{"id":126343,"date":"2018-03-06T14:00:44","date_gmt":"2018-03-06T06:00:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=126343"},"modified":"2018-03-04T22:16:33","modified_gmt":"2018-03-04T14:16:33","slug":"adv-mater-%ef%bc%9a%e5%88%86%e5%ad%90%e5%8d%b0%e8%bf%b9%e5%a4%9a%e5%ad%94%e8%8a%b3%e9%a6%99%e9%aa%a8%e6%9e%b6%e5%8f%8a%e5%85%b6%e9%80%89%e6%8b%a9%e6%80%a7%e8%90%83%e5%8f%96%e9%93%80%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=126343","title":{"rendered":"Adv. Mater.\uff1a\u5206\u5b50\u5370\u8ff9\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\u53ca\u5176\u9009\u62e9\u6027\u8403\u53d6\u94c0\u79bb\u5b50\u7684\u590d\u5408\u7ec4\u5206"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p><span id=\"result_box\" lang=\"zh-CN\">\u7531\u4e8e\u94c0\u7684\u6700\u5927\u6765\u6e90\u662f\u5177\u6709\u5404\u79cd\u5e72\u6270\u79bb\u5b50\uff08Na<sup>+<\/sup>\uff0cK<sup>+<\/sup>\uff0cMg<sup>2+<\/sup>\uff0cCa<sup>2+<\/sup>\u7b49\uff09\u7684\u6d77\u6c34\uff0c\u56e0\u6b64\u4ece\u6c34\u4e2d\u9009\u62e9\u6027\u63d0\u53d6\u94c0\u5df2\u5f15\u8d77\u4e86\u5168\u4e16\u754c\u7684\u5173\u6ce8\u3002 \u7136\u800c\uff0c\u4f20\u7edf\u7684\u5438\u9644\u5242\u5c06\u5176\u5927\u90e8\u5206\u529f\u80fd\u4f4d\u70b9\u5c01\u88c5\u5728\u5176\u81f4\u5bc6\u7ed3\u6784\u4e2d\uff0c\u5bfc\u81f4\u9009\u62e9\u6027\u548c\u5438\u9644\u5bb9\u91cf\u4f4e\u7b49\u95ee\u9898\u3002 \u672c\u6587\u62a5\u9053\u4e86\u7ed3\u5408\u4f4d\u70b9\u9996\u5148\u88ab\u88c5\u9970\u6210\u591a\u5b54\u9aa8\u67b6\uff0c\u5e76\u4e14\u4e3a\u94c0\u63d0\u53d6\u51c6\u5907\u4e86\u4e00\u7cfb\u5217\u5206\u5b50\u5370\u8ff9\u7684\u591a\u5b54\u82b3\u9999\u65cf\u9aa8\u67b6\u3002 \u7531\u4e8e\u591a\u5b54\u7ed3\u6784\u63d0\u4f9b\u4e86\u8bb8\u591a\u53ef\u63a5\u8fd1\u7684\u4f4d\u70b9\uff0c\u4e0e\u4f20\u7edf\u7684\u5206\u5b50\u5370\u8ff9\u805a\u5408\u7269\u76f8\u6bd4\uff0c\u6240\u5f97\u6750\u6599\u5177\u6709\u56db\u500d\u589e\u52a0\u7684\u79bb\u5b50\u5bb9\u91cf\uff0c\u5e76\u4e14\u5728\u6240\u6709\u62a5\u9053\u7684\u94c0\u5438\u9644\u5242\u4e2d\u5177\u6709\u6700\u9ad8\u7684\u9009\u62e9\u6027\u3002 \u6b64\u5916\uff0c\u591a\u5b54\u6846\u67b6\u53ef\u4ee5\u5206\u6563\u5230\u5546\u4e1a\u805a\u5408\u7269\u4e2d\u5f62\u6210\u590d\u5408\u7ec4\u5206\uff0c\u4ee5\u4fbf\u4ece\u6a21\u62df\u6d77\u6c34\u4e2d\u5b9e\u9645\u8403\u53d6\u94c0\u79bb\u5b50\u3002<\/span><\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p><span id=\"result_box\" lang=\"zh-CN\"><span title=\"Organic porous materials have emerged as  innovative  functional  porous materials  in  the  last  20  years.\">\u5728\u8fc7\u53bb\u768420\u5e74\u4e2d\uff0c\u6709\u673a\u591a\u5b54\u6750\u6599\u5df2\u7ecf\u6210\u4e3a\u521b\u65b0\u578b\u529f\u80fd\u6027\u591a\u5b54\u6750\u6599\u3002<\/span><span title=\"Their  pure  organic   compositions  and spatial  structures  have stimulated    applications    in    catalysis, mole cule separation, and optoelectronics.\">\u5176\u7eaf\u51c0\u7684\u6709\u673a\u6210\u5206\u548c\u7a7a\u95f4\u7ed3\u6784\u6fc0\u53d1\u4e86\u50ac\u5316\u3001\u5206\u5b50\u5206\u79bb\u548c\u5149\u7535\u5b50\u5e94\u7528\u3002<\/span><span title=\"Porous   aromatic   frameworks  (PAFs) as amorphous members are known for their large surface areas and designabl skeletons.