{"id":130727,"date":"2018-03-21T06:30:32","date_gmt":"2018-03-20T22:30:32","guid":{"rendered":"\/\/m.iemloyee.com\/?p=130727"},"modified":"2018-03-17T21:35:57","modified_gmt":"2018-03-17T13:35:57","slug":"%e6%ad%a6%e7%90%86%e9%ba%a6%e7%ab%8b%e5%bc%ba%e5%ae%89%e7%90%b4%e5%8f%8bnano-energy-cus%e6%ad%a3%e6%9e%81%e5%82%a8%e9%95%81%e6%80%a7%e8%83%bd%e5%92%8c%e6%9c%ba%e7%90%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=130727","title":{"rendered":"\u6b66\u7406\u9ea6\u7acb\u5f3a&\u5b89\u7434\u53cbNano Energy : CuS\u6b63\u6781\u50a8\u9541\u6027\u80fd\u548c\u673a\u7406"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u4e8e\u91d1\u5c5e\u9541\u5177\u6709\u8f83\u9ad8\u7684\u5bb9\u91cf(2205 mAh\u00b7g-1<\/sup>\u548c3833 mAh\u00b7cm-3<\/sup>)\u3001\u8f83\u4f4e\u7684\u8fd8\u539f\u7535\u4f4d(-2.37 V vs. SHE)\u3001\u50a8\u91cf\u4e30\u5bcc\u4ee5\u53ca\u65e0\u679d\u6676\u7b49\u826f\u597d\u7279\u6027\uff0c\u9541\u7535\u6c60\u5438\u5f15\u4e86\u8bb8\u591a\u7814\u7a76\u4eba\u5458\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0cMg2+<\/sup>\u79bb\u5b50\u8f83\u9ad8\u7684\u7535\u8377\/\u534a\u5f84\u5b9a\u91cf\u4f7f\u5f97\u79bb\u5b50\u548c\u4e3b\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u8f83\u5f3a\uff0c\u8fd9\u5bf9\u6b63\u6781\u6750\u6599\u8981\u6c42\u8f83\u9ad8\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u9002\u5b9c\u7684\u6b63\u6781\u6750\u6599\u5bf9\u4e8e\u9541\u7535\u6c60\u7684\u53d1\u5c55\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u6559\u6388\u3001\u5b89\u7434\u53cb\u526f\u7814\u7a76\u5458(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u901a\u8fc7\u8c03\u8282\u7535\u6781-\u7535\u89e3\u6db2\u754c\u9762\u5b9e\u73b0\u4e86CuS\u6b63\u6781\u5ba4\u6e29\u4e0b\u7684\u9ad8\u50a8\u9541\u6d3b\u6027(\u8d85\u8fc7300 mAh\u00b7g-1<\/sup>)\uff0c\u5e76\u5728Nano Energy<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cMagnesium Storage Performance and Mechanism of CuS Cathode<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5728\u9541\u5168\u7535\u6c60\u4e2d\uff0c\u4ee550 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u5faa\u73af30\u6b21\u540e\uff0cCuS\u6b63\u6781\u5bb9\u91cf\u4ecd\u9ad8\u8fbe119 mAh\u00b7g-1<\/sup>\u3002\u53e6\u5916\uff0c\u4f5c\u8005\u63a2\u7a76\u4e86CuS\u6b63\u6781\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4f53\u7cfb\u3001\u4e0d\u540c\u5de5\u4f5c\u6e29\u5ea6\u7684\u50a8\u9541\u6027\u80fd\uff0c\u5e76\u901a\u8fc7\u975e\u539f\u4f4dXRD\u7b49\u8868\u5f81\u624b\u6bb5\u8bc1\u5b9e\u4e86\u8f6c\u6362\u578b\u5b58\u50a8\u673a\u7406\u3002\u8fd9\u9879\u5de5\u4f5c\u8bc1\u660eCuS\u4f5c\u4e3a\u9541\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u524d\u666f\u826f\u597d\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 CuS\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) CuS\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

