{"id":132948,"date":"2018-04-07T14:00:44","date_gmt":"2018-04-07T06:00:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=132948"},"modified":"2018-04-05T16:39:33","modified_gmt":"2018-04-05T08:39:33","slug":"energ-environ-sci-%ef%bc%9a%e5%90%ab%e8%bf%87%e6%b0%a7%e5%8c%96%e6%b0%a2%e6%94%be%e7%94%b5%e4%ba%a7%e5%93%81%e7%9a%84%e6%97%a0li2co3%e7%9a%84li-o2co2%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=132948","title":{"rendered":"Energ. Environ. Sci.\uff1a\u542b\u8fc7\u6c27\u5316\u6c22\u653e\u7535\u4ea7\u54c1\u7684\u65e0Li2CO3\u7684Li-O2\/CO2\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u57fa\u4e8e\u9502\u6c27\u5316\u5b66\u7684\u6781\u9ad8\u7684\u80fd\u91cf\u6f5c\u529b\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\u6210\u4e3a\u5f53\u524d\u6700\u5148\u8fdb\u7684\u9502\u79bb\u5b50\u7535\u6c60\u7684\u66ff\u4ee3\u54c1\u800c\u88ab\u63d0\u5347\u3002\u7136\u800c\uff0c\u7531\u4e8e\u73af\u5883\u7a7a\u6c14\u4e2d\u5b58\u5728\u975eO2<\/sub>\u6210\u5206\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u5b9e\u9645\u6027\u80fd\u4ec5\u9650\u4e8e\u51e0\u4e2a\u5468\u671f\u4e14\u80fd\u91cf\u6548\u7387\u4f4e\u3002\u7279\u522b\u662fCO2<\/sub>\u8fdb\u5165\u7535\u6c60\u7cfb\u7edf\uff0c\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u4e0d\u53ef\u907f\u514d\u5730\u5f62\u6210Li2<\/sub>CO3<\/sub>\uff0c\u8fd9\u5bfc\u81f4\u5145\u7535\u7535\u52bf\u7684\u4e25\u91cd\u6500\u5347\u548c\u76f8\u5173\u7535\u6c60\u7ec4\u4ef6\u7684\u5206\u89e3\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u65e5\u672c\u56fd\u7acb\u4ea7\u4e1a\u6280\u672f\u7efc\u5408\u7814\u7a76\u6240\u5468\u8c6a\u614e<\/b><\/strong>\u6559\u6388<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u8bfe\u9898\u7ec4<\/b><\/strong>\u7684\u5e26\u9886\u4e0b\uff0c\u4e0e\u5357\u4eac\u5927\u5b66\u3001<\/b><\/strong>\u65e5\u672c\u7b51\u6ce2\u5927\u5b66<\/b><\/strong>\u548c\u5929\u6d25\u7406\u5de5\u5927\u5b66<\/b><\/strong>\u5408\u4f5c\uff0c\u62a5\u9053\u4e86\u57fa\u4e8e\u8d85\u6d53\u7f29\u7535\u89e3\u8d28\u7684\u72ec\u7279\u529f\u80fd\uff0c\u5f15\u5165\u4e86\u7531DMSO-\u62a4\u5957\u63a5\u89e6\u79bb\u5b50\u5bf9\uff08CIP\uff09\u7ec4\u6210\u7684\u805a\u96c6\u7535\u89e3\u8d28\u4f53\u7cfb\u3002\u4e0e\u7a00\u91ca\u7535\u89e3\u8d28\u4e0d\u540c\uff0c\u5f15\u5165\u7684\u7535\u89e3\u8d28\u7ec4\u6210\u7684\u805a\u5408\u7269\u6d41\u4f53\u7f51\u7edc\u5c06\u6709\u6548\u6291\u5236\u5176\u4e0eLi+<\/sup>\u7684\u7ed3\u5408\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u8fc7\u6c27\u4e8c\u78b3\u9178\u916f\uff08C2<\/sub>O6<\/sub>2-<\/sup>\uff09\u800c\u4e0d\u662fLi2<\/sub>CO3<\/sub>\u3002Li-O2<\/sub>\/CO2<\/sub>\u7535\u6c60\u5177\u6709\u8d85\u4f4e\u5145\u7535\u7535\u52bf\uff083.5V vs.Li\/Li+<\/sup>\uff09\u548c\u8fd0\u884c100\u6b21\u4ee5\u4e0a\u7684\u5faa\u73af\u5bff\u547d\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cA Li<\/b><\/strong>2<\/b><\/sub><\/strong>CO<\/b><\/strong>3<\/b><\/sub><\/strong>-Free Li-O<\/b><\/strong>2<\/b><\/sub><\/strong>\/CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0Battery with Peroxide Discharge Product<\/b><\/strong>\u201d\u53d1\u8868\u5728\u4e86Energ. Environ. Sci.<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>1 <\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5bf9\u975e\u8d28\u5b50\u6c27\u51cf\u5c11\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u5404\u79cd\u4f53\u79ef\u6bd4\u7684O2<\/sub>\/CO2<\/sub>\u6df7\u5408\u6c14\u4f53\u5728\uff08a\uff09\u4e0d\u542bLi\u7684TBAClO4<\/sub>\/DMSO\u548c\uff08b\uff09\u542bLi\u7684TBAClO4<\/sub>\/DMSO\u7684\u7535\u89e3\u8d28\uff0c\u5728400mA\/g\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08c-f\uff09\u5728\u76f8\u5e94\u5145\u653e\u7535\u72b6\u6001\u4e0b\u8bb0\u5f55\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff1a\uff08c\uff09\u4e0d\u540cO2<\/sub>\/CO2<\/sub>\u6bd4\u7387\u7684\u65e0Li\u7535\u6c60\u8bb0\u5f55\u7684\u653e\u7535\u72b6\u6001\u7ed3\u675f\uff1b\uff08d\uff09\u5728\u5177\u6709\u7279\u5b9a\u7684O2<\/sub>\/CO2<\/sub>\u6bd4\u7387\uff084\/1\u4f53\u79ef\u6bd4\uff09\u7684\u65e0Li\u7535\u6c60\u4e2d\u5faa\u73af\u671f\u95f4\u8bb0\u5f55\u7684\u7279\u5b9a\u70b9\uff0c\u5e76\u901a\u8fc7Gaussian-Lorentzian\u5206\u5e03\u51fd\u6570\u62df\u5408\uff1b\uff08e\uff09\u4e0d\u540cO2<\/sub>\/CO2<\/sub>\u6bd4\u7387\u7684\u542bLi\u7535\u6c60\u5728\u6bcf\u6b21\u653e\u7535\u7ed3\u675f\u65f6\u6536\u96c6\u7684\u5149\u8c31\uff1b\uff08f\uff09\u4e0d\u540cO2<\/sub>\/CO2<\/sub>\u6bd4\u7387\u7684\u542bLi\u7535\u6c60\u5728\u6bcf\u6b21\u5145\u7535\u7ed3\u675f\u65f6\u6536\u96c6\u7684\u5149\u8c31\u3002<\/p>\n

