{"id":126984,"date":"2018-02-25T06:30:07","date_gmt":"2018-02-24T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=126984"},"modified":"2018-02-24T18:51:32","modified_gmt":"2018-02-24T10:51:32","slug":"macromolecules%ef%bc%9a%e9%a6%99%e8%b1%86%e7%b4%a0%e7%ab%af%e5%9f%ba%e4%ba%8c%e8%81%9a%e8%af%b1%e5%af%bc%e7%9a%84%e5%85%89%e6%95%8f%e9%81%a5%e7%88%aa%e8%81%9a%e9%9b%86%e9%ab%98%e5%88%86%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=126984","title":{"rendered":"Macromolecules\uff1a\u9999\u8c46\u7d20\u7aef\u57fa\u4e8c\u805a\u8bf1\u5bfc\u7684\u5149\u654f\u9065\u722a\u805a\u96c6\u9ad8\u5206\u5b50\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u5f02\u5e38\u77ac\u6001\u7f51\u7edc\u548c\u6d41\u53d8\u884c\u4e3a"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7531\u758f\u6c34\u672b\u7aef\u57fa\u548c\u4eb2\u6c34\u9aa8\u67b6\u7ec4\u6210\u7684\u9065\u722a\u578b\u805a\u96c6\u9ad8\u5206\u5b50\uff08TAPs\uff09\u5728\u6c34\u6eb6\u6db2\u4e2d\u5728\u5176\u4e34\u754c\u805a\u96c6\u6d53\u5ea6\uff08cac\uff09\u4ee5\u4e0a\u53ef\u5f62\u6210\u7531\u82b1\u73af\uff08\u4eb2\u6c34\u9aa8\u67b6\uff09\u548c\u80f6\u675f\u6838\u5fc3\uff08\u758f\u6c34\u7aef\u57fa\uff09\u7ec4\u6210\u7684\u6240\u8c13\u7684\u82b1\u74e3\u72b6\u80f6\u675f\u3002\u800c\u968f\u7740\u805a\u5408\u7269\u6d53\u5ea6\u7684\u589e\u52a0\uff0c\u4e00\u4e9b\u9ad8\u5206\u5b50\u94fe\u53ef\u4ee5\u901a\u8fc7\u67b6\u6865\u7684\u65b9\u5f0f\u8fde\u63a5\u76f8\u90bb\u7684\u80f6\u675f\uff0c\u8fdb\u800c\u5f62\u6210\u52a8\u6001\u7269\u7406\u4ea4\u8054\u7f51\u7edc\uff0c\u5bfc\u81f4\u6eb6\u6db2\u7c98\u5ea6\u6025\u5267\u4e0a\u5347\u3002\u57fa\u4e8e\u6b64\u6027\u8d28\uff0cTAPs\u88ab\u5e7f\u6cdb\u7528\u4f5c\u6d41\u53d8\u6539\u6027\u5242\uff0c\u7528\u4e8e\u6539\u5584\u5de5\u4e1a\u9886\u57df\u4e2d\u6eb6\u6db2\u7684\u6d41\u53d8\u6027\u8d28\u3002\u7814\u7a76\u4eba\u5458\u5728\u9065\u722a\u805a\u5408\u7269\u7684\u57fa\u7840\u4e4b\u4e0a\uff0c\u8bbe\u8ba1\u5e76\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u5149\u654f\u6027\u9999\u8c46\u7d20\u5b98\u80fd\u5316\u7684\u9065\u722a\u578b\u805a\u96c6\u6a21\u578b\u805a\u5408\u7269\uff08CouTAP\uff09\uff0c\u7528\u4e8e\u7814\u7a76\u9999\u8c46\u7d20\u7aef\u57fa\u5149\u8bf1\u5bfc\u4e8c\u805a\u5316\u5bf9\u805a\u5408\u7269\u7ed3\u6784\u548c\u6eb6\u6db2\u6d41\u53d8\u6027\u7684\u5f71\u54cd\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea<strong>\u534e\u5357\u7406\u5de5\u5927\u5b66<\/strong>\u7684<strong>\u4efb\u78a7\u91ce\u6559\u6388<\/strong>\u548c<strong>\u534e\u5357\u5e08\u8303\u5927\u5b66\u8463\u4efb\u5cf0\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u53ca<strong>\u535a\u58eb\u751f\u675c\u67f1\u5eb7\uff08\u7b2c\u4e00\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728\u8fd1\u671f\u7684<strong>Macromolecules<\/strong>\u671f\u520a\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201c<strong>Unusual Transient Network and Rheology of a Photo-Responsive Telechelic Associative Model Polymer in Aqueous Solution Induced by Dimerization of Coumarin End