{"id":124949,"date":"2018-03-01T06:30:39","date_gmt":"2018-02-28T22:30:39","guid":{"rendered":"\/\/m.iemloyee.com\/?p=124949"},"modified":"2018-02-27T21:59:02","modified_gmt":"2018-02-27T13:59:02","slug":"%e5%be%b7%e5%85%8b%e8%90%a8%e6%96%afam%e5%a4%a7%e5%ad%a6jacs%ef%bc%9a%e9%80%9a%e8%bf%87%e5%8f%af%e6%8e%a7%e9%85%8d%e4%bd%93%e7%83%ad%e8%a7%a3%e4%bb%8e%e5%a4%9a%e5%85%83%e9%87%91%e5%b1%9e%e6%9c%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=124949","title":{"rendered":"\u5fb7\u514b\u8428\u65afA&M\u5927\u5b66JACS\uff1a\u901a\u8fc7\u53ef\u63a7\u914d\u4f53\u70ed\u89e3\u4ece\u591a\u5143\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5236\u5907\u591a\u7ea7\u5b54\u6846\u67b6\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u662f\u4e00\u7c7b\u591a\u5b54\u6676\u4f53\u6750\u6599\uff0c\u5176\u5728\u6c14\u4f53\u5438\u9644\u3001\u5206\u79bb\u3001\u50ac\u5316\u548c\u4f20\u611f\u65b9\u9762\u5177\u6709\u5f88\u597d\u7684\u5e94\u7528\u3002MOF\u7684\u5b54\u7ed3\u6784\u80fd\u591f\u901a\u8fc7\u63a7\u5236\u8fde\u63a5\u4f53\u7684\u957f\u5ea6\u3001\u7c7b\u578b\u3001\u5b98\u80fd\u56e2\uff0c\u91d1\u5c5e\u7ed3\u70b9\u7684\u6838\u6570\u548c\u8fde\u63a5\u6570\u3001\u91d1\u5c5e\u7ed3\u70b9\u7c7b\u578b\u53ca\u5176MOF\u6750\u6599\u7684\u62d3\u6251\u7ed3\u6784\u8fdb\u884c\u8c03\u63a7\u3002\u4f46\u662f\u5927\u90e8\u5206MOFs\u6750\u6599\u5177\u6709\u5fae\u5b54\u7684\u7279\u70b9\uff0c\u6781\u5927\u5730\u963b\u788d\u4e86\u5927\u5206\u5b50\u5728\u5b54\u5185\u7684\u6269\u6563\u3002\u90e8\u5206MOFs\u7684\u7ed3\u6784\uff0c\u5728\u6f6e\u6e7f\u7a7a\u6c14\u4e0b\uff0c\u6c34\u6eb6\u6db2\u4e2d\u6216\u8005\u9ad8\u6e29\u4e0b\uff0c\u751a\u81f3\u4f1a\u51fa\u73b0\u574d\u584c\u5206\u89e3\u7684\u60c5\u51b5\uff0c\u8fd9\u9650\u5236\u4e86\u5b83\u4eec\u5728\u50ac\u5316\u548c\u5176\u4ed6\u65b9\u9762\u7684\u5e94\u7528\u3002\u6b64\u5916\uff0c\u5f53 MOF\u7528\u6765\u56fa\u5b9a\u9176\u6216\u8005\u5176\u4ed6\u5927\u7684\u50ac\u5316\u5242\uff0c\u5176\u6d3b\u6027\u4f4d\u70b9\u548c\u50ac\u5316\u6d3b\u6027\u4f1a\u56e0\u4e3a\u5b54\u7684\u5835\u585e\u800c\u4e0b\u964d\u3002\u56e0\u6b64\u8db3\u591f\u7684\u5b54\u5f84\u5c3a\u5bf8\u3001\u9002\u5f53\u7684\u7a33\u5b9a\u6027\u548c\u591a\u7ea7\u7684\u5b54\u7ed3\u6784\u662f\u9762\u5411\u5927\u5206\u5b50\u5438\u9644\u548c\u50ac\u5316\u7684\u6846\u67b6\u7ed3\u6784\u8bbe\u8ba1\u7684\u91cd\u8981\u56e0\u7d20\u3002\u6700\u8fd1\u57fa\u4e8e\u4e0d\u7a33\u5b9a\u5316\u5b66\u952e\u7684\u8bbe\u8ba1\u7b56\u7565\u88ab\u5e7f\u6cdb\u62a5\u9053\uff0c\u8fd9\u4e9b\u7b56\u7565\u6709\u671b\u5728\u591a\u7ea7\u5b54