{"id":128049,"date":"2018-03-04T06:30:11","date_gmt":"2018-03-03T22:30:11","guid":{"rendered":"\/\/m.iemloyee.com\/?p=128049"},"modified":"2018-03-04T13:34:55","modified_gmt":"2018-03-04T05:34:55","slug":"%e5%8c%97%e7%90%86%e5%b7%a5%e5%90%b4%e9%94%8b%e3%80%81%e9%99%88%e4%ba%ba%e6%9d%b0adv-energy-mater-%ef%bc%9a%e5%85%b7%e6%9c%89%e8%b6%85%e9%95%bf%e5%be%aa%e7%8e%af%e5%af%bf%e5%91%bd%e3%80%81%e5%8f%af","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=128049","title":{"rendered":"\u5317\u7406\u5de5\u5434\u950b&#038;\u9648\u4eba\u6770Adv. Energy Mater.\uff1a\u5177\u6709\u8d85\u957f\u5faa\u73af\u5bff\u547d\u3001\u53ef\u5927\u89c4\u6a21\u5236\u5907\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u78b3\u8d1f\u6781\u6750\u6599"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7531\u4e8e\u4e0d\u65ad\u589e\u957f\u7684\u80fd\u6e90\u9700\u6c42\u548c\u5bf9\u5316\u77f3\u80fd\u6e90\u8d1f\u9762\u5f71\u54cd\u7684\u8ba4\u8bc6\uff0c\u793e\u4f1a\u5df2\u7ecf\u5c31\u5f00\u53d1\u5229\u7528\u592a\u9633\u80fd\u548c\u98ce\u80fd\u7b49\u53ef\u518d\u751f\u80fd\u6e90\u7684\u9700\u6c42\u8fbe\u6210\u5171\u8bc6\u3002\u95f4\u6b47\u6027\u53ef\u518d\u751f\u80fd\u6e90\u5728\u73b0\u4ee3\u7535\u7f51\u4e2d\u7684\u5e7f\u6cdb\u5e94\u7528\uff0c\u5219\u9700\u8981\u5efa\u7acb\u5927\u89c4\u6a21\u7684\u7535\u529b\u5b58\u50a8\u8bbe\u5907\u3002\u4e3a\u4e86\u964d\u4f4e\u6210\u672c\u548c\u5ef6\u957f\u5faa\u73af\u5bff\u547d\uff0c\u5e76\u6ee1\u8db3\u5927\u7535\u6d41\u5145\u653e\u8981\u6c42\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u88ab\u8ba4\u4e3a\u662f\u5b58\u50a8\u8bbe\u5907\u9886\u57df\u6781\u5177\u524d\u666f\u7684\u9009\u62e9\u4e4b\u4e00\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u5434\u950b\u9662\u58eb\u3001\u9648\u4eba\u6770\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u94b1\u9aa5\u535a\u58eb\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u7b49\u4eba\u5f00\u53d1\u4e86\u4e00\u79cd\u4f4e\u6210\u672c\u4e14\u80fd\u591f\u5927\u89c4\u6a21\u5236\u5907\u7684\u786b\u63ba\u6742\u78b3\u8d1f\u6781\u6750\u6599\uff0c\u5176\u5177\u6709\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u5bff\u547d\uff1a\u5728\u9ad8\u8fbe10 A g<sup>-1<\/sup>\u7684\u5145\u653e\u7535\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u8be5\u6750\u6599\u80fd\u591f\u63d0\u4f9b142 mA h g<sup>-1<\/sup>\u7684\u53ef\u9006\u5bb9\u91cf\uff1b10000\u6b21\u5faa\u73af\u540e\uff0c\u5bb9\u91cf\u7ef4\u6301\u5728126.5 mA h g<sup>-1<\/sup>\uff0c\u662f\u521d\u59cb\u503c\u768489.1\uff05\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u63ba\u786b\u78b3\u5bf9\u94a0\u5177\u6709\u5f3a\u7ed3\u5408\u4eb2\u548c\u529b\uff0c\u53ef\u4fc3\u8fdb\u50a8\u5b58\uff1b\u540c\u65f6\uff0c\u52a8\u529b\u5b66\u5206\u6790\u8868\u660e\u7535\u5bb9\u884c\u4e3a\u7684\u7535\u8377\u5b58\u50a8\u4e3a\u94a0\u50a8\u5b58\u7684\u4e3b\u8981\u8d21\u732e\u8005\uff0c\u8fd9\u6709\u5229\u4e8e\u8d85\u5feb\u901f\u50a8\u5b58\u94a0\u79bb\u5b50\u3002\u8be5\u7814\u7a76\u4e3a\u4e0b\u4e00\u4ee3\u5927\u89c4\u6a21\u7535\u529b\u50a8\u5b58\u7528\u78b3\u57faSIBs\u8d1f\u6781\u6750\u6599\u63d0\u51fa\u4e86\u65b0\u7684\u8bbe\u8ba1\u65b9\u6cd5\u3002\u8be5\u6210\u679c\u4ee5\u201c<strong>Boosting Fast Sodium Storage of a Large-Scalable Carbon Anode with an Ultralong Cycle Life<\/strong>\u201d\u4e3a\u9898\u4e8e2018\u5e742\u670819\u65e5\u53d1\u8868\u5728\u671f\u520a<strong>Advanced Energy Materials<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1. \u6750\u6599\u8bbe\u8ba1<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128053\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0001.jpg\" alt=\"\" width=\"600\" height=\"525\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0001.