\u56fe<\/b><\/strong>2 <\/b><\/strong>\u7535\u89e3\u8d28\u7ed3\u6784\u7684\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\uff08b\uff09\u5177\u6709\u4e0d\u540c\u6469\u5c14\u6bd4\u7684LiTFSI\/DMSO\u6eb6\u6db2\u7684\u62c9\u66fc\u5149\u8c31\u3002\u5149\u8c31\u901a\u8fc7Gaussian-Lorentzian\u5206\u5e03\u51fd\u6570\u62df\u5408\uff0c\u5e76\u4e14TFSI–<\/sup>\uff08\u84dd\u8272\u8f6e\u5ed3\uff09\u4e2d\u7684SNS\u62c9\u4f38\u533a\u57df\u88ab\u653e\u5927\u3002\u5728\u6469\u5c14\u6bd4\u4e3a1\uff1a3\u7684LiTFSI\/DMSO\u7535\u89e3\u8d28\u4e2d\uff0c\u4e0d\u80fd\u89c2\u5bdf\u5230\u6e38\u79bb\u7684DMSO\u5206\u5b50\u548c\u6eb6\u5242\u5206\u79bb\u79bb\u5b50\u5bf9\uff08SSIP\uff09\u3002\u76f8\u53cd\uff0c\u88abDMSO\u5206\u5b50\u5305\u88f9\uff0cLi+<\/sup>\u548cTFSI–<\/sup>\u5728\u63a5\u89e6\u79bb\u5b50\u5bf9\uff08CIP\uff09\u6d41\u4f53\u7f51\u7edc\u5185\u5b8c\u5168\u805a\u96c6\uff08AGG\uff09\uff1b<\/p>\n