\u6750\u6599\u7684\u6784\u9020\u4e2d\u53d1\u6325\u8f83\u5927\u6f5c\u529b\u3002\u672c\u6587\u53d1\u73b0\u4e86\u4e00\u79cd\u5728\u591a\u5143MOFs\u4e2d\u5229\u7528\u53ef\u63a7\u914d\u4f53\u70ed\u89e3\u5236\u5907\u4ecb\u5b54\u6750\u6599\u7684\u65b9\u6cd5\u3002\u8fd9\u79cd\u65b9\u6cd5\u5229\u7528\u4e86\u4e0d\u540c\u5b98\u80fd\u5316\u7684\u8fde\u63a5\u4f53\u4e4b\u95f4\u5177\u6709\u8f83\u5927\u70ed\u7a33\u5b9a\u6027\u5dee\u5f02\u7684\u7279\u70b9\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5728\u591a\u5143MOF\u4f53\u7cfb\u9009\u62e9\u6027\u88c2\u89e3\u8fde\u63a5\u4f53\u7684\u7b56\u7565\u3002\u8be5\u7b56\u7565\u4e0d\u4ec5\u53ef\u4ee5\u5f62\u6210\u8d85\u7a33\u5b9a\u7684\u591a\u7ea7\u5b54\u9053\u7ed3\u6784\uff0c\u4e5f\u80fd\u5728\u6846\u67b6\u7ed3\u6784\u4e2d\u5f62\u6210\u8d85\u5c0f\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u9897\u7c92\uff0c\u4e3a\u5236\u5907MO@HP-MOF\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u6cd5\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8be5\u7b56\u7565\u5145\u5206\u63a2\u8ba8\u4e86\u591a\u5143MOFs\u4e2d\u8fde\u63a5\u4f53\u5206\u5e03\u4e0e\u591a\u7ea7\u5b54MOFs\u4e2d\u4ecb\u5b54\u5e03\u5c40\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u5bf9\u63ed\u793a\u591a\u5143\u7cfb\u7edf\u4e2d\u65e0\u5e8f\u5206\u5e03\u95ee\u9898\u63d0\u51fa\u65b0\u7684\u89c6\u89d2\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8db3\u591f\u7684\u5b54\u5c3a\u5bf8\u3001\u5408\u9002\u7684\u7a33\u5b9a\u6027\u548c\u591a\u7ea7\u7684\u5b54\u9053\u7ed3\u6784\u662f\u7528\u4e8e\u8bbe\u8ba1\u836f\u7269\u4f20\u9012\uff0c\u9176\u7684\u56fa\u5b9a\u548c\u5927\u5206\u5b50\u50ac\u5316\u7684\u6846\u67b6\u7ed3\u6784\u7684\u5148\u51b3\u6761\u4ef6\u3002\u8fd1\u65e5\uff0c\u5fb7\u514b\u8428\u65af<\/strong>A&M<\/strong>\u5927\u5b66<\/strong>\u5468\u5b8f\u624d\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\uff0c\u7814\u7a76\u53d1\u73b0\u4e00\u79cd\u901a\u7528\u7684\u5408\u6210\u7b56\u7565-\u53ef\u63a7\u914d\u4f53\u70ed\u89e3-\u5236\u5907\u8d85\u7a33\u591a\u7ea7\u7ed3\u6784\u7684MOFs\u6750\u6599\uff0c\u5176\u5b54\u5f84\u5206\u5e03\u53ca\u5c3a\u5bf8\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u70ed\u4e0d\u7a33\u5b9a\u914d\u4f53\u6bd4\u4f8b\uff0c\u52a0\u70ed\u65f6\u95f4\u548c\u52a0\u70ed\u6e29\u5ea6\u5b9e\u73b0\u7cbe\u786e\u8c03\u63a7\u3002\u5fae\u5b54\u7684\u591a\u5143MOF\u6676\u4f53\u901a\u8fc7\u70ed\u5206\u89e3\uff08\u8131\u7fa7\u8fc7\u7a0b\uff09\u540e\u5f62\u6210\u6676\u4f53\u7f3a\u9677\uff0c\u4ecd\u7136\u4fdd\u7559\u539f\u672c\u5fae\u5b54MOF\u7684\u9ad8