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0001-300x263.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff09SPC\u7684\u5236\u5907\uff1b<\/p>\n<p>b\uff09S\uff0cPAN\u548cSPC\u7684\u7167\u7247\u56fe\u7247\uff1b<\/p>\n<p>c\uff09PC1000\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>d\uff09SPC1000\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>e\uff09\u901a\u8fc7\u5143\u7d20\u5206\u6790\u548cXPS\u5206\u6790\u83b7\u5f97\u7684PC\/SPC\u6837\u54c1\u4e2dN\/S\u7684\u542b\u91cf\uff1b<\/p>\n<p>f\uff0cg\uff09\u4e0d\u540c\u6837\u54c1\u7684XPS\u8c31\uff08N1s\uff0cS2p\uff09\u3002<\/p>\n<p><strong>\u56fe2. \u4e0d\u540c\u6837\u54c1\u7684\u5faa\u73af\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128054\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0002.jpg\" alt=\"\" width=\"520\" height=\"745\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0002.jpg 520w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0002-209x300.jpg 209w\" sizes=\"(max-width: 520px) 100vw, 520px\" \/><\/p>\n<p>a\uff09\u5728500 mA g<sup>-1<\/sup>\u65f6\uff0c\u6837\u54c1PC1000\u548cSPC800\/1000\/1200\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\uff1b<\/p>\n<p>b\uff09\u4e0d\u540c\u6837\u54c1\u7b2c2000\u6b21\u5faa\u73af\u65f6\u7684\u653e\u7535-\u5145\u7535\u66f2\u7ebf\uff1b<\/p>\n<p>c\uff09\u4e0d\u540c\u6837\u54c1\u5faa\u73af\u6b21\u6570-\u521d\u59cb\u7535\u538b\u7684\u5173\u7cfb\uff1b<\/p>\n<p>d\uff09SPC1000\u572810 A g<sup>-1<\/sup>\u65f6\u7684\u5faa\u73af\u6027\u80fd\u548c\u76f8\u5e94\u5e93\u4ed1\u6548\u7387\uff1b<\/p>\n<p>e\uff09\u7b2c2001\u81f32020\u6b21\u5faa\u73af\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe3. \u4e0d\u540c\u6837\u54c1\u7684\u76f8\u5173\u8868\u5f81\u6570\u636e<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128055\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0003.jpg\" alt=\"\" width=\"600\" height=\"233\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0003.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0003-300x117.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a-d\uff09SPC800\uff0cSPC1000\uff0cSPC1200\u548cPC1000\u7684HRTEM\u56fe\u50cf\uff0c\u63d2\u56fe\u4e3aSPC1000\/PC1000\u7684SAED\u56fe\u6848\uff1b<\/p>\n<p>e\uff09XRD\u56fe\u8c31\uff1b<\/p>\n<p>f\uff09\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n<p>g\uff09\u7535\u5bfc\u7387\u503c\uff1b<\/p>\n<p>h\uff09\u6837\u54c1PC1000\u548cSPC800\/1000\/1200\u7684BET\u8868\u9762\u79ef\u3002<\/p>\n<p><strong>\u56fe4. \u52a8\u529b\u5b66\u5206\u6790\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128056\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0004.jpg\" alt=\"\" width=\"600\" height=\"355\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0004.