\uff08c\uff09\u65b0\u5f15\u5165\u7684\u7531[Li(DMSO)3<\/sub>] +<\/sup>-[TFSI–<\/sup>]\u7ec4\u6210\u7684\u8d85\u6d53\u7f29\u6d41\u4f53\u7f51\u7edc\u7535\u89e3\u6db2\u7684\u793a\u610f\u56fe\u3002\u7531\u4e8eCIP\u7ec4\u6210\u7684\u7535\u89e3\u8d28\u4f53\u7cfb\u7684\u7535\u4e2d\u6027\uff0cLi\u9633\u79bb\u5b50\u548cC2<\/sub>O6<\/sub>2-<\/sup>\u9634\u79bb\u5b50\u4e4b\u95f4\u7684\u7535\u76f8\u4e92\u4f5c\u7528\u53ef\u4ee5\u88ab\u6709\u6548\u5730\u963b\u65ad\uff0c\u8fdb\u800c\u4eceC2<\/sub>O6<\/sub>2-<\/sup>\u5230CO3<\/sub>2-<\/sup>\u7684\u8fd8\u539f\u4e5f\u53ef\u4ee5\u88ab\u6291\u5236\u3002<\/p>\n

\u56fe<\/b><\/strong>3 <\/b><\/strong>\u7535\u5316\u5b66\u548c\u5149\u8c31\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u4e0d\u540c\u6469\u5c14\u6bd4\u7684LiTFSI \/ DMSO\u7535\u89e3\u8d28\u4e2d\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\uff1a400mA\/g\u64cd\u4f5cLi-O2<\/sub>\/CO2<\/sub>\u7535\u6c60\uff081\uff1a1\u4f53\u79ef\u6bd4\uff09\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

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\uff08i\uff0cj\uff09\u5728\u4e0d\u540cLiTFSI\uff1aDMSO\u6469\u5c14\u6bd4\u7684\u7535\u6c60\u5728\u5145\u7535\u671f\u95f4\uff0cCO2<\/sub>\u548cO2<\/sub>\u7684\u6c14\u4f53\u91ca\u653e\u901f\u7387\u7684DEMS\u7ed3\u679c\uff1a\uff08i\uff091:\uff1a20\u548c\uff08j\uff091\uff1a3\u3002\u7531\u865a\u7ebf\u6807\u8bb0\u7684\u7535\u5b50\u6570\uff08\u76f8\u5bf9\u4e8eCO2<\/sub>\u548cO2<\/sub>\u6c14\u4f53\u5206\u5b50\uff09\u5bf9\u5e94\u4e8e\u6240\u5217\u7684\u7279\u5b9a\u53cd\u5e94\u8def\u5f84\u3002<\/p>\n

\u56fe<\/b><\/strong>4 <\/b><\/strong>Li-O<\/b><\/strong>2<\/b><\/sub><\/strong>\/CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u7279\u5b9aLiTFSI\/DMSO\u6469\u5c14\u6bd4\uff081\uff1a3\uff0c\u6469\u5c14\u6bd4\uff09\u7535\u89e3\u8d28\u7684Li-O2<\/sub>\/CO2<\/sub>\u7535\u6c60\uff081\uff1a1\uff0c\u4f53\u79ef\u6bd4\uff09\u7684\u6052\u7535\u6d41\u7535\u538b\u66f2\u7ebf\u3002\uff08a\uff09\u7535\u6d41\u5bc6\u5ea6\u4ece200\u5230600mA\/g\u7684\u521d\u59cb\u5faa\u73af\u3002\uff08b\uff09\u5728400mA\/g\u4e0b\u7535\u4f4d\u6781\u9650\u4ece6\u52303.65V\u768420\u4e2a\u5faa\u73af\u7684\u5168\u90e8\u5145\u653e\u7535\u66f2\u7ebf;<\/p>\n

