{"id":128617,"date":"2018-03-08T14:00:41","date_gmt":"2018-03-08T06:00:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=128617"},"modified":"2018-03-07T22:00:26","modified_gmt":"2018-03-07T14:00:26","slug":"%e8%83%a1%e6%96%87%e5%b9%b3adv-energy-mater-%ef%bc%9aco%e9%83%a8%e5%88%86%e5%8f%96%e4%bb%a3%e6%9d%82%e5%8c%96%e9%92%99%e9%92%9b%e7%9f%bf%e5%88%b6%e5%a4%87%e9%ab%98%e6%95%88%e9%92%99%e9%92%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=128617","title":{"rendered":"\u80e1\u6587\u5e73Adv. Energy Mater. \uff1aCo\u90e8\u5206\u53d6\u4ee3\u6742\u5316\u9499\u949b\u77ff\u5236\u5907\u9ad8\u6548\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5728\u8fc7\u53bb\u516b\u5e74\u4e2d\uff0c\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u7531\u4e8e\u5176\u9ad8\u5438\u6536\u7cfb\u6570\uff0c\u53cc\u6781\u7535\u8377\u8f7d\u6d41\u5b50\u4f20\u8f93\u548c\u9ad8\u7535\u8377\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u800c\u5f15\u8d77\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u754c\u7684\u9ad8\u5ea6\u5173\u6ce8\u3002\u636e\u62a5\u9053\uff0c\u5728B\u4f4d\u7528\u5176\u4ed6\u91d1\u5c5e\u9633\u79bb\u5b50\u53d6\u4ee3Pb2+<\/sup>\u662f\u8c03\u8282\u6df7\u5408\u9499\u949b\u77ff\u6750\u6599\u5149\u7535\u6027\u80fd\u7684\u6700\u6709\u6548\u548c\u6700\u5bb9\u6613\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u5df2\u7ecf\u6709\u7814\u7a76\u901a\u8fc7\u8c03\u8282CH3<\/sub>NH3<\/sub>Pb1-x<\/sub>Snx<\/sub>I3<\/sub>\u7684\u7ec4\u6210\u5c06\u5149\u5b66\u5e26\u9699\uff08Eg\uff09\u4ece1.55\u63d0\u9ad8\u52301.17eV\u3002\u6b64\u5916\uff0c\u6676\u4f53\u7ed3\u6784\u4ece\u56db\u65b9\u76f8\u8fc7\u6e21\u5230\u63a5\u8fd1\u5bf9\u79f0\u7684\u7acb\u65b9\u76f8\uff0c\u5e76\u4e14\u540e\u8005\u6709\u5229\u4e8e\u7535\u8377\u4f20\u8f93\u3002\u4f46\u662f\uff0c\u7814\u7a76\u53d1\u73b0\u5177\u6709\u5bf9\u79f0\u7acb\u65b9\u6676\u76f8\u7684CH3<\/sub>NH3<\/sub>Pb0.5<\/sub>Sn0.5<\/sub>I3<\/sub>\u8584\u819c\u5177\u6709\u5dee\u7684\u8584\u819c\u5f62\u6001\uff0c\u5bfc\u81f4\u5668\u4ef6\u6027\u80fd\u8f83\u5dee\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u963f\u514b\u4f26\u5927\u5b66Xiong Gong\u3001\u5929\u6d25\u5927\u5b66\u80e1\u6587\u5e73\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u7528\u94b4\uff08Co2+<\/sup>\uff09\u90e8\u5206\u66ff\u4ee3\u94c5\uff08Pb2+<\/sup>\uff09\u6765\u5f00\u53d1\u65b0\u578b\u6df7\u5408\u9499\u949b\u77ff\u6750\u6599CH3<\/sub>NH3<\/sub>Pb1-x<\/sub>Cox<\/sub>I3<\/sub>\u3002\u7814\u7a76\u53d1\u73b0\u65b0\u578b\u9499\u949b\u77ff\u8584\u819c\u5177\u6709\u7acb\u65b9\u6676\u4f53\u7ed3\u6784\uff0c\u5177\u6709\u4f18\u5f02\u7684\u8584\u819c\u5f62\u8c8c\u548c\u8f83\u5927\u7684\u6676\u7c92\u5c3a\u5bf8\uff0c\u4e0e\u5177\u6709\u56db\u65b9\u6676\u4f53\u7ed3\u6784\u548c\u8f83\u5c0f\u6676\u7c92\u5c3a\u5bf8\u7684\u539f\u59cb\u8584\u819c\u660e\u663e\u4e0d\u540c\u3002\u6b64\u5916\uff0c\u53d1\u73b0Co2+<\/sup>\u76843d\u8f68\u9053\u786e\u4fdd\u4e86CH3<\/sub>NH3<\/sub>Pb1-x<\/sub>Cox<\/sub>I3<\/sub>\u8584\u819c\u7684\u7535\u5b50\u8fc1\u79fb\u7387\u548c\u7535\u5bfc\u7387\uff0c\u6bd4\u539f\u59cb\u7684CH3<\/sub>NH3<\/sub>Pb4<\/sub>\u8584\u819c\u66f4\u9ad8\u3002\u7ed3\u679c\uff0c\u7531CH3<\/sub>NH3<\/sub>Pb0.9<\/sub>Co0.1<\/sub>I3<\/sub>\u8584\u819c\u5236\u9020\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u8fbe\u523021.43\uff05\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cEfficient Perovskite Solar Cells Fabricated by Co Partially Substituted Hybrid Perovskite<\/strong>\u201d\u53d1\u8868\u5728\u4e86Advanced Energy Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 XPS\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u6765\u81eaCH3<\/sub>NH3<\/sub>Pb0.9<\/sub>Co0.1<\/sub>I3<\/sub>\u8584\u819c\u7684Co 2p\uff0c\u4ee5\u53ca\u6765\u81eaCH3<\/sub>NH3<\/sub>Pb1-x<\/sub>Cox<\/sub>I3<\/sub>\uff08\u5176\u4e2dx = 0,0.1\u548c0.2\uff09\u8584\u819cb\uff09I 3d\uff0cc\uff09N 1s\u548cd\uff09Pb 4f5<\/sub>\u548cPb 4f7<\/sub>\u7684XPS\u5149\u8c31<\/p>\n