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/0004-300x178.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a-d\uff09SPC800\/1000\/1200\u548cPC1000\u57280.2\u81f31 mV\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n<p>e-h\uff09\u57281 mV s<sup>-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\u7684\u7535\u8377\u5b58\u50a8\uff1b<\/p>\n<p>i\uff09\u63ba\u786b\u78b3\u8868\u9762\u4e0a\u7684\u7535\u5bb9\u7535\u8377\u50a8\u5b58\u7684\u793a\u610f\u56fe\uff1b<\/p>\n<p>j\uff0ck\uff09\u94a0\u539f\u5b50\u4e0e\u65e0\u7f3a\u9677\u6216\u786b\u63ba\u6742\u7684\u78b3\u8868\u9762\u548c\u76f8\u5e94\u7684E<sub>-b<\/sub>\u503c\uff08\u7ed3\u5408\u80fd\u7684\u8d1f\u503c\uff09\u7684\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u3002\u7070\u8272\u3001\u9ec4\u8272\u548c\u6a59\u8272\u7684\u7403\u5206\u522b\u4ee3\u8868\u78b3\u3001\u786b\u548c\u94a0\u539f\u5b50\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u8868\u660e\uff0c\u63ba\u786b\u78b3\u6750\u6599\u7684\u94a0\u50a8\u5b58\u6027\u80fd\u975e\u5e38\u4f18\u5f02\uff0c\u5728\u7535\u6d41\u9ad8\u8fbe10 A g<sup>-1<\/sup>\u65f6\uff0c\u53ef\u9006\u5bb9\u91cf\u4e3a142 mA h g<sup>-1<\/sup>\uff1b10000\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u5728126.5 mA h g<sup>-1<\/sup>\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a89.1\uff05\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8bc1\u660e\u4e86\u786b\u63ba\u6742\u5728\u94a0\u50a8\u5b58\u4e2d\u7684\u4f5c\u7528\uff0c\u5373\u589e\u5f3a\u4e86\u78b3\u8868\u9762\u4e0e\u94a0\u4e4b\u95f4\u7684\u7ed3\u5408\uff1b\u540c\u65f6\u4f18\u5316\u786e\u7acb\u6700\u4f73\u786b\u542b\u91cf\uff0c\u907f\u514d\u4e86\u8fc7\u91cf\u786b\u63ba\u6742\u5bfc\u81f4\u5faa\u73af\u8fc7\u7a0b\u4e2d\u78b3\u6750\u6599\u7ed3\u6784\u7684\u7834\u574f\u3002\u7814\u7a76\u7ed3\u679c\u4e3a\u5f00\u53d1\u7528\u4e8e\u4e0b\u4e00\u4ee3\u5927\u89c4\u6a21\u7535\u80fd\u50a8\u5b58\u7684\u8d85\u957f\u5bff\u547dSIBs\u7684\u78b3\u8d1f\u6781\u6750\u6599\u5f00\u8f9f\u4e86\u4e00\u6761\u6280\u672f\u65b0\u9014\u5f84\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aenm.201703159\/full\" target=\"_blank\" rel=\"noopener\">Boosting Fast Sodium Storage of a Large-Scalable Carbon Anode with an Ultralong Cycle Life<\/a>\uff08Adv. Energy Mater.\uff0c2018\uff0cDOI: 10.1002\/aenm.201703159\uff09<\/p>\n<p>\u76f8\u5173\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u9879\u76ee\u201c\u9ad8\u5b89\u5168\u3001\u957f\u5bff\u547d\u548c\u4f4e\u6210\u672c\u94a0\u57fa\u50a8\u80fd\u7535\u6c60\u7684\u57fa\u7840\u79d1\u5b66\u95ee\u9898\u7814\u7a76\u201d\uff08\u590d\u65e6\u5927\u5b66\u590f\u6c38\u59da\u8001\u5e08\u4e3a\u9996\u5e2d\u79d1\u5b66\u5bb6\uff09\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u5317\u4eac\u5e02\u6559\u59d4\u7b49\u90e8\u95e8\u7684\u652f\u6301\u3002<\/p>\n<p><strong>\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p><strong>\u5434\u950b\u6559\u6388<\/strong><\/p>\n<p>\u4e2d\u56fd\u5de5\u7a0b\u9662\u9662\u58eb\uff0c\u957f\u671f\u4ece\u4e8b\u65b0\u80fd\u6e90\u6750\u6599\u3001\u73af\u5883\u6750\u6599\u548c\u7eff\u8272\u4e8c\u6b21\u7535\u6c60\u7b49\u65b9\u9762\u7684\u7814\u7a76\u4e0e\u4ea7\u4e1a\u5316\u5f00\u53d1\u3002\u5148\u540e\u4e3b\u6301\u627f\u62c5\u56fd\