{"id":126158,"date":"2018-02-23T14:00:40","date_gmt":"2018-02-23T06:00:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=126158"},"modified":"2018-02-22T10:56:43","modified_gmt":"2018-02-22T02:56:43","slug":"angew-chem-int-ed-%ef%bc%9a%e9%93%9f%e6%8e%ba%e6%9d%82%e5%a4%9a%e5%ad%94%e7%a2%b3mop-%e7%ba%b3%e7%b1%b3%e9%a2%97%e7%b2%92-%e5%87%ba%e8%89%b2%e7%9a%84%e9%ab%98%e6%95%88co2%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=126158","title":{"rendered":"Angew. Chem. Int. Ed.\uff1a\u94df\u63ba\u6742\u591a\u5b54\u78b3MoP \u7eb3\u7c73\u9897\u7c92\u2014\u2014\u51fa\u8272\u7684\u9ad8\u6548CO2\u7535\u8fd8\u539f\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

CO2<\/sub>\u4e0d\u4ec5\u662f\u4e3b\u8981\u7684\u6e29\u5ba4\u6c14\u4f53\u4e5f\u662f\u4e00\u79cd\u5ec9\u4ef7\u7684\uff0c\u4e30\u5bcc\u7684\u5b89\u5168\u7684\u78b3\u6e90\u3002\u91c7\u7528CO2<\/sub>\u751f\u4ea7\u71c3\u6599\u6216\u8005\u5316\u5b66\u54c1\u5bf9\u4e8e\u5b9e\u73b0\u78b3\u80fd\u91cf\u5faa\u73af\u662f\u975e\u5e38\u6709\u524d\u666f\u7684\u3002\u5728\u4f17\u591aCO2<\/sub>\u8f6c\u6362\u65b9\u6cd5\u4e2d\uff0c\u7535\u5316\u5b66\u8fd8\u539f\u7cfb\u7edf\u662f\u7eff\u8272\u7684\uff0c\u6a21\u5757\u5316\u7684\u5e76\u4e14\u4fbf\u4e8e\u5927\u89c4\u6a21\u5e94\u7528\u7684\u3002\u7528\u4e8e\u8fc7\u7a0b\u9a71\u52a8\u7684\u7535\u80fd\u53ef\u4ee5\u901a\u8fc7\u53ef\u518d\u751f\u80fd\u6e90\u4ea7\u51fa\uff0c\u4f8b\u5982\u592a\u9633\u80fd\uff0c\u98ce\u80fd\u3002\u5728\u8fc7\u53bb\u51e0\u5341\u5e74\u4e2d\uff0c\u8bb8\u591a\u91d1\u5c5e\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u4ee5\u53ca\u78b3\u57fa\u6750\u6599\u88ab\u7528\u6765\u4f5c\u4e3a\u5728\u6c34\u6eb6\u6db2\u4e2d\u6216\u8005\u79bb\u5b50\u6db2\u4f53\uff08IL\uff09\u4e2dCO2<\/sub>\u8fd8\u539f\u7684\u7535\u6781\u3002\u867d\u7136\u8fd9\u4e9b\u7535\u6781\u6750\u6599\u5c55\u73b0\u51fa\u4e86\u4e00\u5b9a\u7684CO2<\/sub>\u8fd8\u539f\u6027\u80fd\uff0c\u4f46\u662f\u5b83\u4eec\u4ecd\u65e7\u4e0d\u591f\u9ad8\u6548\u548c\u5145\u5206\u4f7f\u7528\u3002<\/p>\n

