{"id":134096,"date":"2018-04-16T06:30:40","date_gmt":"2018-04-15T22:30:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=134096"},"modified":"2018-04-13T18:20:46","modified_gmt":"2018-04-13T10:20:46","slug":"nature%e5%ad%90%e5%88%8a%ef%bc%9a%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e5%85%89%e5%82%ac%e5%8c%96%e8%bf%98%e5%8e%9f%e7%9a%84%e6%b4%bb%e6%80%a7%e5%92%8c%e9%80%89%e6%8b%a9%e6%80%a7%e4%be%9d%e8%b5%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=134096","title":{"rendered":"Nature\u5b50\u520a\uff1a\u4e8c\u6c27\u5316\u78b3\u5149\u50ac\u5316\u8fd8\u539f\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u4f9d\u8d56\u4e8e\u94c2\u7eb3\u7c73\u7c92\u5b50\u7684\u5c3a\u5bf8"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4e8c\u6c27\u5316\u78b3\u662f\u6700\u5e38\u89c1\u7684\u6e29\u5ba4\u6c14\u4f53\u4e4b\u4e00\uff0c\u5b83\u7684\u8fc7\u91cf\u6392\u653e\u5bfc\u81f4\u4e86\u5168\u7403\u53d8\u6696\uff0c\u8fdb\u800c\u5f15\u53d1\u4e86\u4e25\u91cd\u7684\u73af\u5883\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u663e\u7136\u8feb\u5207\u9700\u8981\u627e\u5230\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u7684\u53ef\u80fd\u529e\u6cd5\u3002\u5728\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u6280\u672f\u7684\u57fa\u7840\u4e0a\uff0cCO2<\/sub>\u548cH2<\/sub>O\u53ef\u4ee5\u5728\u592a\u9633\u5149\u7167\u5c04\u4e0b\u8f6c\u5316\u4e3aCH4<\/sub>\u7b49\u6709\u7528\u7684\u5316\u5b66\u7269\u8d28\uff0c\u662f\u89e3\u51b3\u4e0a\u8ff0CO2<\/sub>\u6392\u653e\u95ee\u9898\u7684\u7406\u60f3\u9014\u5f84\u3002\u7136\u800c\uff0c\u7531\u4e8eCO2<\/sub>\u662f\u7a33\u5b9a\u7684\u5206\u5b50\uff0c\u5176\u5149\u50ac\u5316\u8fd8\u539f( CO2PR )\u4e0eH2<\/sub>O\u4ea7\u751fCH4<\/sub>\u662f\u5438\u70ed\u53cd\u5e94\uff0c\u5e76\u4e14\u9700\u8981\u591a\u4e2a\u7535\u5b50\u548c\u8d28\u5b50\u7684\u53c2\u4e0e\u3002\u56e0\u6b64\uff0c\u672a\u7ecf\u4fee\u9970\uff0c\u88f8\u534a\u5bfc\u4f53\u901a\u5e38\u8868\u73b0\u51fa\u8f83\u5dee\u7684CO2PR\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u6790\u6c22\u53cd\u5e94( HER )\u5e38\u5e38\u4e0eCO2 PR\u7ade\u4e89\u5149\u751f\u7535\u5b50\uff0c\u5bfc\u81f4CO2PR\u9009\u62e9\u6027\u964d\u4f4e\u3002\u6839\u636e\u4ee5\u5f80\u7684\u7814\u7a76\uff0c\u8d1f\u8f7d\u9002\u5f53\u7684\u52a9\u50ac\u5316\u5242\u540e\uff0c\u590d\u5408\u5149\u50ac\u5316\u5242\u5728CO2PR\u4e2d\u7684\u6027\u80fd\u5f97\u5230\u663e\u8457\u63d0\u9ad8\u3002\u94c2\u7eb3\u7c73\u7c92\u5b50( Pt