u5bb6\u201c863\u8ba1\u5212\u201d\u9879\u76ee\u3001\u201c973\u8ba1\u5212\u201d\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u548c\u56fd\u9632\u79d1\u7814\u7b49\u9879\u76ee26\u9879\uff0c\u4e3b\u6301\u521b\u5efa\u4e86\u56fd\u5bb6863\u954d\u6c22\u7535\u6c60\u4e2d\u8bd5\u57fa\u5730\u548c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u7eff\u8272\u4e8c\u6b21\u7535\u6c60\u4e0e\u76f8\u5173\u6750\u6599\u8bbe\u8ba1\u3001\u5236\u5907\u3001\u8bc4\u4ef7\u4e0e\u5e94\u7528\u4e00\u4f53\u5316\u7684\u521b\u65b0\u7814\u7a76\u5e73\u53f0\u3002\u7814\u7a76\u6210\u679c\u83b7\u56fd\u5bb6\u79d1\u5b66\u6280\u672f\u8fdb\u6b65\u5956\u4e8c\u7b49\u5956\u548c\u56fd\u5bb6\u6280\u672f\u53d1\u660e\u4e8c\u7b49\u5956\u54041\u9879\uff0c\u83b7\u5f972012\u5e74\u5ea6\u4f55\u6881\u4f55\u5229\u57fa\u91d1\u79d1\u5b66\u4e0e\u6280\u672f\u8fdb\u6b65\u5956\u30014\u9879\u56fd\u9645\u5956\u548c12\u9879\u7701\u90e8\u7ea7\u79d1\u6280\u5956\u3002\u5728\u56fd\u5185\u5916\u5b66\u672f\u520a\u7269\u53d1\u8868SCI\u6536\u5f55\u8bba\u6587400\u4f59\u7bc7\uff0c\u4e3b\u7f16\u51fa\u7248\u5b66\u672f\u4e13\u84572\u90e8\u3001\u53c2\u7f16\u591a\u90e8\uff0c\u83b7\u5f97\u53d1\u660e\u4e13\u5229\u6388\u674381\u9879\uff0c\u4e3b\u6301\u5236\u5b9a\u56fd\u5bb6\u6c7d\u8f66\u884c\u4e1a\u52a8\u529b\u7535\u6c60\u6807\u51c64\u9879\u3002\u66fe\u4efb\u56fd\u5bb6\u9ad8\u6280\u672f\u201c863\u201d\u8ba1\u5212\u529f\u80fd\u6750\u6599\u4e13\u5bb6\u7ec4\u6210\u5458\u3001\u526f\u7ec4\u957f\uff0c\u201c863\u201d\u8ba1\u5212\u65b0\u6750\u6599\u9886\u57df\u4e13\u5bb6\u59d4\u5458\u4f1a\u59d4\u5458\u3001\u5e38\u59d4\uff0c\u56fd\u5bb6\u79d1\u6280\u90e8\u954d\u6c22\u7535\u6c60\u4e13\u5bb6\u7ec4\u7ec4\u957f\uff0c\u201c863\u201d\u7535\u52a8\u6c7d\u8f66\u91cd\u5927\u4e13\u9879\u603b\u4f53\u4e13\u5bb6\u7ec4\u6210\u5458\uff08\u52a8\u529b\u84c4\u7535\u6c60\u8d23\u4efb\u4e13\u5bb6\uff09\u7b49\u3002\u76ee\u524d\uff0c\u62c5\u4efb\u56fd\u5bb6\u91cd\u70b9\u57fa\u7840\u7814\u7a76\uff08973\uff09\u8ba1\u5212\u7eff\u8272\u4e8c\u6b21\u7535\u6c60\u9879\u76ee\u9996\u5e2d\u79d1\u5b66\u5bb6\u3001\u4e2d\u56fd\u7535\u6c60\u5de5\u4e1a\u534f\u4f1a\u526f\u7406\u4e8b\u957f\uff0c\u4e2d\u56fd\u5316\u5b66\u4e0e\u7269\u7406\u7535\u6e90\u884c\u4e1a\u534f\u4f1a\u526f\u7406\u4e8b\u957f\uff0c\u56fd\u5bb6\u5de5\u4fe1\u90e8\u65b0\u80fd\u6e90\u6c7d\u8f66\u51c6\u5165\u4e13\u5bb6\u59d4\u5458\u4f1a\u59d4\u5458\u7b49\u3002<\/p>\n<p><strong>\u9648\u4eba\u6770\u6559\u6388<\/strong><\/p>\n<p>\u4e3b\u8981\u4ece\u4e8b\u7eff\u8272\u80fd\u6e90\u6750\u6599\u3001\u4e8c\u6b21\u7535\u6c60\u65b0\u4f53\u7cfb\u53ca\u5173\u952e\u6750\u6599\u3001\u73af\u5883\u53cb\u597d\u6750\u6599\u7b49\u9886\u57df\u7684\u6559\u5b66\u548c\u79d1\u7814\uff0c\u5728\u79bb\u5b50\u6db2\u4f53\u53ca\u529f\u80fd\u6dfb\u52a0\u5242\/\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u3001\u591a\u7535\u5b50\u9ad8\u6bd4\u80fd\u9502\u786b\u4e8c\u6b21\u7535\u6c60\u53ca\u5173\u952e\u6750\u6599\u3001\u7279\u79cd\u529f\u80fd\u7535\u6e90\/\u8584\u819c\u7535\u6c60\u53ca\u5f02\u6784\u7eb3\u7c73\u6750\u6599\u3001\u65b0\u578b\u94a0\u79bb\u5b50\u7535\u6c60\u5173\u952e\u6750\u6599\u7b49\u65b9\u9762\u5f00\u5c55\u7814\u7a76\u5de5\u4f5c\u3002\u4f5c\u4e3a\u8d1f\u8d23\u4eba\uff0c\u5148\u540e\u627f\u62c5\u56fd\u5bb6