Groups<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u672c\u6587\u4ecb\u7ecd\u4e86\u7814\u7a76\u4eba\u5458\u5728\u9065\u722a\u805a\u5408\u7269\u7684\u57fa\u7840\u4e4b\u4e0a\uff0c\u8bbe\u8ba1\u5e76\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u5149\u654f\u6027\u9999\u8c46\u7d20\u5b98\u80fd\u5316\u7684\u9065\u722a\u578b\u805a\u96c6\u6a21\u578b\u805a\u5408\u7269\uff08CouTAP\uff09\uff0c\u7528\u4e8e\u7814\u7a76\u5149\u7167\u5f3a\u5ea6\uff0c\u7167\u5c04\u65f6\u95f4\uff0c\u805a\u5408\u7269\u6d53\u5ea6\uff0c\u6e29\u5ea6\u7b49\u56e0\u7d20\u5bf9CoTAP\u6c34\u6eb6\u6db2\u77ac\u6001\u7f51\u7edc\u548c\u6d41\u53d8\u884c\u4e3a\u7684\u5f71\u54cd\u3002\u7814\u7a76\u8868\u660e\uff0c\u4e8c\u805a\u5316\u7684CouTAP\u6c34\u6eb6\u6db2\u7684\u6d41\u53d8\u6027\u8d28\u8868\u73b0\u51fa\u8f83\u5f31\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\uff0c\u5e76\u4e14\u7531\u4e8e\u4e09\u5d4c\u6bb5\u8f6c\u5316\u4e3a\u591a\u5d4c\u6bb5\u805a\u5408\u7269\uff0c\u52a8\u529b\u5b66\u6027\u8d28\u51e0\u4e4e\u4e0d\u4f9d\u8d56\u4e8e\u6d53\u5ea6\u3002\u7814\u7a76\u4eba\u5458\u7684\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u5c06\u4e3a\u9999\u8c46\u7d20\u672b\u7aef\u57fa\u56e2\u7684\u5149\u8bf1\u5bfc\u4e8c\u805a\u5316\u5bf9CouTAP\u6eb6\u6db2\u7684\u7f51\u7edc\u7ed3\u6784\u548c\u6d41\u53d8\u5b66\u6027\u8d28\u7684\u5f71\u54cd\u63d0\u4f9b\u65b0\u7684\u89c1\u89e3\uff0c\u800c\u4e14\u4e3a\u4e24\u4eb2\u805a\u5408\u7269\u7684\u53ef\u63a7\u81ea\u7ec4\u88c5\u548c\u4e00\u4e9b\u7279\u6b8a\u5e94\u7528\u5f00\u542f\u4e86\u4e00\u4e2a\u65b0\u7684\u89c6\u89d2\uff1aTAPs\u5728\u5236\u9020\u548c\u4f20\u8f93\u8f6f\u8d28\u6750\u6599\uff0c\u6c34\u6027\u6d82\u6599\uff0c\u6cb9\u58a8\uff0c\u836f\u54c1\uff0c\u5316\u5986\u54c1\u7b49\u65b9\u9762\u5747\u6709\u72ec\u7279\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 CouC<sub>11<\/sub>OH\u5c01\u7aef\u5242\u548cCouTAP\u6a21\u578b\u805a\u5408\u7269\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126985 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72471-17.png\" alt=\"\" width=\"600\" height=\"380\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72471-17.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72471-17-300x190.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe2 CouTAP\u6c34\u6eb6\u6db2\u7684\u7d2b\u5916\u5149\u8c31\u53ca\u4e8c\u805a\u5316\u7a0b\u5ea6\u66f2\u7ebf\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126986 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72472-16.png\" alt=\"\" width=\"600\" height=\"246\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72472-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72472-16-300x123.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>A\uff093wt\uff05\u7684CouTAP\u6c34\u6eb6\u6db2\u7684\u7d2b\u5916\u5149\u8c31\u968f\u7167\u5c04\u65f6\u95f4t\u7684\u53d8\u5316\uff1b<\/p>\n<p>B\uff09\u4e8c\u805a\u5316\u7a0b\u5ea6D\u4e0e\u4e0d\u540c\u5149\u7167\u5f3a\u5ea6\u7684\u7167\u5c04\u65f6\u95f4t\u7684\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe3 \u4e0d\u540c\u65f6\u95f4\u7d2b\u5916\u5149\u7167\u4e0b0.1wt%\u7684\u7eafPEG20000\u548cCouTAP\u6c34\u6eb6\u6db2\u7684DLS\u6d4b\u91cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126987 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72473-16.png\" alt=\"\" width=\"600\" height=\"542\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72473-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72473-16-300x271.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8be5\u56fe\u6240\u793a\u53ea\u6709\u7eaf\u7684PEG20000\u663e\u793a\u72ed\u7a84\u7684\u677e\u5f1b\u6a21\u5f0f\u3002<\/p>\n<p><strong>\u56fe4 \u4e0d\u540c\u65f6\u95f4\u7d2b\u5916\u5149\u7167\u4e0b3wt%CouTAP\u6c34\u6eb6\u6db2\u4e2d\u6a21\u91cfG&#8217;\u548cG&#8221;\u4e0e\u89d2\u9891\u7387\u03c9\u7684\u5173\u7cfb\u66f2\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126988 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72474-15.png\" alt=\"\" width=\"600\" height=\"710\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72474-15.