{"id":133992,"date":"2018-04-13T06:30:39","date_gmt":"2018-04-12T22:30:39","guid":{"rendered":"\/\/m.iemloyee.com\/?p=133992"},"modified":"2018-04-12T22:44:26","modified_gmt":"2018-04-12T14:44:26","slug":"nano-energy%ef%bc%9a%e6%b0%af%e5%8f%96%e4%bb%a3%e4%b8%a4%e7%bb%b4%e5%85%b1%e8%bd%ad%e8%81%9a%e5%90%88%e7%89%a9-%e7%94%b2%e8%8b%af%e5%88%b6%e5%a4%87%e8%81%9a%e5%90%88%e7%89%a9%e5%a4%aa","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=133992","title":{"rendered":"Nano Energy\uff1a\u6c2f\u53d6\u4ee3\u4e24\u7ef4\u5171\u8f6d\u805a\u5408\u7269\u2014\u2014\u7532\u82ef\u5236\u5907\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u8fbe\u523013.1%"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60( PSCs )\u4f5c\u4e3a\u4e00\u79cd\u65b0\u5174\u7684\u6e05\u6d01\u80fd\u6e90\u6280\u672f\uff0c\u7531\u4e8e\u5176\u5177\u6709\u534a\u900f\u660e\u6027\u3001\u67d4\u6027\u4ee5\u53ca\u53ef\u5927\u9762\u79ef\u5236\u5907\u7b49\u4f18\u70b9\uff0c\u8fd1\u5e74\u6765\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fd1\u4e09\u5e74\u6765\uff0cn\u578b\u6709\u673a\u534a\u5bfc\u4f53(n<\/em>-OSs)\u4f5c\u4e3a\u975e\u5bcc\u52d2\u70ef(NF)\u53d7\u4f53\u5728\u9ad8\u6027\u80fdPSCs\u4e2d\u5f97\u5230\u4e86\u84ec\u52c3\u53d1\u5c55\uff0c\u8fd9\u662f\u56e0\u4e3a\u4e0e\u4f20\u7edf\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u76f8\u6bd4\uff0cn\u578b\u6709\u673a\u534a\u5bfc\u4f53\u5177\u6709\u524d\u4f53\u6765\u6e90\u5e7f\u6cdb\u3001\u5236\u5907\u6210\u672c\u4f4e\u3001\u5438\u6536\u548c\u80fd\u7ea7\u53ef\u8c03\u3001\u80fd\u91cf\u635f\u5931\u5c0f\u3001\u5f62\u8c8c\u7a33\u5b9a\u6027\u9ad8\u7b49\u4f18\u70b9\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5355\u7ed3NF-PSCs\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387(PCEs)\u5df2\u8fbe\u523011\u201313%\u3002\u5728\u4e0e\u5bbd\u5e26\u9699\u805a\u5408\u7269\u5171\u6df7\u65f6\uff0cIT-4F\u57faPSCs\u663e\u793a\u51fa\u9ad8\u8fbe13.1 %\u7684PCE\u3002\u7531\u4e8e\u826f\u597d\u5339\u914d\u7684\u805a\u5408\u7269\u7ed9\u4f53\u548cn – OS\u53d7\u4f53\u5728\u83b7\u5f97\u9ad8\u6548PSCs\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u56e0\u6b64\u5e7f\u6cdb\u7684\u5408\u6210\u53d8\u5316(\u5982\u539f\u5b50\u53d6\u4ee3\u3001\u4fa7\u94fe\u4fee\u9970\u548c\u5f15\u5165\u82b3\u65cf\u7a20\u73af)\u88ab\u7528\u4e8e\u4f18\u5316\u9ad8\u6027\u80fd\u805a\u5408\u7269\u7ed9\u4f53\u3002\u5176\u4e2d\u539f\u5b50\u53d6\u4ee3\uff0c\u7279\u522b\u662f\u6c1f(F)\u539f\u5b50\u53d6\u4ee3\u6c22\u539f\u5b50\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5e76\u5728\u5206\u5b50\u8bbe\u8ba1\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\"\"<\/p>\n