\u9ad8\u6280\u672f\u201c863\u201d\u8ba1\u5212\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u3001\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u9879\u76ee\u3001\u56fd\u5bb6\u79d1\u6280\u5408\u4f5c\u9879\u76ee\u7b49\u8bfe\u9898\uff0c2009\u5e74\u5165\u9009\u6559\u80b2\u90e8\u201c\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u652f\u6301\u8ba1\u5212\u201d\uff0c2010\u5e74\u5165\u9009\u5317\u4eac\u5e02\u201c\u4f18\u79c0\u4eba\u624d\u57f9\u517b\u8d44\u52a9\u8ba1\u5212\u201d\u548c\u201c\u79d1\u6280\u65b0\u661f\u8ba1\u5212\u201d\u3002\u73b0\u62c5\u4efb\u4e2d\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u7406\u4e8b\u3001\u4e2d\u56fd\u56fa\u6001\u79bb\u5b50\u5b66\u4f1a\u7406\u4e8b\u3001\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u5b66\u4f1a\uff08IAOEES\uff09\u59d4\u5458\u4f1a\u59d4\u5458\u3001\u5317\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743-2006\uff09\uff1b\u53c2\u4e0e\u7f16\u5199\u8457\u4f5c3\u90e8\uff1a\u300a\u7eff\u8272\u4e8c\u6b21\u7535\u6c60\u53ca\u5176\u65b0\u4f53\u7cfb\u7814\u7a76\u8fdb\u5c55\u300b\u3001\u300a\u79bb\u5b50\u6db2\u4f53\u4e0e\u7eff\u8272\u5316\u5b66\u300b\u548c\u300a\u7eff\u8272\u4e8c\u6b21\u7535\u6c60\uff1a\u65b0\u4f53\u7cfb\u4e0e\u7814\u7a76\u65b9\u6cd5\u300b\uff1b\u4f5c\u4e3a\u4e3b\u8981\u5b8c\u6210\u4eba\uff0c\u83b7\u56fd\u5bb6\u6280\u672f\u53d1\u660e\u4e8c\u7b49\u59561\u9879\u3001\u90e8\u7ea7\u6280\u672f\u53d1\u660e\u4e00\u7b49\u59562\u9879\u3001\u90e8\u7ea7\u79d1\u6280\u8fdb\u6b65\u4e00\u7b49\u59561\u9879\u3002<\/p>\n<p><strong>\u8c22\u5ada\u526f\u6559\u6388<\/strong><\/p>\n<p>\u4e3b\u8981\u4ece\u4e8b\u65b0\u80fd\u6e90\u6750\u6599\u3001\u7eff\u8272\u4e8c\u6b21\u7535\u6c60\u8bbe\u5907\u7684\u5f00\u53d1\u4e0e\u5e94\u7528\uff0c\u5305\u62ec\u9ad8\u6bd4\u80fd\u9502\u4e8c\u6b21\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u5927\u89c4\u6a21\u50a8\u80fd\u7528\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u8d1f\u6781\u6750\u6599\u3002\u53c2\u4e0e\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u201c\u957f\u5bff\u547d\u4f4e\u6210\u672c\u94a0\u57fa\u50a8\u80fd\u7535\u6c60\u57fa\u7840\u79d1\u5b66\u95ee\u9898\u201d\u9879\u76ee\u3001\u56fd\u5bb6\u91cd\u70b9\u57fa\u7840\u7814\u7a76\u201c973\u201d\u9879\u76ee\u201c\u7eff\u8272\u4e8c\u6b21\u7535\u6c60\u65b0\u4f53\u7cfb\u76f8\u5173\u57fa\u7840\u7814\u7a76\u201d\u3001\u201c\u65b0\u578b\u4e8c\u6b21\u7535\u6c60\u53ca\u76f8\u5173\u80fd\u6e90\u6750\u6599\u7684\u57fa\u7840\u7814\u7a76\u201d\u53ca\u56fd\u5bb6\u9ad8\u6280\u672f\u201c863\u201d\u8ba1\u5212\u8282\u80fd\u4e0e\u65b0\u80fd\u6e90\u6c7d\u8f66\u91cd\u5927\u4e13\u9879\u201c\u8f66\u7528\u52a8\u529b\u84c4\u7535\u6c60\u9ad8\u529f\u7387\u3001\u9ad8\u80fd\u91cf\u548c\u5bbd\u6e29\u5e26\u6027\u80fd\u6539\u8fdb\u5173\u952e\u6280\u672f\u7814\u7a76\u201d\u9879\u76ee\u7b49\u8bfe\u9898\u3002\u4f5c\u4e3a\u4e3b\u8981\u5b8c\u6210\u4eba\uff0c\u83b7\u90e8\u7ea7\u79d1\u5b66\u6280\u672f\u4e00\u7b49\u59561\u9879\uff0c\u5728\u56fd\u5185\u5916\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u658740\u4f59\u7bc7\uff0c\u83b7\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u52295\u9879\u3002<\/p>\n<p>\u94b1\u9aa5<\/p>\n<p>\u5728\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