{"id":129984,"date":"2018-03-15T09:00:57","date_gmt":"2018-03-15T01:00:57","guid":{"rendered":"\/\/m.iemloyee.com\/?p=129984"},"modified":"2018-03-15T09:38:22","modified_gmt":"2018-03-15T01:38:22","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e7%86%8a%e5%ae%87%e6%9d%b0%e5%be%90%e8%88%aa%e5%8b%8bangew-chem-int-ed-%ef%bc%9a%e7%94%b1%e8%b6%85%e8%96%84%e5%8c%96%e5%90%88%e7%89%a9%e7%ba%b3%e7%b1%b3%e7%89%87","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=129984","title":{"rendered":"\u4e2d\u79d1\u5927\u718a\u5b87\u6770&\u5f90\u822a\u52cbAngew. Chem. Int. Ed.\uff1a\u7531\u8d85\u8584\u5316\u5408\u7269\u7eb3\u7c73\u7247\u7ec4\u6210\u7684\u8303\u5fb7\u534e\u529b\u5f02\u8d28\u7ed3\u6784\u7528\u4e8eZ\u578b\u9ad8\u6548\u5168\u89e3\u6c34"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4eba\u4eec\u4e00\u76f4\u5728\u601d\u7d22\u5982\u4f55\u5728\u4e0d\u4f7f\u7528\u727a\u7272\u5242\u7684\u60c5\u51b5\u4e0b\u7814\u53d1\u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u5316\u5b66\u67d3\u6599\u7684\u5149\u50ac\u5316\u5168\u89e3\u6c34\u7cfb\u7edf\u3002\u867d\u7136\u7ed3\u6784\u53ef\u8c03\u578b\u9ad8\u5206\u5b50\u5316\u5408\u7269\u5149\u50ac\u5316\u5242\u53ef\u88ab\u89c6\u4f5c\u65e0\u673a\u5149\u89e3\u6c34\u5149\u50ac\u5316\u5242\u7684\u4ee3\u66ff\u54c1\uff0c\u4f46\u662f\u4ec5\u6709\u975e\u5e38\u5c11\u7684\u805a\u5408\u7269\u5149\u50ac\u5316\u5242\u6709\u5408\u9002\u7684\u80fd\u5e26\u7ed3\u6784\uff0c\u5373\u62e5\u6709\u53ef\u540c\u65f6\u9a71\u52a8\u6c34\u7684\u6c27\u5316\u548c\u8d28\u5b50\u7684\u8fd8\u539f\u7684\u6c27\u5316\u8fd8\u539f\u52bf\uff0c\u6240\u4ee5\u7814\u53d1\u5355\u6210\u5206\u5149\u89e3\u6c34\u5149\u50ac\u5316\u5242\u4ecd\u5177\u6709\u6311\u6218\u3002\u53d7\u81ea\u7136\u754c\u5149\u5408\u4f5c\u7528\u542f\u53d1\uff0cZ\u578b\u5149\u50ac\u5316\u7cfb\u7edf\u5728\u5b9e\u73b0\u9ad8\u6548\u5168\u89e3\u6c34\u4e2d\u6709\u91cd\u5927\u6f5c\u529b\u3002\u7136\u800c\uff0c\u5982\u4f55\u5236\u9020\u65e0\u91d1\u5c5e\u7684Z\u578b\u5149\u50ac\u5316\u7cfb\u7edf\u4ecd\u662f\u4e2a\u96be\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u5927\u718a\u5b87\u6770\u6559\u6388\u548c\u5f90\u822a\u52cb\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5229\u7528\u57fa\u4e8e\u8303\u5fb7\u74e6\u8033\u65af\u529b\u529b\u7684\u9ad8\u5206\u5b50\u805a\u5408\u7269\u5f02\u8d28\u7ed3\u6784\u5b9e\u73b0\u4e86\u65e0\u91d1\u5c5eZ\u578b\u5149\u50ac\u5316\u7cfb\u7edf\u7684\u6784\u5efa\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u76ee\u201cVan der Waals Heterostructures Comprised of Ultrathin Polymer Nanosheets for Efficient Z-Scheme Overall Water Splitting<\/strong>\u201d\u53d1\u8868\u4e8e\u671f\u520aAngew. Chem. Int. Ed.<\/strong>\u3002\u901a\u8fc7\u5229\u7528\u963f\u624e\u80de\u82f7\u5171\u8f6d\u5fae\u5b54\u805a\u5408\u7269\uff08aza-CMP\uff09\u548cC2<\/sub>N\u8d85\u8584\u7eb3\u7c73\u7247\u5206\u522b\u4f5c\u4e3aO2<\/sub>\u548cH2<\/sub>\u7684\u50ac\u5316\u5242\uff0c\u8be5\u5f02\u8d28\u7ed3\u6784\u7cfb\u7edf\u5b9e\u73b0\u4e860.23 %\u7684\u5149\u8f6c\u6c22\u6548\u7387\u3002\u5229\u7528\u77f3\u58a8\u70ef\u4f5c\u4e3a\u7535\u5b50\u4f20\u9012\u5a92\u4ecb\u589e\u5f3a\u754c\u9762\u7535\u8377\u8f6c\u79fb\uff0c\u8be5\u7cfb\u7edf\u5149\u8f6c\u6c22\u6548\u7387\u53ef\u8fdb\u4e00\u6b65\u88ab\u63d0\u9ad8\u52300.4 %\uff0c \u8be5\u6210\u679c\u63ed\u793a\u4e86\u9ad8\u5206\u5b50\u805a\u5408\u7269\u5728\u5168\u89e3\u6c34\u65b9\u9762\u7684\u6f5c\u529b\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. Z<\/strong>\u578b\u5149\u89e3\u6c34\u7cfb\u7edf\u7684\u5316\u5b66\u7ed3\u6784\u3001TEM<\/strong>\u56fe\u548cAFM<\/strong>\u56fe<\/strong><\/p>\n

