{"id":130691,"date":"2018-03-20T14:00:09","date_gmt":"2018-03-20T06:00:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=130691"},"modified":"2018-03-17T21:32:01","modified_gmt":"2018-03-17T13:32:01","slug":"%e5%8d%97%e6%b4%8b%e7%90%86%e5%b7%a5%e9%a2%9c%e6%b8%85%e5%ae%87nano-energy-%e8%b6%85%e8%96%84%e4%ba%8c%e7%bb%b4%e9%93%81%e6%8e%ba%e6%9d%82%e7%a1%ab%e4%bb%a3%e7%a3%b7%e9%85%b8%e9%95%8d%e7%ba%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=130691","title":{"rendered":"\u5357\u6d0b\u7406\u5de5\u989c\u6e05\u5b87Nano Energy : \u8d85\u8584\u4e8c\u7ef4\u94c1\u63ba\u6742\u786b\u4ee3\u78f7\u9178\u954d\u7eb3\u7c73\u7247\u53ca\u5176\u9ad8\u6548\u7535\u50ac\u5316\u4ea7\u6c27"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u8bb8\u591a\u7eb3\u7c73\u8fc7\u6e21\u91d1\u5c5e\u975e\u6c27\u5316\u7269\uff0c\u5305\u62ec\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\u3001\u786b\u5316\u7269\u3001\u787c\u5316\u7269\u7852\u5316\u7269\u548c\u78f7\u5316\u7269\u7b49\uff0c\u5df2\u4f5c\u4e3aOER\u7535\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7814\u7a76\u3002\u4f5c\u4e3a\u826f\u597d\u7684\u7535\u50ac\u5316\u5242\u4e00\u822c\u9700\u8981\uff1a(1)\u5177\u6709\u53ef\u8c03\u7535\u5b50\u7ed3\u6784\uff1b(2)\u5bfc\u7535\u6027\u5f3a\uff1b(3)\u5173\u952e\u7269\u79cd\u7684Gibbs\u81ea\u7531\u5438\u9644\u80fd\u6700\u4f18\u5316\uff0c\u4ee5\u589e\u5f3a\u7535\u8377\u8f6c\u79fb\u548c\u672c\u5f81OER\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u7cbe\u5fc3\u8bbe\u8ba1\u7684\u7eb3\u7c73\u7ed3\u6784(\u5982\u8d85\u85842D\u7eb3\u7c73\u7247)\u7531\u4e8e\u5177\u6709\u9ad8\u5ea6\u66b4\u9732\u7684\u8868\u9762\u548c\u8fb9\u7f18\uff0c\u80fd\u591f\u63d0\u4f9b\u4e30\u5bcc\u7684\u7535\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u4ee5\u53caOER\u8fc7\u7a0b\u4e2d\u7535\u8377\u8f6c\u79fb\u548c\u8d28\u91cf\u4f20\u8f93\u901a\u9053\u3002\u6b64\u5916\uff0c2D\u7eb3\u7c73\u7247\u5728\u6db2\u76f8\u4e2d\u7684\u5206\u6563\u6027\u826f\u597d\uff0c\u6613\u4e8e\u52a0\u5de5\uff0c\u7a33\u5b9a\u6027\u826f\u597d\uff0c\u5bf9\u4e8e\u672a\u6765\u7684\u5b9e\u9645\u5e94\u7528\u5341\u5206\u6709\u5229\u3002\u7531\u4e8e\u5185\u5728\u7684\u5c42\u72b6\u7ed3\u6784\u3001\u591a\u6837\u6027\u548c\u72ec\u7279\u7684\u4e09\u5143\u7ec4\u5408\uff0c\u8fc7\u6e21\u91d1\u5c5e\u786b\u4ee3\u78f7\u9178\u76d0(MTPs)\u7528\u4e8e\u7535\u50ac\u5316\u6c34\u5206\u89e3\u5f97\u5230\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\uff0c\u5176\u590d\u6742\u7ec4\u5206\u80fd\u591f\u5bf9\u7535\u5b50\u7ed3\u6784\u8fdb\u884c\u8c03\u8282\u4ee5\u964d\u4f4eOER\u8def\u5f84\u7684\u80fd\u5792\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u989c\u6e05\u5b87\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5229\u7528\u7b80\u5355\u7684\u56fa\u76f8\u6cd5\u5927\u89c4\u6a21\u5236\u5907\u4e86\u8d85\u8584\u5355\u6676Fe\u63ba\u6742\u786b\u4ee3\u78f7\u9178\u954d(NiPS3<\/sub>)\u7eb3\u7c73\u7247\uff0c\u5177\u6709\u9ad8\u6548\u7535\u50ac\u5316OER\u6d3b\u6027\uff0c\u5e76\u5728Nano Energy<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cAchieving Highly Efficient Electrocatalytic Oxygen Evolution with Ultrathin 2D Fe-doped Nickel Thiophosphate Nanosheets<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u663e\u793a\uff0cFe\u63ba\u6742\u901a\u8fc7\u51cf\u5c11NiPS3<\/sub>\u8868\u9762\u7684\u542b\u6c27\u7269\u79cd\u7ea6\u675f\u6709\u6548\u964d\u4f4e\u4e86OER\u8def\u5f84\u7684\u80fd\u5792\u3002\u56e0\u6b64\uff0cFe\u63ba\u6742NiPS3<\/sub>\u7eb3\u7c73\u7247\u4ee5256 mV\u7684\u8fc7\u7535\u52bf\u8fbe\u523030 mA\u00b7cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u548c46 mV\u00b7dec-1<\/sup>\u7684\u5854\u83f2\u5c14\u659c\u7387\uff0c\u662f\u8fc4\u4eca\u4e3a\u6b62\u78b1\u6027\u4ecb\u8d28\u4e2d\u6700\u4f18\u7684OER\u7535\u50ac\u5316\u5242\u3002\u6df1\u5165\u7684\u673a\u7406\u7814\u7a76\u8868\u660e\uff0cOER\u8fc7\u7a0b\u4e2d\u53d1\u751f\u4e86\u8868\u9762\u6c27\u5316\u53cd\u5e94\uff0c\u539f\u4f4d\u5f62\u6210\u4e86Fe\u63ba\u6742\u954d\u6c27\u5316\u7269\/\u6c22\u6c27\u5316\u7269\u5c42\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u4f5c\u4e3a\u826f\u597d\u7684\u7535\u50ac\u5316\u7269\u79cd\uff0c\u4e5f\u63d0\u9ad8\u4e86Fe\u63ba\u6742NiPS3<\/sub>\u5728\u78b1\u6027\u7535\u89e3\u6db2\u4e2d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 Fe\u63ba\u6742NiPS3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u548c\u8868\u9762\u5143\u7d20<\/strong><\/p>\n

