{"id":130798,"date":"2018-03-21T06:30:01","date_gmt":"2018-03-20T22:30:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=130798"},"modified":"2018-03-20T18:45:03","modified_gmt":"2018-03-20T10:45:03","slug":"%e5%8c%97%e4%ba%ac%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6nano-energy%ef%bc%9apt-au%e5%8d%8f%e5%90%8c%e4%bc%98%e5%8c%96%e6%9e%84%e5%bb%ba%e9%ab%98%e6%95%88%e7%94%b2%e9%85%b8%e6%b0%a7%e5%8c%96%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=130798","title":{"rendered":"\u5317\u4eac\u79d1\u6280\u5927\u5b66Nano Energy\uff1aPt-Au\u534f\u540c\u4f18\u5316\u6784\u5efa\u9ad8\u6548\u7532\u9178\u6c27\u5316\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u76f4\u63a5\u7532\u9178\u71c3\u6599\u7535\u6c60\u5177\u6709\u5f00\u8def\u7535\u52bf\u9ad8\u3001\u71c3\u6599\u6e17\u900f\u5c0f\u3001\u6bd2\u6027\u4f4e\u7b49\u7279\u70b9\uff0c\u5728\u4fbf\u643a\u5f0f\u80fd\u6e90\u9886\u57df\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u524d\u666f\u3002\u7532\u9178\u5206\u5b50\u7ed3\u6784\u7b80\u5355\uff0c\u5176\u6c27\u5316\u53cd\u5e94\u662f\u7814\u7a76\u7535\u50ac\u5316\u5242\u6784\u6548\u5173\u7cfb\u3001\u7406\u89e3\u7535\u50ac\u5316\u8fc7\u7a0b\u57fa\u672c\u539f\u7406\u7684\u91cd\u8981\u6a21\u578b\u53cd\u5e94\u3002\u5728Pt\u57fa\u50ac\u5316\u5242\u8868\u9762\uff0c\u7532\u9178\u6c27\u5316\u4e3b\u8981\u6709\u4e24\u79cd\u8def\u5f84\uff1a\u76f4\u63a5\u8def\u5f84\uff0c\u4ea7\u751f\u6d3b\u6027\u4e2d\u95f4\u4ea7\u7269\u7684\u8131\u6c34\u8fc7\u7a0b\uff1b\u95f4\u63a5\u8def\u5f84\uff0c\u4ea7\u751fCO\u4e2d\u6bd2\u7269\u79cd\u7684\u8131\u6c22\u8fc7\u7a0b\u3002\u8bbe\u8ba1\u5408\u6210\u7279\u5b9a\u7684\u591a\u7ec4\u5206\u6750\u6599\uff0c\u7cbe\u786e\u8c03\u63a7\u5176\u8868\u754c\u9762\u7ed3\u6784\uff0c\u4fc3\u8fdb\u76f4\u63a5\u8def\u5f84\u901f\u7387\uff0c\u6291\u5236\u4e2d\u6bd2\u7269\u79cd\u4ea7\u751f\uff0c\u662f\u63d0\u9ad8Pt\u57fa\u7532\u9178\u6c27\u5316\u7535\u50ac\u5316\u5242\u6027\u80fd\u7684\u91cd\u8981\u9014\u5f84\u3002\u8fd1\u5e74\u6765\uff0cPt-Au\u4f53\u7cfb\u88ab\u53d1\u73b0\u5728\u7532\u9178\u6c27\u5316\u53cd\u5e94\u4e2d\u663e\u793a\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u4f18\u5316Pt-Au\u534f\u540c\u4f5c\u7528\uff0c\u6784\u5efa\u5177\u6709\u4e30\u5bcc\u6d3b\u6027\u4f4d\u70b9\u7684\u50ac\u5316\u5242\u6750\u6599\uff0c\u662f\u7814\u7a76\u4e2d\u7684\u91cd\u70b9\u548c\u96be\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/span><\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5317\u4eac\u79d1\u6280\u5927\u5b66\u738b\u8363\u660e\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u5f00\u53d1\u51fa\u4e00\u79cd\u7b80\u4fbf\u7684\u65