\"\"a\uff09Aza-CMP\u548cC2<\/sub>N\u7684\u5316\u5b66\u7ed3\u6784<\/p>\n

b\uff09\u5df2\u5265\u79bbaza-CMP\u7684TEM\u56fe<\/p>\n

c\uff09\u5df2\u5265\u79bbC2<\/sub>N\u7684TEM\u56fe<\/p>\n

d\uff09Aza-CMP\u7684AFM\u56fe\u548c\u76f8\u5e94\u7684\u9ad8\u5ea6\u8f6e\u5ed3\u56fe<\/p>\n

e\uff09C2<\/sub>N\u7684AFM\u56fe\u548c\u76f8\u5e94\u7684\u9ad8\u5ea6\u8f6e\u5ed3\u56fe<\/p>\n

\u56fe2. Aza-CMP<\/strong>\u3001C2<\/sub>N<\/strong>\u7684SRPES<\/strong>\u8c31\u548cUV\/NIR <\/strong>\u6f2b\u53cd\u5c04\u5149\u8c31<\/strong><\/p>\n

\"\"a\uff09\u7531SPRES\u6d4b\u5f97\u7684aza-CMP\u548cC2<\/sub>N\u7eb3\u7c73\u7247\u7684\u4e8c\u6b21\u7535\u5b50\u622a\u6b62\u8c31<\/p>\n

b\uff09\u7531SPRES\u6d4b\u5f97\u7684aza-CMP\u548cC2<\/sub>N\u7eb3\u7c73\u7247\u7684\u4ef7\u5e26\u8c31<\/p>\n

c\uff09Aza-CMP\u548cC2<\/sub>N\u7684Tauc\u56fe<\/p>\n

d\uff09\u5bfc\u81f4Z\u578b\u5149\u50ac\u5316\u7ed3\u6784\u7684aza-CMP\u548cC2<\/sub>N\u7eb3\u7c73\u7247\u7684\u7535\u5b50\u80fd\u5e26\u7ed3\u6784<\/p>\n

\u56fe3. <\/strong>Aza-CMP<\/strong>\u3001<\/strong>C2<\/sub>N<\/strong>\u3001<\/strong>aza-CMP\/C2<\/sub>N<\/strong>\u5f02\u8d28\u7ed3\u6784\u7684\u6210\u4efd\u3001\u7ed3\u6784\u8868\u5f81\u548c<\/strong>aza-CMP\/C2<\/sub>N<\/strong>\u5f02\u8d28\u7ed3\u6784\u7684\u5149\u89e3\u6c34\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"a\uff09Aza-CMP\u548cC2<\/sub>N\u5f02\u8d28\u7ed3\u6784\u7684TEM\u56fe\uff0c\u7bad\u5934\u8868\u793a\u91cd\u53e0\u7684\u754c\u9762<\/p>\n

