{"id":132436,"date":"2018-04-02T06:30:04","date_gmt":"2018-04-01T22:30:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=132436"},"modified":"2018-04-09T19:14:35","modified_gmt":"2018-04-09T11:14:35","slug":"%e6%96%b0%e5%9e%8b%e5%87%86%e4%b8%80%e7%bb%b4%e5%90%84%e5%90%91%e5%bc%82%e6%80%a7%e7%9a%84%e5%b1%82%e7%8a%b6%e6%9d%90%e6%96%99%ef%bc%9a%e7%a2%b1%e9%87%91%e5%b1%9e%e8%bf%87%e7%a3%b7%e5%8c%96%e7%89%a9mp","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=132436","title":{"rendered":"\u65b0\u578b\u51c6\u4e00\u7ef4\u5404\u5411\u5f02\u6027\u7684\u5c42\u72b6\u6750\u6599\uff1a\u78b1\u91d1\u5c5e\u8fc7\u78f7\u5316\u7269MP15(M=Li, Na, K)"},"content":{"rendered":"<p>\u4ee5\u77f3\u58a8\u70ef\uff08graphene\uff09\u4e3a\u4ee3\u8868\u7684\u4e8c\u7ef4\u6750\u6599\u56e0\u5176\u72ec\u7279\u7684\u5c42\u72b6\u7ed3\u6784\u548c\u591a\u6837\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u81ea\u8bde\u751f\u4e4b\u521d\u5c31\u53d7\u5230\u4e86\u79d1\u5b66\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u65b0\u578b\u4e8c\u7ef4\u6750\u6599\u4e0d\u65ad\u88ab\u5f00\u53d1\u51fa\u6765\uff0c\u5176\u79cd\u7c7b\u5df2\u8d85\u8fc7200\u79cd\u3002\u76f8\u6bd4\u8f83\u77f3\u58a8\u70ef\u3001\u786b\u5316\u94bc\uff08MoS<sub>2<\/sub>\uff09\u7b49\u5177\u6709\u8f83\u9ad8\u6676\u683c\u5bf9\u79f0\u6027\u7684\u4e8c\u7ef4\u6676\u4f53\uff0c\u540c\u65f6\u8fd8\u5b58\u5728\u4e00\u7c7b\u4f4e\u5bf9\u79f0\u6027\u7684\u4e8c\u7ef4\u6750\u6599\uff0c\u5728\u4e8c\u7ef4\u9762\u5185\u5b58\u5728\u5404\u5411\u5f02\u6027\uff0c\u8f83\u666e\u901a\u4e8c\u7ef4\u6750\u6599\u5177\u6709\u66f4\u52a0\u4e30\u5bcc\u6709\u8da3\u7684\u6027\u8d28\u3002\u76ee\u524d\u5404\u5411\u5f02\u6027\u7684\u4e8c\u7ef4\u6750\u6599\u4e3b\u8981\u5305\u62ec\u8936\u76b1\u8702\u7a9d\u72b6\u7684\u4e8c\u7ef4\u9ed1\u78f7\u53ca\u5176\u5408\u91d1\u3001\u626d\u66f21T\u76f8\u7ed3\u6784\u7684\u8fc7\u6e21\u91d1\u5c5e\u786b\u65cf\u5316\u7269\uff081T\u2019-TMDs\uff09\u3001\u6b63\u4ea4\u76f8\u7684IV\u65cf\u91d1\u5c5e\u786b\u65cf\u5316\u7269\uff08GIVMCs\uff09\u4ee5\u53ca\u4e00\u4e9bIV-V\u65cf\u534a\u5bfc\u4f53\uff08\u5982GeAs\uff09\u7b49\u3002\u7136\u800c\uff0c\u8584\u5c42\u9ed1\u78f7\u4f1a\u56e0\u5149\u81f4\u6c27\u5316\u800c\u53d1\u751f\u964d\u89e3\uff0c\u5316\u5b66\u7a33\u5b9a\u6027\u6b20\u4f73\uff1b\u91d1\u5c5e\u786b\u5316\u7269\u534a\u5bfc\u4f53\u4e2d\u7684\u672c\u5f81\u7f3a\u9677\u8f83\u591a\u3002\u56e0\u6b64\uff0c\u5bfb\u627e\u6027\u8d28\u7a33\u5b9a\u3001\u6027\u80fd\u4f18\u5f02\u53ca\u6210\u672c\u4f4e\u5ec9\u7684\u65b0\u578b\u5404\u5411\