\">\u4f5c\u4e3a\u65e0\u5b9a\u5f62\u6784\u4ef6\u7684\u591a\u5b54\u82b3\u65cf\u9aa8\u67b6\uff08PAF\uff09\uff0c\u56e0\u5176\u5927\u7684\u8868\u9762\u79ef\u548c\u53ef\u8bbe\u8ba1\u7684\u9aa8\u67b6\u800c\u4f17\u6240\u5468\u77e5\u3002<\/span><span title=\"Through various organic coupling   reactions   and   easily   designed  building  monomers,  a  diversity  of  PAFs with defined fragments can be prepared.\n\">\u901a\u8fc7\u5404\u79cd\u6709\u673a\u5076\u8054\u53cd\u5e94\u548c\u5bb9\u6613\u8bbe\u8ba1\u7684\u5efa\u7b51\u5355\u4f53\uff0c\u53ef\u4ee5\u5236\u5907\u5177\u6709\u9650\u5b9a\u7247\u6bb5\u7684\u591a\u79cdPAF\u3002<\/span><\/span><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u7684\u6731\u5e7f\u5c71\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Adv. Mater.\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201c<strong>Molecularly Imprinted Porous Aromatic Frameworks and Their Composite Components for Selective Extraction of Uranium Ion<\/strong>s\u201d\u7684\u6587\u7ae0\u3002<span id=\"result_box\" lang=\"zh-CN\"><span title=\"Herein,  we  synthesize   a   UO22+-imprinted  complex   via  molecular  imprinting  technology  and  construct  a  series  of molecularly  imprinted  porous  aromatic  frameworks  (MIPAFs).\n\">\u8be5\u7814\u7a76\u901a\u8fc7\u5206\u5b50\u5370\u8ff9\u6280\u672f\u5408\u6210\u4e86UO22+\u5370\u8ff9\u590d\u5408\u7269\uff0c\u5e76\u6784\u5efa\u4e86\u4e00\u7cfb\u5217\u5206\u5b50\u5370\u8ff9\u591a\u5b54\u82b3\u9999\u65cf\u9aa8\u67b6\uff08MIPAF\uff09\u3002\u5728\u5185\u90e8\u7a7a\u95f4\u4e2d\u5177\u6709\u5927\u91cf\u53ef\u63a5\u8fd1\u6d3b\u6027\u90e8\u4f4d\u7684MIPAF\uff0c\u663e\u793a\u51fa\u6bd4\u4f20\u7edfMIP\u66f4\u9ad8\u7684UO<sub>2<\/sub> <sup>2+<\/sup>\u79bb\u5b50\u5438\u6536\u6027\u3002 \u53e6\u5916\uff0c\u5b83\u4eec\u5bf9UO<sub>2<\/sub> <sup>2+<\/sup>\u79bb\u5b50\u6355\u83b7\u5bf9\u6297\u5e72\u6270\u91d1\u5c5e\u79bb\u5b50\u7684\u9009\u62e9\u6027\u6700\u9ad8\u3002 \u800c\u4e14MIPAF\u80fd\u591f\u4e0e\u5176\u5b83\u805a\u5408\u7269\u6709\u5f88\u597d\u7684\u76f8\u5bb9\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u5177\u6709\u663e\u8457\u7684\u64cd\u4f5c\u7b80\u4fbf\u6027\u548c\u7075\u6d3b\u6027\uff0c\u53ef\u4ee5\u5f62\u6210\u590d\u5408\u7ea4\u7ef4\u3001\u8584\u819c\u548c\u6d82\u5c42\u3002<br \/>\n <\/span><\/span><\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \u6784\u5efa\u5355\u5143\u53ca\u5408\u6210\u9014\u5f84<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127566 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/1-38.png\" alt=\"\" width=\"700\" height=\"753\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/1-38.