{"id":132536,"date":"2018-04-02T14:00:37","date_gmt":"2018-04-02T06:00:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=132536"},"modified":"2018-04-01T20:09:15","modified_gmt":"2018-04-01T12:09:15","slug":"%e8%b0%a2%e6%af%85joule%ef%bc%9a%e7%ba%a2%e5%a4%96%e5%85%89%e9%a9%b1%e5%8a%a8%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e5%9c%a8%e5%ae%a4%e6%b8%a9%e4%b8%8b%e6%95%b4%e4%bd%93%e5%88%86%e8%a7%a3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=132536","title":{"rendered":"\u8c22\u6bc5Joule\uff1a\u7ea2\u5916\u5149\u9a71\u52a8\u4e8c\u6c27\u5316\u78b3\u5728\u5ba4\u6e29\u4e0b\u6574\u4f53\u5206\u89e3"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u592a\u9633\u80fd\u4e8c\u6c27\u5316\u78b3\u6574\u4f53\u5206\u89e3\u6210\u78b3\u6c22\u5316\u5408\u7269\u548c\u6c27\u6c14\uff0c\u5176\u4e2d\u6c34\u4f5c\u4e3a\u8d28\u5b50\u6e90\u5e76\u4ecb\u5bfc\u7535\u5b50\u8f6c\u79fb\uff0c\u4ee3\u8868\u4e86\u592a\u9633\u80fd\u8f6c\u6362\u7684\u7ec8\u6781\u201c\u5723\u676f\u201d\u6280\u672f\u3002\u7136\u800c\uff0c\u7531\u4e8e\u7ea2\u5916\u5149\u5229\u7528\u548c\u4e8c\u6c27\u5316\u78b3\u5149\u8fd8\u539f\u4e4b\u95f4\u4e0d\u53ef\u903e\u8d8a\u7684\u77db\u76fe\uff0c\u8fc4\u4eca\u4e3a\u6b62\uff0c\u8fd150\uff05\u592a\u9633\u80fd\u7684\u7ea2\u5916\uff08IR\uff09\u5149\u4ece\u672a\u88ab\u5229\u7528\u8fc7\u3002\u4f8b\u5982\uff0c\u4ece\u7406\u8bba\u4e0a\u8bb2\uff0cCO\u5206\u89e3\u4e3aCO\u548cO2<\/sub>\u9700\u89811.35 eV\uff0c\u8fd9\u610f\u5473\u7740920 nm\u4ee5\u4e0a\u7684\u7ea2\u5916\u5149\u4e0d\u80fd\u540c\u65f6\u89e6\u53d1\u4e24\u4e2a\u534a\u53cd\u5e94\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u8c22\u6bc5\u3001\u5b59\u6c38\u798f\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u4e3a\u4e86\u7a81\u7834\u4e0a\u8ff0\u5c40\u9650\u6027\uff0c\u8bbe\u8ba1\u4e86\u8d85\u8584\u4e2d\u9891\u5e26\u534a\u5bfc\u4f53\uff0c\u56e0\u6b64\u9996\u5148\u5b9e\u73b0\u4e86IR\u9a71\u52a8\u7684CO2<\/sub>\u5728\u5355\u4e00\u6750\u6599\u4e0a\u7684\u6574\u4f53\u5206\u89e3\u3002\u4ee5\u5408\u6210\u7684\u8d85\u8584\u7acb\u65b9WO3<\/sub>\u5c42\u4e3a\u4f8b\uff0c\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u4ea7\u751f\u7684\u6c27\u7a7a\u4f4d\u8fbe\u5230\u4e34\u754c\u5bc6\u5ea6\u540e\uff0c\u4ea7\u751f\u4e2d\u95f4\u5e26\uff0c\u53ef\u7531\u540c\u6b65\u8f90\u5c04\u4ef7\u5e26\u8c31\uff0c\u5149\u81f4\u53d1\u5149\u5149\u8c31\uff0c\u7d2b\u5916-\u53ef\u89c1-\u8fd1\u7ea2\u5916\u5149\u8c31\uff0c \u548c\u540c\u6b65\u8f90\u5c04\u7ea2\u5916\u53cd\u5c04\u5149\u8c31\u8bc1\u5b9e\u3002\u7ed3\u679c\uff0c\u7f3a\u6c27\u7684WO3<\/sub>\u539f\u5b50\u5c42\u663e\u793aIR\u9a71\u52a8\u7684CO2<\/sub>\u5168\u90e8\u5206\u89e3\u6210CO\u548cO2<\/sub>\uff0c\u800c\u5176\u50ac\u5316\u6d3b\u6027\u5373\u4f7f\u57283\u5929\u540e\u4e5f\u6ca1\u6709\u5931\u6d3b\u3002\u6b64\u5916\uff0c\u66f4\u9ad8\u7684\u6c27\u7a7a\u4f4d\u6d53\u5ea6\u6709\u5229\u4e8eCO2<\/sub>\u5438\u9644\u548c\u6d3b\u5316\u6210COOH *\u81ea\u7531\u57fa\uff0c\u56e0\u6b64\u4fdd\u8bc1\u4e86CO\u548cO2<\/sub>\u5f62\u6210\u901f\u7387\u7684\u589e\u52a0\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cInfrared Light-Driven CO2\u00a0Overall Splitting at Room Temperature<\/strong>\u201d\u53d1\u8868\u5728\u4e86Joule<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u5bccVo<\/sub>\u7684WO3<\/sub>\u539f\u5b50\u5c42\u7684<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A-D\uff09TEM\u56fe\u50cf\uff08A\uff09\u548c\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\uff08B;\u7ea2\u8272\u7f51\u683c\u7ebf\u8868\u793a\u6676\u683c\u65e0\u5e8f\uff09; \uff08C\uff09\u5bf9\u5e94\u4e8e\uff08D\uff09\u4e2dAFM\u56fe\u50cf\u7684\u9ad8\u5ea6\u8f6e\u5ed3<\/p>\n