u5f02\u6027\u4e8c\u7ef4\u6750\u6599\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u5f20\u6c38\u54f2\u6559\u6388\u4e0e\u5218\u4e39\u654f\u6559\u6388\u8054\u5408\u56e2\u961f\u4f7f\u7528\u7406\u8bba\u9884\u6d4b\u4e0e\u5b9e\u9a8c\u7ed3\u5408\u7684\u65b9\u6cd5\u7814\u7a76\u4e86\u4e00\u7c7b\u65b0\u578b\u51c6\u4e00\u7ef4\u5404\u5411\u5f02\u6027\u7684\u5c42\u72b6\u6750\u6599\uff1a\u78b1\u91d1\u5c5e\u8fc7\u78f7\u5316\u7269MP<sub>15 <\/sub>(M=Li, Na, K)\u3002\u8fd9\u7c7b\u6750\u6599\u5177\u6709\u5bf9\u79f0\u6027\u6781\u4f4e\u7684\u4e09\u659c\u6676\u4f53\u7ed3\u6784\uff0c\u5c5e\u4e8eP1<sup>&#8211;<\/sup>\uff08NO.2\uff09\u7a7a\u95f4\u7fa4\uff0c\u786e\u4fdd\u4e86MP<sub>15<\/sub>\u7684\u5e73\u9762\u9ad8\u5404\u5411\u5f02\u6027\u3002\u7406\u8bba\u8ba1\u7b97\u53d1\u73b0\u8fd9\u7c7b\u6750\u6599\u5177\u6709\u95f4\u63a5\u5e26\u9699\u534a\u5bfc\u4f53\u6027\u8d28\uff0c\u5e26\u9699\u968f\u5c42\u6570\u53d8\u5316\u5e45\u5ea6\u8f83\u5c0f\uff0c\u5e76\u4e14\u5bfc\u5e26\u80fd\u7ea7\u8fdc\u4f4e\u4e8e\u6c34\u6c27\u53d7\u4f53\u7684\u6c27\u5316\u80fd\u7ea7\uff0c\u5177\u6709\u4f18\u5f02\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u5bf9\u4e8e\u5355\u5c42MP<sub>15<\/sub>\uff0c\u5176\u8f7d\u6d41\u5b50\u6cbf[P<sup>&#8211;<\/sup><sub>15<\/sub>]\u65b9\u5411\u7684\u8fc1\u79fb\u7387\u8fdc\u5927\u4e8e\u9762\u5185\u7684\u5782\u76f4\u65b9\u5411\uff0c\u5e76\u4e14\u5728\u8be5\u65b9\u5411\u4e0a\u7a7a\u7a74\u8f83\u7535\u5b50\u5177\u6709\u66f4\u9ad8\u7684\u8fd0\u52a8\u901f\u5ea6\uff0c\u662f\u4e00\u7c7b\u5177\u5907\u9ad8\u5404\u5411\u5f02\u6027\u3001\u6f5c\u5728\u9ad8\u8fc1\u79fb\u7387\u5e76\u4e14\u5316\u5b66\u6027\u8d28\u7a33\u5b9a\u7684\u65b0\u578b\u5c42\u72b6\u6750\u6599\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-132437\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-94.jpg\" alt=\"\" width=\"732\" height=\"421\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-94.jpg 732w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-94-300x173.jpg 300w\" sizes=\"(max-width: 732px) 100vw, 732px\" \/><\/p>\n<p><strong>\u56fe1.<\/strong> (a) MP<sub>15<\/sub>\u7c7b\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1b(b) \u5e26\u9699\u968f\u5c42\u6570\u7684\u53d8\u5316\uff1b(c) \u9ad8\u5404\u5411\u5f02\u6027\u7684\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u3002<\/p>\n<p>\u56e2\u961f\u91c7\u7528\u5316\u5b66\u6c14\u76f8\u4f20\u8f93\u6cd5\u6210\u529f\u5236\u5f97KP<sub>15<\/sub>\u3001NaP<sub>15<\/sub>\u6676\u4f53\uff0c\u5e76\u91c7\u7528\u5355\u6676\u884d\u5c04\u9996\u6b21\u83b7\u5f97\u4e86KP<sub>15<\/sub>\u7684\u7cbe\u7ec6\u6676\u4f53\u7ed3\u6784\uff08\u8be5\u6570\u636e\u5df2\u88ab\u56fd\u9645\u6676\u4f53\u6570\u636e\u673a\u6784FIZ Karlsruhe\u7684ICSD \u7ec4\u6536\u5f55\uff0cCSD\u7f16\u53f7433301\uff09\u3002\u540c\u65f6\u91c7\u7528\u89d2\u5206\u8fa8\u62c9\u66fc\u5149\u8c31\u3001\u89d2\u5206\u8fa8\u5149\u81f4\u53d1\u5149\u8c31\u624b\u6bb5\uff0c\u7cfb\u7edf\u7814\u7a76\u4e86\u4f53\u7cfb\u5404\u5411\u5f02\u6027\u7684\u58f0\u5b50\u632f\u52a8\u6a21\u3001\u6fc0\u53d1\u548c\u53d1\u5c04\u5404\u5411\u5f02\u6027\uff0c\u5370\u8bc1\u4e86\u4f53\u7cfb\u9ad8\u5404\u5411\u5f02\u6027\u7684\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u548c\u5149\u5438\u6536\u7279\u6027\u3002\u6839\u636e\u7ed3\u6784\u9884\u6d4b\uff0cMP<sub>15<\/sub>\u4f53\u7cfb\u9762\u5185[P<sup>&#8211;<\/sup><sub>15<\/sub>]\u7ba1\u95f4\u7ed3\u5408\u529b\u8f83\u5f31\uff0c\u56e0\u6b64\u56e2\u961f\u91c7\u7528\u673a\u68b0\u5265\u79bb\u5bf9KP<sub>15<\/sub>\u8fdb\u884c\u51cf\u8584\uff0c\u5df2\u83b7\u5f97\u539a20nm\u3001\u5bbd80nm\u7684KP<sub>15<\/sub>\u7eb3\u7c73\u7ebf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-132438\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-80.jpg\" alt=\"\" width=\"650\" height=\"556\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-80.jpg 650w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-80-300x257.jpg 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p><strong>\u56fe2.<\/strong> (a) KP<sub>15<\/sub>\u7684\u89d2\u5206\u8fa8\u62c9\u66fc\u5149\u8c31\uff1b(b) KP<sub>15<\/sub>\u5404\u5411\u5f02\u6027\u7684\u5149\u81f4\u53d1\u5149\u7279\u6027\uff1b(c) \u673a\u68b0\u5265\u79bb\u6240\u5f97\u51c6\u4e00\u7ef4KP<sub>15<\/sub>\u3002<\/p>\n<p><strong>\u5c0f\u7ed3<\/strong>\uff1a\u7814\u7a76\u4eba\u5458\u4ece\u7406\u8bba\u548c\u5b9e\u9a8c\u4e0a\u62a5\u9053\u4e86\u4e00\u7c7b\u5177\u6709\u9762\u5185\u9ad8\u5f02\u6027\u3001\u6f5c\u5728\u9ad8\u8fc1\u79fb\u7387\u7684\u65b0\u578b\u51c6\u4e00\u7ef4\u5404\u5411\u5f02\u6027\u7684\u5c42\u72b6\u6750\u6599MP<sub>15<\/sub>(M=Li, Na, K)\u3002\u7cfb\u7edf\u7814\u7a76\u4e86\u5176\u7535\u5b50\u7ed3\u6784\u3001\u8f7d\u6d41\u5b50\u8f93\u8fd0\u6027\u8d28\u3001\u5404\u5411\u5f02\u6027\u7684\u58f0\u5b50\u632f\u52a8\u6a21\u5f0f\u53ca\u5149\u81f4\u53d1\u5149\u7279\u6027\uff0c\u8fd9\u4e00\u7cfb\u5217\u7814\u7a76\u5de5\u4f5c\u6709\u671b\u6fc0\u53d1\u672a\u6765\u5bf9\u51c6\u4e00\u7ef4\u5c42\u72b6\u6750\u6599\u7684\u7814\u7a76\u5174\u8da3\u3002\u8be5\u5de5\u4f5c\u5f97\u5230\u4e86\u4e2d\u56fd\u79d1\u5b66\u9662\u534a\u5bfc\u4f53\u7814\u7a76\u6240\u5e38\u51ef\u7814\u7a76\u5458\u3001\u8c2d\u5e73\u6052\u7814\u7a76\u5458\u53ca\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u674e\u5efa\u8363\u6559\u6388\u7684\u5927\u529b\u652f\u6301\uff0c\u76f8\u5173\u6210\u679c\u5747\u5df2\u53d1\u8868\uff08<em>J. Phys. Chem. Lett. 