b9\u6cd5\u5236\u5907\u51fa\u9ad8\u6548\u7684Pt-Au\/C\u7532\u9178\u6c27\u5316\u7535\u50ac\u5316\u5242\uff0c\u70ad\u9ed1\u9897\u7c92\u4e0a\u8d1f\u8f7d\u7684Pt\u548cAu\u7c92\u5b50\u7684\u5e73\u5747\u5c3a\u5bf8\u5206\u522b\u7ea6\u4e3a1.6\u548c5.4nm\uff0cPt\/Au\u539f\u5b50\u6bd4\u7ea6\u4e3a32:68\uff0c\u91d1\u5c5e\u603b\u8d1f\u8f7d\u91cf\u7ea6\u4e3a33wt%\u3002\u8be5\u65b9\u6cd5\u5728\u65e0\u8868\u9762\u6d3b\u6027\u5242\u5b58\u5728\u7684\u4e59\u9187\/\u6c34\u6df7\u5408\u6eb6\u6db2\u4e2d\uff0c\u5229\u7528\u8d85\u58f0\u6ce2\u7684\u7a7a\u5316\u4f5c\u7528\uff0c\u6709\u6548\u5730\u9632\u6b62\u4e86Pt\u548cAu\u7c92\u5b50\u7684\u56e2\u805a\uff0c\u5b9e\u73b0\u4e86Pt\u3001Au\u7c92\u5b50\u5728\u70ad\u9ed1\u9897\u7c92\u4e0a\u7684\u9ad8\u5bc6\u5ea6\u5747\u5300\u8d1f\u8f7d\u3002\u901a\u8fc7\u6df1\u5165\u7ec6\u81f4\u7684\u900f\u5c04\u7535\u5b50\u663e\u5fae\u5b66\u7b49\u8868\u5f81\u5206\u6790\u53d1\u73b0\uff0c\u5408\u6210\u51fa\u7684Pt-Au\/C\u50ac\u5316\u5242\u5177\u6709\u8868\u9762\u5e72\u51c0\u3001\u9897\u7c92\u8d1f\u8f7d\u5bc6\u5ea6\u9ad8\u3001Pt-Au\u6bd7\u8fde\u4f4d\u70b9\u4e30\u5bcc\u7b49\u7279\u70b9\u3002\u5728\u7532\u9178\u6c27\u5316\u7535\u50ac\u5316\u53cd\u5e94\u4e2d\uff0cPt-Au\/C\u663e\u793a\u51fa14.5 A\uf0d7mg\uf0d7Pt-1\u7684\u8d28\u91cf\u6bd4\u6d3b\u6027\uff0c\u662f\u5546\u4e1aPt\/C\u50ac\u5316\u5242\u7684153\u500d\u3002\u57280.05V\uff08vs. SCE\uff09\u4e0b\u6d4b\u8bd5\u50ac\u5316\u5242\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\u53d1\u73b0\uff0cPt-Au\/C\u663e\u793a\u51fa\u8fdc\u9ad8\u4e8ePt\/C\u7684\u7535\u6d41\u7a33\u5b9a\u6027\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u6bd7\u8fde\u7684Pt\u548cAu\u7c92\u5b50\uff08\u76f8\u8ddd\u7ea60.7-1 nm\uff09\u4f4d\u70b9\u4e0a\uff0c\u7532\u9178\u5206\u5b50\u6c27\u5316\u76f4\u63a5\u8def\u5f84\u7684\u52bf\u5792\u8981\u4f4e\u4e8e\u95f4\u63a5\u8def\u5f84\uff0c\u4e5f\u4f4e\u4e8e\u7eafPt\u4f4d\u70b9\u4e0a\u7684\u76f4\u63a5\u8def\u5f84\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u63ed\u793a\u4e86\u7532\u9178\u6c27\u5316\u8fc7\u7a0b\u4e2dPt-Au\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\uff0c\u4e5f\u4e3a\u5408\u6210\u9ad8\u6027\u80fd\u8f7d\u4f53\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u7eff\u8272\u3001\u7b80\u4fbf\u548c\u6709\u6548\u7684\u601d\u8def\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5Extraordinary electrocatalytic performance for formic acid oxidation by the synergistic effect of Pt and Au on carbon black<\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u5728\u8fd1\u671f\u7684Nano Energy<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/span><\/strong><\/p>\n