NPs )\u4f5c\u4e3a\u5e38\u7528\u7684\u52a9\u50ac\u5316\u5242\u4e4b\u4e00\uff0c\u4e00\u76f4\u88ab\u8ba4\u4e3a\u662f\u5149\u50ac\u5316\u4e2d\u7684\u7535\u5b50\u6355\u83b7\u5242\u548c\u6d3b\u6027\u4e2d\u5fc3\u3002\u5c3d\u7ba1\u4eba\u4eec\u5bf9Pt\u5728\u5149\u50ac\u5316\u4e2d\u7684\u4f5c\u7528\u548c\u6027\u8d28\u8fdb\u884c\u4e86\u5927\u91cf\u7684\u7814\u7a76\uff0c\u4f46\u5bf9\u4e8ePt NPs\u5728CO2PR\u4e2d\u7684\u7c92\u5f84\u8303\u56f4\u5bbd\u3001\u7c92\u5f84\u5206\u5e03\u7cbe\u786e\u7684\u7c92\u5f84\u6548\u5e94\uff0c\u5c24\u5176\u662f\u5bf9Pt NPs\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\u7684\u6df1\u5165\u4e86\u89e3\uff0c\u8fd8\u7f3a\u4e4f\u5ba2\u89c2\u3001\u7cfb\u7edf\u7684\u7814\u7a76\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u7684\u5f20\u91d1\u9f99\u6559\u6388\u4e0e\u90a2\u660e\u9633\u526f\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f<\/strong>\u5728Nature Communications\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cSize-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles\u201d\u3002\u901a\u8fc7\u5bf9\u4e0d\u540c\u7c92\u5f84Pt NPs\u7684\u51e0\u4f55\u7279\u5f81\u548c\u7535\u5b50\u6027\u8d28\u7684\u5206\u6790\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0Pt NPs\u5728\u4e8c\u6c27\u5316\u78b3\u5149\u50ac\u5316\u8fd8\u539f\u6d3b\u6027\u548c\u9009\u62e9\u6027\u65b9\u9762\u5177\u6709\u663e\u8457\u7684\u5c3a\u5bf8\u6548\u5e94\u3002\u51cf\u5c0fPt NPs\u7684\u5c3a\u5bf8\u63d0\u9ad8\u4e86\u7535\u8377\u8f6c\u79fb\u6548\u7387\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u4e8c\u6c27\u5316\u78b3\u5149\u50ac\u5316\u8fd8\u539f\u548c\u6790\u6c22\u53cd\u5e94( HER )\u6d3b\u6027\uff0c\u4f46\u5bfc\u81f4\u5bf9\u6c22\u6c14\u7684\u9009\u62e9\u6027\u9ad8\u4e8e\u7532\u70f7\u3002\u7ed3\u5408\u5b9e\u9a8c\u7ed3\u679c\u548c\u7406\u8bba\u8ba1\u7b97\uff0c\u63ed\u793a\u4e86Pt NPs\u662f\u7532\u70f7\u751f\u6210\u7684\u6d3b\u6027\u4f4d\u70b9\uff1b\u4e0e\u6b64\u540c\u65f6\uff0c\u4f4e\u914d\u4f4d\u6570\u7684\u53cd\u5e94\u4f4d\u70b9\u66f4\u6709\u5229\u4e8e\u4e0eHER\u7684\u7ade\u4e89\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. Pt\u7eb3\u7c73\u9897\u7c92\u7684\u5236\u5907\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff1a\u9178\u78b1\u4ecb\u5bfc\u7684\u4e59\u9187\u8fd8\u539f\u6cd5\u63a7\u5236\u94c2\u7eb3\u7c73\u7c92\u5b50\u5c3a\u5bf8\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