9, 4, 732-738<\/em>\uff1b<em>ACS Nano, 12, 2, 1712-1719<\/em>\uff09\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<\/p>\n<p>1.\u00a0<a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.jpclett.7b02817\" target=\"_blank\" rel=\"noopener\">Rediscovering the MP15 Family (M = Li, Na, and K) as an Anisotropic Layered Semiconducting Material\u00a0<\/a>\uff08J. Phys. Chem. Lett. 9, 4, 732-738\uff09<\/p>\n<p>2.\u00a0<a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acsnano.7b08368\" target=\"_blank\" rel=\"noopener\">High Anisotropy in Tubular Layered Exfoliated KP15<\/a>\uff08ACS Nano\u00a012,\u00a02,\u00a01712-1719\uff09<\/p>\n<p>\u672c\u6587\u7531\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u5f20\u6c38\u54f2\u6559\u6388\u4e0e\u5218\u4e39\u654f\u6559\u6388\u8054\u5408\u56e2\u961f\u63d0\u4f9b\uff0c\u7279\u6b64\u611f\u8c22\uff01<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4ee5\u77f3\u58a8\u70ef\uff08graphene\uff09\u4e3a\u4ee3\u8868\u7684\u4e8c\u7ef4\u6750\u6599\u56e0\u5176\u72ec\u7279\u7684\u5c42\u72b6\u7ed3\u6784\u548c\u591a\u6837\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u81ea\u8bde\u751f\u4e4b\u521d\u5c31\u53d7\u5230\u4e86\u79d1\u5b66\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u65b0\u578b\u4e8c\u7ef4\u6750\u6599\u4e0d\u65ad\u88ab\u5f00\u53d1\u51fa\u6765\uff0c\u5176&#8230;<\/p>\n","protected":false},"author":9,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[113],"class_list":["post-132436","post","type-post","status-publish","format-standard","hentry","category-keji","tag-semiconductor"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/132436"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/9"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=132436"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/132436\/revisions"}],"predecessor-version":[{"id":134172,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/132436\/revisions\/134172"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=132436"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=132436"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=132436"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}