{"id":129167,"date":"2018-03-15T14:00:42","date_gmt":"2018-03-15T06:00:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=129167"},"modified":"2018-03-10T16:57:16","modified_gmt":"2018-03-10T08:57:16","slug":"%e5%8a%a0%e5%b7%9e%e5%a4%a7%e5%ad%a6%e4%bc%af%e5%85%8b%e5%88%a9%e5%88%86%e6%a0%a1nat-mater-%ef%bc%9a%e7%94%a8%e4%ba%8e%e6%b7%b7%e5%90%88%e9%87%91%e5%b1%9e%e6%b0%a7%e5%8c%96%e7%89%a9%e7%9a%84%e5%88%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=129167","title":{"rendered":"\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Nat. Mater.\uff1a\u7528\u4e8e\u6df7\u5408\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u5206\u5b50\u4ea4\u8054\u6cd5"},"content":{"rendered":"<p>\u3010<strong>\u5f15\u8a00<\/strong>\u3011<\/p>\n<p>\u5168\u7403\u5feb\u901f\u5de5\u4e1a\u5316\u5bfc\u81f4\u9646\u5730\u5143\u7d20\u8d44\u6e90\u9ad8\u5ea6\u7d27\u5f20\uff0c\u8bf8\u5982\u94c1\uff0c\u7845\uff0c\u949b\u548c\u94dd\u7b49\u5143\u7d20\u7684\u6c27\u5316\u7269\u56e0\u5730\u8868\u542b\u91cf\u4e30\u5bcc\u800c\u6781\u5177\u5438\u5f15\u529b\uff0c\u540c\u65f6\u5b83\u4eec\u5728\u80fd\u91cf\u50a8\u5b58\uff0c\u50ac\u5316\u4f5c\u7528\u548c\u91c7\u5149\u7b49\u91cd\u8981\u9886\u57df\u6709\u7740\u91cd\u8981\u4f5c\u7528\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u91d1\u5c5e\u6c27\u5316\u7269\u4ecb\u5bfc\u8f6c\u5316\u8fc7\u7a0b\u7684\u80fd\u529b\u662f\u6709\u9650\uff0c\u901a\u8fc7\u6e29\u548c\u800c\u7b80\u5355\u7684\u65b9\u6cd5\u5bf9\u8fd9\u4e9b\u6750\u6599\u6027\u80fd\u8fdb\u884c\u5fae\u8c03\u4ee5\u8fbe\u5230\u9ad8\u7684\u8f6c\u5316\u6548\u7387\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\u3002\u6700\u8fd1\uff0c\u6709\u5b66\u8005\u62a5\u9053\u4e86\u7528\u5206\u5b50\u4ea4\u8054\u7684\u65b9\u6cd5\u6539\u6027\u91d1\u5c5e\u6c27\u5316\u7269\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u7684Alexander M. Spokoyny (\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u4eba\u5728<strong>Nat. Mater.<\/strong>\u4e0a\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201c<strong>A molecular cross-linking approach for hybrid metal oxides<\/strong>\u201d\u3002\u4f5c\u8005\u521b\u65b0\u7684\u901a\u8fc7\u201c\u5206\u5b50\u4ea4\u8054\u201d\u6cd5\u6210\u529f\u5730\u5bf9\u91d1\u5c5e\u6c27\u5316\u7269\u8fdb\u884c\u4e86\u6539\u6027\u3002\u5176\u4e2d\u6df7\u5408\u5206\u5b50\u6c27\u5316\u787c\u6750\u6599\u7531\u591a\u9762\u4f53\u787c\u7c07\u524d\u4f53\u5f62\u6210\uff0c\u8fd9\u79cd\u65b0\u65b9\u6cd5\u7531\u787c\u7c07\u5206\u5b50\u7ed3\u6784\u5355\u5143\u56fa\u6709\u7684\u575a\u56fa\u6027\u6240\u652f\u6301\u7684\uff0c\u8be5\u7ed3\u6784\u4e0e\u91d1\u5c5e\u6c27\u5316\u7269\u5408\u6210\u6240\u9700\u82db\u523b\u7684\u70ed\u5b66\u548c\u6c27\u5316\u6761\u4ef6\u76f8\u5bb9\u3002\u6587\u4e2d\uff0c\u4f5c\u8005\u5229\u7528\u4e00\u7cfb\u5217\u5b9e\u9a8c\u6280\u672f\u548c\u6750\u6599\u6a21\u62df\u624b\u6bb5\uff0c\u5c55\u793a\u4e86\u8fd9\u79cd\u6750\u6599\u5982\u4f55\u4e0eTiO<sub>2<\/sub>\u548c\u5176\u4ed6\u91d1\u5c5e\u6c27\u5316\u7269\u6210\u529f\u5bf9\u63a5\uff0c\u4ece\u800c\u5236\u5907\u51fa\u4e86\u5177\u6709\u4f18\u5f02\u5149\u7269\u7406\u548c\u7535\u5316\u5b66\u7279\u6027\u7684\u5bcc\u787c\u6742\u5316\u6750\u6599\u3002<\/p>\n<p>\u3010<strong>\u56fe\u7247\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1 \u73b0\u6709\u5236\u5907\u65b9\u6cd5\u6982\u8ff0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-129168\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-23.jpg\" alt=\"\" width=\"600\" height=\"434\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-23.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/1-23-300x217.