\uff08c\uff09\u5728\u56fa\u5b9a\u5bb9\u91cf200mAh\/g\uff08\u5728400mA\/g\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff09\u7684\u5faa\u73af\u671f\u95f4\uff0c\u5728\u5178\u578b\u7684\u5faa\u73af\u4e2d\u6bcf\u6b21\u653e\u7535\uff08\u7ea2\u8272\uff09\u548c\u5145\u7535\uff08\u84dd\u8272\uff09\u72b6\u6001\u7ed3\u675f\u65f6\u6536\u96c6\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n

\u603b\u4e4b\uff0c\u4e3a\u4e86\u5f25\u8865\u4f20\u7edfLi-O2<\/sub>\/CO2<\/sub>\u7535\u6c60\u7684\u56fa\u6709\u7f3a\u9677\uff0c\u5f15\u5165\u4e00\u79cd\u7531DMSO\u6eb6\u5242\u5316\u7684\u63a5\u89e6\u79bb\u5b50\u5bf9\uff08CIP\uff09\u7ec4\u6210\u7684\u8d85\u6d53\u7f29\u7535\u89e3\u8d28\u3002\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u7535\u89e3\u6db2\u4f53\u7cfb\u5185\u7684\u805a\u5408\u7269\u6d41\u4f53\u7f51\u7edc\u901a\u8fc7\u963b\u65ad\u8fdb\u4e00\u6b65\u8fd8\u539f\u6210Li2<\/sub>CO3<\/sub>\u6765\u6709\u6548\u5730\u7a33\u5b9a\u8fc7\u6c27\u5316\u4e8c\u78b3\u9178\u916f\uff0c\u8fd9\u6210\u529f\u5730\u5bfc\u81f4\u5145\u7535\u7535\u52bf\u7684\u663e\u7740\u964d\u4f4e\u5e76\u663e\u7740\u63d0\u9ad8\u80fd\u91cf\u6548\u7387\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8fd9\u4e0d\u4ec5\u5f25\u8865\u4e86\u63ba\u5165CO2<\/sub>\u7684Li-O2<\/sub>\u7535\u5316\u5b66\u7684\u56fa\u6709\u7f3a\u9677\uff0c\u800c\u4e14\u4e3a\u66f4\u5b9e\u7528\u7684\u9502\u7a7a\u6c14\u7535\u6c60\u7cfb\u7edf\u94fa\u5e73\u4e86\u9053\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>A Li<\/u>2<\/sub><\/u>CO<\/u>3<\/sub><\/u>-Free Li-O<\/u>2<\/sub><\/u>\/CO<\/u>2<\/sub><\/u>\u00a0Battery with Peroxide Discharge Product<\/u><\/a>\uff08Energ. Environ. Sci.<\/b><\/strong>,\u00a02018, DOI: 10.1039\/C7EE03341A\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n

\u5468\u8c6a\u614e \u6559\u6388\uff0c<\/strong>\u957f\u6c5f\u5b66\u8005\u3001973\u9996\u5e2d\u79d1\u5b66\u5bb6\u3001\u5357\u4eac\u5927\u5b66\u4e2d\u7ec4\u90e8\u7279\u8058\u201c\u5343\u4eba\u8ba1\u5212\u201d\u4e13\u5bb6\u3001\u65e5\u672c\u4ea7\u4e1a\u7814\u7a76\u6240\uff08AIST\uff09 \u9996\u5e2d\u7814\u7a76\u5458\u3001\u65e5\u672c\u56fd\u7acb\u4e1c\u4eac\u5927\u5b66 \u7279\u8058\u6559\u6388\u3001\u65e5\u672c\u56fd\u7acb\u7b51\u6ce2\u5927\u5b66 \u7279\u8058\u6559\u6388\u3002<\/p>\n

\uff081\uff09\u80fd\u6e90\u3001\u7535\u6c60\u9886\u57df\u6587\u7ae0\u5217\u8868<\/strong>\uff1a<\/p>\n

