{"id":133118,"date":"2018-04-02T19:20:03","date_gmt":"2018-04-02T11:20:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=133118"},"modified":"2018-04-02T19:22:57","modified_gmt":"2018-04-02T11:22:57","slug":"%e4%b8%8a%e6%b5%b7%e4%ba%a4%e5%a4%a7%e8%b5%b5%e4%b8%80%e6%96%b0sci-bull-%e4%ba%8c%e6%ac%a1%e7%94%b5%e6%b1%a0%e6%9d%90%e6%96%99%e6%b0%a2%e6%b0%a7%e5%8c%96%e9%95%8d%e4%bd%9c%e4%b8%ba%e4%b8%80","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=133118","title":{"rendered":"\u4e0a\u6d77\u4ea4\u5927\u8d75\u4e00\u65b0Sci. Bull.: \u4e8c\u6b21\u7535\u6c60\u6750\u6599\u6c22\u6c27\u5316\u954d\u4f5c\u4e3a\u4e00\u79cdNi\u57fa\u5f02\u76f8\u50ac\u5316\u5242\u7528\u4e8e\u6fc0\u53d1\u4ea7\u751f\u786b\u9178\u6839\u81ea\u7531\u57fa"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u542b\u6c27\u81ea\u7531\u57fa\u51ed\u501f\u5176\u5f3a\u6c27\u5316\u6027\uff0c\u5728\u5316\u5b66\u5408\u6210\u548c\u73af\u5883\u4fee\u590d\u9886\u57df\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5728\u7ecf\u5178\u7684\u82ac\u987f\u53cd\u5e94\u4e2d\u4f7f\u7528\u7684\u7f9f\u57fa\u81ea\u7531\u57fa\uff08\u2022OH\uff0cEo<\/sup>=1.90-2.70V\uff09\u53ef\u4ee5\u964d\u89e3\u5f88\u591a\u96be\u964d\u89e3\u6709\u673a\u7269\uff0c\u4f46\u662f\u5176\u6c27\u5316\u80fd\u529b\u53d7\u9650\u4e8e\u5176\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff0c\u5c1a\u6709\u4e00\u4e9b\u7f3a\u9677\uff0c\u5e76\u4e14\u4f20\u7edf\u7684\u82ac\u987f\u53cd\u5e94\u9700\u8981\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\uff08pH 3-4\uff09\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u786b\u9178\u6839\u81ea\u7531\u57fa\uff08\u2022SO4<\/sub>–<\/sup>\uff09\u5177\u6709\u66f4\u5f3a\u7684\u6c27\u5316\u6027\uff08Eo<\/sup>=2.60-3.10V\uff09\uff0c\u5e76\u4e14\u9002\u7528\u7684pH\u8303\u56f4\u66f4\u52a0\u5bbd\u6cdb\uff08pH 3-10\uff09\uff0c\u5b58\u5728\u5bff\u547d\u66f4\u957f\uff0c\u5df2\u7ecf\u4f5c\u4e3a\u4e00\u79cd\u4f18\u5f02\u7684\u6c27\u5316\u5242\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u53bb\u9664\u96be\u964d\u89e3\u6709\u673a\u6c61\u67d3\u7269\u5982\u6297\u751f\u7d20\u7c7b\u836f\u7269\uff0c\u81f4\u764c\u836f\u7269\u548c\u6740\u866b\u5242\u7b49\u3002\u5e76\u4e14\u4ea7\u2022SO4<\/sub>–<\/sup>\u6240\u4f7f\u7528\u7684\u8fc7\u786b\u9178\u6839\uff08PDS\uff09\u6216\u5355\u8fc7\u786b\u9178\u6839\uff08PMS\uff09\u76f8\u6bd4\u4e8e\u82ac\u987f\u53cd\u5e94\u4f7f\u7528\u7684H2<\/sub>O2<\/sub>\u66f4\u6613\u50a8\u5b58\u548c\u4fbf\u4e8e\u8fd0\u8f93\uff0c\u4f46\u662f\u6fc0\u53d1\u8fd9\u4e9bPDS\u6216\u8005PMS\u6240\u9700\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u8ddf\u5927\u90e8\u5206\u91d1\u5c5e\u5728\u6c34\u76f8\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4e0d\u5339\u914d\uff0c\u4ece\u800c\u5bfc\u81f4\u4f20\u7edf\u7684\u82ac\u987f\u50ac\u5316\u5242\u5728\u7528\u4e8e\u6fc0\u53d1\u4ea7\u751