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a<\/strong>) \u91d1\u5c5e\u6c27\u5316\u7269\u5316\u5b66\u6539\u6027\u7684\u4e0d\u540c\u65b9\u6cd5:\u4f7f\u7528\u6709\u673a\u548c\u65e0\u673a\u67d3\u6599\u654f\u5316\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\uff1b<\/p>\n<p>(<strong>b<\/strong>) \u6750\u6599\u5408\u6210\u7684\u7efc\u5408\u8def\u5f84\uff1b<\/p>\n<p>(<strong>c<\/strong>) \u6750\u65993\u7684\u6f2b\u53cd\u5c04UV-vis\u6570\u636e\u3002<\/p>\n<p><strong>\u56fe2 \u6750\u65993\u7684\u7ed3\u6784\u6570\u636e<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-129169\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-20.jpg\" alt=\"\" width=\"600\" height=\"343\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-20.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/2-20-300x172.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a<\/strong>) \u5546\u7528TiO2\u548c\u6750\u65993\u7684PXRD\u56fe\u63ed\u793a\u4e86\u5728\u9510\u949b\u77ff\u76f8\u4e2d\u5b58\u5728TiO<sub>2<\/sub>\u6676\u4f53\uff1b<\/p>\n<p>(<strong>b<\/strong>) \u6750\u65993\u7684TEM\u56fe\u50cf\uff1b<\/p>\n<p>(<strong>c<\/strong>) \u6750\u65993\u7684STEM\u56fe\u50cf\uff0c\u663e\u793a\u4e86\u5d4c\u5165\u6750\u65992\u4e2d\u7684\u81f4\u5bc6TiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\uff1b<\/p>\n<p>(<strong>d<\/strong>) [NnBu<sub>4<\/sub>]<sub>2<\/sub>[B<sub>12<\/sub>(OH)1<sub>2<\/sub>] \u7684\u787c1s\u533a\u5728187.8eV\u548c191.2eV\u5904\u663e\u793a\u4e24\u4e2a\u5cf0\uff1b<\/p>\n<p>(<strong>e<\/strong>) \u6750\u65993\u7684\u949b2p\u533a\u57df\u5206\u522b\u5728459.1eV\u548c464.8eV\u5904\u663e\u793a\u51fa\u5cf0\uff1b<\/p>\n<p>(<strong>f<\/strong>) TiO<sub>2<\/sub>\uff0c\u6750\u65992\u548c3\u7684\u6c271s\u533a\u57df\u3002<\/p>\n<p><strong>\u56fe3 \u9510\u949b\u77ffTiO2\u548c\u6750\u65993 \u7684XANES\u548cEXAFS\u6570\u636e<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-129170\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/3-22.jpg\" alt=\"\" width=\"600\" height=\"240\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/3-22.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/3-22-300x120.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a<\/strong>) \u6750\u65993\u7684XANES\u6d4b\u91cf\u7ed3\u679c\u4e0e\u9510\u949b\u77ffTiO2\u7684\u6d4b\u91cf\u7ed3\u679c\u8fdb\u884c\u6bd4\u8f83\uff1b<\/p>\n<p>(<strong>b<\/strong>) \u6750\u65993\u548c\u9510\u949b\u77ff\u7684k\u5e73\u65b9\u52a0\u6743EXAFS\u51fd\u6570\u3002<\/p>\n<p><strong>\u56fe4 \u56fa\u6001\u787c\u7684 MAS NMR\u548cPDF\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-129171\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/4-19.jpg\" alt=\"\" width=\"600\" height=\"497\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/4-19.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/4-19-300x249.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a<\/strong>) \u6750\u65993\u7684\u56fa\u60011D\u5355\u8109\u51b211B MAS NMR(\u9876\u90e8)\u548c11B {1H} CP-MAS(\u5e95\u90e8)\u5149\u8c31\uff1b<\/p>\n<p>(<strong>b<\/strong>) \u6750\u65992\u76842D J-\u4ecb\u5bfc\u7684(\u901a\u8fc7\u952e)11B {11B}\u76f8\u5173\u8c31\uff1b<\/p>\n<p>(<strong>c<\/strong>) \u6750\u65992\u548c3\u7684PDF\u5206\u6790\uff1b<\/p>\n<p>(<strong>d<\/strong>) \u4f7f\u7528B<sub>2<\/sub>O<sub>3<\/sub>\u548c\u65e0\u5b9a\u5f62\u787c\u63a7\u5236\u6750\u65992\u548c3\u7684\u9644\u52a0PDF\u5206\u6790\u3002<\/p>\n<p><strong>\u56fe5 \u6750\u6599\u7535\u5316\u5b66\u6027\u8d28\u7684\u6570\u636e3<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-129172\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/5-14.jpg\" alt=\"\" width=\"600\" height=\"308\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/5-14.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/5-14-300x154.