{"id":127011,"date":"2018-03-02T06:30:51","date_gmt":"2018-03-01T22:30:51","guid":{"rendered":"\/\/m.iemloyee.com\/?p=127011"},"modified":"2018-02-28T16:33:17","modified_gmt":"2018-02-28T08:33:17","slug":"angew-chem-int-ed-%ef%bc%9a%e8%b6%85%e8%96%84pd%e7%94%b5%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=127011","title":{"rendered":"Angew Chem. Int. Ed.\uff1a\u8d85\u8584Pd\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5bf9\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u7684\u7cbe\u786e\u63a7\u5236\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u6750\u6599\u7684\u539f\u5b50\u5229\u7528\u7387\uff0c\u964d\u4f4e\u8d35\u91d1\u5c5e\u7684\u7528\u91cf\u548c\u51cf\u5c0f\u6210\u672c\u7684\u540c\u65f6\u4fdd\u6301\u751a\u81f3\u63d0\u9ad8\u6750\u6599\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u8fd1\u5e74\u6765\uff0c\u4ec5\u6709\u51e0\u4e2a\u539f\u5b50\u5c42\u751a\u81f3\u5355\u539f\u5b50\u5c42\u7684\u8d85\u8584\u7684\u91d1\u5c5e\u7eb3\u7c73\u7247(NSs)\u7531\u4e8e\u5176\u72ec\u7279\u7684\u6027\u80fd\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4f8b\u5982\uff0c\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u5f20\u534e\u6559\u6388\u8bfe\u9898\u7ec4\u5408\u6210\u4e86\u4e00\u79cd\u548c\u5e38\u89c1\u9762\u5fc3\u7acb\u65b9\u76f8\u4e0d\u540c\u7684\u3001\u5177\u6709\u516d\u65b9\u76f8\u7ed3\u6784\u7684\u8d85\u8584Au\u7eb3\u7c73\u7247\uff08Nature Commun. <\/em>2011<\/strong>, 2<\/em>, 292\uff09;\u6b64\u5916\uff0c\u8d85\u8584\u7eb3\u7c73\u7247\u7684\u5927\u91cf\u539f\u5b50\u5206\u5e03\u5728\u8868\u9762\uff0c\u5f62\u6210\u4e86\u9ad8\u7684\u8868\u9762\u79ef\u548c\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u4ece\u800c\u53ef\u80fd\u5177\u6709\u6781\u597d\u7684\u50ac\u5316\u6027\u80fd\u3002\u4f8b\u5982\uff0c\u674e\u4e9a\u680b\u9662\u58eb\u8bfe\u9898\u7ec4\u57282014\u5e74\u521d\u62a5\u9053\u4e86\u5177\u6709\u9ad8\u52a0\u6c22\u53cd\u5e94\u6d3b\u6027\u7684\u5355\u5c42\u539f\u5b50Rh\u50ac\u5316\u5242\uff08Nat. Commun. <\/em>2014<\/strong>, 5<\/em>, 3093\uff09\u3002\u5728\u8d85\u8584\u7684\u7eb3\u7c73\u7247\u4e2d\u6784\u9020\u5b54\u53ef\u4ee5\u589e\u52a0\u5176\u6bd4\u8868\u9762\u79ef\u4ee5\u53ca\u66b4\u9732\u4e0d\u540c\u7684\u6676\u4f53\u9762\uff0c\u4ece\u800c\u53ef\u80fd\u8fdb\u4e00\u6b65\u589e\u52a0\u50ac\u5316\u6d3b\u6027\u3002\u7136\u800c\uff0c\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u9664\u4e86\u5728\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(TEM)\u7684\u6d4b\u91cf\u4e0b\uff0c\u7eb3\u7c73\u8584\u7247\u53d7\u5230\u7535\u5b50\u675f\u7684\u7167\u5c04\u5f62\u6210\u65e0\u5e8f\u4e0d\u89c4\u5219\u7684\u5b54\u4e4b\u5916\uff0c\u8fd8\u6ca1\u6709\u6709\u6548\u7684\u65b9\u6cd5\u6765\u5408\u6210\u6709\u5b54\u7684\u8d85\u8584\u7684\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u3002\u7eb3\u7c73\u7247\u4e0a\u5236\u9020\u5b54\uff0c\u7279\u522b\u662f\u5728\u8d85\u8584\u7684\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7247\u4e2d\u7cbe\u786e\u63a7\u5236\u5b54\u7684\u5c3a\u5bf8\u548c\u5bc6\u5ea6\u662f\u76f8\u5f53\u56f0\u96be\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7684\u6d2a\u52cb\u526f\u6559\u6388\u548c\u6e05\u534e\u5927\u5b66\u7684\u674e\u4e9a\u680b\u9662\u58eb<\/strong>\u7b49\u4eba\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cUltrathin Palladium Nanomesh for Electrocatalysis<\/strong>\u201d\u3002\u7814\u7a76\u4eba\u5458\u91c7\u7528\u4e00\u79cd\u6db2\u76f8\u7f13\u6162\u6c27\u5316\u523b\u8680\u7684\u65b9\u6cd5\u5236\u5907\u4e86\u4e00\u79cd\u539a\u5ea6\u7ea6\u4e3a3nm\u7684\u6709\u5e8f\u7684Pd\u7eb3\u7c73\u7b5b\u3002\u8fd9\u79cd\u8d85\u8584\u7684Pd\u7eb3\u7c73\u7b5b\u5177\u6709\u5185\u90e8\u8fde\u63a5\u7684\u5bc6\u96c6\u7684\u6392\u5217\u7684\u4e8c\u7ef4\u7f51\u7edc\u7ed3\u6784\uff0c\u800c\u4e14\u5177\u6709\u6bd4\u8f83\u6709\u5e8f\u7684\u5b54\u9053\u7ed3\u6784\u3002\u72ec\u7279\u7684\u4ecb\u5b54\u7ed3\u6784\u4ee5\u53ca\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u4f7f\u8d85\u8584Pd\u7eb3\u7c73\u7b5b\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u4e59\u9187\u7535\u6c27\u5316\u50ac\u5316\u6027\u80fd\uff08\u57280.8\u2005V vs. RHE\uff0c\u8d28\u91cf\u6d3b\u60275.40\u2005A mg\u22121<\/sup>\uff0c\u6bd4\u6d3b\u60277.09\u2005mA\u2009cm\u22122<\/sup>)\u3002\u800c\u4e14\uff0c\u89c4\u5219\u7684\u7f51\u7edc\u7ed3\u6784\u80fd\u591f\u7528\u6765\u652f\u6491\u5176\u4ed6\u8d35\u91d1\u5c5e\u6750\u6599\uff0c\u6bd4\u5982Pt\u8d1f\u8f7d\u540e\uff0c\u5176HER\u6d3b\u6027\u53ca\u7a33\u5b9a\u6027\u4e0e\u5546\u4e1aPt\/C\u76f8\u6bd4\u6709\u8f83\u5927\u63d0\u5347\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. \u8d85\u8584Pd\u7eb3\u7c73\u7f51\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) TEM\u56fe\uff1b<\/p>\n