u9662\u5434\u950b\u9662\u58eb\u548c\u9648\u4eba\u6770\u6559\u6388\u6307\u5bfc\u4e0b\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u4e3b\u8981\u4ece\u4e8b\u9502\u786b\u7535\u6c60\u6b63\u8d1f\u6781\u548c\u7535\u89e3\u6db2\u6750\u6599\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u7684\u7814\u7a76\u548c\u5f00\u53d1\u3002<\/p>\n<p>\u7f57\u9510<\/p>\n<p>\u73b0\u4e8e\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u9662\u5434\u950b\u9662\u58eb\u3001\u9648\u4eba\u6770\u8001\u5e08\u8bfe\u9898\u7ec4\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\uff0c\u4e3b\u8981\u4ece\u4e8b\u94a0\u79bb\u5b50\u7535\u6c60\u5148\u8fdb\u7535\u6781\u6750\u6599\u7684\u5f00\u53d1\u548c\u5236\u5907\u3002<\/p>\n<p>\u9ec4\u6c38\u946b<\/p>\n<p>\u73b0\u4e8e\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u9662\u5434\u950b\u9662\u58eb\u3001\u9648\u4eba\u6770\u8001\u5e08\u8bfe\u9898\u7ec4\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\uff0c\u76ee\u524d\u7684\u7814\u7a76\u65b9\u5411\u662f\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u8d1f\u6781\u6750\u6599\u8bbe\u8ba1\u548c\u65b0\u578b\u7535\u89e3\u8d28\u6750\u6599\u7684\u5f00\u53d1\u3002<\/p>\n<p><strong>\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u76ee\u524d\u5e38\u89c1\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u53ef\u4ee5\u5206\u4e3a\u56db\u7c7b\uff0c\u4e3b\u8981\u5305\u62ec\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u805a\u9634\u79bb\u5b50\u578b\u5316\u5408\u7269\u3001\u666e\u9c81\u58eb\u84dd\u53ca\u5176\u7c7b\u4f3c\u7269\u548c\u6709\u673a\u5316\u5408\u7269\uff1b\u8d1f\u6781\u6750\u6599\u4e3b\u8981\u5305\u62ec\u786c\u78b3\u3001\u78f7\u9178\u949b\u94a0\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\u3001\u7852\u5316\u7269\u548c\u6709\u673a\u5316\u5408\u7269\u3002<\/p>\n<p>\u666e\u9c81\u58eb\u84dd\u6750\u6599\u5177\u6709\u5f00\u653e\u7684\u6846\u67b6\u7ed3\u6784\u63d0\u4f9b\u4e86\u5927\u91cf\u7684\u95f4\u9699\u4f4d\u70b9\uff0c\u6709\u5229\u4e8e\u94a0\u79bb\u5b50\u7684\u8fc1\u79fb\uff1b\u5177\u6709170 mAh g<sup>-1<\/sup>\u7684\u9ad8\u7406\u8bba\u5bb9\u91cf\u548c\u65e0\u6bd2\u3001\u5ec9\u4ef7\u3001\u6613\u4e8e\u5927\u89c4\u6a21\u751f\u4ea7\u7b49\u4f18\u52bf\uff0c\u56e0\u800c\u666e\u9c81\u58eb\u84dd\u53ca\u5176\u7c7b\u4f3c\u7269\u6750\u6599\u5f97\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u8bfe\u9898\u7ec4\u9488\u5bf9\u666e\u9c81\u58eb\u84dd\u53ca\u5176\u7c7b\u4f3c\u7269\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u5f00\u5c55\u4e86\u7cfb\u7edf\u7814\u7a76\uff1a<\/p>\n<p>\uff081\uff09\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u7684Ni\u3001Co\u3001Fe\u4e09\u5143\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u6750\u6599\uff0c\u5176\u4e2d\u60f0\u6027\u5143\u7d20Ni\u63d0\u4f9b\u4e86\u7a33\u5b9a\u7684\u521a\u6027\u9aa8\u67b6\uff0cCo<sup>2+<\/sup>\/<sup>3+<\/sup>\u548cFe(CN)<sub>6<\/sub><sup>4-<\/sup>\/<sup>3-<\/sup>\u4e24\u7ec4\u6c27\u5316\u8fd8\u539f\u7535\u5bf9\u63d0\u4f9b\u4e30\u5bcc\u6d3b\u6027\u4f4d\u70b9\uff0c\u6709\u6548\u63d0\u9ad8\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\uff08Electrochem. Commun., 2015, DOI: 