\u6676\u6001\u548c\u9ad8\u7a33\u5b9a\u6027\u3002\u540c\u65f6\uff0c\u591a\u5143MOF\u4e2d\u7684\u8fde\u63a5\u4f53\u7a7a\u95f4\u5206\u5e03\u5bf9\u4e8e\u5236\u5907\u591a\u7ea7\u5b54MOFs\u6750\u6599\u4e5f\u975e\u5e38\u91cd\u8981\u3002\u8fd9\u4e2a\u7b56\u7565\u4e0d\u4ec5\u5728\u5fae\u5b54\u6750\u6599\u4e2d\u6784\u9020\u4e86\u8f83\u5927\u7684\u4ecb\u5b54\uff0c\u540c\u65f6\u4e5f\u4fc3\u8fdb\u8d85\u5c0f\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u9897\u7c92\u7684\u751f\u6210\uff0c\u590d\u5408\u7269\u8868\u73b0\u51fa\u5bf9\u8def\u6613\u65af\u9178\u50ac\u5316\u53cd\u5e94\u7684\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u672c\u6587\u63d0\u4f9b\u4e86\u4e00\u79cd\u5d2d\u65b0\u89c6\u89d2\uff0c\u89e3\u5bc6\u4e86\u591a\u5143MOFs\u4e2d\u7684\u8fde\u63a5\u4f53\u7a7a\u95f4\u5206\u5e03\u548c\u591a\u7ea7\u5b54MOFs\u4e2d\u7684\u4ecb\u5b54\u7acb\u4f53\u5e03\u5c40\u4e4b\u95f4\u7684\u8054\u7cfb\uff0c\u8fd9\u4e3a\u7814\u7a76\u8fde\u63a5\u4f53\u5728\u591a\u5143\u4f53\u7cfb\u7684\u65e0\u5e8f\u5206\u5e03\u63d0\u4f9b\u4e86\u91cd\u8981\u7ebf\u7d22\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal\u2212Organic Frameworks<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Journal of the American Chemical Society<\/strong>\u4e0a\u3002\u8fd9\u9879\u5de5\u4f5c\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u535a\u58eb\u751f\u51af\u4eae<\/strong>\uff0c\u540c\u65f6\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u8fbe\u62c9\u65af\u5206\u6821<\/strong>\u7684Yves J. Chabal<\/strong>\u6559\u6388\u56e2\u961f\u548c\u6c99\u7279\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66<\/strong>\u7684\u97e9\u5b87<\/strong>\u6559\u6388\u56e2\u961f\u4e5f\u53c2\u4e0e\u4e86\u8be5\u5de5\u4f5c\u7684\u7814\u7a76\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u5728\u5fae\u5b54\u591a\u5143<\/strong>UiO-66<\/strong>\u7ed3\u6784\u4e2d\u7684\u53ef\u63a7\u4ecb\u5b54\u5f62\u6210<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09UiO-66-NH2<\/sub>-26%-350 \u00b0C\u7684\u4e0d\u540c\u52a0\u70ed\u65f6\u95f4\u7684N2<\/sub>\u8131\u5438\u9644\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u5305\u542bR% BDC-NH2<\/sub>\u7684UiO-66-NH2<\/sub>-R%-350 \u00b0C-120 min\u7684N2<\/sub>\u8131\u5438\u9644\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0b\uff0cUiO-66-NH2<\/sub>-26%-120 min\u7684N2<\/sub>\u8131\u5438\u9644\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09UiO-66-NH2<\/sub>-26%-350 \u00b0C\u5728\u4e0d\u540c\u52a0\u70ed\u65f6\u95f4\u540e\u7684\u5b54\u5f84\u5206\u5e03\uff1b<\/p>\n