f\u2022SO4<\/sub>–<\/sup>\u65f6\u7ecf\u5e38\u6548\u679c\u6b20\u4f73\u3002\u76ee\u524d\u7814\u7a76\u4e2d\u5e7f\u6cdb\u4f7f\u7528\u7684\u4ea7\u2022SO4<\/sub>–<\/sup>\u50ac\u5316\u5242\u4e3b\u8981\u5305\u62ec\uff1a\u6fc0\u6d3bPMS\u4ea7\u2022SO4<\/sub>–<\/sup>\u6548\u679c\u6700\u597d\u7684\u94b4\u57fa\u50ac\u5316\u5242\u6216\u8005\u4f7f\u7528\u591a\u79cd\u91d1\u5c5e\u5f62\u6210\u7684\u590d\u6742\u5408\u91d1\u50ac\u5316\u5242\uff0c\u800c\u6709\u6548\u6fc0\u6d3bPDS\u7684\u6700\u4f73\u50ac\u5316\u5242\u7ecf\u5e38\u662f\u57fa\u4e8eAg\u548cRu\u7b49\u8d35\u91d1\u5c5e\u3002\u4e0a\u8ff0\u50ac\u5316\u5242\u5b58\u5728\u7684\u9ad8\u6bd2\u6027\uff0c\u9ad8\u6210\u672c\u548c\u590d\u6742\u5408\u6210\u8fc7\u7a0b\uff0c\u5927\u5927\u9650\u5236\u4e86\u5b83\u4eec\u7684\u8fdb\u4e00\u6b65\u63a8\u5e7f\u53ca\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4ea7\u2022SO4<\/sub>–<\/sup>\u7684\u50ac\u5316\u6750\u6599\u5c06\u6210\u4e3a\u63a8\u5e7f\u2022SO4<\/sub>–<\/sup>\u5e94\u7528\u7684\u5173\u952e\u6027\u6280\u672f\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u73af\u5883\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u8d75\u4e00\u65b0\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bfe\u9898\u7ec4\u5728\u4e3a\u4e86\u89e3\u51b3\u8fc7\u786b\u9178\u6839\u6fc0\u6d3b\u53cd\u5e94\u9700\u8981\u9ad8\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u8fd9\u6837\u5173\u952e\u95ee\u9898\uff0c\u53e6\u8f9f\u8e4a\u5f84\u7684\u8fd0\u7528\u5177\u6709\u826f\u597d\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u53ef\u8c03\u8282\u6027\u4ee5\u53ca\u5176\u4f18\u5f02\u7684\u53ef\u9006\u6027\u7684\u4e8c\u6b21\u7535\u6c60\u6750\u6599\u3002\u9996\u5148\u9009\u53d6\u4e86\u5408\u6210\u7b80\u5355\u73af\u5883\u53cb\u597d\u7684\u03b1-Ni(OH)2<\/sub>\uff0c\u5e76\u5c06\u5176\u7528\u4e8e\u6fc0\u53d1PDS\u6216PMS\uff0c\u5229\u7528\u4ea7\u751f\u7684\u2022SO4<\/sub>–<\/sup>\u964d\u89e3\u6709\u673a\u6c61\u67d3\u7269\u3002\u03b1-Ni(OH)2<\/sub>\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5f88\u5bb9\u6613\u5728\u8868\u9762\u5f62\u6210NiOOH\uff0c\u5e76\u4e14\u03b1-Ni(OH)2<\/sub>\/NiOOH\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u662f\u53ef\u9006\u7684\uff0c\u8fd9\u4f7f\u5f97Ni2+<\/sup>\/Ni3+<\/sup>\u7684\u5faa\u73af\u53cd\u5e94\u66f4\u5bb9\u6613\u53d1\u751f\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u50ac\u5316\u5242\u5bf9PDS\u6216PMS\u7684\u6d3b\u5316\u3002\u8be5\u7814\u7a76\u5229\u7528\u03b1-Ni(OH)2<\/sub>\/NiOOH\u4f53\u7cfb\u4e0e\u6fc0\u53d1PDS\u6216PMS\u76f8\u5339\u914d\u7684\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u4ee5\u53ca\u4f18\u5f02\u7684\u53ef\u9006\u6027\uff0c\u6784\u5efa\u4e86\u9ad8\u6548\u7a33\u5b9a\u7684\u7c7b\u82ac\u987f\u50ac\u5316\u6027\u4f53\u7cfb\uff0c\u4e3a\u5b9e\u73b0\u9ad8\u6548\u4f4e\u6210\u672c\u5904\u7406\u6709\u673a\u5e9f\u6c34\uff0c\u62d3\u5c55\u4e8c\u6b21\u7535\u6c60\u7535\u6781\u6750\u6599\u5728\u6c61\u6c34\u5904\u7406\u4e2d\u7684\u5e94\u7528\u4ee5\u53ca\u4e30\u5bcc\u9ad8\u7ea7\u6c27\u5316\u6280\u672f\u5960\u5b9a\u4e86\u7814\u7a76\u57fa\u7840\u3002<\/p>\n