\"\"<\/p>\n

a) Fe\u63ba\u6742NiPS3<\/sub>\u7684XRD\u56fe\u8c31\u548cRietveld\u7cbe\u4fee\uff0c\u5185\u63d2\uff1aFe\u63ba\u6742NiPS3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\uff1b<\/p>\n

b) Fe\u63ba\u6742NiPS3<\/sub>\u7684Ni 2p XPS\u8c31\u56fe\uff1b<\/p>\n

c) Fe\u63ba\u6742NiPS3<\/sub>\u7684Fe 2p XPS\u8c31\u56fe\uff1b<\/p>\n

d) Fe\u63ba\u6742NiPS3<\/sub>\u7684S 2p XPS\u8c31\u56fe\uff1b<\/p>\n

e) Fe\u63ba\u6742NiPS3<\/sub>\u7684P 2p XPS\u8c31\u56fe\u3002<\/p>\n

\u56fe2 Fe\u63ba\u6742NiPS3<\/sub>\u7684\u5f62\u8c8c\u548c\u5143\u7d20\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

a,b) Fe\u63ba\u6742NiPS3<\/sub>\u7684\u4f4e\u5206\u8fa8\u3001\u9ad8\u5206\u8fa8SEM\u56fe\u50cf\uff1b<\/p>\n

c) Fe\u63ba\u6742NiPS3<\/sub>\u7684TEM\u56fe\u50cf\uff0c\u5185\u63d2\uff1a\u9009\u533a\u7535\u5b50\u884d\u5c04\u56fe\u50cf\uff1b<\/p>\n

d) Fe\u63ba\u6742NiPS3<\/sub>\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

e) Fe\u63ba\u6742NiPS3<\/sub>\u7684\u5143\u7d20\u5206\u5e03\u3002<\/p>\n

\u56fe3 Fe\u63ba\u6742NiPS3<\/sub>\u7684\u7535\u50ac\u5316OER\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u626b\u901f5 mV\u00b7s-1<\/sup>\uff0c1.0 mol\u00b7L-1<\/sup> KOH\u6eb6\u6db2\u4e2dFe\u63ba\u6742NiPS3<\/sub>\u7684iR\u6821\u6b63\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

