{"id":130112,"date":"2018-03-18T06:30:49","date_gmt":"2018-03-17T22:30:49","guid":{"rendered":"\/\/m.iemloyee.com\/?p=130112"},"modified":"2018-03-14T09:36:48","modified_gmt":"2018-03-14T01:36:48","slug":"%e5%8d%97%e4%ba%ac%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%ef%bc%9a%e9%80%9a%e8%bf%87%e5%88%86%e5%ad%90%e5%b1%82%e5%86%85%cf%80-%cf%80%e7%9b%b8%e4%ba%92%e4%bd%9c%e7%94%a8%e6%9e%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=130112","title":{"rendered":"\u5357\u4eac\u5de5\u4e1a\u5927\u5b66Angew. Chem. Int. Ed.\uff1a\u901a\u8fc7\u5206\u5b50\u5c42\u5185\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u6784\u5efa\u6c22\u952e\u6709\u673a\u82b3\u9999\u9aa8\u67b6\u7528\u4e8e\u83b7\u5f97\u8d85\u957f\u78f7\u5149"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n

\u6709\u673a\u591a\u5b54\u53d1\u5149\u6750\u6599\u4e3b\u8981\u5305\u62ec\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\uff0c\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COFs\uff09\u548c\u6c22\u952e\u6709\u673a\u9aa8\u67b6\uff08HOFs\uff09\u3002\u6709\u673a\u591a\u5b54\u53d1\u5149\u6750\u6599\u51ed\u501f\u5176\u5728\u5316\u5b66\u4f20\u611f\u3001\u751f\u7269\u6210\u50cf\u7b49\u65b9\u9762\u7684\u5e94\u7528\u800c\u53d7\u5230\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u53d1\u5149\u5206\u4e3a\u8367\u5149\u548c\u78f7\u5149\u3002\u4e0e\u8367\u5149\u76f8\u6bd4\uff0c\u78f7\u5149\u56e0\u5177\u5907\u8d85\u957f\u5bff\u547d\u3001\u9ad8\u7684\u53d1\u5149\u91cf\u5b50\u6548\u7387\u7b49\u4f18\u70b9\u5728\u751f\u7269\u6210\u50cf\u548c\u5149\u7535\u5668\u4ef6\u7b49\u65b9\u9762\u90fd\u6709\u5f88\u597d\u7684\u4f18\u52bf\u3002\u57fa\u4e8eMOFs\u7684\u78f7\u5149\u6750\u6599\u666e\u904d\u5177\u6709\u8f83\u9ad8\u7684\u751f\u7269\u6bd2\u6027\u3001\u8f83\u5dee\u7684\u7a33\u5b9a\u6027\u3001\u4e25\u82db\u7684\u5236\u5907\u6761\u4ef6\u7b49\u7279\u70b9\uff0c COFs\u00a0\u548c HOFs \u7531\u4e8e\u7f3a\u5c11\u91cd\u539f\u5b50\u7684\u4fc3\u8fdb\u4f5c\u7528\uff0c\u7cfb\u95f4\u7a9c\u8d8a\u56f0\u96be\uff0c\u76ee\u524d\u5c1a\u65e0\u6709\u78f7\u5149\u6750\u6599\u62a5\u9053\u3002\u800cHOFs\u78f7\u5149\u6750\u6599\u51ed\u501f\u5176\u6e29\u548c\u7684\u5236\u5907\u6761\u4ef6\u548c\u53ef\u5faa\u73af\u5229\u7528\u7684\u7279\u70b9\uff0c\u62e5\u6709\u66f4\u5e7f\u6cdb\u7684\u5229\u7528\u524d\u666f\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