\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u4eba\u5458\u5728\u53d1\u5c55\u975e\u8d35\u91d1\u5c5e\u7535\u50ac\u5316\u5242\uff0c\u6bd4\u5982\u5408\u91d1\uff0c\u91d1\u5c5e\u786b\u5316\u7269\uff0c\u78b3\u6750\u6599\uff0c\u78f7\u5316\u7269\u4ee5\u53ca\u6c2e\u5316\u787c\uff0c\u505a\u51fa\u4e86\u5de8\u5927\u7684\u52aa\u529b\u3002\u4f5c\u4e3a\u65b0\u578b\u7684\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5178\u578b\u4ee3\u8868, \u8fc7\u6e21\u91d1\u5c5e\u78f7\u5316\u7269(TMPs), \u7279\u522b\u662fMoP\u5728HER\uff0cORR\u4ee5\u53ca\u76f4\u63a5\u7532\u9187\u6c27\u5316\u53cd\u5e94(DMOR)\u4e2d\u6781\u5177\u524d\u666f\u3002\u540c\u65f6\u91c7\u7528\u591a\u5b54\u78b3\u6750\u6599\u6765\u7a33\u5b9a\u7eb3\u7c73\u7c92\u5b50\u662f\u4e00\u79cd\u6709\u6548\u7684\u9014\u5f84\u6765\u4fdd\u6301MoP\u7684\u9ad8\u6d3b\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u7684\u97e9\u5e03\u5174\u9662\u58eb<\/strong>\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cMoP Nanoparticles Supported on Indium-Doped Porous Carbon: Outstanding Catalysts for Highly Efficient CO2<\/sub> Electroreduction<\/strong>\u201d\u3002\u7814\u7a76\u4eba\u5458\u5408\u6210\u4e86\u94df\u63ba\u6742\u591a\u5b54\u78b3MoP \u7eb3\u7c73\u9897\u7c92\u7535\u50ac\u5316\u5242\uff0c\u5e76\u4e14\u9996\u6b21\u5c06\u5176\u5e94\u7528\u5728\u4e86CO2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\u9886\u57df\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0c\u94df\u63ba\u6742\u591a\u5b54\u78b3MoP \u7eb3\u7c73\u9897\u7c92\u5177\u6709\u51fa\u8272\u7684\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u7532\u9178\u7684\u6027\u80fd\u3002\u5f53\u91c7\u7528\u79bb\u5b50\u6db2\u4f531-\u4e01\u57fa-3- \u7532\u57fa\u54aa\u5511\u516d\u6c1f\u78f7\u9178\u76d0\u4f5c\u4e3a\u7535\u89e3\u6db2\u65f6\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u7535\u6d41\u5bc6\u5ea6\u5206\u522b\u8fbe\u5230\u4e8696.5%\u548c43.8mA cm-2<\/sup>\u3002\u7535\u6d41\u5bc6\u5ea6\u8981\u6bd4\u76ee\u524d\u62a5\u9053\u8fc7\u7684\u5177\u6709\u9ad8\u6cd5\u62c9\u7b2c\u6548\u7387\u7684\u50ac\u5316\u5242\u7684\u7535\u6d41\u5bc6\u5ea6\u9ad8\u3002MoP\u548c\u63ba\u6742\u7684In2<\/sub>O3<\/sub>\u5171\u540c\u4fc3\u8fdb\u4e8c\u6c27\u5316\u78b3\u7684\u7535\u8fd8\u539f\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. MoP@In-PC\u7ed3\u6784\u6210\u5206\u8868\u5f81<\/p>\n

\"\"<\/p>\n

A) SEM\u56fe\uff1b<\/p>\n

B) TEM\u56fe\uff1b<\/p>\n

C) HR-TEM\u56fe\u5e76\u4e14\u7bad\u5934\u5c55\u793a\u4e86MoP\u6676\u683c\uff1b<\/p>\n

D) MoP@In-PC\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

E), F), G) \u5206\u522b\u4e3aMoP@In-PC\u7684In 3d, Mo 3d, P 2p\u8f68\u9053\u7684XPS\u56fe\uff1b<\/p>\n

\u56fe2. \u4e8c\u6c27\u5316\u78b3\u7535\u8fd8\u539f\u53cd\u5e94<\/p>\n

\"\"<\/p>\n

A) 5\u4e2d\u7535\u6781\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

B) 5\u4e2d\u7535\u6781\u5728\u4e0d\u540c\u504f\u538b\u4e0b6\u5c0f\u65f6\u7535\u89e3\u4ea7\u751f\u7532\u9178\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff1aMoP@In-PC (a), MoP@Ga-PC (b), MoP@PC-1 (c), MoP@PC-2 (d), \u5757\u4f53MoP (e) \uff1b<\/p>\n

C)\u5728\u20132.2 V (vs. Ag\/Ag+)\u6761\u4ef6\u4e0b\u7535\u89e3\u8fc7\u7a0b\u7684\u7a33\u5b9a\u6027\uff1b<\/p>\n

D)5\u4e2d\u7535\u6781\u7684\u5854\u83f2\u5c14\u659c\u7387 \uff1b<\/p>\n

\u56fe3. MoP@In-PC\u8868\u9762\u79ef\u8868\u5f81<\/p>\n

\"\"<\/p>\n

A) \u572825\u2103\u4e0b5\u4e2d\u6750\u6599\u7684CO2<\/sub>\u5438\u9644\u66f2\u7ebf\uff1b<\/p>\n

