{"id":130755,"date":"2018-03-25T06:30:03","date_gmt":"2018-03-24T22:30:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=130755"},"modified":"2018-03-23T21:17:39","modified_gmt":"2018-03-23T13:17:39","slug":"%e5%8d%8e%e5%8d%97%e7%90%86%e5%b7%a5macromolecules%ef%bc%9a%e5%8f%af%e6%ba%b6%e4%ba%8e%e6%b0%b4%e9%86%87%e7%9a%84%e8%87%aa%e6%8e%ba%e6%9d%82n-%e5%9e%8b%e5%85%b1%e8%bd%ad%e8%81%9a%e5%90%88%e7%89%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=130755","title":{"rendered":"\u534e\u5357\u7406\u5de5Macromolecules\uff1a\u53ef\u6eb6\u4e8e\u6c34\/\u9187\u7684\u81ea\u63ba\u6742N-\u578b\u5171\u8f6d\u805a\u5408\u7269\u7528\u4e8e\u9ad8\u6027\u80fd\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4f53\u5f02\u8d28\u7ed3\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u67d4\u6027\uff0c\u8d28\u91cf\u8f7b\uff0c\u5927\u9762\u79ef\u548c\u6eb6\u6db2\u6cd5\u5236\u5907\u7b49\u4f18\u70b9\u53d7\u5230\u4e86\u7814\u7a76\u8005\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5176\u6700\u9ad8\u7535\u6c60\u6548\u7387\u8fbe\u5230\u4e8614%\u3002\u63d0\u5347\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u4e3b\u8981\u624b\u6bb5\u6709\uff1a1.\u4f7f\u7528\u65b0\u578b\u65bd\u4e3b\/\u53d7\u4e3b\u6750\u6599\uff1b2.\u8584\u819c\u5f62\u8c8c\u4f18\u5316\uff1b3.\u754c\u9762\u5de5\u7a0b\u3002\u5176\u4e2d\uff0c\u754c\u9762\u5de5\u7a0b\u5bf9\u63d0\u9ad8\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u6709\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u901a\u8fc7\u8c03\u8282\u6d3b\u6027\u5c42\u548c\u7535\u6781\u4e4b\u95f4\u7684\u80fd\u7ea7\u6392\u5217\u53ef\u4ee5\u6709\u6548\u63d0\u9ad8\u7535\u8377\u9009\u62e9\u6027\u548c\u8403\u53d6\u80fd\u529b\uff0c\u4ece\u800c\u4fc3\u8fdb\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u3002<\/p>\n

\u5728\u6240\u6709\u4e0d\u540c\u7c7b\u578b\u7684\u754c\u9762\u6750\u6599\u4e2d\uff0c\u6c34\/\u9187\u6eb6\u6027\u7684\u5171\u8f6d\u805a\u5408\u7269(WSCPs)\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u524d\u666f\u7684\u7535\u6781\u4fee\u9970\u6750\u6599\uff0c\u5e76\u4e14\u5df2\u7ecf\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5148\u8fdb\u7684\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u3002\u7136\u800c\uff0c\u7531\u4e8e\u8be5\u6750\u6599\u7684\u7535\u5b50\u4f20\u8f93\u7279\u6027\u5dee\uff0c\u53ea\u6709\u5728\u8d85\u8584\u7684\u65f6\u5019\u624d\u80fd\u53d1\u6325\u4f5c\u7528\uff0c\u6240\u4ee5\u4e25\u91cd\u9650\u5236\u4e86\u5176\u5728\u5370\u5237\u9886\u57df\u7684\u5927\u89c4\u6a21\u5e94\u7528\u3002\u8fd1\u5e74\u6765\uff0c\u4e3a\u4e86\u514b\u670d\u7535\u5b50\u8f93\u8fd0\u80fd\u529b\u5dee\u7684\u95ee\u9898\uff0cn\u578bWscps\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u7535\u5b50\u4f20\u8f93\u5c42(ETLs)\uff0c\u88ab\u53d1\u5c55\u6210\u4e3a\u4e00\u79cd\u9ad8\u6548\u805a\u5408\u7269\u592a\u9633\u7535\u6c60\uff0c\u5e76\u4ee5\u5176\u81ea\u8eab\u5177\u6709\u81ea\u63ba\u6742\u6548\u5e94\u7684\u4f18\u52bf\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002<\/p>\n

