u548c\u5364\u5316\u7269\u7684\u82b3\u57fa\u5316\u3002\u7531\u82b3\u57fa\u6c5e\u76d0\u548c\u94af\u76d0\u539f\u4f4d\u4ea7\u751f\u7684\u82b3\u57fa\u94af\u76d0\u4e0e\u919b\u70ef\u9187\u916f\u53cd\u5e94\u5f62\u6210\u82b3\u57fa\u4e59\u919b\u884d\u751f\u7269\uff0c\u82b3\u57fa\u4e59\u70ef\u70ef\u9187\u916f\u884d\u751f\u7269\uff0c\u82b3\u57fa\u4e59\u70ef\u548c\u82aa\u3002\u916e\u70ef\u9187\u916f\u548c\u82b3\u57fa\u94af\u76d0\u5f62\u6210\u03b1-\u82b3\u57fa\u916e\u4f5c\u4e3a\u4e3b\u8981\u4ea7\u7269\u3002\u867d\u7136\u6536\u7387\u901a\u5e38\u5f88\u4f4e\uff0c\u4f46\u662f\uff0c\u53cd\u5e94\u63d0\u4f9b\u4e86\u975e\u5e38\u7b80\u5355\u548c\u65b9\u4fbf\u7684\u83b7\u5f97\u5927\u91cf\u53d6\u4ee3\u76842-\u82b3\u57fa\u919b\u548c\u916e\u7684\u65b9\u6cd5\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja01022a037\" target=\"_blank\" rel=\"noopener\">The palladium-catalyzed arylation of enol esters, ethers, and halides. A new synthesis of 2-aryl aldehydes and ketones<\/a>\uff08JACS,1968,DOI:10.1021\/ja01022a037\uff09<\/p>\n<p><strong>5\u3001JACS\uff1a\u7528\u94af\u548c\u94dc\u5364\u5316\u7269\u8fdb\u884c\u82b3\u9999\u65cf\u5364\u4ee3\u4e59\u57fa\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134145\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72475-3.png\" alt=\"\" width=\"582\" height=\"166\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72475-3.png 582w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72475-3-300x86.png 300w\" sizes=\"(max-width: 582px) 100vw, 582px\" \/><\/p>\n<p>\u2167\u65cf\u91d1\u5c5e\u7684\u70f7\u57fa\u884d\u751f\u7269\u4e0e\u70ef\u70c3\u53cd\u5e94\u751f\u6210\u82b3\u57fa\u5316\u7684\u70ef\u70c3\uff0c\u9178\u548c\u91d1\u5c5e\u76d0\u6216\u91d1\u5c5e\u672c\u8eab\u3002\u4f8b\u5982\uff0c\u7531\u6c2f\u5316\u82ef\u6c5e\u548c\u6c2f\u5316\u9502\u6c2f\u5316\u94af\u5236\u5907\u7684\u201c\u82ef\u57fa\u6c2f\u5316\u94af\u201d\u4e0e\u4e59\u70ef\u53cd\u5e94\u5f62\u6210\u82ef\u4e59\u70ef\uff0c\u6c2f\u5316\u6c22\u548c\u94af\u91d1\u5c5e\u3002\u5982\u679c\u53cd\u5e94\u6df7\u5408\u7269\u4e2d\u5305\u542b\u67d0\u4e9b\u6c27\u5316\u5242\u4ee5\u91cd\u65b0\u6c27\u5316\u5143\u7d20\u94af\uff0c\u5219\u8be5\u53cd\u5e94\u53ef\u4ee5\u5bf9\u94af\u50ac\u5316\u3002Richard F. Heck\u63d0\u51fa\u7531\u2167\u65cf\u91d1\u5c5e\u76d0\u548c\u6c5e\uff0c\u9521\u6216\u94c5\u82b3\u57fa\u5316\u5408\u7269\u5236\u5907\u7684\u2167\u65cf\u91d1\u5c5e\u5316\u5408\u7269\u7684\u82b3\u57fa\u884d\u751f\u7269\u5728\u5364\u5316\u94dc\u5b58\u5728\u4e0b\u4e0e\u70ef\u70c3\u53cd\u5e94\u5f62\u62102-\u82b3\u57fa\u4e59\u57fa\u5364\u5316\u7269\u3002\u6c2f\u5316\u7269\u4ee5\u6bd4\u6eb4\u5316\u7269\u66f4\u9ad8\u7684\u6536\u7387\u5f62\u6210\u3002\u901a\u5e38\u6709\u7528\u4e14\u5bb9\u6613\u83b7\u5f97\u7684\u53cd\u5e94\u7269\u662f\u5364\u5316\u82b3\u57fa\u6c5e\uff0c\u5176\u4e2d\u6c2f\u5316\u9502\u94af\u4f5c\u4e3a\u516b\u65cf\u91d1\u5c5e\u5316\u5408\u7269\u3002\u7531\u4e8e\u53ea\u9700\u8981\u50ac\u5316\u94af\u76d0\uff0c\u8be5\u53cd\u5e94\u63d0\u4f9b\u4e86\u5c062-\u5364\u4ee3\u4e59\u57fa\u57fa\u56e2\u5f15\u5165\u82b3\u65cf\u4f53\u7cfb\u7684\u65b9\u4fbf\u65b9\u6cd5\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja01022a038\" target=\"_blank\" rel=\"noopener\">Aromatic