66<\/b><\/strong>\u9ec4\u7ef4\u9662\u58eb<\/b><\/strong>\u548c\u5b89\u4f17\u798f<\/b><\/strong>\u8bfe\u9898\u7ec4\uff0c\u901a\u8fc7\u5206\u5185\u5b50\u5c42\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u6210\u529f\u6784\u5efa\u51fa\u5177\u6709\u4e0d\u540c\u5b54\u5f84\u7684\u6c22\u952e\u6709\u673a\u82b3\u9999\u9aa8\u67b6\uff08HOAFs\uff09\u3002\u6240\u5236\u5907\u7684HOAFs\u9996\u6b21\u5728\u5ba4\u6e29\u7a7a\u6c14\u4e2d\u5b9e\u73b0\u4e86\u8d85\u957f\u6709\u673a\u78f7\u5149\u53d1\u5149\uff0c\u4e5f\u5c31\u662f\u6709\u673a\u957f\u4f59\u8f89\u53d1\u5149\u3002\u5176\u4e2d\uff0cPhTCz-1\u7684\u9ec4\u8272\u8367\u5149\u5bff\u547d\u8fbe79.8\u00a0ms\uff0c\u5728\u505c\u6b62\u6fc0\u53d1\u540e\u53ef\u89c2\u5bdf\u5230\u6301\u7eed\u51e0\u79d2\u957f\u4f59\u8f89\u53d1\u5149\u3002\u800cPhTCz-2\u548cPhTCz-3\uff0c\u7531\u4e8e\u6c27\u6c14\u7684\u731d\u706d\u4f5c\u7528\uff0c\u5176\u957f\u4f59\u8f89\u73b0\u8c61\u53ea\u80fd\u5728\u6c2e\u6c14\u4e2d\u89c2\u5bdf\u5230\uff0c\u9274\u4e8e\u6b64\u7279\u6027\u53ef\u88ab\u7528\u6765\u68c0\u6d4b\u6c27\u6c14\u3002\u8be5\u5de5\u4f5c\u62d3\u5c55\u4e86\u65e0\u91d1\u5c5e\u6709\u673a\u78f7\u5149\u6750\u6599\u7684\u4f53\u7cfb\u3002\u540c\u65f6\uff0c\u8be5\u7c7b\u65b0\u578b\u7684HOAFS\u6750\u6599\u8fd8\u6709\u9ad8\u7684\u70ed\u5206\u89e3\u6e29\u5ea6\uff0c\u8fd9\u4e5f\u4e3a\u8bbe\u8ba1\u65b0\u578b\u9ad8\u6e29\u7a33\u5b9a\u7684HOFs\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Hydrogen-Bonded Organic Aromatic Frameworks for Ultralong Phosphorescence by Intralayer <\/b><\/strong>\u03c0-\u03c0<\/b><\/strong>\u00a0<\/b><\/strong>Interactions<\/b><\/strong>“\u53d1\u8868\u5728Angew. Chem. Int. Ed.<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>1 <\/b><\/strong>\u5178\u578b\u7684\u6c22\u952e\u6709\u673a\u9aa8\u67b6\u793a\u610f\u56fe\u548c\u57fa\u4e8ePhTCz\u7684\u6c22\u952e\u6709\u673a\u82b3\u9999\u9aa8\u67b6\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>2 <\/b><\/strong>PhTCz-1\uff0cPhTCz-2\u548cPhTCz-3\u7684\u5206\u5b50\u5806\u79ef<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>3 <\/b><\/strong>\u5149\u5b66\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A.PhTCz-1\uff0cPhTCz-2\u548cPhTCz-3\u5728365 nm\u6fc0\u53d1\u4e0b\u7684\u8367\u5149\u3001\u78f7\u5149\u5149\u8c31\u4ee5\u53caPhTCz-1\u5728365 nm\u6fc0\u53d1\u65f6\u548c\u6fc0\u53d1\u540e\u7684\u7167\u7247<\/p>\n