10.1016\/j.elecom.2015.07.014\uff09\uff1b<\/p>\n<p>\uff082\uff09\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u542bTi\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\uff0c\u5176\u4e2d\u542b\u6709\u4f4e\u81ea\u65cb\u7684[Fe(CN)<sub>6<\/sub>]<sup>4-<\/sup>\/<sup>3-<\/sup>\u548c\u9ad8\u81ea\u65cb\u7684Ti<sup>3+<\/sup>\/<sup>4+<\/sup>\u4e24\u7ec4\u6c27\u5316\u8fd8\u539f\u7535\u5bf9\u5728\u94a0\u5b58\u50a8\u7684\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u63d0\u4f9b\u4e86\u53ef\u89c2\u7684\u5bb9\u91cf\uff08J. Power Sources, 2016\uff0c DOI\uff1a10.1016\/j.jpowsour.2015.10.042\uff09\uff1b<\/p>\n<p>\uff083\uff09\u4e3a\u4e86\u5bf9\u6750\u6599\u7ed3\u6784\u5b9e\u73b0\u4f18\u5316\u8bbe\u8ba1\u548c\u6709\u6548\u8c03\u63a7\uff0c\u901a\u8fc7\u964d\u4f4e\u53cd\u5e94\u6c89\u6dc0\u901f\u7387\u7684\u65b9\u6cd5\u5408\u6210\u4e86\u9ad8\u54c1\u8d28\u7684\u591a\u5b54\u666e\u9c81\u58eb\u84dd\u6750\u6599\uff0c\u5176\u5177\u6709\u8f83\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u7a33\u5b9a\u7ed3\u6784\uff0c\u5f97\u5230\u4e86\u66f4\u9ad8\u7684\u6bd4\u5bb9\u91cf\u548c\u957f\u5468\u671f\u5bff\u547d\u3002\uff08ACS Appl. Mater. Interfaces, 2016, DOI: 10.1021\/acsami.6b04151\uff09\uff1b<\/p>\n<p>\uff084\uff09\u8bbe\u8ba1\u5f15\u5165\u7ade\u4e89\u914d\u4f4d\u79bb\u5b50\u7684\u65b9\u6cd5\u6765\u51cf\u7f13\u6750\u6599\u7684\u6210\u6838\u901f\u7387\uff0c\u4ee5\u5408\u6210\u9ad8\u54c1\u8d28\u7684\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u6750\u6599\u3002\u5236\u5907\u7684\u9ad8\u7ed3\u6676\u5ea6Na<sub>2<\/sub>NixMnyFe(CN)<sub>6<\/sub>\u6837\u54c1\uff08PBMN\uff09\u8868\u73b0\u51fa\u9ad8\u6bd4\u5bb9\u91cf\u548c\u957f\u5faa\u73af\u5bff\u547d\u3002\uff08ACS Appl. Mater. Interfaces, 2016, DOI: 10.1021\/acsami.6b10884\uff09\uff1b<\/p>\n<p>\uff085\uff09\u9488\u5bf9\u666e\u9c81\u58eb\u84dd\u6750\u6599\u7ed3\u6784\u4e2d\u7684\u7f3a\u9677\u548c\u7ed3\u6676\u6c34\u95ee\u9898\uff0c\u901a\u8fc7\u6dfb\u52a0\u5316\u5b66\u6291\u5236\u5242\u548c\u6e29\u5ea6\u8c03\u63a7\u8bbe\u8ba1\u5f97\u5230\u591a\u8fb9\u754c\u7684\u666e\u9c81\u58eb\u84dd\u6750\u6599\u3002\u591a\u8fb9\u754c\u7684\u7ed3\u6784\u4e0d\u4ec5\u589e\u5927\u4e86\u7535\u6781\u6750\u6599\u548c\u7535\u89e3\u6db2\u6750\u6599\u7684\u63a5\u89e6\u754c\u9762\u3001\u63d0\u4f9b\u66f4\u591a\u7684Na+\u4f20\u8f93\u901a\u9053\uff0c\u540c\u65f6\u83f1\u65b9\u7684\u6676\u4f53\u7ed3\u6784\u6709\u6548\u964d\u4f4e\u4e86Na<sup>+<\/sup>\u7684\u5d4c\u5165\u80fd\u5792\u3002\u57fa\u4e8e\u52a8\u529b\u5b66\u6027\u80fd\u7684\u6539\u826f\uff0c\u8be5\u6750\u6599\u5e94\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u65f6\u5728100mA\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u521d\u59cb\u6bd4\u5bb9\u91cf\u4e3a120mAh\/g\uff0c\u5728280\u5468\u540e\u5bb9\u91cf\u7684\u4fdd\u6301\u7387\u8fbe\u523080%\uff1b\u540c\u65f6\uff0c\u5176\u4e5f\u8868\u73b0\u51fa\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\uff0c\u572810C\u500d\u7387\u4e0b\u4e3a60mAh\/g\uff1b\u7814\u7a76\u8868\u660e\uff0c\u7531\u4e8e\u591a\u8fb9\u754c\u4e0a\u949d\u5316\u5c42\u7684\u5f62\u6210\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u51cf\u5c11\u7535\u6781\u6750\u6599\u5728\u9ad8\u7535\u538b\u4e0b\u53d1\u751f\u526f\u53cd\u5e94\uff0c\u540c\u65f6\u8868\u73b0\u51fa\u4f4e\u7684\u754c\u9762\u963b\u6297\uff0c\u4ece\u800c\u63d0\u5347\u4e86\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u548c\u7535\u5316\u5b66\u6027\u80fd\uff08Nano