\uff08e\uff09\u5305\u542bR% BDC-NH2<\/sub>\u7684UiO-66-NH2<\/sub>-R%-350 \u00b0C-120 min\u7684\u5b54\u5f84\u5206\u5e03\uff1b<\/p>\n

\uff08f\uff09\u4e0d\u540c\u6e29\u5ea6\u5904\u7406\u540eUiO-66-NH2<\/sub>-26%-120 min\u7684\u5b54\u5f84\u5206\u5e03\uff1b<\/p>\n

\uff08g\uff09UiO-66-NH2<\/sub>-26%-350 \u00b0C\u4e0d\u540c\u52a0\u70ed\u65f6\u95f4\u540e\u7684\u4ecb\u5b54\u548c\u5fae\u5b54\u7684\u4f53\u79ef\u6bd4\uff1b<\/p>\n

\uff08h\uff09\u5305\u542bR% BDC-NH2<\/sub>\u7684UiO-66-NH2<\/sub>-R%-350 \u00b0C-120 min\u7684\u4ecb\u5b54\u548c\u5fae\u5b54\u7684\u4f53\u79ef\u6bd4\uff1b<\/p>\n

\uff08i\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0b\uff0cUiO-66-NH2<\/sub>-26%-120 min\u7684\u4ecb\u5b54\u548c\u5fae\u5b54\u7684\u4f53\u79ef\u6bd4\u3002<\/p>\n

\u56fe<\/strong>2 MTV-UiO-66\/HP-UiO-66<\/strong>\u7684\u7ed3\u6784\u8868\u5f81\u53ca\u5176\u70ed\u89e3\u673a\u7406\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09MTV-UiO-66-NH2<\/sub>-R%\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u548c\uff08e\uff09UiO-66-NH2<\/sub>-26%\u70ed\u5904\u7406\u524d\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09\u548c\uff08f\uff09UiO-66-NH2<\/sub>-26%\u70ed\u5904\u7406\u540e\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09HP-UiO-66\u7684PXRD\u8c31\uff1b<\/p>\n

\uff08g\uff09UiO-66-NH2<\/sub>-26%\u7684TGA-MS\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08h\uff09\u53ef\u63a7\u914d\u4f53\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u7684UiO-66-NH2<\/sub>-26%\u539f\u4f4d\u7ea2\u5916\u5438\u6536\u5149\u8c31\u3002<\/p>\n

\u00a0<\/strong>\u56fe3 \u591a\u7ea7\u5b54\u7684\u5f62\u6210\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u76f8\u5bf9\u8f83\u4f4e\u7684\u6e29\u5ea6\u4e0b\uff0c\u6c28\u57fa\u5b98\u80fd\u5316\u7684\u8fde\u63a5\u4f53\u503e\u5411\u4e8e\u53d1\u751f\u8131\u7fa7\u8fc7\u7a0b\uff0c\u901a\u8fc7\u70ed\u5904\u7406\u6216\u8005\u5316\u5b66\u5904\u7406\u53ef\u4ee5\u8fdb\u4e00\u6b65\u9664\u53bb\u672b\u7aef\u914d\u4f53\uff1b<\/p>\n

\uff08b\uff09Zr6<\/sub>O4<\/sub>(OH)4<\/sub>(CO2<\/sub>)12<\/sub>\u7c07\u70ed\u89e3\u540e\u8f6c\u5316\u4e3a\u8131\u7fa7\u8131\u6c34\u7684Zr6<\/sub>O6<\/sub>\u56e2\u7c07\uff0c\u5e76\u8d8b\u5411\u4e8e\u6c27\u5316\u7269\uff0c\u6700\u7ec8\u5f62\u6210\u8d85\u5c0f\u578bMO\u7eb3\u7c73\u9897\u7c92\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c\uff09\u5fae\u5b54MTV-MOF\uff08UiO-66-NH2<\/sub>-R\uff05\uff09\u70ed\u89e3\u8f6c\u5316\u4e3a\u8d85\u5c0fMO\u548cHP-MOF\u590d\u5408\u6750\u6599\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>4 <\/strong>\u53ef\u63a7\u914d\u4f53\u70ed\u89e3\u7684\u591a\u529f\u80fd\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5229\u7528\u4e0d\u540c\u70ed\u7a33\u5b9a\u6027\u7684\u8fde\u63a5\u4f53\u5236\u5907HP-MOF\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09UiO-67-GH\u70ed\u89e3\u524d\u7684\u5355\u6676\u56fe\uff1b<\/p>\n

\uff08c\uff09UiO-67-GH\u70ed\u89e3\u540e\u7684\u5355\u6676\u56fe\uff1b<\/p>\n

\uff08d\uff09UiO-67-GH\u70ed\u89e3\u524d\u540e\u7684N2<\/sub>\u8131\u5438\u9644\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09UiO-67-GH\u70ed\u89e3\u524d\u540e\u7684\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong>5 MTV-MOFs<\/strong>\u8fde\u63a5\u4f53\u7a7a\u95f4\u5206\u5e03\u548c\u591a\u7ea7\u5b54<\/strong>MOFs<\/strong>\u4e2d\u7684\u4ecb\u5b54\u7acb\u4f53\u5e03\u5c40\u7684\u5173\u7cfb<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5927\u533a\u57df\u5206\u5e03\u7684MTV-MOFs\u6a21\u578b\uff1b<\/p>\n