B.PhTCz-1\uff0cPhTCz-2\u548cPhTCz-3\u7684\u78f7\u5149\u5bff\u547d\u8870\u53d8<\/p>\n

\u56fe<\/b><\/strong>4 <\/b><\/strong>PhTCz-1\u7684\u6676\u4f53\u7ed3\u6784\u548c\u673a\u7406\u89e3\u91ca<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A.PhTCz-1\u7684\u5206\u5b50\u5806\u53e0<\/p>\n

B. H-\u805a\u96c6\u7684PhTCz-1\u4e8c\u805a\u4f53\u4f18\u5316\u540e\u6700\u4f4e\u4e09\u7ebf\u6001\uff08T1<\/sub>\uff09\u8dc3\u8fc1\u8f68\u9053\u7535\u5b50\u4e91\u5206\u5e03<\/p>\n

C.HOAFs\u8d85\u957f\u78f7\u5149\u7684\u673a\u7406\u63a8\u6d4b<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u901a\u8fc7\u5206\u5b50\u5c42\u5185\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u6784\u5efa\u4e86\u5177\u6709\u957f\u4f59\u8f89\u7279\u6027\u7684\u6c22\u952e\u6709\u673a\u82b3\u9999\u9aa8\u67b6\u3002\u540c\u4e00\u4e2a\u6784\u5efa\u5355\u5143\u5728\u4e09\u79cd\u4e0d\u540c\u7684\u6eb6\u5242\u4f53\u7cfb\u4e2d\u5f62\u6210\u4e09\u79cd\u4e0d\u540c\u7684\u6c22\u952e\u6709\u673a\u82b3\u9999\u9aa8\u67b6\u3002\u8fd9\u4e09\u79cdHOAFs\u9664\u4e86\u5177\u6709\u4f18\u8d8a\u7684\u70ed\u7a33\u5b9a\u6027\uff0cPhTCz-1\u6676\u4f53\u53d7\u6fc0\u53d1\u540e\u957f\u4f59\u8f89\u8fbe\u51e0\u79d2\uff0cPhTCz-2\u548cPhTCz-3\u6676\u4f53\u78f7\u5149\u5f3a\u5ea6\u968f\u6c27\u542b\u91cf\u7684\u589e\u52a0\u800c\u51cf\u5f31\uff0c\u53ef\u7528\u4e8e\u6c27\u6c14\u4f20\u611f\u3002\u8fd9\u4e2a\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u65e0\u91d1\u5c5e\u78f7\u5149\u591a\u5b54\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Hydrogen-Bonded Organic Aromatic Frameworks for Ultralong Phosphorescence by Intralayer \u03c0-\u03c0\u00a0Interactions.<\/a> (Angew. Chem. Int. Ed., 2018,\u00a0DOI: 10.1002\/anie.201800697)<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n

\u81ea2015\u5e74\uff0c\u9ec4\u7ef4\u9662\u58eb\u548c\u5b89\u4f17\u798f\u8bfe\u9898\u7ec4\u5728\u56fd\u9645\u4e0a\u9996\u6b21\u63d0\u51fa\u4e86H-\u805a\u96c6\u7ed3\u6784\u7a33\u5b9a\u4e09\u7ebf\u6001\u6fc0\u5b50\u5b9e\u73b0\u6709\u673a\u957f\u4f59\u8f89\u53d1\u5149\u7684\u5206\u5b50\u8bbe\u8ba1\u601d\u60f3\uff0c\u6709\u673a\u957f\u4f59\u8f89\u53d1\u5149\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u540c\u65f6\uff0c\u8be5\u8bfe\u9898\u7ec4\u4e00\u76f4\u81f4\u529b\u4e8e\u6709\u673a\u957f\u4f59\u8f89\u53d1\u5149\u7684\u7814\u7a76\uff0c\u5305\u62ec\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\uff0c\u63a2\u7d22\u53d1\u5149\u673a\u7406\uff0c\u5e76\u5c06\u6709\u673a\u957f\u4f59\u8f89\u6750\u6599\u5e94\u7528\u4e8e\u65b0\u578b\u6570\u636e\u52a0\u5bc6\uff0c\u751f\u7269\u6210\u50cf\uff0c\u9632\u4f2a\u4ee5\u53ca\u6c14\u4f53\u4f20\u611f\u7b49\u65b9\u9762\u3002\u8be5\u8bfe\u9898\u7ec4\u5728\u6709\u673a\u957f\u4f59\u8f89\u53d1\u5149\u65b9\u9762\u5f00\u5c55\u4e86\u4e00\u7cfb\u5217\u5de5\u4f5c\uff0c\u5e76\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520a\u4e0a\uff08Nat. Mater<\/i><\/em>,\u00a02015<\/b><\/strong>, 14<\/i><\/em>, 685\uff1bAngew. Chem. Int. Ed<\/i><\/em>, 2018<\/b><\/strong>, 57<\/i><\/em>, 678\uff1bAdv. Mater<\/i><\/em>, 2017<\/b><\/strong>, 29<\/i><\/em>, 1701244\uff1bAdv. Funct. Mater<\/i><\/em>, 2018<\/b><\/strong>, 28<\/i><\/em>, 1705045\uff1bJ. Mater. Chem. C<\/i><\/em>, 2018<\/b><\/strong>, 6<\/i><\/em>, 226\uff09\uff0c\u5176\u4e2d\u4e24\u7bc7\u88ab\u9009\u4e3a\u6742\u5fd7\u5c01\u9762\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002 \u00a0<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002 \u00a0<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u6709\u673a\u591a\u5b54\u53d1\u5149\u6750\u6599\u4e3b\u8981\u5305\u62ec\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\uff0c\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COFs\uff09\u548c\u6c22\u952e\u6709\u673a\u9aa8\u67b6\uff08HOFs\uff09\u3002\u6709\u673a\u591a\u5b54\u53d1\u5149\u6750\u6599\u51ed\u501f\u5176\u5728\u5316\u5b66\u4f20\u611f\u3001\u751f\u7269\u6210\u50cf\u7b49\u65b9\u9762…<\/p>\n","protected":false},"author":7336,"featured_media":130113,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2946,2947],"class_list":["post-130112","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2946","tag-2947"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130112"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7336"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=130112"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130112\/revisions"}],"predecessor-version":[{"id":130211,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/130112\/revisions\/130211"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/130113"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=130112"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=130112"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=130112"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}