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72474-15-254x300.png 254w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe5 \u4e0d\u540c\u65f6\u95f4\u7d2b\u5916\u5149\u7167\u4e0b3wt%CouTAP\u6c34\u6eb6\u6db2\u7684BSW\u5149\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126989 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72475-7.png\" alt=\"\" width=\"600\" height=\"502\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72475-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72475-7-300x251.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e0a\u8ff0\u5149\u8c31\u53ef\u4ee5\u5206\u4e3a\u4e24\u79cd\u72b6\u6001\uff1a\u5feb\u901f\u6a21\u5f0f\u548c\u6162\u901f\u6a21\u5f0f\u3002\u5feb\u901f\u6a21\u5f0f\u4f3c\u4e4e\u6cbf\u7740\u8d1f\u659c\u7387\u7684\u76f4\u7ebf\u5206\u7ec4\uff0c\u800c\u6162\u901f\u6a21\u5f0f\u4f3c\u4e4e\u6cbf\u7740\u6b63\u659c\u7387\u7684\u76f4\u7ebf\u5e76\u4e14\u7136\u540e\u5230\u8fbe\u5cf0\u503c\u3002<\/p>\n<p><strong>\u56fe6 3wt\uff05CouTAP\u6eb6\u6db2\u7684\u7c98\u5ea6\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126990 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72476-7.png\" alt=\"\" width=\"600\" height=\"244\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72476-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72476-7-300x122.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>A\uff09\u5728\u4e0d\u540c\u65f6\u95f4\u7684365nm\u6ce2\u957f\u7684\u5149\u7167\u4e0b3wt\uff05CouTAP\u6eb6\u6db2\u7684\u7a33\u6001\u526a\u5207\u7c98\u5ea6\u03b7\u76f8\u5bf9\u4e8e\u526a\u5207\u901f\u7387\u03b3<sup>\u00b0<\/sup>\u7684\u66f2\u7ebf\u56fe\uff1b<\/p>\n<p>B\uff093wt\uff05\u7684CouTAP\u6c34\u6eb6\u6db2\u7684\u96f6\u526a\u5207\u7c98\u5ea6\u03b7<sub>0<\/sub>\u76f8\u5bf9\u4e8e\u7167\u5c04\u65f6\u95f4t\u7684\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe7 \u7d2b\u5916\u7ebf\u7167\u5c04\u540e\u7684CouTAP\u6c34\u6eb6\u6db2\u7f51\u7edc\u6a21\u578b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126991 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72477-5.png\" alt=\"\" width=\"600\" height=\"673\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72477-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72477-5-267x300.png 267w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe8 3wt\uff05\u4e8c\u805a\u5316\u7684CouTAP\u6c34\u6eb6\u6db2\u7684\u6e29\u5ea6\u626b\u63cf\u6d4b\u91cf\u548c\u9891\u7387\u6d4b\u91cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-126992 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72478-3.png\" alt=\"\" width=\"600\" height=\"249\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72478-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/\u56fe\u72478-3-300x125.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.macromol.7b01514\" target=\"_blank\" rel=\"noopener\">Unusual Transient Network and Rheology of a Photoresponsive Telechelic Associative Model Polymer in Aqueous Solution Induced by Dimerization of Coumarin End Groups<\/a>.<\/strong>\uff08Macromolecules\uff0c2018\uff0cDOI: 10.1021\/acs.macromol.7b01514\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u5b66\u672f\u7ec4Andy\u4f9b\u7a3f\uff0c\u4efb\u78a7\u91ce\u6559\u6388\u56e2\u961f\u5ba1\u6838\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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