{"id":130966,"date":"2018-03-22T14:00:13","date_gmt":"2018-03-22T06:00:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=130966"},"modified":"2018-03-19T11:23:32","modified_gmt":"2018-03-19T03:23:32","slug":"j-am-ceram-soc-%ef%bc%9aybco%e8%b6%85%e5%af%bc%e4%bd%93%e7%a9%ba%e6%b0%94%e4%b8%ad%e6%b0%a7%e5%8c%96%e8%a1%8c%e4%b8%ba%e7%9a%84%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=130966","title":{"rendered":"J. Am. Ceram. Soc.\uff1aYBCO\u8d85\u5bfc\u4f53\u7a7a\u6c14\u4e2d\u6c27\u5316\u884c\u4e3a\u7684\u7814\u7a76"},"content":{"rendered":"<p>\u3010<strong>\u5f15\u8a00<\/strong>\u3011<\/p>\n<p>\u57fa\u4e8eYBa<sub>2<\/sub>Cu<sub>3<\/sub>O<sub>7-\u03b4<\/sub>\u5316\u5408\u7269\u7684\u5757\u72b6\u5355\u6676\u8d85\u5bfc\u4f53\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\u6709\u7740\u975e\u5e38\u91cd\u8981\u7684\u610f\u4e49\uff0c\u56e0\u6b64\u79d1\u5b66\u5bb6\u4eec\u5bf9\u5b83\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u7814\u7a76\u3002\u76ee\u524d\u6765\u770b\uff0c\u6240\u6709\u9ad8\u6e29\u8d85\u5bfc\u4f53\u7cfb\u5217\u90fd\u5bb9\u6613\u53d7\u5230\u73af\u5883\u56e0\u7d20(\u5982\u5927\u6c14\u6c34\u5206)\u7684\u5f71\u54cd\u800c\u53d1\u751f\u964d\u89e3\u3002\u8150\u8680\u8fc7\u7a0b\u4e0d\u4ec5\u5bf9\u73af\u5883\u654f\u611f\uff0c\u800c\u4e14\u5bf9\u8d85\u5bfc\u4f53\u7684\u5fae\u89c2\u7ed3\u6784\u4e5f\u5f88\u654f\u611f\u3002YBCO\u5757\u4f53\u5355\u6676\u6750\u6599\u662f\u7531YBa<sub>2<\/sub>Cu<sub>3<\/sub>O<sub>7-\u03b4<\/sub>\u5355\u6676\u4e0eYBaCuO<sub>5<\/sub>\u7c92\u5b50\u7ec4\u5408\u800c\u6210\u7684\u590d\u5408\u4f53\uff0c\u6700\u8fd1\uff0c\u6709\u5b66\u8005\u7814\u7a76\u4e86YBCO\u5927\u5757\u5355\u6676\u8d85\u5bfc\u4f53\u4e0e\u6e7f\u6da6\u7a7a\u6c14\u53cd\u5e94\u5f15\u8d77\u7684\u8150\u8680\u884c\u4e3a\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u65af\u6d1b\u4f10\u514b\u5b9e\u9a8c\u7269\u7406\u7814\u7a76\u9662\u7684Pavel Diko (\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u4eba\u5728<strong>J. Am. Ceram. Soc.<\/strong>\u4e0a\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u9ad8\u6e29\u8d85\u5bfc\u4f53\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201c<strong>Corrosion of YBCO bulk superconductor in air<\/strong>\u201d\u3002\u672c\u6587\u7814\u7a76\u4e86YBCO\u5927\u5757\u5355\u6676\u8d85\u5bfc\u4f53\u6c27\u5316\u88c2\u7eb9\u8868\u9762\u4e0e\u6e7f\u6da6\u7a7a\u6c14\u53cd\u5e94\u5f15\u8d77\u7684\u8150\u8680\u884c\u4e3a\u3002\u4f5c\u8005\u901a\u8fc7\u5728\u7a7a\u6c14\u4e2d\u66b4\u9732\u7684(001)\u8868\u9762\u4e0a\u8fdb\u884cX\u5c04\u7ebf\u5149\u7535\u5b50\u53d1\u5c04\u5149\u8c31\u5b9e\u9a8c\uff0c\u8bc1\u5b9e\u4e86\u6c27\u952e\u4e0e\u6c22\u6c27\u5316\u94a1\u76f8\u5173\u3002\u6837\u54c1\u7684\u70ed\u5206\u6790\u548c\u8d28\u8c31\u663e\u793a\u6837\u54c1\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u6c22\u6c27\u5316\u94a1\u6c34\u5408\u7269\u5206\u89e3\u5f15\u8d77\u4e86\u6c34\u7684\u91ca\u653e\u3002\u6837\u54c1\u7684\u91cd\u91cf\u968f\u65f6\u95f4\u7684\u53d8\u957f\u800c\u589e\u52a0\uff0c\u8fd9\u4e0e\u5728\u6c27\u5316\u88c2\u7eb9\u8868\u9762\u5f62\u6210\u6c22\u6c27\u5316\u94a1\u76f8\u6709\u5173\u3002 \u6700\u540e\uff0c\u4f5c\u8005\u7528\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\u89c2\u5bdf\u52a0\u70ed\u65f6\u8fd9\u4e9b\u76f8\u7684\u5f62\u6001\u53d8\u5316\u3002<\/p>\n<p>\u3010<strong>\u56fe\u7247\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1 YBCO\u5355\u7c92\u6837\u54c1\u9876\u9762\u7684\u5b8f\u89c2\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-130968\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-25.png\" alt=\"\" width=\"600\" height=\"594\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-25.