{"id":133412,"date":"2018-04-09T14:00:19","date_gmt":"2018-04-09T06:00:19","guid":{"rendered":"\/\/m.iemloyee.com\/?p=133412"},"modified":"2018-04-05T17:07:19","modified_gmt":"2018-04-05T09:07:19","slug":"adv-mater-%ef%bc%9a-%e9%80%9a%e8%bf%873d%e7%9f%b3%e5%a2%a8%e7%83%af%e7%ba%b3%e7%b1%b3%e7%bb%93%e6%9e%84%e5%af%bc%e7%94%b5%e8%81%9a%e5%90%88%e7%89%a9%e6%b0%b4%e5%87%9d%e8%83%b6%e5%ae%9e%e7%8e%b0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=133412","title":{"rendered":"Adv. Mater.\uff1a \u901a\u8fc73D\u77f3\u58a8\u70ef\/\u7eb3\u7c73\u7ed3\u6784\u5bfc\u7535\u805a\u5408\u7269\u6c34\u51dd\u80f6\u5b9e\u73b0\u53ef\u62c9\u4f38\u5168\u51dd\u80f6\u6001\u7ea4\u7ef4\u72b6\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u6765\u4eba\u4eec\u5bf9\u5bfc\u7535\u805a\u5408\u7269\u6c34\u51dd\u80f6\uff08CPHs\uff09\u7684\u5173\u6ce8\u65e5\u76ca\u5bc6\u5207\uff0c\u8fd9\u662f\u56e0\u4e3a\u5176\u7279\u6b8a\u7684\u4e09\u7ef4\u7f51\u7edc\u7eb3\u7c73\u7ed3\u6784\u548c\u826f\u597d\u7684\u5bfc\u7535\u6027\uff0c\u4f7f\u5176\u6210\u4e3a\u6781\u5177\u6f5c\u529b\u7684\u6750\u6599\u8f7d\u4f53\uff0c\u53ef\u7528\u4e8e\u50a8\u80fd\u3001\u50ac\u5316\u3001\u4f20\u611f\u5668\u548c\u836f\u7269\u4f20\u8f93\u7b49\u9886\u57df\u3002\u4f46\u662f\uff0c\u5c06\u5bfc\u7535\u805a\u5408\u7269\u6c34\u51dd\u80f6\u7528\u4e8e\u5177\u6709\u4e00\u5b9a\u673a\u68b0\u5f3a\u5ea6\u7684\u8f7b\u578b\u67d4\u6027\u5668\u4ef6\uff0c\u5982\u5e73\u9762\u578b\u7535\u6781\uff0c\u4ecd\u7136\u5177\u6709\u5f88\u5927\u7684\u6311\u6218\u6027\u3002\u4e3a\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u4e00\u4e2a\u8f83\u597d\u7684\u65b9\u6848\u662f\u52a0\u5165\u6c27\u5316\u77f3\u58a8\u70ef\u6765\u589e\u5f3a\u5bfc\u7535\u805a\u5408\u7269\u6c34\u51dd\u80f6\u7684\u673a\u68b0\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u4f59\u6842\u534e\u6559\u6388\u548c\u56db\u5ddd\u5927\u5b66\u8096\u4e39\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7684\u7814\u7a76\u56e2\u961f\u5728Adv. Mater.<\/strong>\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cStretchable All-Gel-State Fiber-Shaped Supercapacitors Enabled by Macromolecularly Interconnected 3D Graphene\/Nanostructured Conductive Polymer Hydrogels<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u4ed6\u4eec\u62a5\u544a\u4e86\u7531GO\u548cCPHs\u81ea\u7ec4\u88c5\u800c\u6210\u7684\u3001\u5177\u6709\u5927\u5206\u5b50\u76f8\u4e92\u8fde\u63a5\u76843D\u77f3\u58a8\u70ef\/\u7eb3\u7c73\u7ed3\u6784\u5bfc\u7535\u805a\u5408\u7269\u6c34\u51dd\u80f6\u3002\u6240\u5236\u5907\u76843D PANI\/ RGO\u6742\u5316\u6c34\u51dd\u80f6\uff0c\u7531\u4e8e\u805a\u82ef\u80fa\uff08PANI\uff09\u548c\u77f3\u58a8\u70ef\u4e4b\u95f4\u5177\u6709\u5f88\u5f3a\u7684\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u529b\uff0c\u5c55\u73b0\u51fa\u5747\u5300\u7684\u4e92\u8fde\u6027\u548c\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\uff0c\u4ece\u800c\u6709\u6548\u5730\u51cf\u5c11\u4e86\u6210\u578b\u53ca\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u7684\u56e2\u805a\u3002\u57fa\u4e8ePANI \/ RGO\u7ea4\u7ef4\u548c\u805a\u4e59\u70ef\u9187\uff08PVA\uff09\/ H2<\/sub>SO4<\/sub>\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u5168\u6c34\u51dd\u80f6\u72b6\u8d85\u7ea7\u7535\u5bb9\u5668\u5177\u6709\u51fa\u8272\u7684\u67d4\u97e7\u6027\u3001\u53ef\u5851\u6027\u4ee5\u53ca\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4e14\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u8fbe\u7ea640\uff05\u7684\u5e94\u53d8\uff0c\u63d0\u4f9b8.80mWh\u00b7cm-3<\/sup>\u7684\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\uff08\u529f\u7387\u5bc6\u5ea6\u4e3a30.77mW\u00b7cm-3<\/sup>\uff09\uff0c\u4f18\u4e8e\u4e4b\u524d\u62a5\u9053\u7684\u8bb8\u591a\u7ea4\u7ef4\u72b6\u8d85\u7ea7\u7535\u5bb9\u5668\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00<\/strong> \u57fa\u4e8e\u81ea\u7ec4\u88c5\u65b9\u6cd5\u5236\u5907<\/strong>PANI\/GO<\/strong>\u6df7\u5408\u6c34\u51dd\u80f6\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