\u4ee5\u4e0a\u7814\u7a76\u6210\u679c\uff0c\u5df2\u7ecf\u5728Science Bulletin\u4e0a\u53d1\u8868\uff0c\u9898\u4e3a\u201cSecondary battery inspired <\/strong>\u03b1<\/strong>–<\/strong>nickel hydroxide as an efficient Ni-based heterogeneous catalyst for sulfate radical activation\u201d<\/strong>\uff0c\u5229\u7528\u6c34\u70ed\u6cd5\u5236\u5907\u7684\u03b1-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u6784\u5efa\u4e86\u03b1-Ni(OH)2<\/sub>\/PDS\u7c7b\u82ac\u987f\u50ac\u5316\u4f53\u7cfb\uff0c\u5229\u7528\u03b1-Ni(OH)2<\/sub>\u5728\u5145\u653e\u7535\u4e2d\u7684\u50ac\u5316\u6027\u80fd\uff0c\u6fc0\u6d3bPDS\uff0c\u5b9e\u73b0\u4f53\u7cfb\u5728\u5bbd\u7684pH\u8303\u56f4\u5185\u5bf9\u6709\u673a\u6c61\u67d3\u7269\u7684\u964d\u89e3\u3002\u7814\u7a76\u8868\u660e\uff0c\u5236\u5907\u7684\u03b1-Ni(OH)2<\/sub>\u5448\u73b0\u51fa\u7eb3\u7c73\u7247\u72b6\u7ed3\u6784\u3002\u76f8\u6bd4\u4e8eCo\u57fa\u50ac\u5316\u5242\u53ea\u80fd\u6fc0\u6d3bPMS\uff0c\u03b1-Ni(OH)2<\/sub>\u53ef\u4ee5\u6fc0\u6d3bPMS\u548cPDS\uff0c\u66f4\u4e3a\u91cd\u8981\u7684\u662f\u867d\u7136\u03b1-Ni(OH)2<\/sub>\/PMS\u6bd4\u5747\u76f8\u7684Co\/PMS\u6548\u679c\u5dee\uff0c\u4f46\u662f\uff0c\u5176\u5bf9\u6c61\u67d3\u7269\u7684\u964d\u89e3\u6548\u679c\u662fCo3<\/sub>O4<\/sub>\/PMS\u4f53\u7cfb\u76843\u500d\u3002\u7531\u4e8ePDS\u76f8\u6bd4\u4e8ePMS\uff0c\u4ef7\u683c\u66f4\u4f4e\uff0c\u6027\u8d28\u66f4\u52a0\u7a33\u5b9a\uff0c\u56e0\u6b64\uff0c\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u03b1-Ni(OH)2<\/sub>\/PDS\u7c7b\u82ac\u987f\u50ac\u5316\u4f53\u7cfb\u5bf9\u82ef\u915a\u7684\u77ff\u5316\u80fd\u529b\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u4f53\u7cfb\u5bf9TOC\u7684\u53bb\u9664\u7387\u8d85\u8fc790\uff05\uff0c\u5faa\u73af\u4f7f\u7528\u56db\u6b21\uff0c\u50ac\u5316\u4f53\u7cfb\u4f9d\u7136\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u77ff\u5316\u80fd\u529b\uff0c\u540c\u65f6\uff0c\u50ac\u5316\u5242\u5728\u53cd\u5e94\u524d\u540e\uff0c\u6676\u4f53\u7ed3\u6784\u548c\u5fae\u89c2\u5f62\u8c8c\u53d8\u5316\u4e0d\u5927\uff0c\u5145\u5206\u8bc1\u660e\u4e86\u8be5\u50ac\u5316\u5242\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002\u53cd\u5e94\u540e\u7684\u6eb6\u6db2\u4e2d\uff0cNi\u7684\u6d78\u51fa\u91cf\u4f4e\u4e8e<0.1ppm\uff0c\u5b8c\u5168\u7b26\u5408\u6392\u653e\u6807\u51c6\u3002\u8be5\u7814\u7a76\u8fd8\u63ed\u793a\u4e86\u03b1-Ni(OH)2<\/sub>\/PDS\u7c7b\u82ac\u987f\u50ac\u5316\u4f53\u7cfb\u964d\u89e3\u6c61\u67d3\u7269\u7684\u673a\u7406\uff0c\u03b1-Ni(OH)2<\/sub>\u4e2d\u7684Ni(II) \u53ef\u88abPDS\u6c27\u5316\u6210Ni(III)\uff0c\u4f34\u968f\u6709\u2022SO4<\/sub>–<\/sup>\u7684