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-25-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-25-300x297.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe2 \u6837\u54c1\u91cd\u91cf\u4e0e\u7a7a\u6c14\u4e2d\u66b4\u9732\u65f6\u95f4\u7684\u5173\u7cfb\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-130970\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-27.png\" alt=\"\" width=\"600\" height=\"457\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-27.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-27-300x229.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5728\u534a\u5bf9\u6570\u5750\u6807\u4e2d\u89c2\u5bdf\u5230\u7684\u76f8\u5173\u6027\u6e05\u695a\u5730\u663e\u793a\u4e86\u6837\u54c1\u5728\u7a7a\u6c14\u4e2d\u66b4\u9732\u7ea630\u5c0f\u65f6\u540e\u8150\u8680\u8fc7\u7a0b\u7684\u53d8\u5316\uff0c\u8fd9\u79cd\u53d8\u5316\u8868\u73b0\u4e3a\u8d28\u91cf\u6025\u5267\u589e\u52a0\uff0c\u7136\u540e\u662f\u8f83\u9ad8\u7684\u6d4b\u91cf\u4f9d\u8d56\u6027\u659c\u7387\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u542b\u6c27\u6837\u54c1\u4e2d\u91cd\u91cf\u7684\u589e\u52a0\u4e0e\u901a\u8fc7\u6c27\u5316\u88c2\u89e3\u4ea7\u751f\u7684\u5185\u8868\u9762\u6709\u5173\u3002<\/p>\n<p><strong>\u56fe3 \u7ecf\u6c27\u5316\u540e\u6837\u54c1\u7684\u5fae\u89c2\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-130975\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/3-26.png\" alt=\"\" width=\"600\" height=\"592\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/3-26.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/3-26-300x296.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5149\u5b66\u663e\u5fae\u955c\u663e\u5fae\u7167\u7247\uff0c\u5728\u629b\u5149\u548c\u8680\u523b(100)\u6837\u54c1\u8868\u9762\u4e0a\u770b\u5230\u7684\u88c2\u7eb9\u3002<\/p>\n<p><strong>\u56fe4 SEM\u7167\u7247<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-130976\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/4-27.png\" alt=\"\" width=\"600\" height=\"601\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/4-27.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/4-27-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/4-27-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a<\/strong>) \u6c27\u5316\u540e\u7684\u88c2\u7eb9\u6837\u54c1\u663e\u793a\u51fa\u5149\u4eae\u7684(001)\u8868\u9762\uff1b<\/p>\n<p>(<strong>b<\/strong>) \u5728\u7a7a\u6c14\u4e2d\u6837\u54c1\u66b4\u973224\u5c0f\u65f6\u540e\uff0c\u5185\u90e8a\/b\u88c2\u7eb9\u4e0a\u7684\u9897\u7c92\uff1b<\/p>\n<p>(<strong>c<\/strong>) 60\u5929\u540e\u51fa\u73b0\u8f83\u5927\u7684\u76d8\u72b6\u9897\u7c92\uff1b<\/p>\n<p>(d) \u66b4\u97321\u5e74\u540e\u89c2\u5bdf\u5230\u9897\u7c92\u7684\u751f\u957f\u548c\u56e2\u805a\u73b0\u8c61\u3002<\/p>\n<p><strong>\u56fe5 YBCO\u6563\u88c5\u6837\u54c1\u7684\u8d28\u8c31\u5206\u6790\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-130977\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/5-20.png\" alt=\"\" width=\"600\" height=\"218\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/5-20.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/5-20-300x109.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a<\/strong>) \u5728\u6c34\u4e2d\u7b49\u6e29\u505c\u7559\uff1b<\/p>\n<p>(<strong>b<\/strong>) \u5728\u6c27\u6c14\u4e2d\u7b49\u6e29\u505c\u7559\u3002<\/p>\n<p><strong>\u56fe6 \u6837\u54c1SEM\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-130974\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/6-13.png\" alt=\"\" width=\"600\" height=\"960\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/6-13.