\uff08E\u548cF\uff09\u5bf9\u4e8e\u5bccVo<\/sub>\u7684WO3<\/sub>\u539f\u5b50\u5c42\uff0c\u8d2bVo<\/sub>\u7684WO3<\/sub>\u539f\u5b50\u5c42\u548cWO3<\/sub>\u539f\u5b50\u5c42\u7684ESR\u8c31\uff08E\uff09\u548cO 1s XPS\u8c31\uff08F\uff09<\/p>\n

\u56fe2 \u5149\u6fc0\u53d1\u884c\u4e3a\u4e0e\u5b9e\u9a8c\u8c31\u5e26\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08A-E\uff09\u5149\u5438\u6536\u8c31\uff08A\uff09\u548c\u76f8\u5e94\u7684\u5149\u5b66\u5e26\u9699\uff08B;\u57282,500nm\u5904\u7684\u865a\u7ebf\u6307\u793a\u6570\u636e\u8fde\u63a5\u7684\u4f4d\u7f6e\uff09; \uff08C\uff09SRPES\u4ef7\u5e26\u8c31\u548c-1.0\u81f32.0eV\u4e4b\u95f4\u7684\u76f8\u5e94\u653e\u5927\u8c31; \uff08D\uff09\u5728785nm\u6fc0\u53d1\u4e0b\u7684\u5149\u81f4\u53d1\u5149\u5149\u8c31; \uff08E\uff09\u901a\u8fc7SRPES\u5149\u8c31\u6d4b\u91cf\u7684\u4e8c\u6b21\u7535\u5b50\u622a\u6b62\uff08Ecutoff\uff09<\/p>\n

\uff08F\uff09\u7535\u5b50\u8c31\u5e26\u7684\u7ed3\u6784\u56fe\u793a<\/p>\n

\u56fe3 CO2<\/sub>\u5149\u8fd8\u539f\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09\u5728\u6c2e\u5316\u7845\u706f\u7167\u5c04\u4e0b\u4ee5\u53ca\u5728\u9ed1\u6697\u4e2d60\u2103\u4e0b\u7684CO\u548cO2<\/sub>\u5f62\u6210\u901f\u7387<\/p>\n

\uff08B\uff0913<\/sup>CO2<\/sub>\u5149\u8fd8\u539f\u540e\u4ea7\u7269\u7684SVUV-PIMS\u8c31\u56fe<\/p>\n

\uff08C\uff09\u8868\u89c2\u91cf\u5b50\u6548\u7387\uff08\uff05\uff09<\/p>\n

\uff08D\uff09CO\u6f14\u53d8\u7684\u5faa\u73af\u66f2\u7ebf<\/p>\n

\uff08E\uff09CO2<\/sub> TPD\u5149\u8c31<\/p>\n

\uff08F\uff09\u5728\u5bccVo<\/sub>\u7684WO3<\/sub>\u539f\u5b50\u5c42\u4e0aIR\u5149\u9a71\u52a8\u7684CO2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u7684\u539f\u4f4dFTIR\u5149\u8c31<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8fd9\u9879\u5de5\u4f5c\u4e3a\u8bbe\u8ba1IR\u9a71\u52a8\u7684\u5149\u50ac\u5316\u53cd\u5e94\u5982\u6c34\u5206\u89e3\u548cN2<\/sub>\u8fd8\u539f\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8\u4e86\u592a\u9633\u80fd\u5229\u7528\u6548\u7387\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Infrared Light-Driven CO2 Overall Splitting at Room Temperature<\/a> \uff08Joule,2018,DOI:10.1016\/j.joule.2018.02.019\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002
\n <\/b><\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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