\u56fe2 CH3<\/sub>NH3<\/sub>Pb1-x<\/sub>Cox<\/sub>I3<\/sub>\u5149\u8c31\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5438\u6536\u5149\u8c31<\/p>\n

b\uff09\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\uff08PL\uff09\u5149\u8c31<\/p>\n

c\uff09\u7535\u5bfc\u7387\u548c\u585e\u8d1d\u514b\u7cfb\u6570<\/p>\n

\u56fe3 \u6027\u80fd\u5206\u6790<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

a\uff09J-V\u7279\u6027<\/p>\n

b\uff09\u5916\u90e8\u91cf\u5b50\u6548\u7387\uff08EQE\uff09\u8c31<\/p>\n

c\uff09PSC\u7684\u5948\u594e\u65af\u7279\u56fe<\/p>\n

d\uff09PSC\u7684\u5149\u7535\u6d41\u8870\u51cf<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u5229\u7528\u94b4\uff08Co2+<\/sup>\uff09\u90e8\u5206\u66ff\u4ee3\u94c5\uff08Pb2+<\/sup>\uff09\u5f00\u53d1\u4e86\u65b0\u578b\u6df7\u5408\u9499\u949b\u77ff\u6750\u6599CH3<\/sub>NH3<\/sub>Pb1-x<\/sub>Cox<\/sub>I3<\/sub>\u3002\u7ed3\u679c\uff0c\u7531CH3<\/sub>NH3<\/sub>Pb0.9<\/sub>Co0.1<\/sub>I3<\/sub>\u8584\u819c\u5236\u5907\u7684PSC\u663e\u793a\u51fa21.43\uff05\u7684PCE\uff0c\u4e0e\u539f\u59cbCH3<\/sub>NH3<\/sub>PbI3<\/sub>\u8584\u819c\u76f8\u6bd4\uff0c\u6539\u5584\u4e8622\uff05\u3002\u56e0\u6b64 \uff0c\u90e8\u5206\u53d6\u4ee3Pb\u6765\u8c03\u6574\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u7684\u7269\u7406\u6027\u8d28\u4e3a\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u6027\u80fd\u63d0\u4f9b\u4e86\u4e00\u79cd\u5bb9\u6613\u7684\u65b9\u5f0f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Efficient Perovskite Solar Cells Fabricated by Co Partially Substituted Hybrid Perovskite<\/a>\uff08Adv. Energy Mater.\u00a0,2018,DOI:10.1002\/aenm.201703178\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002
\n <\/b><\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5728\u8fc7\u53bb\u516b\u5e74\u4e2d\uff0c\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u7531\u4e8e\u5176\u9ad8\u5438\u6536\u7cfb\u6570\uff0c\u53cc\u6781\u7535\u8377\u8f7d\u6d41\u5b50\u4f20\u8f93\u548c\u9ad8\u7535\u8377\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u800c\u5f15\u8d77\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u754c\u7684\u9ad8\u5ea6\u5173\u6ce8\u3002\u636e\u62a5\u9053\uff0c\u5728B\u4f4d\u7528\u5176\u4ed6\u91d1\u5c5e\u9633\u79bb\u5b50\u53d6\u4ee3…<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2847],"class_list":["post-128617","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2847"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/128617"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=128617"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/128617\/revisions"}],"predecessor-version":[{"id":129035,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/128617\/revisions\/129035"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=128617"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=128617"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=128617"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}