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/6-13-188x300.png 188w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a<\/strong>) 75\u00b0C\u6c29\u6c14\u4e2d\u9000\u706b\u540e\u5927\u9897\u7c92\u7684\u5f62\u72b6\u53d8\u5316\uff1b<\/p>\n<p>(<strong>b<\/strong>) 500\u2103\u9000\u706b\u540e\uff0c\u5728\u5185\u90e8a\/b\u88c2\u7f1d\u4e0a\u4ee5\u7247\u72b6\u5f62\u5f0f\u7194\u5316\u5e76\u7ed3\u6676\u7684\u6c22\u5316\u94a1\uff1b<\/p>\n<p>(<strong>c<\/strong>) 500\u2103\u9000\u706b\u6837\u54c1\u7684\u65b0\u88c2\u5f00\u7684(001)\u8868\u9762\u4e0a\u89c2\u5bdf\u5230a\/c\u88c2\u7f1d\u7684\u6c22\u6c27\u5316\u94a1\u6d41\u51fa\uff1b<\/p>\n<p>(<strong>d<\/strong>) \u66f4\u9ad8\u653e\u5927\u500d\u6570\u4e0b\u7684\u6c22\u6c27\u5316\u94a1\u5f62\u6001<\/p>\n<p>(<strong>e<\/strong>) \u6c22\u6c27\u5316\u94a1\u5c0f\u4e18\u7684EDAX\u70b9\u8c31\u3002<\/p>\n<p>\u3010<strong>\u5c0f\u7ed3<\/strong>\u3011<\/p>\n<p>\u672c\u6587\u7cfb\u7edf\u5730\u7814\u7a76\u4e86YBCO\u5355\u9897\u7c92\u8d85\u5bfc\u4f53\u5728\u7a7a\u6c14\u4e2d\u7684\u8150\u8680\u884c\u4e3a\u3002\u6837\u54c1\u91cd\u91cf\u5bf9\u66b4\u9732\u65f6\u95f4\u7684\u4f9d\u8d56\u6027\u8868\u660e\u8150\u8680\u8fc7\u7a0b\u7684\u53d8\u5316\u662f\u7531\u6025\u5267\u589e\u52a0\u7684\u8f83\u9ad8\u659c\u7387\u6765\u8bc1\u5b9e\u3002\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d\u7684\uff08001\uff09\u8868\u9762\u4e0a\u8fdb\u884cXPS\u8c31\u5b9e\u9a8c\uff0c\u8bc1\u5b9e\u4e86\u6c27\u952e\u4e0e\u6c22\u6c27\u5316\u94a1\u6709\u5173\u3002\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\u89c2\u5bdf\u8bc1\u660e\uff0c\u8150\u8680\u6548\u5e94\u662f\u7531\u5728\u6c27\u5316\u88c2\u7eb9\u8868\u9762\u5f62\u6210\u6c22\u6c27\u5316\u94a1\u6c34\u5408\u7269\u5f15\u8d77\u7684\uff0c\u540c\u65f6\u8868\u5f81\u4e86\u5728\u6837\u54c1\u52a0\u70ed\u65f6\u8fd9\u4e9b\u6c34\u5408\u7269\u7684\u5f62\u6001\u53d8\u5316\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe<\/strong>\u63a5\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1111\/jace.15525\" target=\"_blank\" rel=\"noopener\">Corrosion of YBCO bulk superconductor in air<\/a> (J. Am. Ceram. Soc., 13 March, 2018 , DOI: 10.1111\/jace.15525\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u91d1\u5c5e\u5b66\u672f\u7ec4jcfxs01\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u57fa\u4e8eYBa2Cu3O7-\u03b4\u5316\u5408\u7269\u7684\u5757\u72b6\u5355\u6676\u8d85\u5bfc\u4f53\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\u6709\u7740\u975e\u5e38\u91cd\u8981\u7684\u610f\u4e49\uff0c\u56e0\u6b64\u79d1\u5b66\u5bb6\u4eec\u5bf9\u5b83\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u7814\u7a76\u3002\u76ee\u524d\u6765\u770b\uff0c\u6240\u6709\u9ad8\u6e29\u8d85\u5bfc\u4f53\u7cfb\u5217\u90fd\u5bb9\u6613\u53d7&#8230;<\/p>\n","protected":false},"author":4915,"featured_media":130974,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2964,2963],"class_list":["post-130966","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2964","tag-2963"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130966"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4915"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=130966"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130966\/revisions"}],"predecessor-version":[{"id":131121,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130966\/revisions\/131121"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/130974"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=130966"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=130966"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=130966"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}