TEM\u4e0e\u76f8\u5e94\u7684HR-TEM\u56fe: b, f, j: 1.8PHTSO; c, g, k: 3.4PHTSO; d, h, l: 4.3PHTSO; \u00a0e, i, m: 7.0PHTSO; \u7ea2\u8272\u65b9\u5757\u8868\u793a\u5c40\u90e8\u4f4d\u7f6e\u7684\u9010\u6b65\u653e\u5927;<\/p>\n

n: 1.8 nm Pt\/C3<\/sub>N4<\/sub>\u7684HR-TEM\u56fe;<\/p>\n

o: 3.4 nm Pt\/C3<\/sub>N4<\/sub>\u7684HR-TEM\u56fe;<\/p>\n

p: 4.3 nm Pt\/C3<\/sub>N4<\/sub>\u7684HR-TEM\u56fe;<\/p>\n

q: 7.0 nm Pt\/C3N4\u7684HR-TEM\u56fe;<\/p>\n

b\u2013e\u56fe\u7684\u6bd4\u4f8b\u5c3a\u4e3a50nm; f\u56fe\u7684\u6bd4\u4f8b\u5c3a\u4e3a10nm; g\u2013i\u4ee5\u53can\u2013q\u56fe\u7684\u6bd4\u4f8b\u5c3a\u4e3a20nm; j\u2013m\u56fe\u7684\u6bd4\u4f8b\u5c3a\u4e3a2nm\uff1b<\/p>\n

\u56fe2. xPHTSO\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u8868\u9762\u5f62\u8c8c\u548c\u5149\u5b66\u7279\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a: XRD\u56fe\u4ee5\u53ca35\u201345\u00b0\u8303\u56f4\u7684\u5c40\u90e8\u653e\u5927\u56fe;<\/p>\n

b: UV\u2013Vis DRS\u56fe\u548c\u76f8\u5e94\u7684\u7167\u7247\uff08\u63d2\u56fe\uff09;<\/p>\n

c: 7.0PHTSOde HR-TEM\u56fe, \u6bd4\u4f8b\u5c3a\u4e3a2 nm;<\/p>\n

d: \u57fa\u4e8e\u4e0d\u540c\u5c3a\u5bf8\u7684Pt NPs\u6807\u51c6\u622a\u65ad\u516b\u9762\u4f53\u6a21\u578b\u7684\u89d2, \u5e26\u8fb9, Pt (111)\u548cPt (100)\u8868\u9762\u4f4d\u70b9\u7684\u6bd4\u4f8b;<\/p>\n

\u56fe3. xPHTSO\u7684\u7535\u5b50\u7279\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\u9ad8\u5206\u8fa8Pt 4f XPS\u56fe: a: 1.8PHTSO; b: 3.4PHTSO; c: 4.3PHTSO; d: 7.0PHTSO;<\/p>\n

e:\u6837\u54c11.8PHTSO\u548c4.3PHTSO\u5728310nm\u6fc0\u53d1\u540e\uff0cfs-TA\u56fe350nm\u77ac\u6001\u5438\u6536\u5e26\u52a8\u529b\u5b66\u8868\u5f81;<\/p>\n

f: xPHTSO (x = 1.8, 3.4, 4.3, 7.0)\u77ac\u6001\u5149\u7535\u6d41\uff1b<\/p>\n

\u56fe4. \u4e8c\u6c27\u5316\u78b3\u4e2d\u78b3\u6742\u8d28\u5f71\u54cd\u7684\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

a: xPHTSO ( x = 1.8\u30013.4\u30014.3\u30017.0 )\u5728\u4e0d\u540c\u6c14\u6c1b\u4e2d\u7684CH4<\/sub>\u4ea7\u7387\u6bd4\u8f83\uff0c\u5176\u4e2d\u84dd\u8272\u6761\u8868\u793a\u7531CO2<\/sub>\/ H2<\/sub>O\u6c14\u6c1b\u4ea7\u751f\u7684CH4<\/sub>\u4ea7\u7387\uff0c\u7070\u8272\u6761\u8868\u793a\u7531Ar\/H2<\/sub>O\u6c14\u6c1b\u4ea7\u751f\u7684CH4<\/sub>\u4ea7\u7387;<\/p>\n

b:\u80f6\u4f53\uff08\u63d2\u56fe\uff09\u7684TEM\u56fe\uff0c\u6bd4\u4f8b\u5c3a\u4e3a20\u548c10nm\uff08\u63d2\u56fe\uff09\uff1b<\/p>\n

c: 1.7Pt@PVP\/HTSO\u548c1.8PHTSO CO2<\/sub>\u5149\u8fd8\u539f\u53cd\u5e94\u7684\u6bd4\u8f83\uff1b<\/p>\n