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p>(<strong>a<\/strong>) \u6750\u65992\u548c3\u5728\u5ba4\u6e29\u4e0b\u7684EPR\u5149\u8c31\uff1b<\/p>\n<p>(<strong>b<\/strong>) \u94c1-\u4e9a\u94c1\u6c30\u5316\u7269\u7684\u6c27\u5316\u8fd8\u539fCV\u66f2\u7ebf\uff1b<\/p>\n<p>(<strong>c<\/strong>) \u6750\u65993\uff0c\u9510\u949b\u77ff\u548c\u91d1\u7ea2\u77f3TiO<sub>2<\/sub>\u7684\u7535\u5b50\u8f6c\u79fb\u901f\u7387\u5e38\u6570\uff1b<\/p>\n<p>(<strong>d<\/strong>) \u888b\u5f0f\u7535\u6c60\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u793a\u610f\u56fe\uff1b<\/p>\n<p>(<strong>e<\/strong>) \u888b\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684CV\u66f2\u7ebf\uff1b<\/p>\n<p>(<strong>f<\/strong>) \u6052\u7535\u6d41\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe6 \u6750\u65993\u7684\u7535\u5316\u5b66\u6027\u8d28\u6570\u636e<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-129173\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/6-8.jpg\" alt=\"\" width=\"600\" height=\"386\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/6-8.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/6-8-300x193.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(<strong>a-c<\/strong>) \u4e09\u79cd\u67d3\u6599\u7684\u5149\u50ac\u5316\u964d\u89e3\uff1b<\/p>\n<p>(<strong>d<\/strong>) \u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u3002<\/p>\n<p>\u3010<strong>\u5c0f\u7ed3<\/strong>\u3011<\/p>\n<p>\u4f5c\u8005\u901a\u8fc7TiO<sub>2<\/sub>\u7684\u6210\u529f\u6539\u6027\u8bc1\u5b9e\u4e86\u5206\u5b50\u4ea4\u8054\u53ef\u4f5c\u4e3a\u5b9e\u73b0\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599\u6027\u8d28\u53d8\u5316\u7684\u4e00\u79cd\u65b0\u7b56\u7565\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5206\u5b50\u4ea4\u8054\u7684\u65b9\u6cd5\u53ef\u4ee5\u7528\u5230\u542b\u6709ZrO<sub>2<\/sub>\u7684\u6742\u5316\u6750\u6599\u3002\u6750\u6599\u7684\u72ec\u7279\u7ed3\u6784\u663e\u8457\u6539\u5584\u4e86\u7684\u7535\u548c\u5149\u5316\u5b66\u884c\u4e3a\uff0c\u6587\u4e2d\u901a\u8fc7\u5feb\u901f\u7535\u5b50\u8f6c\u79fb\u901f\u7387\uff0c\u4f4e\u7535\u963b\u7387\u548c\u5728\u7ea2\u5149\u4e0b\u964d\u89e3\u5e38\u89c1\u67d3\u6599\u6c61\u67d3\u7269\u7684\u80fd\u529b\u8bc1\u660e\u4e86\u6027\u80fd\u7684\u63d0\u9ad8\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"https:\/\/www.nature.com\/articles\/s41563-018-0021-9#Sec7\" target=\"_blank\" rel=\"noopener\">A molecular cross-linking approach for hybrid metal oxides<\/a> (Nat. Mater., 05 March, 2018 , DOI: 10.1038\/s41563-018-0021-9\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u91d1\u5c5e\u5b66\u672f\u7ec4jcfxs01\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"https:\/\/www.nature.com\/articles\/s41563-018-0021-9#Sec7\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<br \/>\n <strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><br \/>\n <strong> \u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5168\u7403\u5feb\u901f\u5de5\u4e1a\u5316\u5bfc\u81f4\u9646\u5730\u5143\u7d20\u8d44\u6e90\u9ad8\u5ea6\u7d27\u5f20\uff0c\u8bf8\u5982\u94c1\uff0c\u7845\uff0c\u949b\u548c\u94dd\u7b49\u5143\u7d20\u7684\u6c27\u5316\u7269\u56e0\u5730\u8868\u542b\u91cf\u4e30\u5bcc\u800c\u6781\u5177\u5438\u5f15\u529b\uff0c\u540c\u65f6\u5b83\u4eec\u5728\u80fd\u91cf\u50a8\u5b58\uff0c\u50ac\u5316\u4f5c\u7528\u548c\u91c7\u5149\u7b49\u91cd\u8981\u9886\u57df\u6709\u7740\u91cd&#8230;<\/p>\n","protected":false},"author":4915,"featured_media":129169,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[293,386],"class_list":["post-129167","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-nature","tag-superccapacitor"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/129167"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4915"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=129167"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/129167\/revisions"}],"predecessor-version":[{"id":129489,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/129167\/revisions\/129489"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/129169"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=129167"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=129167"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=129167"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}