{"id":127256,"date":"2018-03-01T06:30:07","date_gmt":"2018-02-28T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=127256"},"modified":"2018-02-28T16:26:53","modified_gmt":"2018-02-28T08:26:53","slug":"joule-%e4%b8%ad%e7%a9%ba%e7%bb%93%e6%9e%84%e5%b0%96%e6%99%b6%e7%9f%b3%e5%9e%8b%e5%a4%9a%e5%ad%94%e6%b0%a7%e5%8c%96%e7%89%a9%e7%94%a8%e4%ba%8e%e6%8c%81%e4%b9%85%e9%ab%98%e6%95%88%e7%9a%84%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=127256","title":{"rendered":"Joule: \u4e2d\u7a7a\u7ed3\u6784\u5c16\u6676\u77f3\u578b\u591a\u5b54\u6c27\u5316\u7269\u7528\u4e8e\u6301\u4e45\u9ad8\u6548\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\u50ac\u5316\u5242"},"content":{"rendered":"<p><strong>\u5f15\u8a00<\/strong><\/p>\n<p>\u53d1\u5c55\u9ad8\u6548\u5ec9\u4ef7\u7684\u6c27\u8fd8\u539f\uff08ORR\uff09\u50ac\u5316\u5242\u5728\u4e0b\u4e00\u4ee3\u80fd\u6e90\u8f6c\u6362\u548c\u5b58\u50a8\u6280\u672f\u4e2d\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002\u7531\u4e8e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u6210\u672c\u9ad8\uff0c\u4e14\u5176\u7528\u4e8e\u8d28\u5b50\u4ea4\u6362\u819c\uff08PEM\uff09\u71c3\u6599\u7535\u6c60\u548c\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7684\u9634\u6781\u65f6\u6c27\u8fd8\u539f\u6d3b\u6027\u4e0b\u964d\uff0c\u800c\u76ee\u524d\u7814\u7a76\u7684\u5176\u4ed6\u4f4e\u6210\u672c\u8d39\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u5b58\u5728\u5f88\u591a\u95ee\u9898\uff0c\u5982\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u901a\u5e38\u5177\u6709\u8f83\u9ad8\u7684\u8fc7\u7535\u4f4d\uff0c\u78b3\u57fa\u50ac\u5316\u5242\u548c\u8fc7\u6e21\u91d1\u5c5e\u5408\u91d1\u7684\u8010\u4e45\u6027\u5dee\u7b49\u3002\u56e0\u6b64\uff0c\u6025\u9700\u5f00\u53d1\u65b0\u578b\u7684\u6301\u4e45\u9ad8\u6548\u7684\u4f4e\u6210\u672c\u6c27\u8fd8\u539f\u53cd\u5e94\u50ac\u5316\u5242\u3002\u76f8\u5173\u6210\u679c\u53d1\u8868\u5728Cell Press\u65d7\u4e0b\u7684\u80fd\u6e90\u671f\u520aJoule\u4e0a \uff08Joule 2, 337-348, 2018\uff09<\/p>\n<p><strong>\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n<p>\u5317\u4eac\u90ae\u7535\u5927\u5b66\u96f7\u9e23\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7814\u7a76\u56e2\u961f\u8054\u5408\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u674e\u7389\u6d9b\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u548c\u4f50\u6cbb\u4e9a\u7406\u5de5\u5b66\u9662Zhiqun\u00a0Lin\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7814\u7a76\u56e2\u961f\u91c7\u7528\u4e24\u6b65\u53cd\u5e94\u6cd5\u6210\u529f\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u4e2d\u7a7a\u5c16\u6676\u77f3\u7ed3\u6784\u591a\u5b54ZnMn<sub>x<\/sub>Co<sub>2<\/sub><sub>&#8211;<\/sub><sub>x<\/sub>O<sub>4<\/sub>\u5fae\u7403\uff0c\u5176\u6bd4\u8868\u9762\u79ef\u5927\u3001\u4e0e\u7535\u89e3\u6db2\u63a5\u89e6\u9762\u79ef\u5927\uff0c\u4ece\u800c\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684ORR\u6027\u80fd\u3002\u76f8\u6bd4\u4e8e\u5176\u4ed6\u7ec4\u5206\uff0c\u4e2d\u7a7a\u7ed3\u6784ZnMnCoO<sub>4<\/sub>\u00a0\uff08x = 1\uff09\u5fae\u7403\u4f5c\u4e3aORR\u50ac\u5316\u5242\u5177\u6709\u8f83\u9ad8\u7684\u8d77\u59cb\u7535\u4f4d\uff081.00V\uff09\u3001\u4e0e\u5546\u7528Pt\/C\u50ac\u5316\u5242\u76f8\u8fd1\u7684\u534a\u6ce2\u7535\u4f4d\uff08\u4ec5\u6bd4Pt\/C\u50ac\u5316\u5242\u4f4e50mV\uff09\u4ee5\u53ca\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u4f18\u5f02\u7684\u6301\u4e45\u6027\u548c\u7a33\u5b9a\u6027\u3002\u5c16\u6676\u77f3\u7ed3\u6784\u56db\u9762\u4f53\u95f4\u9699A\u4f4d\u4e0a\u8f83\u5f3a\u7684Zn<sup>2+<\/sup>-O\u952e\u4ee5\u53ca\u516b\u9762\u4f53\u95f4\u9699B\u4f4d\u4e0aMn<sup>3+<\/sup>\u8f83\u5927\u7684\u79bb\u5b50\u534a\u5f84\u964d\u4f4e\u4e86Co<sup>3+<\/sup>-OH\u7684\u952e\u5408\u5f3a\u5ea6\uff0c\u540c\u65f6\u4f7f\u5f97ZnMnCoO<sub>4<\/sub>\u4e2dCo<sup>3+<\/sup>\u76843d\u7535\u5b50\u7531Co<sub>3<\/sub>O<sub>4<\/sub>\u4e2d\u7684\u4f4e\u81ea\u65cb\u72b6\u6001\u53d8\u4e3a\u9ad8\u81ea\u65cb\u548c\u4f4e\u81ea\u65cb\u6df7\u5408\u6001\uff0c\u4ece\u800c\u52a0\u901f\u4e86O<sup>2-<\/sup>\/OH<sup>&#8211;<\/sup>\u7684\u4f4d\u79fb\u3002<\/p>\n<p><strong>\u56fe\u6587\u5bfc\u8bfb<\/strong><\/p>\n<p><strong>\u56fe1. ZnCo<sub>2<\/sub>O<sub>4<\/sub>(x=0)\u00a0(A)\u548cZnMnCoO<sub>4<\/sub>\u00a0(x = 1) (B)\u7684TEM\u56fe\u7247\uff0c\uff08C-F\uff09\u4e3aZnMnCoO<sub>4<\/sub>\u5fae\u7403\u7684\u5143\u7d20\u5206\u5e03\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127257 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72471-19.png\" alt=\"\" width=\"600\" height=\"383\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72471-19.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72471-19-300x192.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe2. \u00a0\u4e0d\u540c\u6837\u54c1\u7684ORR\u6027\u80fd\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127258 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72472-18.png\" alt=\"\" width=\"600\" height=\"448\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72472-18.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72472-18-300x224.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe3. ZnMn<sub>x<\/sub>Co<sub>2<\/sub><sub>&#8211;<\/sub><sub>x<\/sub>O<sub>4<\/sub>\u7684ORR\u53cd\u5e94\u673a\u7406\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127259 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72473-18.png\" alt=\"\" width=\"600\" height=\"445\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72473-18.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72473-18-300x223.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cell.com\/joule\/fulltext\/S2542-4351(17)30187-3\" target=\"_blank\" rel=\"noopener\">Durable and Efficient Hollow Porous Oxide Spinel Microspheres for Oxygen Reduction. 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