b) CuS\u7684Raman\u5149\u8c31\uff1b<\/p>\n

c) CuS\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

d) CuS\u7684EDS\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

e) CuS\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe2 CuS\u6b63\u6781\u5ba4\u6e29\u4e0b(25 \u00b0C)\u7684\u50a8\u9541\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a,b) 50 mA\u00b7g-1<\/sup>\u4e0b\u3001Mg(ClO4<\/sub>)2<\/sub>\/AN\u7535\u89e3\u6db2\u4e2d\uff0cCuS\u6b63\u6781\u7684\u5faa\u73af\u6027\u80fd\u4ee5\u53ca\u76f8\u5e94\u7684\u5145\/\u653e\u7535\u66f2\u7ebf\uff1b
\n c,d) 20mA\u00b7g-1<\/sup>\u4e0b\u3001APC\/THF\u7535\u89e3\u6db2\u4e2d\uff0c\u5168\u9541\u7535\u6c60CuS\u6b63\u6781\u7684\u5faa\u73af\u6027\u80fd\u4ee5\u53ca\u76f8\u5e94\u7684\u5145\/\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56fe3 \u9ad8\u6e29\u4e0b\u5168\u9541\u7535\u6c60CuS\u6b63\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) 20 mA\u00b7g -1<\/sup>\u4e0d\u540c\u6e29\u5ea6\u4e0bCuS\u7684\u5145\/\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

b) 50 \u00b0C\u65f6CuS\u6b63\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

c) CuS\u548cMo6<\/sub>S8<\/sub>\u7684\u5145\/\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

d) 50 \u00b0C\u65f6\u3001\u626b\u901f0.02 mV\u00b7s-1<\/sup>\u30010.2-1.9 V\u8303\u56f4\u5185CuS\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

e,f) 50 \u00b0C\u65f6 50 mA\u00b7g-1<\/sup>\u4e0b CuS\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe4 CuS\u7684\u50a8\u9541\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001CuS\u7684\u975e\u539f\u4f4dXRD\u8c31\u56fe\u4ee5\u53ca\u76f8\u5e94\u7684\u7535\u538b-\u65f6\u95f4\u66f2\u7ebf\uff1b<\/p>\n

c) \u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001CuS\u7684XPS\u5149\u8c31\uff1b<\/p>\n

d-g) \u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001CuS\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe5 CuS\u7684\u50a8\u9541\u884c\u4e3a<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u9996\u6b21\u653e\u7535\u8fc7\u7a0b\u540eCuS\u7684TEM\u56fe\u50cf\u3001HAADF\u56fe\u50cf\u548c\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

c) GITT\u66f2\u7ebf\uff1b<\/p>\n

d) \u57fa\u4e8eGITT\u66f2\u7ebf\u8ba1\u7b97\u6240\u5f97\u7684Mg2+<\/sup>\u6269\u6563\u968f\u653e\u7535\u5bb9\u91cf\u7684\u53d8\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5728Mg(ClO4<\/sub>)2<\/sub>\/AN\u7535\u89e3\u6db2\u4e2d\uff0cCuS\u6b63\u6781\u7684\u5ba4\u6e29\u50a8\u9541\u6d3b\u6027\u53ef\u9ad8\u8fbe361 mAh\u00b7g-1<\/sup>\u3002\u6b64\u5916\uff0c\u5176\u5728\u9541\u5168\u7535\u6c60\u4e2d\u4e5f\u663e\u793a\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5373\u8f83\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf(165 mAh\u00b7g-1<\/sup>)\u30011.15 V\u7684\u653e\u7535\u7535\u538b\u5e73\u53f0\u4ee5\u53ca\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027(50 mA\u00b7g-1<\/sup>\u4e0b\u5faa\u73af30\u6b21\u540e\u5bb9\u91cf\u4fdd\u6301\u5728119 mAh\u00b7g-1<\/sup>)\uff0c\u4f18\u4e8e\u62a5\u9053\u4e2d\u76f8\u540c\u6e29\u5ea6\u4e0b\u7684\u6700\u597d\u7ed3\u679c\u3002\u6b64\u5916\uff0c\u8fd8\u8bc1\u5b9eCuS\u6b63\u6781\u7684\u50a8\u9541\u673a\u5236\u4e3a\u8f6c\u6362\u53cd\u5e94\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660eCuS\u4f5c\u4e3a\u9541\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u524d\u666f\u826f\u597d\u3002<\/p>\n