haloethylation with palladium and copper halides<\/a>\uff08JACS,1968,DOI:10.1021\/ja01022a038\uff09<\/p>\n<p><strong>6\u3001JACS\uff1a\u70f7\u57fa\u548c\u82b3\u57fa\u6c2f\u5316\u94af\u52a0\u5230\u5171\u8f6d\u4e8c\u70ef\u4e0a<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134146\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72476-2.png\" alt=\"\" width=\"570\" height=\"423\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72476-2.png 570w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72476-2-300x223.png 300w\" sizes=\"(max-width: 570px) 100vw, 570px\" \/><\/p>\n<p>\u5404\u79cd\u8fc7\u6e21\u91d1\u5c5e\u7fb0\u57fa\u884d\u751f\u7269\u4e0e\u5171\u8f6d\u4e8c\u70ef\u7684\u52a0\u6210\u53cd\u5e94\u662f\u4f17\u6240\u5468\u77e5\u7684\u3002\u94b4\u70c3\u57fa\uff0c\u9530\u70c3\u57fa\u548c\u4e9a\u785d\u9170\u57fa\u7fb0\u57fa\u6c22\u5316\u7269\u52a0\u5165\u5230\u4e01\u4e8c\u70ef\u4e2d\u4ee5\u5f62\u62101-\u7532\u57fa-7-\u70ef\u4e19\u57fa\u95f4\u785d\u57fa\u7edc\u5408\u7269\uff0c\u6240\u6709\u8fd9\u4e9b\u90fd\u660e\u663e\u901a\u8fc7I-\u52a0\u6210\u53cd\u5e94\u5f62\u6210\u03b1-\u952e\u5408\u76842-\u4e01\u70ef\u57fa\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u7136\u540e\u73af\u5316\u6210\u03c0\u590d\u5408\u7269\u3002\u56db\u7532\u57fa\u6216\u4e59\u9170\u94b4\u56db\u7fb0\u57fa\u4e0e\u4e01\u4e8c\u70ef\u53cd\u5e94\u5f62\u62101-\u4e59\u9170\u7532\u57fa-\u03c0-\u70ef\u4e19\u57fa\u94b4\u4e09\u7fb0\u57fa\u3002Richard F. Heck\u53d1\u73b0\u7531\u82b3\u57fa\u6216\u70f7\u57fa\u6c5e\u6216\u9521\u5316\u5408\u7269\u548c\u6c2f\u5316\u9502\u6c2f\u5316\u7269\u539f\u4f4d\u5236\u5907\u7684\u82b3\u57fa\u6c2f\u5316\u70f7\u57fa\u548c\u67d0\u4e9b\u70f7\u57fa\u6c2f\u5316\u94af\u5bb9\u6613\u4e0e\u5171\u8f6d\u4e8c\u70ef\u53cd\u5e94\u5f62\u6210I-\u82b3\u57fa\u7532\u57fa\u62161-\u70f7\u57fa-\u70ef\u4e19\u57fa\u6c2f\u5316\u94af\u4e8c\u805a\u4f53\uff0c\u4ea7\u7387\u4f4e\u81f3\u4e2d\u7b49\u3002\u5f53\u65f6\u8fd8\u62a5\u9053\u4e86\u7528\u50ac\u5316\u7684\u4e59\u9178\u94af\u4ece\u5171\u8f6d\u4e8c\u70ef\uff0c\u82b3\u57fa\u6c5e\u76d0\u548c\u56db\u4e59\u9178\u94c5\u50ac\u5316\u5408\u6210\u82b3\u57fa\u4e01\u70ef\u57fa\u4e59\u9178\u916f\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja01022a039\" target=\"_blank\" rel=\"noopener\">The addition of alkyl- and arylpalladium chlorides to conjugated dienes<\/a>\uff08JACS,1968,DOI:10.1021\/ja01022a039\uff09<\/p>\n<p><strong>7\u3001JACS\uff1a\u7531\u82b3\u57fa\u6c5e\u76d0\u5408\u6210\u4e8c\u82b3\u57fa\u916e<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134147\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72477-2.png\" alt=\"\" width=\"576\" height=\"298\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72477-2.png 576w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/04\/\u56fe\u72477-2-300x155.png 300w\" sizes=\"(max-width: 576px) 100vw, 