\u81ea\u63ba\u6742\u6548\u5e94\u901a\u5e38\u4e0e\u5206\u5b50\u80fd\u7ea7\u6709\u5173\u3002\u7136\u800c\uff0c\u8fd9\u4e9bn-Wscp\u4e2d\u542b\u6709\u7f3a\u7535\u5b50\u7684\u8418\u4e8c\u4e9a\u80fa(NDI)\u548c\u805a\u9170\u4e9a\u80fa(PDI)\u5355\u5143\uff0c\u8fd9\u4e9b\u5355\u5143\u56fa\u5b9a\u4e86\u805a\u5408\u7269\u7684LUMO\u80fd\u7ea7\uff0c\u4f7f\u5f97\u65e0\u6cd5\u6709\u6548\u5730\u8c03\u8282LUMO\u503c\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u9ad8\u6027\u80fd\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u81ea\u63ba\u6742\u884c\u4e3a\u4e0e\u5206\u5b50\u80fd\u7ea7\u4e4b\u95f4\u7684\u76f8\u5173\u6027\uff0c\u4ee5\u5f00\u53d1\u66f4\u597d\u7684\u81ea\u63ba\u6742n-Wscp\u6750\u6599\uff0c\u4ecd\u662f\u4e00\u9879\u5177\u6709\u6311\u6218\u6027\u7684\u5de5\u4f5c\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u66f9\u955b\u6559\u6388\u56e2\u961f<\/strong>\u5728Macromolecules<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u540d\u4e3a\u201cN\u2011Type Self-Doped Water\/Alcohol-Soluble Conjugated Polymers\u00a0with Tailored Energy Levels for High-Performance Polymer Solar Cells<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u5229\u7528\u4e0d\u540c\u7a0b\u5ea6\u7684\u916f\u5316\u53d6\u4ee3\u9170\u4e9a\u80fa\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e09\u79cd\u4ee5\u81ea\u63ban-Wscp\u4e3a\u57fa\u7684\u805a\u9170\u4e9a\u80fa\u56db\u7fa7\u9178\u884d\u751f\u7269\uff08PIF-PTE-N, PIF-PMIDE-N\u548cPIF-PDI-N\uff09\u3002\u8fd9\u4e09\u79cd\u65b0\u578b\u7684n-Wscp\u6750\u6599\u53ef\u4ee5\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u5e94\u7528\u4e8e\u9ad8\u6027\u80fd\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u3002\u00a0<\/strong><\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1<\/strong>\uff1a\u4e09\u79cd\u65b0\u578bn-Wscp<\/strong>\u6750\u6599\u7684\u7ed3\u6784\u5f0f<\/strong><\/p>\n

\"\"<\/p>\n

\u00a0 \u4ece\u4e0a\u81f3\u4e0b\u5206\u522b\u662f\uff0cPIF-PTE-N, PEI-PMIDE-N, PIF-PDI-N\u3002<\/p>\n

\u56fe2<\/strong>\uff1a\u7d2b\u5916-<\/strong>\u53ef\u89c1\u5149\u6ce2\u6bb5\u7684\u5438\u6536\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

(a). n-WSCPs\u6c2f\u4eff\u6eb6\u6db2\u7684\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

(b). n-WSCPs\u8584\u819c\u7684\u5438\u6536\u5149\u8c31\u3002<\/p>\n

\u56fe3<\/strong>\uff1an-WSCPs<\/strong>\u65cb\u6d82\u5728\u94c2\u78b3\u7535\u6781\u4e0a\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