\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u6559\u6388\u3001\u5b89\u7434\u53cb\u526f\u7814\u7a76\u5458<\/strong>\u8fd1\u5e74\u6765\u5728\u9541\u57fa\u7535\u6c60\u6b63\u6781\u6750\u6599\u9886\u57df\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u8fdb\u5c55\u3002(1)\u5229\u7528\u77f3\u58a8\u70ef\u4e0e\u9492\u6eb6\u80f6\u7684\u9759\u7535\u5f15\u529b\u4f5c\u7528\uff0c\u7ed3\u5408\u51b7\u51bb\u5e72\u71e5\u6280\u672f\u5236\u5907\u4e86\u77f3\u58a8\u70ef\u4fee\u9970\u7684\u6c34\u5408\u4e94\u6c27\u5316\u4e8c\u9492\u7eb3\u7c73\u7ebf\uff0c\u8be5\u590d\u5408\u6750\u6599\u901a\u8fc7\u5c42\u95f4\u6c34\u7684\u201c\u5c4f\u853d\u6548\u5e94\u201d\u4ee5\u53ca\u77f3\u58a8\u70ef\u5bf9\u7535\u5b50\u4f20\u5bfc\u7684\u589e\u5f3a\u5b9e\u73b0\u4e86\u4f18\u5f02\u7684\u50a8\u9541\u6027\u80fd\uff0c\u5bb9\u91cf\u9ad8\u8fbe330 mAh g-1<\/sup>\uff0c\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af200\u6b21\u5bb9\u91cf\u4fdd\u6301\u738781% (Nano Energy, 2015, 18, 265\u2013272<\/a><\/strong>)\u3002(2)\u5bf9\u591a\u79cd\u9492\u7cfb\u6b63\u6781\u6750\u6599\u7528\u4e8e\u9502\u9541\u6df7\u5408\u79bb\u5b50\u7535\u6c60\u8fdb\u884c\u4e86\u63a2\u7d22\uff0c\u5e76\u83b7\u5f97\u4e86\u4f18\u79c0\u7684\u7535\u5316\u5b66\u6027\u80fd(ACS Applied Materials & Interfaces, 2017, 9, 17060\u221217066<\/a><\/strong>; ACS Applied Materials & Interfaces, 2017, 9, 28667\u221228673<\/a><\/strong>)\u3002\u5176\u4e2d\uff0c\u4e8c\u786b\u5316\u9492\u5b9e\u73b0\u4e8610000\u6b21\u7684\u5faa\u73af\u5bff\u547d\uff0c\u572880 C\u7684\u9ad8\u500d\u7387\u7535\u6d41\u4e0b\uff0c\u5bb9\u91cf\u4ecd\u4fdd\u6301\u5728129 mAh g-1<\/sup> (Energy Storage Materials, 2018, 12, 61-68<\/a><\/strong>)\u3002(3)\u7814\u7a76\u4e86\u5177\u6709NASICON \u7ed3\u6784\u7684\u78f7\u9178\u949b\u76d0\u4f5c\u4e3a\u9541\u57fa\u6df7\u5408\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5e76\u7ed3\u5408\u539f\u4f4dXRD\u53ca\u975e\u539f\u4f4d\u8868\u5f81\u63a2\u7a76\u4e86\u5b58\u50a8\u673a\u5236(Advanced Energy Materials, 2017, 1700247<\/a><\/strong>;Journal of Materials Chemistry A, 2017, 5, 13950<\/a><\/strong>)\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Magnesium Storage Performance and Mechanism of CuS Cathode<\/a><\/strong>\u00a0(Nano Energy<\/strong>, 2018, DOI: 10.1016\/j.nanoen.2018.02.060)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u91d1\u5c5e\u9541\u5177\u6709\u8f83\u9ad8\u7684\u5bb9\u91cf(2205 mAh\u00b7g-1\u548c3833 mAh\u00b7cm-3)\u3001\u8f83\u4f4e\u7684\u8fd8\u539f\u7535\u4f4d(-2.37 V vs. SHE)\u3001\u50a8\u91cf\u4e30\u5bcc\u4ee5\u53ca\u65e0\u679d\u6676…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2263],"class_list":["post-130727","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2263"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130727"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=130727"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130727\/revisions"}],"predecessor-version":[{"id":130938,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130727\/revisions\/130938"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=130727"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=130727"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=130727"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}