\u4ea7\u751f\uff081\uff09\u3002\u2022SO4<\/sub>–<\/sup>\u4e00\u90e8\u5206\u76f4\u63a5\u53c2\u4e0e\u6709\u673a\u6c61\u67d3\u7269\u7684\u964d\u89e3\uff0c\u53e6\u4e00\u90e8\u5206\u5c06\u6c34\u6c27\u5316\u5f62\u6210\u2022OH\uff082\uff09\uff0c\u5728\u5b9e\u73b0\u5bf9\u6709\u673a\u7269\u7684\u77ff\u5316\u3002\u968f\u540e\uff0c\u5728\u5f62\u6210\u7684NiOOH\u4e2d\uff0cNi(III)\u80fd\u591f\u8ddfPDS\u53cd\u5e94\u5f62\u6210\u2022S2<\/sub>O8<\/sub>–<\/sup>\uff083\uff09\u3002\u8be5\u81ea\u7531\u57fa\u65e2\u53ef\u4ee5\u76f4\u63a5\u53c2\u4e0e\u6c61\u67d3\u7269\u7684\u964d\u89e3\uff0c\u4e5f\u80fd\u53d1\u751f\u6b67\u5316\u53cd\u5e94\uff0c\u5f62\u6210\u2022SO4<\/sub>–<\/sup>\uff084\uff09\u3002\u6574\u4e2a\u8fc7\u7a0b\u4e2d\uff0c\u50ac\u5316\u5242\u901a\u8fc7\u03b1-Ni(OH)2<\/sub>\/NiOOH\u4e4b\u95f4\u7684\u53ef\u9006\u53cd\u5e94\uff0c\u6fc0\u53d1PDS\uff0c\u5b9e\u73b0\u4f53\u7cfb\u5bf9\u6709\u673a\u6c61\u67d3\u7269\u7684\u964d\u89e3\u3002<\/p>\n

Ni(II) + S2<\/sub>O8<\/sub>2-<\/sup> \u2192 Ni(III) + SO4<\/sub>2-<\/sup> + \u2022SO4<\/sub>–<\/sup>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (1)<\/p>\n

\u00a0\u2022SO4<\/sub>–<\/sup>\u00a0\u00a0 + H2<\/sub>O \u2192 SO4<\/sub>2-<\/sup> + H+<\/sup> + \u2022OH\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(2)<\/p>\n

Ni(III) + S2<\/sub>O8<\/sub>2-<\/sup> \u2192 Ni(II) + \u2022S2<\/sub>O8<\/sub>–<\/sup>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(3)<\/p>\n

\u00a0\u2022S2<\/sub>O8<\/sub>–\u00a0 + SO4<\/sub>2-<\/sup> \u2192 \u2022SO4<\/sub>–<\/sup> + \u2022S2<\/sub>O8<\/sub>2-\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/sup>(4)<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1.<\/strong> \u03b1-Ni(OH)2<\/sub><\/strong>\u7eb3\u7c73\u7247\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u548c\u73af\u5883\u50ac\u5316\u6027\u80fd\u3002<\/strong><\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u03b1-Ni(OH)2<\/sub>\u7eb3\u7c73\u7247\u7684XRD\u56fe\uff08a\uff09\uff0cSEM\uff08b\uff09\uff0cTEM\uff08c\uff09\u548cHRTEM\uff08d\uff09\u53ca\u76f8\u5e94\u7684FFT\u884d\u5c04\u56fe\uff08\u63d2\u5165\u56fe1d\uff09\uff1b\u03b1-Ni(OH)2<\/sub>\u3001Co2+<\/sup>\u6fc0\u6d3bPDS \u964d\u89e3\u82ef\u915a\u7684\u6027\u80fd\u5bf9\u6bd4\uff08e\uff09\uff0c\u03b1-Ni(OH)2<\/sub>\u3001Co2+<\/sup>\u3001Co3<\/sub>O4<\/sub>\u6fc0\u6d3bPMS\u964d\u89e3\u82ef\u915a\u7684\u6027\u80fd\u3002\u5b9e\u9a8c\u6761\u4ef6\uff1a[\u82ef\u915a] = 50mg\/L\uff0c[PDS] = 0.4g\/L\uff0c[\u03b1-Ni(OH)2<\/sub>] = 0.5g\/L\uff085.4mmol\/L\uff09\uff0c[Co3<\/sub>O4<\/sub>] =5.4mmol\/L\uff0cT = 298 K\uff0cpH 10.0\u3002<\/p>\n