\u56fe5. CO2PR\u7684\u9009\u62e9\u6027\u548c\u6d3b\u6027\u5bf9Pt NPs\u5c3a\u5bf8\u4f9d\u8d56\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a: xPHTSO\u4e2d\u7532\u70f7\u9009\u62e9\u6027\u4e0e\u8868\u9762\u4f4d\u7f6e\u6bd4\u4f8b\u7684\u5173\u7cfb( x = 1.8\uff0c3.4\uff0c4.3\uff0c7.0 )\uff1b<\/p>\n

b : Pt ( 111 )\u8868\u9762\u548cPt55\u8868\u9762\u70ed\u5316\u5b66\u6a21\u578bCO2<\/sub>\u8fd8\u539f\u4e3aCH4<\/sub>\u7684\u81ea\u7531\u80fd\u56fe\uff1b<\/p>\n

c : CO\u5206\u6b65\u5438\u9644-\u89e3\u5438\u6539\u60271.8 PHTSO\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

d : CO\u8109\u51b2\u5438\u9644\u3001\u5206\u6b65CO\u8109\u51b2\u5438\u9644\u548cHe\u6d41\u89e3\u5438\u540e\u76841.8 PHTSO\u7684CO – TPD\u7ed3\u679c\uff1b<\/p>\n

e: 1.8PHTSO\u548cCO-1.8PHTSO\u7684CO2PR\u7684\u6027\u80fd\u6bd4\u8f83, RE\u4f5c\u4e3a\u53cd\u5e94\u7535\u5b50, CH4<\/sub> S\u4f5c\u4e3aCH4\u9009\u62e9\u6027\uff1b<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5728HTSO\u4e0a\u6210\u529f\u5730\u5b9e\u73b0\u4e86\u7c92\u5f84\u4e3a1.8\uff5e7.0 nm\u7684\u65e0\u914d\u4f53Pt NPs\u3002Pt NPs\u7684\u5c3a\u5bf8\u63a7\u5236\u662f\u901a\u8fc7\u52a0\u5165\u9178\u6027\u6216\u78b1\u6027\u6dfb\u52a0\u5242\u8c03\u8282\u6210\u6838\u91cf\u6765\u5b9e\u73b0\u7684\uff0cABAR\u5408\u6210\u5de5\u827a\u6613\u4e8e\u63a8\u5e7f\u5230\u5176\u4ed6\u6750\u6599\u3002\u5728CO2PR\u4e2d\uff0cPt NPs\u5bf9\u6d3b\u6027\u548c\u9009\u62e9\u6027\u90fd\u6709\u663e\u8457\u7684\u5c3a\u5bf8\u6548\u5e94\u3002\u66f4\u5c0f\u7684Pt NPs\u548c\u66f4\u5927\u7684\u91d1\u5c5e-\u534a\u5bfc\u4f53\u754c\u9762\u9762\u79ef\u4fc3\u8fdb\u7535\u8377\u8f6c\u79fb\u6548\u7387\uff0c\u56e0\u6b64\u5728CH4<\/sub>\u548cH2<\/sub>\u751f\u6210\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6d3b\u6027\u3002\u8f83\u5927\u7684Pt NPs\u53ef\u4ee5\u83b7\u5f97\u8f83\u9ad8\u7684CH4<\/sub>\u9009\u62e9\u6027\uff0c\u8fd9\u662f\u56e0\u4e3a\u201c\u9762\u201d\u4f4d\u70b9\u7684\u6bd4\u4f8b\u8f83\u9ad8\u3002\u7ed3\u679c\u8868\u660e\uff0cPt NP\u7684\u201c\u9762\u201d\u4f4d\u70b9\u662fCH4<\/sub>\u751f\u6210\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u4f4e\u914d\u4f4d\u4f4d\u70b9\uff08\u201c\u89d2\u201d\u548c\u201c\u8fb9\u201d\uff09\u5728HER\u4e2d\u66f4\u4e3a\u6709\u5229\uff0c\u53ef\u4ee5\u9010\u6e10\u88abCO\u5931\u6d3b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aSize-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles<\/a>, (Nature Communications, 2018, DOI: 10.1038\/s41467-018-03666-2)<\/p>\n