576px\" \/><\/p>\n<p>\u6c2f\u7532\u57fa\uff08\u4e09\u4e59\u57fa\u81a6\uff09\u7532\u57fa\u94af\u5bb9\u6613\u4e0e\u4e00\u6c27\u5316\u78b3\u53cd\u5e94\u5f62\u6210\u76f8\u5e94\u7684\u9170\u57fa\u94af\u5316\u5408\u7269\u3002\u4e00\u6c27\u5316\u78b3\u4e5f\u51fa\u73b0\u5728\u8bb8\u591a\u94af\u50ac\u5316\u7684\u7fb0\u57fa\u5316\u53cd\u5e94\u4e2d\u3002\u4f8b\u5982\uff0c\u5728\u7531\u70ef\u70c3\u6216\u4e8c\u70ef\u5f62\u6210\u916f\u65f6\uff0c\u5728\u7531\u70ef\u70c3\u5f62\u6210\u7c98\u5eb7\u9178\u916f\u65f6\u7531\u70ef\u70c3\u5f62\u62103-\u6c2f\u9170\u6c2f\uff0c\u70ef\u4e19\u57fa\u5364\u5316\u7269\u6216\u03b1-\u70ef\u4e19\u57fa\u5364\u5316\u94af\u7684\u7fb0\u57fa\u5316\u53cd\u5e94\u3002Richard F. Heck\u53d1\u73b0\u5728\u67d0\u4e9b\u6761\u4ef6\u4e0b\u4e8c\u82b3\u57fa\u916e\u4e5f\u53ef\u4ee5\u7531\u82b3\u57fa\u6c5e\u76d0\u548c\u4e00\u6c27\u5316\u78b3\u4e0e\u94af\u76d0\u50ac\u5316\u5242\u4ee5\u4e2d\u7b49\u4ea7\u7387\u5f62\u6210\u3002\u4e09\u6c2f\u5316\u94d1\u53ca\u5176\u4e09\u70f7\u57fa\u81a6\u884d\u751f\u7269\u8bc1\u660e\u662f\u6bd4\u94af\u76d0\u66f4\u597d\u7684\u50ac\u5316\u5242; \u4ed6\u4eec\u4ee5\u66f4\u597d\u7684\u6536\u7387\u751f\u4ea7\u4e8c\u82b3\u57fa\u916e\uff0c\u901a\u5e38\u6ca1\u6709\u53ef\u89c2\u91cf\u7684\u7fa7\u9178\u884d\u751f\u7269\u7684\u540c\u65f6\u5f62\u6210\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja01022a040\" target=\"_blank\" rel=\"noopener\">A synthesis of diaryl ketones from arylmercuric salts<\/a>\uff08JACS,1968,DOI:10.1021\/ja01022a040\uff09<\/p>\n<p>\u867d\u7136Richard F. Heck\u5728\u5b66\u672f\u4e0a\u7684\u6210\u5c31\u5df2\u7136\u662f\u5927\u5e08\u7ea7\u522b\uff0c\u4f46\u7ed3\u5c40\u5374\u4ee4\u4eba\u60cb\u60dc\u3002\u5728\u9000\u4f11\u540e\u6ca1\u6709\u989d\u5916\u6536\u5165\u6765\u6e90\uff0c\u4e3b\u8981\u4f9d\u9760\u6bcf\u67082500\u7f8e\u5143\u517b\u8001\u91d1\u30022012\u5e74\uff0c\u59bb\u5b50\u53bb\u4e16\uff0cRichard F. Heck\u7cbe\u795e\u906d\u53d7\u5de8\u5927\u6253\u51fb\uff0c\u52a0\u4e0a\u60a3\u4e0a\u591a\u79cd\u91cd\u75c5\uff0c\u5065\u5eb7\u72b6\u51b5\u6076\u5316\uff0c\u7531\u4f84\u5b50\u548c\u4e24\u4e2a\u4fdd\u59c6\u7167\u987e\u3002\u7531\u4e8e\u7ecf\u5e38\u51fa\u5165\u533b\u9662\uff0c\u82b1\u8d39\u4e0d\u83f2\u30022015\u5e7410\u67086\u65e5\uff0cRichard F. Heck\u5728\u65e9\u9910\u65f6\u7a81\u7136\u5455\u5410\uff0c\u88ab\u9001\u5f80\u594e\u677e\u5e02\u4e00\u5bb6\u9876\u5c16\u7684\u79c1\u7acb\u533b\u9662\uff0c\u56e0\u6536\u8d39\u9ad8\u5728\u6025\u8bca\u5ba4\u4f4f\u4e86\u51e0\u5929\u540e\uff0c\u533b\u9662\u8ba4\u4e3a\uff0c\u4fdd\u9669\u516c\u53f8\u672a\u7ed9\u8d6b\u514b\u4ed8\u8d26\uff0c\u62d2\u7edd\u7ee7\u7eed\u6cbb\u7597\u3002\u56e0\u6b64\uff0c\u4f84\u5b50\u7eb3\u5c14\u591a\u53ea\u80fd\u5c06\u8d6b\u514b\u8f6c\u5f80\u4e00\u5bb6\u516c\u7acb\u533b\u9662\uff0c\u4f46\u83f2\u5f8b\u5bbe\u516c\u7acb\u533b\u9662\u666e\u904d\u6548\u7387\u4f4e\u4e0b\uff0c\u57fa\u672c\u65e0\u6cd5\u533b\u6cbb\u91cd\u75c5\uff0c\u8d6b\u514b\u5c31\u6b64\u6b7b\u5728\u75c5\u5e8a\u4e0a\u4eab\u5e7484\u5c81\u3002<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4ebaAllen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><b>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<br \/>\n <\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Richard F. 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