\u56fe<\/strong>2.<\/strong>\u4e0d\u540c\u50ac\u5316\u5242\u5bf9<\/strong>PDS<\/strong>\u548c\u50ac\u5316\u5242\u7684\u50ac\u5316\u4f5c\u7528\u82ef\u915a\u7684\u964d\u89e3\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u03b1-Ni(OH)2<\/sub>\u3001Ni0<\/sup>\u3001Ni2+<\/sup>\u6fc0\u6d3bPMS\u964d\u89e3\u82ef\u915a\u7684\u6027\u80fd\u5bf9\u6bd4\u3002\u5b9e\u9a8c\u6761\u4ef6\uff1a[\u82ef\u915a] = 50mg\/L\uff0c[PDS] = 0.4g\/L\uff0c5.4mmol\/L\u7684\u03b1-Ni(OH)2<\/sub>\uff0c5.4mmol\/L\u7684Ni0<\/sup>\u548c1ppm\u7684Ni2+<\/sup>\uff0c pH 7.0\uff08a\uff09\uff0c\u4e0d\u540cpH\u4e0bDMPO\u81ea\u65cb\u6355\u6349\u2022OH \u7684EPR\u5149\u8c31\u56fe\uff08b\uff09\uff0c\u03b1-Ni(OH)2<\/sub>\/PDS\u7c7b\u82ac\u987f\u4f53\u7cfb\u964d\u89e3\u82ef\u915a\u673a\u7406\u793a\u610f\u56fe\uff08c\uff09\uff0c\u53cd\u5e94\u524d\u540e\u03b1-Ni(OH)2<\/sub>\u4e2dNi\u7684XPS\u8c31\u56fe\uff08d\uff09\uff0c\u53cd\u5e94\u524d\u540e\u03b1-Ni(OH)2<\/sub>\u7684XRD\u56fe\uff08e\uff09\uff0c\u53cd\u5e94\u540e\u03b1-Ni(OH)2<\/sub>\u7684TEM\uff08f\uff09\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u6211\u4eec\u9996\u6b21\u62a5\u9053\u4e86\u4e00\u79cdNi\u57fa\u7684\u5f02\u76f8\u7c7b\u82ac\u987f\u50ac\u5316\u5242\u03b1-Ni(OH)2<\/sub>\uff0c\u7528\u4e8e\u6fc0\u6d3bPMS\u4ee5\u53caPDS\uff0c\u5176\u50ac\u5316\u6027\u80fd\u6bd4Co3<\/sub>O4<\/sub>\u7eb3\u7c73\u9897\u7c92\u8fd8\u8981\u4f18\u5f02\u3002\u5176\u539f\u56e0\u5728\u4e8e\u03b1-Ni(OH)2<\/sub>\/NiOOH\u4e4b\u95f4\u7684\u53ef\u9006\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u53ef\u4ee5\u5b9e\u73b0Ni2+<\/sup>\/Ni3+<\/sup>\u7684\u5faa\u73af\uff0c\u8fdb\u800c\u5b9e\u73b0\u03b1-Ni(OH)2<\/sub>\u9ad8\u6548\u7a33\u5b9a\u7684\u50ac\u5316\u6027\u80fd\u3002\u8fd9\u4e00\u7814\u7a76\u6210\u679c\uff0c\u662f\u57fa\u4e8e\u4e8c\u6b21\u7535\u6c60\u6750\u6599\u03b1-Ni(OH)2<\/sub>\u53ca\u5176\u6709\u6548\u7684\u6c27\u5316\u8fd8\u539f\u5faa\u73af\u53cd\u5e94\uff0c\u56e0\u6b64\uff0c\u6709\u671b\u5ef6\u4f38\u5230\u5176\u4ed6\u4e8c\u6b21\u7535\u6c60\u6750\u6599\u4f5c\u4e3a\u6f5c\u5728\u50ac\u5316\u5242\uff0c\u5e94\u7528\u4e8e\u6df1\u5ea6\u6c27\u5316\u964d\u89e3\u6709\u673a\u5e9f\u6c34\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/strong>Secondary battery inspired \u03b1-nickel hydroxide as an efficient Ni-based heterogeneous catalyst for sulfate radical activation<\/a>\uff08Sci. Bull., 2018, DOI:10.1016\/j.scib.2018.02.002\uff09<\/p>\n

\u81f4\u8c22<\/strong><\/p>\n

\u4e0a\u8ff0\u7814\u7a76\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1(No. 21777096\u3001No. 21777097)\u548c\u4e2d\u56fd\u535a\u58eb\u540e\u57fa\u91d1(2017M621483)\u7684\u652f\u6301\u3002<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\u8d75\u4e00\u65b0\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u73af\u5883\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u30022002\u5e74\u548c2005\u5e74\u6bd5\u4e1a\u4e8e\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\uff0c\u83b7\u5f97\u5e94\u7528\u5316\u5b66\u5b66\u58eb\u548c\u7855\u58eb\u5b66\u4f4d\u30022010\u5e74\u6bd5\u4e1a\u4e8e\u51ef\u65af\u897f\u50a8\u5927\u5b66\uff08Case