(a) PM7\u5408\u6210\u8def\u7ebf\uff1b<\/p>\n

(b) \u5728B3LYP\/6\u201331G*(d, p)\u7ea7DFT\u8ba1\u7b97\u5f97\u5230\u7684HOMO\u548cLUMO\u7535\u5b50\u5206\u5e03\u4ee5\u53ca\u80fd\u7ea7\uff1b<\/p>\n

(c) \u5355\u4f53\u5728\u6d53\u5ea6\u4e3a1\u00d710 \u2013 5<\/sup>M\u7532\u82ef\u6eb6\u6db2\u4e2d\u7684\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

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\"\"<\/p>\n

(a) \u5206\u5b50\u7ed3\u6784<\/p>\n

(b) \u805a\u5408\u7269\u7ed9\u4f53\u548c\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53IT-4F\u7684\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

(c) \u805a\u5408\u7269\u7ed9\u4f53\u548c\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53IT-4F\u7684\u5206\u5b50\u80fd\u7ea7\u56fe\uff1b<\/p>\n

\u56fe3. \u5149\u4f0f\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

\"\"(a) \u57285G\u5149\u6e90(100\u202fmW\u202fcm-2<\/sup>)\u7167\u5c04\u4e0b\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

(b) PM7\uff1aIT-4F\u5171\u6df7\u5236\u5907\u7684PSCs\u7684EQE\u66f2\u7ebf;<\/p>\n

(c) PM7\uff1aIT-4F\u5171\u6df7\u5236\u5907\u7684PSCs\u6d3b\u6027\u5c42\u539a\u5ea6\u4e0ePCE\u7684\u5173\u7cfb\u8d8b\u52bf\u56fe\uff1b<\/p>\n

(d) Jph <\/sub>vs Veff<\/sub>\uff1b<\/p>\n

(e) PM7\uff1aIT-4F\u5171\u6df7\u5236\u5907\u7684PSCs\u4e2dVoc\u968f\u5149\u5f3a\u7684\u53d8\u5316\uff1b<\/p>\n

(f) PM7\uff1aIT-4F\u5171\u6df7\u5236\u5907\u7684PSCs\u4e2dJph\u968f\u5149\u5f3a\u7684\u53d8\u5316\uff1b<\/p>\n

\u56fe4. \u4e8c\u7ef4GIWAXS\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u7eaf\u805a\u5408\u7269\u53ca\u76f8\u5173\u5171\u6df7\u819c\u7684\u4e8c\u7ef4GIWAXS\u5256\u9762\u53ca\u76f8\u5e94\u7684( b ) IP\u548c( c ) OOP\u7ebf\u5207\uff1b<\/p>\n

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\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u5408\u6210\u4e86\u57fa\u4e8e\u4e00\u79cd\u65b0\u7684\u542b\u6c2f\u7684BDT-2Cl\u7ed9\u4f53\u5355\u5143\u7684\u805a\u5408\u7269PM7\uff0c\u5e76\u5c06\u5176\u4f5c\u4e3a\u7ed9\u4f53\u5e94\u7528\u4e8e\u975e\u5bcc\u52d2\u70ef\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u3002\u4e0e\u4f20\u7edf\u7684\u5206\u5b50\u4e3b\u94fe\u4e0a\u5e26\u6709\u6c2f\u53d6\u4ee3\u57fa\u7684\u6c2f\u5316\u805a\u5408\u7269\u4e0d\u540c\uff0cPM7\u5728\u805a\u5408\u7269\u5171\u8f6d\u4fa7\u94fe\u4e0a\u6c2f\u5316\uff0c\u6709\u5229\u4e8e\u51cf\u5f31Cl\u539f\u5b50\u5728\u805a\u5408\u7269\u4e3b\u94fe\u4e0a\u7684\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u3002\u4e0ePBDB-T\u76f8\u6bd4\uff0cPM7\u5177\u6709\u8f83\u4f4e\u7684HOMO\u80fd\u7ea7\u3001\u8f83\u9ad8\u7684\u5438\u6536\u7cfb\u6570\u3001\u8f83\u5f3a\u7684\u7ed3\u6676\u6027\u548c\u8f83\u9ad8\u7684\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u3002\u6b64\u5916\uff0c\u57fa\u4e8ePM7: IT-4F\u7684\u7532\u82ef\u4f5c\u6eb6\u5242\u7684\u5149\u4f0f\u5668\u4ef6\u5f97\u5230\u4e86Voc<\/sub>\u4e3a0.88 V\u3001Jsc<\/sub>\u4e3a20.9 mA\u00b7cm – 2<\/sup>\u548cFF\u4e3a71.1 %\u7684\u60c5\u51b5\u4e0b\uff0cPCE\u9ad8\u8fbe13.1 %\uff0c\u800c\u57fa\u4e8ePBDB – T : IT – 4F\u7684PSC\u4ec5\u83b7\u5f975.3 %\u7684PCE\u300213.1 %\u7684PCE\u662f\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u975e\u5364\u6eb6\u5242\u5236\u5907\u7684\u5149\u4f0f\u5668\u4ef6\u7684\u6700\u9ad8\u503c\u4e4b\u4e00\u3002\u7ed3\u679c\u8868\u660e\uff0c\u6c2f\u4ee3\u662f\u8bbe\u8ba1\u9ad8\u6027\u80fd\u805a\u5408\u7269\u5149\u4f0f\u6750\u6599\u7684\u4e00\u79cd\u7b80\u5355\u3001\u5ec9\u4ef7\u3001\u6709\u6548\u7684\u7b56\u7565\u3002<\/p>\n