b) AFM\u76f8\u56fe(\u63d2\u56fe)\u4ee5\u53ca\u76f8\u5e94\u7684\u5b54\u5f84\u5206\u5e03\uff1b<\/p>\n

c) HAADF-STEM\u56fe\uff1b\u8fd9\u79cd\u7eb3\u7c73\u7b5b\u7ed3\u6784\u5728TEM\u7535\u5b50\u675f\u7167\u5c04\u4e0b\u53ef\u4ee5\u4fdd\u6301\u7a33\u5b9a\u3002<\/p>\n

d) \u539f\u5b50\u5206\u8fa8\u7684HAADF-STEM\u56fe\uff1b<\/p>\n

\u56fe2. \u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a) Pd NMs\u5408\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

b)\u2013e) \u4e0d\u540c\u6c27\u5316\u523b\u8680\u901f\u7387\u7684\u76f8\u5e94\u7684TEM\u56fe\uff1b<\/p>\n

\u4e0a\u90e8\u8def\u7ebf: \u65f6\u95f4\u8def\u7ebf\u548c\u4ea7\u7269b) Pd \u7eb3\u7c73\u7247\uff1bc) \u8d85\u8584Pd \u7eb3\u7c73\u7b5b\u7f13\u6162\u6c27\u5316\u4e00\u5468\u7684\u4e2d\u95f4\u4ea7\u7269\uff1b<\/p>\n