<\/strong><\/p>\n

\u56fe\u4e8c<\/strong> PANI\/RGO<\/strong>\u7ea4\u7ef4\u548c<\/strong>RGO<\/strong>\u7ea4\u7ef4\u7684\u5f62\u6001<\/strong><\/p>\n

<\/p>\n

a, b, c\uff09PANI\/RGO\u7ea4\u7ef4\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

d, e\uff09RGO\u7ea4\u7ef4\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

f\uff09PANI\/RGO\u7ea4\u7ef4\u7684EDS\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e09<\/strong> \u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

<\/p>\n

a\uff09PANI\/RGO, RGO\u548cPANI\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n

b\uff09PANI \/ RGO\u548cPANI\u7684XPS N 1s\u5149\u8c31\uff1b<\/p>\n

c\uff09PANI \/ RGO\u7684XPS C 1s\u5149\u8c31;<\/p>\n

d\uff09PANI, PA\u548cRGO\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u793a\u610f\u56fe\uff1a\u9ed1\u8272-RGO\uff0c\u7eff\u8272-PANI\u94fe\uff0c\u94f6\u767d\u8272-PA\u5206\u5b50\uff0c\u7d2b\u8272-\u542b\u6c27\u57fa\u56e2;<\/p>\n

e\uff09RGO\uff0cPANI \/ RGO\u548cPANI\u7ea4\u7ef4\u7684\u5e94\u53d8-\u5e94\u529b\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u56db<\/strong> \u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

<\/p>\n

a\uff0910mV s-1<\/sup>\u65f6\uff0cRGO\u3001PANI \/ RGO\u548cPANI\u7684CV\u66f2\u7ebf;<\/p>\n

b, c, d\uff09\u7ec4\u88c5\u5bf9\u79f0\u5168\u7535\u6c60\u7684CV\u66f2\u7ebf\uff0cGCD\u66f2\u7ebf\u4ee5\u53ca\u76f8\u5e94\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

e\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a1.26 A g-1<\/sup>\u65f6\uff0c\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027;<\/p>\n

f\uff09Ragone\u56fe\uff1aPANI\/RGO\u5168\u51dd\u80f6\u72b6\u5168\u7535\u6c60\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u5176\u4ed6\u7ea4\u7ef4\u72b6\u8d85\u7ea7\u7535\u5bb9\u5668\u76f8\u6bd4\u8f83\uff08\u6839\u636e\u4e24\u4e2a\u7535\u6781\u7684\u603b\u4f53\u79ef\u548c\u8d28\u91cf\u6765\u8ba1\u7b97\u6bd4\u7535\u5bb9\uff0c\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\uff0c\u800c\u4e0d\u8003\u8651\u7535\u89e3\u8d28\uff09\u3002<\/p>\n

\u56fe\u4e94<\/strong> \u5b9e\u9645\u5e94\u7528<\/strong><\/p>\n

<\/p>\n

a\uff09\u7ec4\u88c5\u7684\u5168\u6c34\u51dd\u80f6\u72b6\u7535\u6c60\u5728\u6b63\u5e38\uff0c\u5f2f\u66f2\u548c\u626d\u66f2\u72b6\u6001\u4e0b\u7684CV\u66f2\u7ebf;<\/p>\n

b, c\uff09\u5f39\u7c27\u72b6\u5168\u7535\u6c60\u7684\u5f39\u6027\uff1b<\/p>\n

d\uff09\u5168\u7535\u6c60\u4e32\u8054\u540e\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