b\uff09Aza-CMP\u3001C2<\/sub>N\u548caza-CMP\/C2<\/sub>N\u7684\u6c2eK\u5cf0XANES\u8c31<\/p>\n

c\uff09\u94c2\u6807\u8bb0\u7684C2<\/sub>N\u548c\u94b4\u6807\u8bb0\u7684aza-CMP\u5f62\u6210\u7684\u5f02\u8d28\u7ed3\u6784HAADF-STEM\u5143\u7d20\u56fe<\/p>\n

d\uff09\u4e0d\u540c\u6210\u4efd\u7684aza-CMP\/C2<\/sub>N\u5f02\u8d28\u7ed3\u6784\u5168\u89e3\u6c34\u8868\u73b0<\/p>\n

e\uff09Aza-CMP\/RGP\/C2<\/sub>N\u5149\u50ac\u5316\u5242\u7684TEM\u56fe<\/p>\n

f\uff09\u5728\u53ef\u89c1\u5149\u7167\u4e0baza-CMP\/RGP\/C2<\/sub>N\u4ea7\u751fH2<\/sub>\u548cO2<\/sub>\u7684\u5178\u578b\u65f6\u5e8f\u56fe<\/p>\n

\u56fe4. Aza<\/strong>-CMP<\/strong>\u3001<\/strong>C2<\/sub>N<\/strong>\u3001<\/strong>aza-CMP\/C2<\/sub>N<\/strong>\u7b49\u50ac\u5316\u5242\u7684\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"a\uff09\u4e0d\u540c\u50ac\u5316\u5242\u7684\u5149\u81f4\u53d1\u5149\u8c31<\/p>\n

b\uff09\u4e0d\u540c\u50ac\u5316\u5242\u7684EIS\u56fe<\/p>\n

c\uff09\u4e0d\u540c\u50ac\u5316\u5242\u5728\u9ed1\u6697\u4e0b\u548c\u5149\u7167\u4e0b\u7684J-V\u66f2\u7ebf<\/p>\n

d\uff09\u4e0d\u540c\u50ac\u5316\u5242\u5728\u9ed1\u6697\u4e0b\u548c\u5149\u7167\u4e0b\u7684J-V\u66f2\u7ebf<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u5de5\u4f5c\u9610\u660e\u4e86\u5229\u7528\u8303\u5fb7\u534e\u529b\u53ef\u5c06\u4e0d\u540c\u7684\u8d85\u8584\u5316\u5408\u7269\u7eb3\u7c73\u7247\u7ec4\u5408\u6210\u65b0\u5174\u7684Z\u578b\u5168\u89e3\u6c34\u5149\u50ac\u5316\u7cfb\u7edf\uff0c\u4f18\u5316\u540e\u7684\u8be5\u7cfb\u7edf\u53ef\u8fbe\u52300.23 %\u7684\u5149\u8f6c\u6c22\u6548\u7387\u3002\u901a\u8fc7\u52a0\u5165\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u4f5c\u4e3a\u56fa\u4f53\u7535\u5b50\u5a92\u4ecb\uff0c\u5149\u8f6c\u6c22\u6548\u7387\u53ef\u7ee7\u7eed\u88ab\u63d0\u5347\u81f30.4 %\uff0c\u8fd9\u4e00\u7ed3\u6784\u80fd\u591f\u6709\u6548\u8f6c\u79fb\u7535\u8377\u5e76\u4fc3\u8fdb\u5149\u751f\u6fc0\u5b50\u8f6c\u79fb\u3002\u8be5\u5de5\u4f5c\u9996\u6b21\u63d0\u51fa\u5229\u75282D\u5316\u5408\u7269\u7eb3\u7c73\u7247\u6784\u9020\u7528\u4e8eZ\u578b\u5168\u89e3\u6c34\u7684\u8303\u5fb7\u534e\u5f02\u8d28\u7ed3\u6784\uff0c\u4e3aZ\u578b\u5168\u89e3\u6c34\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u7814\u53d1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aVan der Waals Heterostructures Comprised of Ultrathin Polymer Nanosheets for Efficient Z-Scheme Overall Water Splitting<\/a> (Angew. Chem. Int. Ed., 2018 , DOI: 10.1002\/anie.201710557)<\/p>\n

\u672c\u6750\u6599\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5c0f\u65af\u540c\u5b66\u7f16\u8bd1\uff0c\u5218\u5b87\u9f99\u5ba1\u6838\u3002\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/strong><\/p>\n

\u00a0<\/strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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