Energy, 2017, 10.1016\/j.nanoen.2017.07.005\uff09\u3002<\/p>\n<p>\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u65b9\u9762\uff0c\u8bfe\u9898\u7ec4\u9488\u5bf9\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u548c\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u7279\u70b9\u7684Ti\u57fa\u6c27\u5316\u7269\u6750\u6599\u548c\u786b\u5316\u7269\u6750\u6599\u5f00\u5c55\u4e86\u7cfb\u7edf\u7814\u7a76\uff1a<\/p>\n<p>\uff081\uff09\u901a\u8fc7rGO\u7684\u590d\u5408\u6784\u7b51\u4e86\u5177\u6709\u4e09\u7ef4\u5bfc\u7535\u7f51\u7edc\u7ed3\u6784\u7684TiO<sub>2<\/sub> NSs@rGO\u8d1f\u6781\uff0c\u7247\u72b6\u7684TiO<sub>2<\/sub>\u548c\u7247\u72b6rGO\u4e4b\u95f4\u53ef\u4ee5\u5f62\u6210\u5145\u5206\u7684\u9762\u9762\u63a5\u89e6\uff0c\u4f7f\u5f97\u7535\u5b50\u548c\u79bb\u5b50\u53ef\u4ee5\u5b9e\u73b0\u5feb\u901f\u4f20\u9012\uff08J. Power Sources, 2017, 10.1016\/j.jpowsour.2016.12.077\uff09\uff1b<\/p>\n<p>\uff082\uff09\u901a\u8fc7\u4f18\u5316\u53cd\u5e94\u901f\u5ea6\u5e94\u7528\u6c34\u89e3\u65b9\u6cd5\u5408\u6210\u4e86TiO<sub>2<\/sub>\u7eb3\u7c73\u6676\uff0c\u5e76\u901a\u8fc7\u7145\u70e7\u7684\u65b9\u6cd5\u8fdb\u4e00\u6b65\u63d0\u5347\u7ed3\u6676\u5ea6\uff1b\u5c06\u5176\u4e0e\u78b3\u7684\u590d\u5408\uff0c\u6709\u6548\u63d0\u5347\u78b3\u5305\u8986TiO<sub>2<\/sub>\u6750\u6599\u7684\u7535\u5b50\u7535\u5bfc\u7387\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\uff08J. Power Sources, 2017, DOI: 10.1016\/j.jpowsour.2017.07.050\uff09\uff1b<\/p>\n<p>\uff083\uff09\u901a\u8fc7\u6c34\u70ed\u6cd5\u5408\u6210\u4e8c\u7ef4Na<sub><sup>2<\/sup><\/sub>Ti<sub>3<\/sub>O<sub>7<\/sub>\u7eb3\u7c73\u7247\uff0c\u518d\u901a\u8fc7\u5b9a\u5411\u7ec4\u88c5\u7684\u65b9\u6cd5\u5f62\u6210\u4e09\u7ef4\u7684\u82b1\u72b6\u7ed3\u6784(Na-TMFs)\uff1b\u8be5\u7ed3\u6784\u63d0\u4f9b\u4e86\u4e30\u5bcc\u7684\u5b54\u9053\u548c\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u6709\u5229\u4e8e\u94a0\u79bb\u5b50\u7684\u8fc1\u79fb\u548c\u5438\u9644\uff0c\u63d0\u4f9b\u8f83\u5927\u7684\u8d5d\u7535\u5bb9\u5bb9\u91cf\uff0c\u6709\u6548\u6539\u5584\u6750\u6599\u7684\u50a8\u94a0\u52a8\u529b\u5b66\u6027\u80fd\uff08ACS Appl. Mater. Interfaces, 2017, DOI: 10.1021\/acsami.7b01519\uff09\uff1b<\/p>\n<p>\uff084\uff09\u8bbe\u8ba1\u5236\u5907\u4e86\u4e2d\u7a7a\u706f\u7b3c\u72b6\u7684Ti<sub>0.25<\/sub>Sn<sub>0.75<\/sub>S<sub>2<\/sub>\u8d1f\u6781\uff0c\u4e00\u65b9\u9762\u53ef\u6709\u6548\u7f13\u89e3\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\uff0c\u53e6\u4e00\u65b9\u9762Ti\u5143\u7d20\u7684\u63ba\u6742\u5f15\u5165\u4e86\u60f0\u6027\u7ec4\u5206\uff0c\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86\u4fdd\u62a4\u5c42\uff0c\u6709\u6548\u6291\u5236\u4e86\u6750\u6599\u7c89\u5316\uff0c\u5b9e\u73b0\u7535\u6c60\u5faa\u73af\u5bff\u547d\u7684\u6709\u6548\u6539\u5584\uff08Energy Storage Mater.\uff0c2018\uff0cDOI\uff1a10.1016\/j.ensm.2017.10.004\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128050\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/03\/5-2.jpg\" alt=\"\" width=\"600\" height=\"508\" 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