\u5f20\u91d1\u9f99\u6559\u6388\u4e0e\u90a2\u660e\u9633\u526f\u6559\u6388\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n

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\u8bfe\u9898\u7ec4\u7167\u7247\uff1a<\/strong><\/p>\n

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\u8bfe\u9898\u7ec4\u7b80\u4ecb\uff1a<\/strong><\/p>\n

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\u90a2\u660e\u9633\uff0c\u7537\uff0c\u535a\u58eb\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u526f\u6559\u6388\uff0c\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u201c\u9752\u5e74\u79d1\u5b66\u5bb6\u201d\u9879\u76ee\u83b7\u5f97\u8005\uff08\u539f\u9752\u5e74\u201c973\u201d\uff09\uff1b\u4e0a\u6d77\u5e02\u201c\u6d66\u6c5f\u5b66\u8005\u201d\u3001\u201c\u6668\u5149\u5b66\u8005\u201d\uff1b\u4e2d\u56fd\u611f\u5149\u5b66\u4f1a\u5149\u50ac\u5316\u4e13\u4e1a\u59d4\u5458\u4f1a\u9752\u5e74\u59d4\u5458\uff1b\u83b72017\u5e74\u5ea6\u4e0a\u6d77\u5e02\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956\u3002\u4e3b\u8981\u7814\u7a76\u9886\u57df\uff1a\uff081\uff09\u5149\u50ac\u5316\u534f\u540cFenton\u53cd\u5e94\u7b49\u9ad8\u7ea7\u6c27\u5316\u6280\u672f\uff08AOPs\uff09\u5904\u7406\u96be\u964d\u89e3\u6709\u673a\u6c61\u67d3\u7269\u5e9f\u6c34\u7684\u7814\u7a76\uff1b\uff082\uff09\u5149\u50ac\u5316\u8fd8\u539fCO2<\/sub>\uff1b\uff083\uff09\u5149\u89e3\u6c34\u4ea7\u6c22\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5171\u53d1\u8868SCI\u8bba\u658768\u7bc7\uff0c\u88ab\u5f15\u75283348\u6b21\uff0c\u201ch-index\u201d\u4e3a31\u3002\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5728CHEM<\/em><\/strong>\u3001Nature Commun.<\/em><\/strong>\u3001Chem. Soc. Rev.<\/em><\/strong>\u3001J. Am. Chem. Soc.<\/em><\/strong>\u3001Angew. Chem. Int. Ed.<\/em><\/strong>\u3001Adv. Funct. Mater.<\/em><\/strong>\u3001J. Photoch. Photobiol. C<\/em><\/strong>\u3001Mater. Horiz.<\/em><\/strong>\u3001Small<\/em><\/strong>\u3001Appl. Catal. B<\/em><\/strong>\u7b49\u56fd\u9645\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u658748\u7bc7\uff0c5\u7bc7\u5165\u9009\u201cESI\u9ad8\u88ab\u5f15\u8bba\u6587\u201d\uff0c2\u7bc7\u5165\u9009\u201c0.1%\u70ed\u70b9\u6587\u7ae0\u201d \uff0c2\u7bc7\u5165\u9009\u671f\u520a\u5c01\u9762\u8bba\u6587\uff0c\u6388\u6743\u53d1\u660e\u4e13\u52294\u9879\uff1b\u53c2\u7f16\u82f1\u6587\u4e13\u84572\u90e8\uff08Wily book, Springer book\uff09\u3002<\/p>\n

\u56e2\u961f\u5728\u5149\u50ac\u5316\u9886\u57df\u5de5\u4f5c\u6c47\u603b\uff1a<\/strong><\/p>\n

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\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8<\/strong>\u8350\uff1a<\/strong><\/p>\n

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  8. Chunyang Dong, Mingyang Xing, Jinlong Zhang, Horiz.<\/em>, 2016, 3, 608-612<\/li>\n<\/ol>\n

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