\u4e2d\u95f4\u8def\u7ebf\uff1a\u51cf\u7f13\u6c27\u5316\u523b\u8680\u901f\u7387\u548c\u4ea7\u7269d)\u5e26\u6709\u7f51\u7edc\u7684Pd \u7eb3\u7c73\u7247\uff1b<\/p>\n

\u4e0b\u90e8\u8def\u7ebf: \u52a0\u901f\u6c27\u5316\u523b\u8680\u901f\u7387\u548c\u4ea7\u7269e) Pd \u6ce2\u72b6\u7eb3\u7c73\u7ebf\uff1b<\/p>\n

\u56fe3. \u7535\u5316\u5b66\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a)\u8d85\u8584Pd \u7eb3\u7c73\u7b5bNMs, \u8d85\u8584Pd \u7eb3\u7c73\u7247, \u5546\u4e1aPd\/C in 1.0M KOH\u6eb6\u6db2\u4e2d\u7684CVs\uff1b<\/p>\n

b) \u57280M KOH\u548c1.0M\u4e59\u9187\u6eb6\u6db2\u4e2d\u7684\u4e0d\u540c\u50ac\u5316\u5242\u5bf9EOR\u7684\u8d28\u91cf\u6d3b\u6027\u7684CVs\uff1b<\/p>\n

c) \u57280M KOH\u548c1.0M\u4e59\u9187\u6eb6\u6db2\u4e2d\u7684\u4e0d\u540c\u50ac\u5316\u5242\u5bf9EOR\u7684\u8d28\u91cf\u548c\u6bd4\u6d3b\u6027\u7684\u76f4\u65b9\u56fe\uff1b<\/p>\n

d) \u57280M KOH\u548c1.0M \u4e59\u9187\u6eb6\u6db2\u4e2d\u7684\u8ba1\u65f6\u7535\u6d41(CA)\u66f2\u7ebf\uff1b<\/p>\n

e) Pd NMs\/Pt, Pd NMs\u548c\u5546\u4e1aPt\/C\u7535\u50ac\u5316\u5242\u57285M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

f) Pd NMs\/Pt\u548c\u5546\u4e1aPt\/C\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u9996\u6b21\u91c7\u7528\u81ea\u4e0a\u800c\u4e0b\u7684\u65b9\u6cd5\u5408\u6210\u4e86\u53ef\u63a7\u7684\u6709\u5e8f\u591a\u5b54\u6750\u6599\u2014\u2014\u4e00\u79cd\u539a\u5ea6\u7ea6\u4e3a3nm\u7684\u6709\u5e8f\u7684Pd\u7b5b\u3002\u8fd9\u79cd\u8d85\u8584\u7684Pd\u7eb3\u7c73\u7b5b\u5177\u6709\u5185\u90e8\u8fde\u63a5\u7684\u5bc6\u96c6\u7684\u6392\u5217\u7684\u4e8c\u7ef4\u7f51\u7edc\u7ed3\u6784\uff0c\u800c\u4e14\u5e26\u6709\u6bd4\u8f83\u6709\u5e8f\u7684\u5b54\u7ed3\u6784\u3002\u72ec\u7279\u7684\u4ecb\u5b54\u7ed3\u6784\u4ee5\u53ca\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u4f7f\u8d85\u8584Pd\u7eb3\u7c73\u7f51\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u4e59\u9187\u7535\u6c27\u5316\u50ac\u5316\u6027\u80fd\uff08\u57280.8\u2005V vs. RHE\uff0c\u8d28\u91cf\u6d3b\u60275.40\u2005A mg\u22121<\/sup>\uff0c\u6bd4\u6d3b\u60277.09\u2005mA\u2009cm\u22122<\/sup>)\u3002\u901a\u8fc7\u5d4c\u5165Pt\u7eb3\u7c73\u9897\u7c92\uff0c\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u6574\u4f53\u7684HER\u6027\u80fd\u4e5f\u6709\u6240\u63d0\u5347\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ultrathin Palladium Nanomesh for Electrocatalysis<\/a>, (Angew. Chem. Int. Ed.,2018, DOI:\u00a02018, 10.1002\/anie.201800552)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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