PIF-PTE-N, PEI-PMIDE-N, PIF-PDI-N\u4e09\u79cdn-WSCPs\u6750\u6599\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n

\u56fe4<\/strong>\uff1a\u987a\u78c1\u5171\u632f\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

\u4e09\u79cd\u56fa\u6001n-WSCPs\u6750\u6599\u7684\u7535\u5b50\u987a\u78c1\u5171\u632f\u8c31\u3002<\/p>\n

\u56fe5<\/strong>\uff1a\u5668\u4ef6\u7ed3\u6784\u4e0e\u6d3b\u6027\u5c42\u5316\u5b66\u7ed3\u6784\u5f0f<\/strong><\/p>\n

\"\"<\/p>\n

\u00a0 \u4f20\u7edf\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b PTB7-Th, PNTT\u548cPC71<\/sub>BM\u6d3b\u6027\u6750\u6599\u7684\u5316\u5b66\u7ed3\u6784\u5f0f\u3002<\/p>\n

\u56fe6: J-V<\/strong>\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(a). \u4e0d\u540c\u7535\u5b50\u4f20\u8f93\u5c42\uff08\u4e09\u79cdn-WSCPs\u6750\u6599\uff09\uff0c\u4e0d\u540c\u539a\u5ea6\u65f6\uff0c\u4ee5PTB7-Th\/PC71<\/sub>BM\u6d3b\u6027\u5c42\u7684\u805a\u5408\u7269\u7535\u6c60\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

(b). \u4e0d\u540c\u7535\u5b50\u4f20\u8f93\u5c42\uff08\u4e09\u79cdn-WSCPs\u6750\u6599\uff09\uff0c\u4e0d\u540c\u539a\u5ea6\u65f6\uff0c\u4ee5PNTT\/PC71<\/sub>BM\u6d3b\u6027\u5c42\u7684\u805a\u5408\u7269\u7535\u6c60\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u8005\u901a\u8fc7\u4e0d\u540c\u7a0b\u5ea6\u7684\u916f\u5316\u53d6\u4ee3\u9170\u4e9a\u80fa\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e09\u79cd\u4ee5\u81ea\u63ban-Wscp\u4e3a\u57fa\u7684\u805a\u9170\u4e9a\u80fa\u56db\u7fa7\u9178\u884d\u751f\u7269\uff08PIF-PTE-N, PIF-PMIDE-N\u548cPIF-PDI-N\uff09\u3002\u4ee5\u8fd9\u4e9b\u6750\u6599\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u8fbe\u523010%\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>N\u2011Type Self-Doped Water\/Alcohol-Soluble Conjugated Polymers with Tailored Energy Levels for High-Performance Polymer Solar Cells<\/a> (Macrolecules, 2018, DOI:10.1021\/acs.macromol.8b00126)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4\u91d1\u4e5f\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>RDD-2011-CHERISH<\/strong>\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u4f53\u5f02\u8d28\u7ed3\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u67d4\u6027\uff0c\u8d28\u91cf\u8f7b\uff0c\u5927\u9762\u79ef\u548c\u6eb6\u6db2\u6cd5\u5236\u5907\u7b49\u4f18\u70b9\u53d7\u5230\u4e86\u7814\u7a76\u8005\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5176\u6700\u9ad8\u7535\u6c60\u6548\u7387\u8fbe\u5230\u4e8614%\u3002\u63d0\u5347\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u4e3b\u8981\u624b\u6bb5\u6709\uff1a…<\/p>\n","protected":false},"author":2114,"featured_media":130759,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[78],"class_list":["post-130755","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-photovoltaic"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130755"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2114"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=130755"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130755\/revisions"}],"predecessor-version":[{"id":131768,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130755\/revisions\/131768"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/130759"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=130755"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=130755"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=130755"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}