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/1-38-279x300.png 279w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff09Heck\u5076\u8054\u53cd\u5e94\u7684\u6784\u5efa\u5355\u4f4d\uff1b<\/p>\n<p>b\uff09MIPAF-11-a\u7684\u5408\u6210\u9014\u5f84\u548c\u53ef\u80fd\u7684\u7247\u6bb5\uff1b<\/p>\n<p>c\uff09\u57fa\u4e8e\u5b54\u5f84\u5206\u5e03\u7684MIPAF 11b-11d\u3002<\/p>\n<p><strong>\u56fe2 \u7ea2\u5916\u5149\u8c31\u53ca\u6838\u78c1\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127565 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/2-37.png\" alt=\"\" width=\"700\" height=\"1370\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/2-37.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/2-37-153x300.png 153w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/2-37-523x1024.png 523w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<div id=\"gt-res-c\">\n<div id=\"gt-res-p\">\n<div id=\"gt-res-data\">\n<div id=\"gt-res-wrap\">\n<div id=\"gt-res-content\">\n<div id=\"gt-res-dir-ctr\" dir=\"ltr\"><span id=\"result_box\" lang=\"zh-CN\">a\uff091,3,5-\u4e09\uff084-\u6eb4\u82ef\u57fa\uff09\u82ef\uff08\u9ed1\u8272\uff09\uff0cMIPAF 11a\uff08\u84dd\u8272\uff09\uff0c11b\uff08\u7ea2\u8272\uff09\uff0c11c\uff08\u7eff\u8272\uff09\u548c11d\uff08\u7c89\u7ea2\u8272\uff09\u7684FT-IR\u5149\u8c31\uff1b<\/span><\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">b\uff09MIPAF 11a\uff08\u9ed1\u8272\uff09\uff0c11b\uff08\u7eff\u8272\uff09\uff0c11c\uff08\u7ea2\u8272\uff09\u548c11d\uff08\u84dd\u8272\uff09\u768413 C CP \/ MAS NMR\u8c31\u56fe\u3002<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\"><strong>\u56fe3 \u5438\u9644\u7b49\u6e29\u7ebf\u56fe<\/strong><\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127567 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/3-29.png\" alt=\"\" width=\"700\" height=\"1065\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/3-29.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/3-29-197x300.png 197w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/3-29-673x1024.png 673w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/div>\n<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<\/div>\n<div dir=\"ltr\">a\uff09\u6c2e\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">b\uff09MIPAF\u7684UO<sub>2<\/sub> <sup>2+<\/sup>\u79bb\u5b50\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\"><strong>\u56fe4 \u79bb\u5b50\u5bb9\u91cf\u56fe<\/strong><\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<\/div>\n<\/div>\n<div dir=\"ltr\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127568 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/4-24.png\" alt=\"\" width=\"700\" height=\"1042\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/4-24.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/4-24-202x300.png 202w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/4-24-688x1024.png 688w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/div>\n<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">a\uff09MIPAF-11c\u5728\u5b58\u5728\u4e0d\u540c\u5e72\u6270\u79bb\u5b50\u7684\u60c5\u51b5\u4e0b\u7684\u79bb\u5b50\u5bb9\u91cf\uff1b<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">b\uff09MIPAF-11c\u4e0e\u5176\u4ed6\u57fa\u51c6\u6750\u6599\u7684UO<sub>2<\/sub> <sup>2+<\/sup>\u79bb\u5b50\u9009\u62e9\u6027\u548c\u9971\u548c\u5438\u6536\u91cf\u7684\u6bd4\u8f83\u3002<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\"><strong>\u56fe5 \u590d\u5408\u7ea4\u7ef4\u3001\u590d\u5408\u6d82\u5c42\u7684\u6027\u80fd\u8bd5\u9a8c<\/strong><\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-127569 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/5-20.png\" alt=\"\" width=\"700\" height=\"518\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/5-20.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/02\/5-20-300x222.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">a\uff09MIPAF-11c\u590d\u5408\u7ea4\u7ef4\u548c\u6d82\u5c42\uff1b<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">b\uff09MIPAF-11c\u590d\u5408\u6d82\u5c42\u7684UO<sub>2<\/sub> <sup>2+<\/sup>\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">c\uff09\u5728\u5404\u79cd\u5e72\u6270\u79bb\u5b50\u5b58\u5728\u4e0bMIPAF-11c\u590d\u5408\u6d82\u5c42\u7684UO<sub>2<\/sub> <sup>2+<\/sup>\u79bb\u5b50\u5bb9\u91cf\uff1b<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">d\uff09MIPAF-11c\u590d\u5408\u6d82\u5c42\u7684\u56de\u6536\u5b9e\u9a8c\u3002<\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\"><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\">\u7814\u7a76\u4eba\u5458\u5c06\u5206\u5b50\u5370\u8ff9\u6280\u672f\u4e0e\u591a\u5b54\u6750\u6599\u7684\u7ed3\u6784\u76f8\u7ed3\u5408\uff0c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u7528\u4e8e\u9009\u62e9\u6027\u63d0\u53d6UO<sub>2<\/sub><sup>2+<\/sup>\u79bb\u5b50\u7684MIPAF\u3002 \u5177\u6709\u5927\u91cf\u53ef\u8bbf\u95ee\u7684\u5370\u8ff9\u4f4d\u70b9\u7684MIPAFs\u6709\u6548\u5730\u9632\u6b62\u4e86UO<sub>2<\/sub><sup>2+<\/sup>\u79bb\u5b50\u6cc4\u6f0f\uff0c\u5e76\u4e14\u4e0e\u4f20\u7edf\u7684MIP\u76f8\u6bd4\uff0c<span style=\"line-height: 1.5;\">\u589e\u52a0\u4e86<\/span><span style=\"line-height: inherit;\">\u8fd1400\uff05\u7684\u5bb9\u91cf\u3002 MIPAF-11c\u7684\u52a0\u8f7d\u9009\u62e9\u6027\u662f\u8fc4\u4eca\u62a5\u9053\u7684\u6240\u6709UO<sub>2<\/sub><sup>2+<\/sup>\u79bb\u5b50\u5438\u9644\u5242\u4e2d\u62a5\u9053\u503c\u6700\u9ad8\u7684\u3002 \u6700\u91cd\u8981\u7684\u662f\uff0cMIPAF\u7c89\u672b\u53ef\u4ee5\u5206\u6563\u5230\u5546\u4e1a\u805a\u5408\u7269\u4e2d\u5236\u5907\u590d\u5408\u7ea4\u7ef4\u3001\u8584\u819c\u548c\u6d82\u6599\u3002 MIPAF\u53ca\u5176\u590d\u5408\u90e8\u4ef6\u7684\u7b80\u4fbf\u3001\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\u548c\u9ad8\u5bb9\u91cf\u4e3a\u5b9e\u9645UO<sub>2<\/sub><sup>2+<\/sup><\/span><span style=\"line-height: 1.5;\">\u7684<\/span><span style=\"line-height: inherit;\">\u79bb\u5b50\u8403\u53d6\u63d0\u4f9b\u4e86\u5149\u660e\u7684\u524d\u9014\u3002<\/span><\/div>\n<div dir=\"ltr\">\u00a0<\/div>\n<div dir=\"ltr\"><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201706507\/full\" target=\"_blank\" rel=\"noopener\"><strong>Molecularly Imprinted Porous Aromatic Frameworks and Their Composite Components for Selective Extraction of Uranium Ions<\/strong><\/a>\uff08Adv. 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