\u56fe1 \u8d85\u58f0\u8f85\u52a9\u65b9\u6cd5\u5408\u6210Pt-Au\/C\u3001Pt\/C\u548cAu\/C<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2 Pt-Au\/C\u3001Pt\/C\u548cAu\/C\u7684XRD\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe3 Pt-Au\/C\u3001Pt\/C\u548cAu\/C\u7684SEM\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe4 Pt-Au\/C\u7684HAADF STEM\u548cHRTEM\u56fe<\/strong><\/p>\n

\"\"\u2003
\n \u56fe5 Pt-Au\/C\u7684EDS mapping\u56fe\u548cHAADF STEM\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe6 \u7532\u9178\u6c27\u5316\u50ac\u5316\u7ed3\u679c<\/strong><\/p>\n

\"\"
\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

\u8be5\u7814\u7a76\u5f00\u53d1\u4e86\u4e00\u79cd\u7eff\u8272\u3001\u7b80\u4fbf\u548c\u6709\u6548\u7684\u65b9\u6cd5\uff0c\u5408\u6210\u51fa\u5177\u6709\u9ad8\u7532\u9178\u6c27\u5316\u50ac\u5316\u6d3b\u6027\u7684Pt-Au\/C\u6750\u6599\u3002\u65e0\u8868\u9762\u6d3b\u6027\u5242\u7684\u6c34\/\u4e59\u9187\u6eb6\u6db2\u4f53\u7cfb\u786e\u4fdd\u4e86\u50ac\u5316\u5242\u5177\u6709\u5e72\u51c0\u7684\u8868\u9762\uff0c\u8d85\u58f0\u8f85\u52a9\u7684\u7b56\u7565\u4f7f\u5f97Pt\u548cAu\u7c92\u5b50\u5728\u70ad\u9ed1\u9897\u7c92\u8868\u9762\u5177\u6709\u9ad8\u5bc6\u5ea6\u4e14\u5747\u5300\u7684\u8d1f\u8f7d\u3002\u8be5\u50ac\u5316\u5242\u5177\u6709\u4e30\u5bcc\u7684Pt-Au\u6bd7\u8fde\u4f4d\u70b9\uff0c\u5728\u7532\u9178\u6c27\u5316\u4e2d\u663e\u793a\u51fa153\u500d\u4e8e\u5546\u4e1aPt\/C\u7684\u8d28\u91cf\u6bd4\u6d3b\u6027\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660ePt-Au\u6bd7\u8fde\u4f4d\u70b9\u5177\u6709\u660e\u663e\u4f18\u4e8e\u7eafPt\u4f4d\u70b9\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8be5Pt-Au\/C\u50ac\u5316\u5242\u5728\u76f4\u63a5\u7532\u9178\u71c3\u6599\u7535\u6c60\u4e2d\u5177\u6709\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\uff0c\u8d85\u58f0\u8f85\u52a9\u7684\u5408\u6210\u65b9\u6cd5\u4e5f\u4e3a\u5236\u5907\u9ad8\u6548\u7684\u8f7d\u4f53\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u3010\u76f8\u5173\u7814\u7a76\u3011<\/span><\/strong><\/p>\n

\u738b\u8363\u660e\u6559\u6388\u8bfe\u9898\u7ec4\u8fd1\u5e74\u6765\u5728\u53cc\u5143\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u6750\u6599\u7684\u8bbe\u8ba1\u8c03\u63a7\u3001\u539f\u5b50\u7ed3\u6784\u8868\u5f81\u548c\u6784\u6548\u5173\u7cfb\u7814\u7a76\u7b49\u65b9\u9762\u83b7\u5f97\u4e86\u4e00\u7cfb\u5217\u8fdb\u5c55\u3002\u53d1\u73b0\u4e86FePt\u7eb3\u7c73\u7c92\u5b50\u8868\u5c42\u5b58\u5728\u7684\u6676\u683c\u9a70\u8c6b\u73b0\u8c61\u548c\u539f\u5b50\u91cd\u6784\u73b0\u8c61\uff0c\u53d1\u73b0\u5176\u5177\u6709\u5bccPt\u68af\u5ea6\u58f3\u5c42\u6b63\u4e8c\u5341\u9762\u4f53\u7ed3\u6784[Phys. Rev. Lett. 100 (2008) 017205; J. Phys. Chem. C 113 (2009) 4395; Nanoscale 1 (2009) 276]\uff1b\u539f\u4f4d\u7814\u7a76\u4e86NiAu\u7c92\u5b50\u7684\u539f\u5b50\u7ed3\u6784\u6f14\u5316\u89c4\u5f8b\uff0c\u53d1\u73b0\u771f\u7a7a\u70ed\u5904\u7406\u8fc7\u7a0b\u4e2dNiAu\u7c92\u5b50\u7ecf\u5386\u4e86\u56db\u4e2a\u6f14\u5316\u9636\u6bb5\uff0c\u63d0\u51fa\u4e86\u76f8\u5e94\u7684\u539f\u5b50\u7ed3\u6784\u6f14\u5316\u6a21\u578b[Nanoscale 5 (2013) 5067]\uff1b\u8bbe\u8ba1\u5408\u6210\u4e86\u8d85\u8584\u58f3\u5c42NiPt\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784[J. Mater. Chem. 21 (2011) 1925; J. Mater. Chem. A 3 (2015) 1031]\u3001\u5bccPt\u58f3\u5c42NiPt\u516b\u9762\u4f53\u7eb3\u7c73\u6676\u4f53[ACS Appl. Mater. Interfaces 8 (2016) 10841]\uff0c\u7814\u7a76\u5176\u539f\u5b50\u7ed3\u6784\u6f14\u5316\u53ca\u5176\u4e0e\u50ac\u5316\u3001\u78c1\u5b66\u4e4b\u95f4\u7684\u5173\u7cfb[Chem. Commun. 50 (15) (2014) 1804; Nanoscale 8 (2016) 11432; Nano Res. 10 (2017) 187; Nano Res. 10 (2017) 3238].<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aExtraordinary electrocatalytic performance for formic acid oxidation by the synergistic effect of Pt and Au on carbon black<\/a>\u00a0(Nano Energy, 2018, DOI: 10.1016\/j.nanoen.2018.03.018)<\/p>\n

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