\u5bfc\u5e08\u4ecb\u7ecd\uff1a<\/p>\n

\u5f20\u8302\u6770\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u5305\u62ec\uff1a\u805a\u5408\u7269\u5149\u4f0f\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\uff1b\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u6784\u7b51\u4e0e\u5668\u4ef6\u7269\u7406\u30022008\u5e74\u5f00\u59cb\u4ece\u4e8b\u6709\u5173\u6709\u673a\u5149\u4f0f\u6750\u6599\u4e0e\u5668\u4ef6\u76f8\u5173\u7684\u79d1\u5b66\u7814\u7a76\u3002\u8fc4\u4eca\u4e3a\u6b62\u5171\u53d1\u8868SCI\u7814\u7a76\u8bba\u6587100\u4f59\u7bc7\uff0c\u6388\u6743\u4e2d\u56fd\u4e13\u52292\u9879\u3002\u520a\u7269\u5305\u62ecAdv. Mater.<\/em>\u3001<\/em>Energy Environ. Sci.<\/em>\u3001<\/em>Adv. Energy Mater.<\/em>\u3001<\/em>Adv. Funct. Mater.<\/em>\u3001<\/em>Chem. Mater.<\/em>\u3001<\/em>Macromolecules<\/em>\u7b49\u3002\u53d1\u8868\u8bba\u6587SCI\u4ed6\u4eba\u5f15\u75284000\u4f59\u6b21\uff0cH\u56e0\u5b5037\u3002\u5176\u4e2d\uff0c15\u7bc7\u8bba\u6587\u5355\u7bc7\u4ed6\u4eba\u5f15\u7528\u8d85\u8fc7100\u6b21\uff0c12\u7bc7\u8bba\u6587\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff0c\u6709\u4e24\u7bc7\u8bba\u6587\u5165\u9009\u201c<\/strong>\u4e2d\u56fd\u767e\u7bc7\u6700\u5177\u5f71\u54cd\u56fd\u9645\u5b66\u672f\u8bba\u6587\u201d<\/strong>\u3002\u56fd\u5bb6\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u3001\u6c5f\u82cf\u7701\u201c\u53cc\u521b\u4eba\u624d\u201d\u83b7\u5f97\u8005\u3002<\/strong><\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u5316\u5b66<\/strong>SCIENCE CHINA Chemistry<\/strong><\/a>\u4e0e\u4e2d\u56fd\u5316\u5b66<\/strong>Chinese Journal of Chemistry<\/strong><\/a>\u9752\u5e74\u7f16\u59d4\u3002<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Chlorine substituted 2D-conjugated polymer for high-performance polymer solar cells with 13.1% efficiency via toluene processing<\/a>, (Nano Energy, 2018, DOI: https:\/\/doi.org\/10.1016\/j.nanoen.2018.04.002)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

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