{"id":133314,"date":"2018-04-09T06:30:46","date_gmt":"2018-04-08T22:30:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=133314"},"modified":"2018-04-05T16:57:34","modified_gmt":"2018-04-05T08:57:34","slug":"%e7%be%8e%e5%9b%bd%e7%bd%97%e6%a0%bc%e6%96%af%e5%a4%a7%e5%ad%a6%e6%9d%8e%e9%9d%99%e8%af%be%e9%a2%98%e7%bb%84energy-environ-sci-%ef%bc%9a%e4%b8%80%e7%a7%8d%e5%be%ae%e5%ad%94%e9%87%91%e5%b1%9e%e6%9c%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=133314","title":{"rendered":"\u7f8e\u56fd\u7f57\u683c\u65af\u5927\u5b66Energy Environ. Sci.\uff1a\u4e00\u79cd\u5fae\u5b54\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5206\u5b50\u7b5b\u7528\u4e8e\u76f4\u94fe,\u5355\u652f\u94fe\u548c\u53cc\u652f\u94fe\u70f7\u70c3\u5f02\u6784\u4f53\u7684\u5438\u9644\u6027\u5206\u79bb"},"content":{"rendered":"
\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n \u5c06\u6df7\u5408\u7684\u5316\u5b66\u7ec4\u4efd\u63d0\u7eaf\u4e3a\u7eaf\u7ec4\u4efd\u662f\u4e00\u4e2a\u80fd\u6e90\u6d88\u8017\u91cf\u5f88\u5927\u7684\u8fc7\u7a0b\uff0c\u5360\u5168\u7403\u80fd\u6e90\u6d88\u8017\u91cf\u768410-15%\u3002\u56e0\u6b64\uff0c\u53d1\u5c55\u66f4\u52a0\u8282\u80fd\u7684\u5206\u79bb\u65b9\u5f0f\u5728\u8282\u7ea6\u80fd\u6e90\u548c\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u65b9\u9762\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002\u5176\u4e2d\uff0c\u5206\u79bb\u4e0d\u540c\u652f\u5316\u5ea6\u7684\u70f7\u70c3\u540c\u5206\u5f02\u6784\u4f53\u5728\u77f3\u6cb9\u5316\u5de5\u9886\u57df\u4f9d\u7136\u9762\u4e34\u4e00\u5b9a\u7684\u6280\u672f\u6311\u6218\u3002\u9664\u4e86\u4f20\u7edf\u80fd\u8017\u8f83\u9ad8\u7684\u84b8\u998f\u5206\u79bb\uff0c\u76ee\u524d\u7528\u4e8e\u70f7\u70c3\u540c\u5206\u5f02\u6784\u4f53\u5206\u79bb\u7684\u5438\u9644\u5242\u6750\u6599\u662f5A\u5206\u5b50\u7b5b\u3002\u867d\u71365A\u5206\u5b50\u7b5b\u80fd\u8f83\u6709\u6548\u5730\u5206\u79bb\u76f4\u94fe\u548c\u652f\u94fe\u70f7\u70c3\uff0c\u4f46\u5176\u4e0d\u80fd\u7528\u4e8e\u5206\u79bb\u5355\u652f\u94fe\u548c\u53cc\u652f\u94fe\u7684\u70f7\u70c3\u5f02\u6784\u4f53\uff0c\u800c\u8fd9\u4e00\u5206\u79bb\u8fc7\u7a0b\u662f\u8fdb\u4e00\u6b65\u63d0\u9ad8\u6c7d\u6cb9\u8f9b\u70f7\u503c\u7684\u5173\u952e\u3002\u56e0\u6b64\u9700\u8981\u63a2\u7d22\u66f4\u597d\u7684\u6280\u672f\u6765\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n \u8fd1\u65e5\uff0c\u7f8e\u56fd\u7f57\u683c\u65af\u5927\u5b66<\/b><\/strong>\u7684\u674e\u9759\u6559\u6388<\/b><\/strong>\u8bfe\u9898\u7ec4\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u9499\u7684\u5fae\u5b54\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5316\u5408\u7269\uff0c\u5e76\u9996\u6b21\u5b9e\u73b0\u4e86\u901a\u8fc7\u5355\u79cd\u5438\u9644\u5242\u5b8c\u5168\u5206\u79bb\u76f4\u94fe\u3001\u5355\u652f\u94fe\u548c\u53cc\u652f\u94fe\u7684\u70f7\u70c3\u540c\u5206\u5f02\u6784\u4f53\u3002\u8fd9\u79cd\u53ef\u4ee5\u5b8c\u5168\u7b5b\u5206\u5355\u652f\u94fe\u548c\u53cc\u652f\u94fe\u70f7\u70c3\u540c\u5206\u5f02\u6784\u4f53\u7684\u5206\u79bb\u6280\u672f\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u83b7\u5f97\u5177\u6709\u66f4\u9ad8\u8f9b\u70f7\u503c\u7684\u6c7d\u6cb9\uff0c\u5e76\u4e14\u586b\u8865\u4e86\u76ee\u524d\u5206\u79bb\u6280\u672f\u7684\u7a7a\u767d\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”One-of-A-Kind:\u00a0A Microporous Metal-Organic Framework\u00a0Capable of Adsorptive Separation of Linear, Mono- and Di-branched Alkane Isomers via Temperature- and Adsorbate-Dependent Molecular Sieving<\/b><\/strong>“\u53d1\u8868\u5728Energy Environ<\/b><\/strong>. <\/b><\/strong>Sci<\/b><\/strong>.<\/b><\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n \u56fe<\/b><\/strong>1 <\/b><\/strong>Ca(H<\/b><\/strong>2<\/b><\/sub><\/strong>tcpb)\u7684\u6676\u4f53\u7ed3\u6784\u548c\u4e00\u7ef4\u901a\u9053\u5f62\u72b6<\/b><\/strong><\/p>\n (a).Ca(H2<\/sub>tcpb)\u7684\u6676\u4f53\u7ed3\u6784<\/p>\n (b).Ca(H2<\/sub>tcpb)\u7684\u4e00\u7ef4\u901a\u9053\u5f62\u72b6<\/p>\n \u56fe<\/b><\/strong>2 <\/b><\/strong>Ca(H<\/b><\/strong>2<\/b><\/sub><\/strong>tcpb)\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5bf9\u4e0d\u540c\u7269\u8d28\u7684\u7b49\u6e29\u5438\u9644\u66f2\u7ebf<\/b><\/strong><\/p>\n (a), (b), \u548c(c) \u5206\u522b\u4e3a\u6b63\u5df1\u70f7\uff0c3-\u7532\u57fa\u620a\u70f7\uff0c\u548c2,2-\u4e8c\u7532\u57fa\u4e01\u70f7\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002\u9ed1\u8272\uff0c\u7ea2\u8272\uff0c\u84dd\u8272\uff0c\u7d2b\u8272\uff0c\u7eff\u8272\u5206\u522b\u4ee3\u886830,60,90,120,150 \u00b0C\u7684\u5438\u9644\u66f2\u7ebf\u3002(d)\u548c(e)\u4e3a\u4e09\u79cd\u5f02\u6784\u4f53\u572860\u548c120 \u00b0C\u65f6\u7684\u5438\u9644\u66f2\u7ebf\u5bf9\u6bd4\u3002\u00a0(f)\u4e3a\u8bbe\u8ba1\u5206\u79bb\u793a\u610f\u56fe\u3002<\/p>\n \u56fe<\/b><\/strong>3 <\/b><\/strong>\u5206\u79bb\u88c5\u7f6e\u548c\u5206\u79bb\u7ed3\u679c<\/b><\/strong><\/p>\n (a)\/(d)\u4e3a\u6b63\u5df1\u70f7\u30013-\u7532\u57fa\u620a\u70f7\u30012,2-\u4e8c\u7532\u57fa\u4e01\u70f7\u7684\u4e09\u7ec4\u5206\u900f\u8fc7\u88c5\u7f6e\u548c\u7ed3\u679c\u3002<\/p>\n (b)\/(e)\u4e3a\u6b63\u5df1\u70f7\u30013-\u7532\u57fa\u620a\u70f7\u7684\u53cc\u7ec4\u5206\u900f\u8fc7\u88c5\u7f6e\u548c\u7ed3\u679c\u3002\u00a0(c)\/(f)\u4e3a3-\u7532\u57fa\u620a\u70f7\u30012,2-\u4e8c\u7532\u57fa\u4e01\u70f7\u7684\u53cc\u7ec4\u5206\u900f\u8fc7\u88c5\u7f6e\u548c\u7ed3\u679c\u3002<\/p>\n \u56fe<\/b><\/strong>4 <\/b><\/strong>\u4e0d\u540c\u5438\u9644\u5f62\u5f0f\u7684Ca(H<\/b><\/strong>2<\/b><\/sub><\/strong>tcpb)\u7684XRD\u7ed3\u679c<\/b><\/strong><\/p>\n \u901a\u8fc7\u5bf9\u4e0d\u540c\u5438\u9644\u5f62\u5f0f\u7684XRD\u5206\u6790\uff0c\u4f5c\u8005\u5c06\u8be5\u6750\u6599\u72ec\u7279\u7684\u5438\u9644\u5206\u79bb\u6027\u80fd\u5f52\u7ed3\u4e3a\u5176\u7ed3\u6784\u7279\u70b9\u4ee5\u53ca\u5bf9\u4e0d\u540c\u70f7\u70c3\u5f02\u6784\u4f53\u5206\u5b50\u7684\u4e0d\u540c\u4f5c\u7528\u529b\u3002\u00a0\u8be5\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u6709\u4e00\u5b9a\u7684\u67d4\u6027\uff0c\u5176\u5bf9\u4e0d\u540c\u70f7\u70c3\u5f02\u6784\u4f53\u5206\u5b50\u7684\u5438\u9644\u5177\u6709\u7279\u5b9a\u7684\u6548\u5e94\uff0c\u5e76\u4e14\u5bf9\u540c\u4e00\u5206\u5b50\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5438\u9644\u6548\u5e94\u4e5f\u4e0d\u540c\uff0c\u56e0\u6b64\u53ef\u5b9e\u73b0\u6e29\u5ea6\u8c03\u63a7\u4e0b\u7684\u6709\u6548\u5206\u79bb\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n \u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cd\u53ef\u7528\u4e8e\u5b8c\u5168\u5206\u79bb\u76f4\u94fe\u3001\u5355\u652f\u94fe\u548c\u53cc\u652f\u94fe\u70f7\u70c3\u540c\u5206\u5f02\u6784\u4f53\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5316\u5408\u7269\u3002\u5728\u63d0\u4f9b\u66f4\u9ad8\u8d28\u91cf\u6c7d\u6cb9\u7684\u540c\u65f6\uff0c\u89e3\u51b3\u4e86\u4f20\u7edf\u5206\u79bb\u6750\u6599\u4e0d\u80fd\u5206\u79bb\u5355\u652f\u94fe\u548c\u53cc\u652f\u94fe\u70f7\u70c3\u540c\u5206\u5f02\u6784\u4f53\u7684\u95ee\u9898\uff0c\u586b\u8865\u4e86\u6b64\u7c7b\u5206\u79bb\u6280\u672f\u7684\u7a7a\u767d\u3002\u8fd9\u4e2a\u5de5\u4f5c\u4e3a\u540e\u7eed\u5206\u79bb\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>One-of-A-Kind: A Microporous Metal-Organic Framework Capable of Adsorptive Separation of Linear, Mono- and Di-branched Alkane Isomers via Temperature- and Adsorbate-Dependent Molecular Sieving.<\/a>(Energy Environ. Sci., 2018,\u00a0DOI: 10.1039\/C8EE00459E)<\/p>\n \u3010\u56e2\u961f\u4ecb\u7ecd<\/b><\/strong>\u3011<\/p>\n \u8be5\u8bba\u6587\u4f5c\u8005\u4e2d\u6587\u540d\uff1a\u738b\u6d69\uff0c\u8463\u5174\u9686\uff0c\uff08Ever Velasco\uff0cDavid H. Olson\uff09\uff0c\u97e9\u5b87\uff0c\u674e\u9759\u3002<\/p>\n \u56e2\u961f\u4fe1\u606f: \u674e\u9759\u6559\u6388\u4e8e1989\u5e74\u5728\u7f8e\u56fd\u5eb7\u5948\u5c14\u5927\u5b66\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff08\u5e08\u4ece\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u5f97\u4e3b\u7f57\u5fb7\u00b7\u970d\u592b\u66fc\u6559\u6388\uff09\uff0c\u73b0\u4efb\u7f8e\u56fd\u7f57\u683c\u65af\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5b66\u751f\u7269\u5b66\u7cfb\u8d44\u6df1\u7ec8\u8eab\u6559\u6388\uff0c\u7f8e\u56fd\u5316\u5b66\u4f1a\u300a\u6676\u4f53\u751f\u957f\u4e0e\u8bbe\u8ba1\u300b\u526f\u4e3b\u7f16\uff0c\u7f8e\u56fd\u79d1\u5b66\u4fc3\u8fdb\u534f\u4f1a\u4f1a\u5458\uff0c\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u5458\u3002\u66fe\u83b7\u7f8e\u56fd\u603b\u7edf\u5956\u3001\u7f8e\u56fd\u80fd\u6e90\u90e8\u9881\u53d1\u7684\u9996\u5c4a\u6e05\u6d01\u80fd\u6e90\u521b\u65b0\u8d21\u732e\u5956\u3001\u5fb7\u56fd\u6d2a\u5821\u57fa\u91d1\u4f1a\u7684\u6d2a\u5821\u7814\u7a76\u5956\u7b49\uff0c\u5e76\u4e8e2015\u30012016\u8fde\u7eed\u4e24\u5e74\u5165\u9009\u6c64\u68ee\u8def\u900f\u96c6\u56e2\u9881\u5e03\u7684\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u540d\u5355\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u65b0\u578b\u6742\u5316\u534a\u5bfc\u4f53\u6750\u6599\u548c\u5fae\u5b54\u6750\u6599\u7684\u8bbe\u8ba1\u5f00\u53d1\u4ee5\u53ca\u5b83\u4eec\u5728\u8282\u80fdLED\u3001\u592a\u9633\u80fd\u7535\u6c60\uff0c\u6c14\u4f53\u50a8\u5b58\u3001\u6c14\u4f53\u5206\u79bb\u3001\u6709\u5bb3\u7269\u68c0\u6d4b\u53ca\u53bb\u9664\u548c\u57fa\u4e8e\u8367\u5149\u5316\u5b66\u68c0\u6d4b\u65b9\u9762\u7684\u5e94\u7528\u3002\u8fc4\u4eca\u53d1\u8868\u5b66\u672f\u8bba\u6587330\u4f59\u7bc7\uff0c\u5e76\u62e5\u670913\u9879\u4e13\u5229\u3002<\/p>\n \u674e\u9759\u6559\u6388\u56e2\u961f\u8fd1\u5e74\u6765\u5728\u8bbe\u8ba1\u3001\u5408\u6210\u65b0\u578b\u591a\u5b54\u6750\u6599\u5e76\u7528\u4e8e\u70c3\u7c7b\u5206\u79bb\uff0c\u7a00\u6709\u6c14\u4f53\u5206\u79bb\u3001\u6709\u5bb3\u7269\u6355\u83b7\u7b49\u9886\u57df\u53d6\u5f97\u6301\u7eed\u8fdb\u5c55\uff0c\u662f\u6700\u65e9\u5c06\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\u7528\u4e8e\u78b3\u6c22\u5316\u5408\u7269\u5438\u9644\u5206\u79bb\u7684\u8bfe\u9898\u7ec4\u4e4b\u4e00\u3002\u5728\u8fd9\u4e00\u9886\u57df\u4ee3\u8868\u6027\u5de5\u4f5c\u5305\u62ec\uff1a<\/p>\n Angew. 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Commun., <\/i><\/em>2018<\/b><\/strong>, 9.<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002 \u00a0<\/p>\n \u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002 \u00a0<\/p>\n<\/p>\n
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