Nature Materials; Nature\u00a0Energy; Nature Commun.\uff085\u7bc7\uff09; Angew. Chem. Int. Ed.\uff0812\u7bc7\uff09; Energy Environment Sci.\uff0825\u7bc7\uff09; Adv. Mater.\uff0817\u7bc7\uff09\u3001JACS\uff085\u7bc7\uff09; Adv. Energy Mater.; Nano Letter\uff1bACS Nano\uff1bAdv. Fun. Mater.\u7b49\u5b66\u672f\u520a\u7269\u4e0a\u53d1\u8868\u8bba\u6587\u8d85300 \u7bc7\uff0c\u5176\u4e2dIF>10.0 \u7684\u8d85110\u7bc7\uff0c\u4ed6\u5f15\u8d8528047\u00a0\u6b21\uff0c\u5355\u7bc7\u5f15\u7528\u8d85\u8fc7100\u6b21\u7684\u8bba\u658770\u4f59\u7bc7\uff0cH \u56e0\u5b5088 \uff08\u6570\u636e\u6765\u6e90\u8c37\u6b4c\u5b66\u672f\uff09\u3002<\/p>\n

\uff082\uff09\u80fd\u6e90\u7535\u6c60\u9886\u57df\u4e13\u5229\u3001\u4f01\u4e1a\u5408\u4f5c\uff1a<\/strong><\/p>\n

NEDO\uff0cJST\uff0cJSPS\u7b49\u65e5\u672c\u56fd\u5bb6\u5927\u578b\u7814\u7a76\u9879\u76ee\uff0c\u540c\u65f6\u4e3b\u6301\u591a\u9879\u4e0e\u65e5\u672c\u7684\u6c7d\u8f66\u3001\u5316\u5de5\u3001\u7535\u529b\u7b49\u9886\u57df\u77e5\u540d\u516c\u53f8\u5408\u4f5c\u7684\u7814\u53d1\u9879\u76ee\u3002\u76ee\u524d\uff0c\u5df2\u53d6\u5f97\u4e13\u522930\u4f59\u9879\uff0c\u8f6c\u8ba9\u6280\u672f\u5e76\u88ab\u63a8\u5411\u4ea7\u4e1a\u7684\u67092\u9879\u3002<\/p>\n

\u56e2\u961f<\/strong>\u5728\u8be5<\/strong>\u9886\u57df<\/strong>\u7684\u5de5\u4f5c\u6c47\u603b<\/strong>\uff1a<\/strong><\/p>\n

\uff081\uff09\u4f20\u7edf\u9502\u6c27\u6c14\u7535\u6c60\u65b9\u5411\uff1a<\/strong>\u56e2\u961f\u5728\u7535\u6781\u50ac\u5316\u5242\u548c\u7535\u89e3\u6db2\u4f18\u5316\u7814\u7a76\u65b9\u5411\uff0c\u53d1\u8868\u4e86\u8bb8\u591a\u7814\u7a76\u6210\u679c\uff1a\u5185\u5bb9\u6d89\u53ca\u948c\u7cfb\u50ac\u5316\u5242\u7684\u4f18\u5316\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u7814\u53d1\uff0c\u7845\u8d1f\u6781\u5168\u7535\u6c60\u7684\u5f15\u5165\uff0c\u4ee5\u53ca\u7535\u89e3\u6db2\u9632\u8fc7\u5145\u6dfb\u52a0\u5242\u7684\u5f15\u5165\u3002\u76f8\u5173\u7684\u6587\u732e\u5982\u4e0b\uff1a<\/p>\n