b) \u626b\u901f5 mV\u00b7s-1<\/sup>\uff0c1.0 mol\u00b7L-1<\/sup> KOH\u6eb6\u6db2\u4e2dFe\u63ba\u6742NiPS3<\/sub>\u7684\u5854\u83f2\u5c14\u659c\u7387\uff1b<\/p>\n

c) \u6052\u8fc7\u7535\u52bf(256 mV)\u4e0b\u7535\u6d41\u5bc6\u5ea6\u968f\u65f6\u95f4\u53d8\u5316\u66f2\u7ebf\uff1b<\/p>\n

d) \u7535\u5316\u5b66\u53cc\u7535\u5c42\u7535\u5bb9\u8fd1\u4f3c\u3002<\/p>\n

\u56fe4 Fe\u63ba\u6742NiPS3<\/sub>\u7684\u7406\u8bba\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

a) NiPS3<\/sub>\u548cFe\u63ba\u6742NiPS3<\/sub>\u7684DOS\u8ba1\u7b97\uff1b<\/p>\n

b) Fe\u63ba\u6742NiPS3<\/sub> DFT + U\u8ba1\u7b97\u4e2dNi\u548cFe\u7684DOS\uff1b<\/p>\n

c,d) \u7528\u4e8e\u8ba1\u7b97NiPS3<\/sub>\u548cFe\u63ba\u6742NiPS3<\/sub>\u8868\u9762\u542b\u6c27\u4e2d\u95f4\u4f53\u5438\u9644\u81ea\u7531\u80fd\u7684\u6700\u4f18\u7ed3\u6784\u3002<\/p>\n

\u56fe5 Fe\u63ba\u6742NiPS3<\/sub>\u7684\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a) \u672a\u8fdb\u884cOER\u6d4b\u8bd5\u7684Fe\u63ba\u6742NiPS3<\/sub>\u7eb3\u7c73\u7247\u7684HRTEM \u56fe\u50cf\uff1b<\/p>\n

b-d) 1.0 M KOH\u4e2d\uff0cCV\u626b\u63cfFe\u63ba\u6742NiPS3<\/sub>\u7eb3\u7c73\u724720\u3001200\u548c1000\u6b21\u540e\u7684\u6781\u5316\u66f2\u7ebfHRTEM \u56fe\u50cf\uff0c\u5185\u63d2\u5747\u4e3a\u76f8\u5e94\u7684\u5085\u91cc\u53f6\u53d8\u6362\u56fe\u50cf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5927\u89c4\u6a21\u5236\u5907\u4e86\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u3001\u9ad8\u7535\u50ac\u5316\u6c27\u5316\u6c34\u6d3b\u6027\u7684\u8d85\u85842D Fe\u63ba\u6742NiPS3<\/sub>\u7eb3\u7c73\u7247\u3002\u4f18\u79c0\u7684OER\u6027\u80fd\u5e94\u5f52\u56e0\u4e8eFe\u63ba\u6742\u3001\u53ef\u8c03\u7ec4\u6210\u30012D\u8d85\u8584\u7eb3\u7c73\u7ed3\u6784\u548c\u9ad8\u66b4\u9732\u8868\u9762\u7684\u534f\u540c\u6548\u5e94\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u6269\u5927\u4e86\u9ad8\u6548\u3001\u4f4e\u5ec9\u7684OER\u7535\u50ac\u5316\u5242\u7684\u8303\u56f4\uff0c\u4e5f\u4fc3\u8fdb\u4e862D\u4e09\u5143\u5c42\u72b6MPTs\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Achieving Highly Efficient Electrocatalytic Oxygen Evolution with Ultrathin 2D Fe-doped Nickel Thiophosphate Nanosheets<\/a><\/strong>\u00a0(Nano Energy<\/strong>, 2018, DOI: 10.1016\/j.nanoen.2018.02.048)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\uff0c\u8bb8\u591a\u7eb3\u7c73\u8fc7\u6e21\u91d1\u5c5e\u975e\u6c27\u5316\u7269\uff0c\u5305\u62ec\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\u3001\u786b\u5316\u7269\u3001\u787c\u5316\u7269\u7852\u5316\u7269\u548c\u78f7\u5316\u7269\u7b49\uff0c\u5df2\u4f5c\u4e3aOER\u7535\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7814\u7a76\u3002\u4f5c\u4e3a\u826f\u597d\u7684\u7535\u50ac\u5316\u5242\u4e00\u822c\u9700\u8981\uff1a…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2958],"class_list":["post-130691","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2958"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130691"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=130691"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130691\/revisions"}],"predecessor-version":[{"id":130934,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130691\/revisions\/130934"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=130691"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=130691"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=130691"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}