B) \u5728-2.2V (vs. Ag\/Ag+<\/sup>)\u8fd8\u539f\u7535\u6d41\u5bc6\u5ea6\u66f2\u7ebf\u4e0e\u626b\u901f\u7684\u5173\u7cfb\uff1a(a)MoP@In-PC, (b)MoP@Ga-PC, (c)MoP@PC-1, (d)MoP@PC-2, (e)\u5757\u4f53 MoP\uff1b<\/p>\n

\u56fe4. \u7535\u5316\u5b66\u963b\u6297<\/p>\n

\"\"<\/p>\n

A)5\u79cd\u7535\u6781\u7684\u80fd\u65af\u7279\u66f2\u7ebf\uff1b<\/p>\n

B) 5\u4e2d\u7535\u6781\u5728\u9971\u548c\u6c2e\u6c14\u76840.1M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684\u5355\u4e00\u6c27\u5316LSV\u66f2\u7ebf\uff1b<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u901a\u8fc7MoP@In-PC, MoP@Ga-PC, MoP@PC-1, MoP@PC-2, \u5757\u4f53MoP\u5bf9\u4e8c\u6c27\u5316\u78b3\u7535\u50ac\u5316\u8fd8\u539f\u4e3a\u7532\u9178\u8fdb\u884c\u4e86\u7814\u7a76\u3002 \u7814\u7a76\u4eba\u5458\u53d1\u73b0MoP@In-PC\u662f\u975e\u5e38\u6709\u6548\u800c\u4e14\u7a33\u5b9a\u7684\u50ac\u5316\u5242\u3002\u5f53\u91c7\u7528\u79bb\u5b50\u6db2\u4f531-\u4e01\u57fa-3- \u7532\u57fa\u54aa\u5511\u516d\u6c1f\u78f7\u9178\u76d0\u4f5c\u4e3a\u7535\u89e3\u6db2\u65f6\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u7535\u6d41\u5bc6\u5ea6\u5206\u522b\u8fbe\u5230\u4e8696.5%\u548c43.8mA cm-2<\/sup>\u3002\u7814\u7a76\u8868\u660eMoP@In-PC\u51fa\u8272\u7684\u50ac\u5316\u6027\u80fd\u6765\u81ea\u4e8eMoP\u7684\u7eb3\u7c73\u5c3a\u5ea6\uff0c\u4f4e\u7684\u754c\u9762\u7535\u8377\u4f20\u8f93\u963b\u6297\uff0c\u5f3a\u7684CO2<\/sub> \u548cCO2<\/sub>\u00b7-<\/sup> \u4e2d\u95f4\u4f53\u5438\u9644\u80fd\u529b\uff0c\u4ee5\u53caMoP\u548c\u94df\u63ba\u6742\u78b3\u7684\u534f\u540c\u6548\u5e94\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aMoP Nanoparticles Supported on Indium-Doped Porous Carbon: Outstanding Catalysts for Highly Efficient CO2<\/sub> Electroreduction<\/a>,\uff08Angew. Chem. Int. Ed., 2018, DOI:\u00a010.1002\/aenm.201702839\uff09.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 CO2\u4e0d\u4ec5\u662f\u4e3b\u8981\u7684\u6e29\u5ba4\u6c14\u4f53\u4e5f\u662f\u4e00\u79cd\u5ec9\u4ef7\u7684\uff0c\u4e30\u5bcc\u7684\u5b89\u5168\u7684\u78b3\u6e90\u3002\u91c7\u7528CO2\u751f\u4ea7\u71c3\u6599\u6216\u8005\u5316\u5b66\u54c1\u5bf9\u4e8e\u5b9e\u73b0\u78b3\u80fd\u91cf\u5faa\u73af\u662f\u975e\u5e38\u6709\u524d\u666f\u7684\u3002\u5728\u4f17\u591aCO2\u8f6c\u6362\u65b9\u6cd5\u4e2d\uff0c\u7535\u5316…<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[116,33],"class_list":["post-126158","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-catalyst","tag-nano"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/126158"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=126158"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/126158\/revisions"}],"predecessor-version":[{"id":126595,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/126158\/revisions\/126595"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=126158"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=126158"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=126158"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}