1 Nature Commun.\u00a04, 1817 (2013).<\/p>\n

2 Angew. Chem.-Int. Edit.\u00a053, 442-446 (2014).<\/p>\n

3 Adv Mater\u00a026, 4659 (2014).<\/p>\n

4 Energy Environ Sci\u00a09, 3262-3271 (2016).<\/p>\n

5 Energy Environ. Sci.\u00a07, 1648-1652 (2014).<\/p>\n

6 Energy Environ. Sci.\u00a08, 1992-1997 (2015).<\/p>\n

7 Energy Environ. Sci.\u00a08, 2664-2667 (2015).<\/p>\n

8 Energy Environ. Sci.\u00a09, 1024-1030 (2016).<\/p>\n

9 Energy Environ. Sci.\u00a04, 4994-4999 (2011).<\/p>\n

10 Adv. Energy Mater.\u00a03, 532-538 (2013).<\/p>\n

11 ACS Energy Letters, 1378-1384 (2017).<\/p>\n

\uff082\uff09\u5728\u9502\u6c27\u6c14\u7535\u6c60\u5411\u9502\u7a7a\u6c14\u7535\u6c60\u8f6c\u53d8\u7684\u7814\u7a76\u65b9\u5411\uff1a:<\/strong>\u8bfe\u9898\u7ec4\u8fd1\u671f\u53d1\u8868\u4e86\u8bb8\u591a\u7814\u7a76\u6210\u679c\uff0c\u5185\u5bb9\u6d89\u53ca\u7a7a\u6c14\u4e2d\u6c34\u5bf9\u4e8e\u5145\u653e\u7535\u673a\u7406\u7684\u5f71\u54cd\uff0c\u6c34\u5bf9\u4e8e\u7535\u89e3\u6db2\u4ee5\u53ca\u6dfb\u52a0\u5242\u7684\u5f71\u54cd\uff0c\u4e8c\u6c27\u5316\u78b3\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u8d28\u8c31\u5206\u6790\uff0c\u4ee5\u53ca\u7eaf\u4e8c\u6c27\u5316\u78b3\u7535\u6c60\u7684\u673a\u7406\u7814\u7a76\u7b49\u3002\u76f8\u5173\u7684\u6587\u732e\u5982\u4e0b\uff1a<\/p>\n

1 Nat. Common.\u00a06, 8843 (2015).<\/p>\n

2 Nature Comm.\u00a08, 15607 (2017).<\/p>\n

3 Angew. Chem. Int. Ed.\u00a056, 4960-4964 (2017).<\/p>\n

4 Joule\u00a01, 359-370 (2017).<\/p>\n

5 Energy Environ. Sci.\u00a09, 1650-1654 (2016).<\/p>\n

6 Energy Environ. Sci.\u00a010, 972-978 (2017).<\/p>\n

7 Energy Environ Sci, doi. 10.1039\/C1037EE03341A (2018).-(\u672c\u6587)<\/p>\n

8 Adv. Energy Mater.\u00a07, 1601759 (2017).<\/p>\n

9 ACS Catalysis\u00a08, 1082-1089 (2018).<\/p>\n

10 Adv Funct Mater\u00a026, 3291-3298 (2016).<\/p>\n

\u76f8\u5173\u4f18\u8d28\u6587\u732e<\/strong>\u63a8\u8350<\/strong>\uff1a<\/strong><\/p>\n

\uff081\uff09\u8bfe\u9898\u7ec4\u76f8\u5173\u5de5\u4f5c\u63a8\u8350\uff1a<\/strong><\/p>\n

1.Qiao, Y., Yi, J., Wu, S., Liu, Y., Yang, S., He, P. & Zhou, H., Li-CO2<\/sub>Electrochemistry: A New Strategy for CO2 <\/sub>Fixation and Energy Storage. Joule.1<\/strong>, 359-370 (2017).<\/p>\n

2.Yang, S., He, P. & Zhou, H., Exploring the electrochemical reaction mechanism of carbonate oxidation in Li-air\/CO2<\/sub>battery through tracing missing oxygen. Energy Environ. Sci.9<\/strong>, 1650-1654 (2016).<\/p>\n

3.Yang, S., Qiao, Y., He, P., Liu, Y., Cheng, Z., Zhu, J.-j. & Zhou, H., A reversible lithium-CO2 battery with Ru nanoparticles as a cathode catalyst. Energy Environ. Sci.<\/em>10<\/strong>, 972-978 (2017).<\/p>\n

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1 Gowda, S. R., Brunet, A., Wallraff, G. M. & McCloskey, B. D., Implications of CO2<\/sub>\u00a0Contamination in Rechargeable Nonaqueous Li-O2<\/sub>\u00a0Batteries. J. Phys. Chem. Lett.\u00a04<\/strong>, 276-279 (2013).<\/p>\n

2 Lim, H. K., Lim, H. D., Park, K. Y., Seo, D. H., Gwon, H., Hong, J., Goddard, W. A., Kim, H. & Kang, K., Toward a Lithium-“Air” Battery: The Effect of CO2 <\/sub>on the Chemistry of a Lithium-Oxygen Cell. J. Am. Chem. Soc.\u00a0135<\/strong>, 9733-9742 (2013).<\/p>\n

23 Liu, Y., Wang, R., Lyu, Y., Li, H. & Chen, L., Rechargeable Li\/CO2<\/sub>-O2<\/sub>\u00a0(2 : 1) battery and Li\/CO2<\/sub>\u00a0battery. Energy Environ. Sci.\u00a07<\/strong>, 677-681 (2014).<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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