{"id":126476,"date":"2018-02-24T14:00:44","date_gmt":"2018-02-24T06:00:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=126476"},"modified":"2018-02-22T11:06:02","modified_gmt":"2018-02-22T03:06:02","slug":"%e9%a9%ac%e9%87%8c%e5%85%b0%e5%a4%a7%e5%ad%a6%e7%8e%8b%e6%98%a5%e7%94%9f%e6%95%99%e6%8e%88angew-chem-int-ed-%ef%bc%9a%e5%81%b6%e6%b0%ae%e5%8c%96%e5%90%88%e7%89%a9%e9%92%a0%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=126476","title":{"rendered":"\u9a6c\u91cc\u5170\u5927\u5b66\u738b\u6625\u751f\u6559\u6388Angew. Chem. Int. Ed.\uff1a\u5076\u6c2e\u5316\u5408\u7269\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u53ef\u9006\u6c27\u5316\u8fd8\u539f\u5316\u5b66"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n \u4f7f\u7528\u53ef\u518d\u751f\u6709\u673a\u7535\u6781\u7684\u53ef\u6301\u7eed\u94a0\u79bb\u5b50\u7535\u6c60\uff08SSIBs\uff09\u662f\u7528\u4e8e\u5927\u89c4\u6a21\u53ef\u518d\u751f\u80fd\u6e90\u50a8\u5b58\u7684\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6709\u524d\u666f\u7684\u66ff\u4ee3\u54c1\u3002\u7136\u800c\uff0c\u7f3a\u4e4f\u9ad8\u6027\u80fd\u9633\u6781\u6750\u6599\u9650\u5236\u4e86SIBs\u7684\u53d1\u5c55\uff0c\u56e0\u4e3a\u9ad8\u6027\u80fdLIB\u9633\u6781\uff08\u4f8b\u5982\u77f3\u58a8\u548c\u7845\uff09\u5bf9\u4e8eSIB\u800c\u8a00\u662f\u65e0\u6d3b\u6027\u7684\uff0c\u800c\u91d1\u5c5e\u94a0\u5219\u53d7\u5230\u679d\u6676\u751f\u957f\u5f15\u8d77\u7684\u5b89\u5168\u95ee\u9898\u7684\u5f71\u54cd\u3002\u5c3d\u7ba1\u94a0\u79bb\u5b50\u53ef\u4ee5\u5728\u4f4e\u7535\u4f4d\u4e0b\u4e0e\u4e8c\u7518\u9187\u4e8c\u7532\u919a\u5171\u5d4c\u5165\u77f3\u58a8\u4e2d\uff0c\u4f46\u5176\u4f4e\u6bd4\u5bb9\u91cf\uff08<100mAh g-1<\/sup>\uff09\u9650\u5236\u4e86SIB\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u9ad8\u6027\u80fd\u53ef\u518d\u751f\u9633\u6781\u6750\u6599\u6210\u4e3aSSIBs\u7684\u4e3b\u8981\u6311\u6218\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n \u8fd1\u65e5\uff0c\u5728\u7f8e\u56fd<\/b><\/strong>\u9a6c\u91cc\u5170\u5927\u5b66\u738b\u6625\u751f\u6559\u6388<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u8bfe\u9898\u7ec4<\/b><\/strong>\u7684\u5e26\u9886\u4e0b\uff0c\u4e0e\u7f8e\u56fd<\/b><\/strong>\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4<\/b><\/strong>\u3001<\/b><\/strong>\u534e\u4e2d\u79d1\u6280\u5927\u5b66<\/b><\/strong>\u3001<\/b><\/strong>\u6c99\u7279\u963f\u62c9\u4f2f\u4f0a\u739b\u76ee\u963f\u535c\u675c\u52d2\u62c9\u8d6b\u66fc\u5927\u5b66<\/b><\/strong>\u5408\u4f5c\uff0c\u62a5\u544a\u4e86\u4e00\u79cd\u57fa\u4e8e\u5076\u6c2e\u57fa\u56e2\uff08N = N\uff09\u7684\u65b0\u578b\u6709\u673aSSIB\u7535\u6781\u6750\u6599\u3002\u5076\u6c2e\u57fa\u56e2\u53ef\u4ee5\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u4e2d\u5fc3\u4e0eNa+<\/sup>\u53d1\u751f\u53ef\u9006\u53cd\u5e94\u3002\u9009\u62e9\u4e09\u79cd\u6709\u673a\u5316\u5408\u7269\uff1a\u5076\u6c2e\u82ef\uff08AB\uff09\uff0c4-\uff08\u82ef\u5076\u6c2e\uff09\u82ef\u7532\u9178\u94a0\u76d0\uff08PBASS\uff09\u548c\u5076\u6c2e\u82ef-4,4′-\u4e8c\u7fa7\u9178\u94a0\u76d0 \uff08ADASS\uff09\u4f5c\u4e3a\u6a21\u578b\u5076\u6c2e\u5316\u5408\u7269\u4ee5\u8bc4\u4f30\u5b83\u4eec\u5728SIB\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002AB\u88ab\u9009\u4e3a\u57fa\u672c\u6a21\u578b\u82b3\u9999\u65cf\u5076\u6c2e\u5316\u5408\u7269\uff0c\u56e0\u4e3a\u5b83\u5728\u4e2d\u5fc3\u4ec5\u542b\u6709\u4e00\u4e2a\u529f\u80fd\u6027\u5076\u6c2e\u57fa\u56e2\u3002\u7136\u800c\uff0c\u5b83\u5728\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u5177\u6709\u9ad8\u6eb6\u89e3\u5ea6\u3002\u4e0eAB\u6df7\u5408\u540e\uff0c\u65e0\u8272\u7535\u89e3\u6db2\u53d8\u6210\u6a59\u8272\u3002\u4e3a\u4e86\u6291\u5236AB\u7684\u6eb6\u89e3\uff0c\u5728AB\u4e2d\u52a0\u5165\u7fa7\u9178\u76d0\u57fa\u56e2\u4ee5\u751f\u6210PBASS\u548cADASS\u3002\u5176\u4e2d\uff0cADASS\u5728\u9ad8\u500d\u7387\u6027\u80fd\u548c\u957f\u5faa\u73af\u5bff\u547d\u65b9\u9762\u8868\u73b0\u51fa\u6700\u4f73\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002ADASS\u57280.2C\u4e0b\u5bb9\u91cf\u4e3a170mAh g-1<\/sup>\uff0c\u5e76\u4e14\u5f53\u7535\u6d41\u5bc6\u5ea6\u589e\u52a0\u523010C\u548c20C\u65f6\uff0c\u5bb9\u91cf\u5206\u522b\u4fdd\u755966\uff05\u548c58\uff05\u3002\u6b64\u5916\uff0c\u572820C\u4e0b\u4fdd\u63012000\u6b21\u5faa\u73af\uff0c\u53ef\u9006\u5bb9\u91cf\u4e3a98mAh g-1<\/sup>\uff0c\u6bcf\u6b21\u5faa\u73af\u5bb9\u91cf\u8870\u51cf\u7387\u4e3a0.0067\uff05\u3002\u7ecf\u8868\u5f81\u8bc1\u5b9e\uff1a\u5076\u6c2e\u57fa\u56e2\u7684\u529f\u80fd\u662f\u4f5c\u4e3a\u4e0eNa+<\/sup>\u53ef\u9006\u952e\u5408\u7684\u7535\u5316\u5b66\u6d3b\u6027\u4f4d\u70b9\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cReversible Redox Chemistry of Azo Compounds for Sodium-Ion Batteries<\/b><\/strong>\u201d\u53d1\u8868\u5728\u4e86Angew. Chem. Int. Ed.<\/b><\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n \u56fe<\/b><\/strong>1<\/b><\/strong>\u00a0\u6709\u673a\u7535\u6781\u6750\u6599\u7684\u53cd\u5e94\u673a\u7406<\/b><\/strong><\/p>\n \u56fe<\/b><\/strong>2 <\/b><\/strong>ADASS\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong>\u8868\u5f81<\/b><\/strong><\/p>\n \uff08a\uff09ADASS\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u57280.2C\u4e0b\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n \uff08b\uff09ADASS\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u57280.1mV s-1<\/sup>\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b<\/p>\n \uff08c\uff09ADASS\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u57280.2C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u5bb9\u91cf\u548c\u5e93\u4f26\u6548\u7387\u4e0e\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb\uff1b<\/p>\n \uff08d\uff09ADASS\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u5728\u4e0d\u79cd\u500d\u7387\u4e0b\u7684\u6bd4\u5bb9\u91cf\uff1b<\/p>\n \uff08e\uff09ADASS\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u572810C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u5bb9\u91cf\u548c\u5e93\u4f26\u6548\u7387\u4e0e\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb\uff1b<\/p>\n \uff08f\uff09ADASS\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u572820C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u5bb9\u91cf\u548c\u5e93\u4f26\u6548\u7387\u4e0e\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb\u3002<\/p>\n \u56fe<\/b><\/strong>3 <\/b><\/strong>ADASS<\/b><\/strong>\u7535\u6781<\/b><\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong>\u8868\u5f81<\/b><\/strong><\/p>\n \uff08a\uff09\u5728\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f\uff08GITT\uff09\u6d4b\u91cf\u671f\u95f4ADASS\u7535\u6781\u7684\u7b2c\u4e00\u5708\u7535\u4f4d\u54cd\u5e94\uff1b<\/p>\n \uff08b\uff09\u5728GITT\u6d4b\u91cf\u671f\u95f4ADASS\u7535\u6781\u7684\u7b2c\u4e8c\u5708\u7535\u4f4d\u54cd\u5e94\uff1b<\/p>\n \uff08c\uff09\u5728GITT\u6d4b\u91cf\u671f\u95f4ADASS\u7535\u6781\u7684\u7b2c\u4e09\u5708\u7535\u4f4d\u54cd\u5e94\uff1b<\/p>\n \uff08d\uff09\u5728GITT\u6d4b\u91cf\u671f\u95f4\u7684\u5e73\u8861\u7535\u4f4d\u4e0e\u6bd4\u5bb9\u91cf\u7684\u5173\u7cfb\uff1b\u00a0<\/p>\n \uff08e\uff09\u4e0d\u79cd\u626b\u63cf\u901f\u7387\u4e0bADASS\u7684CV\u66f2\u7ebf\uff1b\u00a0<\/p>\n \uff08f\uff09ADASS\u7684\u5cf0\u503c\u7535\u6d41\u548c\u626b\u63cf\u901f\u7387\u7684\u5173\u7cfb\u3002<\/p>\n \u56fe<\/b><\/strong>4<\/b><\/strong>\u00a0<\/b><\/strong>ADASS<\/b><\/strong>\u7535\u6781<\/b><\/strong>\u7684<\/b><\/strong>\u53cd\u5e94\u673a\u7406<\/b><\/strong><\/p>\n \uff08a\uff09ADASS\u7535\u6781\u7684\u539f\u4f4d\u540c\u6b65\u52a0\u901f\u5668XRD\u56fe\u548c\u5f69\u8272\u56fe\u8c31\u4ee5\u53ca\u76f8\u5e94\u7684\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n \uff08b\uff095\u4e2a\u5faa\u73af\u4e4b\u524d\u548c\u4e4b\u540e\u7684ADASS\u7535\u6781\u7684XRD\u5149\u8c31\uff1b\u00a0<\/p>\n \uff08c\uff095\u4e2a\u5faa\u73af\u548c20\u4e2a\u5faa\u73af\u4e4b\u524d\u548c\u4e4b\u540e\u7684ADASS\u7535\u6781\u7684\u62c9\u66fc\u5149\u8c31\uff1b\u00a0<\/p>\n \uff08d\uff09AB\uff0cPBASS\u548cADASS\u7684\u76f8\u5bf9\u80fd\u91cf\u548c\u4f18\u5316\u7ed3\u6784\u7684DFT\u8ba1\u7b97\u7ed3\u679c\uff08\u53f3\u8f74\u5c06\u771f\u7a7a\u4e2d\u7684\u76f8\u5bf9\u80fd\u91cf\u4e0eSHE\u7684\u76f8\u5bf9\u7535\u52bf\u5bf9\u9f50\uff09\u3002<\/p>\n \u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n \u5076\u6c2e\u5316\u5408\u7269\u662f\u4e00\u7cfb\u5217\u65b0\u578b\u7684\u6709\u673a\u6d3b\u6027\u6750\u6599\uff0c\u5728SIBs\u4e2d\u88ab\u7528\u4f5c\u9633\u6781\u6750\u6599\u3002\u91c7\u7528\u82b3\u9999\u65cf\u5076\u6c2e\u5316\u5408\u7269ADASS\u4f5c\u4e3a\u7814\u7a76\u5076\u6c2e\u5316\u5408\u7269\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u673a\u7406\u7684\u6a21\u578b\u3002ADASS\u57280.2C\u4e0b\u7684\u53ef\u9006\u5bb9\u91cf\u4e3a170 mAh g-1<\/sup>\uff0c\u572810C\u4e0b\u5faa\u73af1000\u6b21\u548c20C\u4e0b\u5faa\u73af2000\u6b21\u5206\u522b\u4fdd\u6301\u53ef\u9006\u5bb9\u91cf113 mAh g-1<\/sup>\u548c98 mAh g-1<\/sup>\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002\u8be6\u7ec6\u7684\u8868\u5f81\u548cDFT\u8ba1\u7b97\u53d1\u73b0\uff0c\u5c0f\u7684\u76f8\u95f4\u7535\u963b\u548c\u4f4e\u7535\u4f4d\u6ede\u540e\u6709\u52a9\u4e8e\u9ad8\u500d\u7387\u6027\u80fd\uff0c\u5e76\u4e14ADASS\u4e2d\u7684\u5076\u6c2e\u57fa\u56e2\u5145\u5f53\u4e0eNa+<\/sup>\u53ef\u9006\u952e\u5408\u7684\u7535\u5316\u5b66\u6d3b\u6027\u4f4d\u70b9\u3002\u56e0\u6b64\uff0c\u5076\u6c2e\u5316\u5408\u7269\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u6709\u673a\u7535\u6781\u6750\u6599\u6709\u671b\u7528\u4e8e\u5f00\u53d1\u957f\u5468\u671f\u5bff\u547d\u548c\u9ad8\u500d\u7387\u7684SSIBs\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Reversible Redox Chemistry of Azo Compounds for Sodium-Ion Batteries<\/u><\/a>\uff08Angew. Chem. Int. Ed., 2018, DOI: 10.1002\/anie.201713417\uff09<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u6728\u6587\u97ec\u7f16\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/b><\/u><\/strong><\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n