e\uff09\u5728\u6b63\u5e38\u548c\u5f2f\u66f2\u72b6\u6001\u4e0b\uff08\u6bd4\u4f8b\u5c3a\u4e3a2\u5398\u7c73\uff09\uff0c\u4e3a\u4e24\u4e2aLED\u706f\u4f9b\u7535\u7684\u67d4\u6027\u7535\u6c60\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u56e2\u961f\u901a\u8fc7GO\u548cPANI\u6c34\u51dd\u80f6\u7684\u5927\u5206\u5b50\u81ea\u7ec4\u88c5\u5236\u5907\u4e86\u7ea4\u7ef4\u72b6\u6c34\u51dd\u80f6\u7535\u6781\uff0c\u4e0eRGO\u7ea4\u7ef4\u76f8\u6bd4\uff0c\u5176\u8868\u73b0\u51fa\u66f4\u5927\u7684\u6bd4\u7535\u5bb9\u548c\u66f4\u5f3a\u7684\u673a\u68b0\u6027\u80fd\u3002\u5177\u4f53\u800c\u8a00\uff0cPANI \/ GO\u6742\u5316\u6c34\u51dd\u80f6\u4e2dGO\u3001PANI\u548cPA\u4e4b\u95f4\u5b58\u5728\u5f88\u5f3a\u7684\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\uff0c\u5305\u62ec\u9759\u7535\u76f8\u4e92\u4f5c\u7528\uff0c\u6c22\u952e\u6548\u5e94\u548c\u03c0-\u03c0\u5806\u53e0\uff0c\u8fd9\u5bf9\u51cf\u5c11\u540e\u7eed\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u7684\u660e\u663e\u805a\u96c6\u662f\u6709\u5efa\u8bbe\u6027\u4f5c\u7528\u7684\u3002\u968f\u7740PVA\u57fa\u7535\u89e3\u8d28\u7684\u8fdb\u4e00\u6b65\u51dd\u80f6\u5316\uff0c\u5f00\u53d1\u4e86\u5168\u51dd\u80f6\u6001\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u5176\u4e0d\u4ec5\u6709\u6781\u5927\u7684\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8fd8\u663e\u793a\u51fa\u4f18\u5f02\u7684\u673a\u68b0\u7075\u6d3b\u6027\u548c\u8010\u7528\u6027\uff0c\u53ef\u4ee5\u5236\u6210\u50a8\u80fd\u7eb1\u7ebf\uff0c\u662f\u4e3a\u4e0b\u4e00\u4ee3\u53ef\u7a7f\u6234\u548c\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u63d0\u4f9b\u52a8\u529b\u7684\u6709\u529b\u5019\u9009\u4eba\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Stretchable All\u2010Gel\u2010State Fiber\u2010Shaped Supercapacitors Enabled by Macromolecularly Interconnected 3D Graphene\/Nanostructured Conductive Polymer Hydrogels <\/a>\uff08Adv. Mater. 2018, DOI: 10.1002\/ adma.201800124\uff09<\/p>\n

\u76f8\u5173\u6587\u732e\u63a8\u8350\uff1a<\/strong><\/p>\n

“Multifunctional Nanostructured Conductive Polymer Gels: Synthesis, Properties & Applications<\/a>“, Acc. Chem. Res. 50, 1734 (2017).<\/p>\n

“Energy Gels: A Bio-Inspired Material Platform for Advanced Energy Applications<\/a>“, Nano Today, 11, 738 (2016).<\/p>\n

“Nanostructured Conductive Polymers for Advanced Energy Storage<\/a>“, Chem. Soc. Rev., 44, 6684 (2015).<\/p>\n

“3D nanostructured conductive polymer hydrogels for high-performance electrochemical devices<\/a>“, Energy Environ. Sci., 6, 2856 (2013).<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n

UT Austin\u4f59\u6842\u534e\u6559\u6388\u7814\u7a76\u56e2\u961f\u5f00\u521b\u5e76\u957f\u671f\u81f4\u529b\u4e8e\u4e09\u7ef4\u7eb3\u7c73\u7ed3\u6784\u7684\u5bfc\u7535\u6c34\u51dd\u80f6\u591a\u529f\u80fd\u6750\u6599\u7684\u7814\u7a76\uff0c\u5728\u56fd\u9645\u77e5\u540d\u671f\u520a\u4e0a\u53d1\u8868\u8fc7\u8bb8\u591a\u76f8\u5173\u5de5\u4f5c\uff0c\u5305\u62ec\uff1aNature Nanotech., Nature Commun., Acc. Chem. Res., Chem. Soc. Rev., Energy Environ. Sci., Angew. Chem. Int. Ed., Adv. Mater., Nano Lett., PNAS, Nano Today\u7b49\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4\u4e5f\u4e50\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>RDD-2011-CHERISH<\/strong>\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

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