Western Reserve University\uff09\u83b7\u5f97\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u535a\u58eb\u671f\u95f4\u4e3b\u8981\u7814\u7a76\u5f00\u53d1\u5e94\u7528\u4e8e\u80fd\u91cf\u8f6c\u5316\u7684\u529f\u80fd\u6750\u6599\u3002\u535a\u58eb\u6bd5\u4e1a\u540e\u5148\u540e\u5728\u5bbe\u5dde\u5dde\u7acb\u5927\u5b66\u548c\u7f8e\u56fd\u53ef\u518d\u751f\u80fd\u6e90\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u4ece\u4e8b\u53ef\u518d\u751f\u80fd\u6e90\u65b9\u9762\u7684\u7814\u7a76\u30022013\u5e74\u5165\u9009\u201c\u9752\u5e74\u5343\u4eba\u8ba1\u5212\u201d\u5e76\u5165\u804c\u4e0a\u6d77\u4ea4\u5927\u62c5\u4efb\u7279\u522b\u7814\u7a76\u5458\uff0c2018\u5e74\u664b\u5347\u4e3a\u6559\u6388\uff0c2015\u5e74\u5165\u9009\u6559\u80b2\u90e8\u970d\u82f1\u4e1c\u9752\u5e74\u57fa\u91d1\uff0c2017\u5e74\u5165\u9009\u4e0a\u6d77\u5e02\u201c\u66d9\u5149\u5b66\u8005\u201d\u3002\u5728Chem Rev\uff0cChem Soc Rev\uff0cScience Advances\uff0cNature Communication, PNAS, JACS, Energy Environ. Sci, Angew. Chem. Int. Ed., Nano Lett, EST \u7b49\u56fd\u9645\u6743\u5a01\u671f\u520a\u53d1\u8868\u8bba\u658790\u591a\u7bc7\uff0c\u88ab\u5f154400\u591a\u6b21, H-index 38, \u5176\u4e2d14\u7bc7\u4e00\u4f5c\u548c\u901a\u8baf\u4f5c\u8005\u8bba\u6587\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff081%\uff09\u3002<\/p>\n

 <\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4ebalyh_wv\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

 <\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37\uff01<\/strong>http:\/\/www.ceshigu.com\/<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u542b\u6c27\u81ea\u7531\u57fa\u51ed\u501f\u5176\u5f3a\u6c27\u5316\u6027\uff0c\u5728\u5316\u5b66\u5408\u6210\u548c\u73af\u5883\u4fee\u590d\u9886\u57df\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5728\u7ecf\u5178\u7684\u82ac\u987f\u53cd\u5e94\u4e2d\u4f7f\u7528\u7684\u7f9f\u57fa\u81ea\u7531\u57fa\uff08\u2022OH\uff0cEo=1.90-2.70V\uff09\u53ef\u4ee5\u964d\u89e3…<\/p>\n","protected":false},"author":871,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,113,33],"class_list":["post-133118","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-catalyst","tag-semiconductor","tag-nano"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/133118"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/871"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=133118"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/133118\/revisions"}],"predecessor-version":[{"id":133126,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/133118\/revisions\/133126"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=133118"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=133118"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=133118"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}