\uff08b\uff09\u5c0f\u533a\u57df\u5206\u5e03\u7684MTV-MOFs\u6a21\u578b\uff1b<\/p>\n

\uff08c\uff09\u968f\u673a\u5206\u5e03\u7684MTV-MOFs\u6a21\u578b\uff1b<\/p>\n

\uff08d\uff09\u6709\u5e8f\u5206\u5e03\u7684MTV-MOFs\u6a21\u578b\uff1b<\/p>\n

\uff08e\uff09\u533a\u57df\u5206\u5e03\u6a21\u578bMTV-MOF\u5bf9\u5e94\u7684HP-MOF\u4e2d\u7684\u7c07\u7f3a\u9677\uff1b<\/p>\n

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\u00a0<\/strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>“<\/strong>Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal\u2212Organic Frameworks”<\/strong><\/a> \uff08J. Am. Chem. Soc., 2018, DOI: 10.1021\/jacs.7b12916\uff09\u3002<\/p>\n

\uff081\uff09\u56e2\u961f\u4ecb\u7ecd\uff1a\u5468\u5b8f\u624d\u6559\u6388\uff0c2000\u5e74\u83b7\u7f8e\u56fd\u5fb7\u514b\u8428\u65afA&M\u5927\u5b66\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u7f8e\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58ebF. A. Cotton\u6559\u6388\u3002\u968f\u540e\u4ed6\u8ddf\u968f\u54c8\u4f5b\u5927\u5b66\u7f8e\u56fd\u79d1\u5b66\u9662\u9662\u58ebR. H. Holm\u6559\u6388\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u30022002\u5e74\u53d7\u8058\u8fc8\u963f\u5bc6\u5927\u5b66\uff0c2008\u5e74\u81f3\u7f8e\u56fd\u5fb7\u514b\u8428\u65afA&M\u5927\u5b66\u4efb\u5168\u804c\u6559\u6388\u30022014\u5e74\u4efbDavidson\u79d1\u5b66\u8bb2\u5e2d\u6559\u6388\uff0c2015\u5e74\u4efbRobert A. Welch\u5316\u5b66\u8bb2\u5e2d\u6559\u6388\u30022016\u5e74\uff0c\u88ab\u9009\u4e3a\u7f8e\u56fd\u5316\u5b66\u4f1a\u4f1a\u58eb\uff08Fellow of the American Chemical Society\uff09\u3002\u5468\u5b8f\u624d\u6559\u6388\u662fMOFs\u7814\u7a76\u9886\u57df\u7684\u9886\u519b\u4eba\u7269\uff0c\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728MOFs\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u53ca\u5176\u5728\u6c14\u4f53\u5438\u9644\u3001\u5206\u79bb\u548c\u50ac\u5316\u7b49\u9886\u57df\u7684\u5e94\u7528\u30022012\u5e74\u548c2014\u5e74\u4f5c\u4e3a\u5ba2\u5ea7\u7f16\u8f91\u5728Chem. Rev.\uff08\u7f8e\u56fd\u5316\u5b66\u4f1a\u7efc\u8ff0\uff09\u548cChem. Soc. Rev.\uff08\u82f1\u56fd\u5316\u5b66\u4f1a\u8bc4\u8bba\uff09\u4e0a\u51fa\u7248\u4e86\u9996\u671f\u6709\u5173MOFs\u7684\u4e13\u520a\u30022013\u5e74\u5f00\u59cb\u4efb\u7f8e\u56fd\u5316\u5b66\u4f1a\u65d7\u4e0bInorganic Chemistry\u6742\u5fd7\u7684\u526f\u4e3b\u7f16\u3002\u8fc4\u4eca\u5df2\u53d1\u8868SCI\u8bba\u6587\u4e24\u767e\u4f59\u7bc7\uff0c\u5176\u4e2d\u6709\u4e00\u767e\u4f59\u7bc7\u8bba\u6587\u53d1\u8868\u5728Nat. Chem.\uff08\u81ea\u7136\u5316\u5b66\uff09, Nat. Commun.\uff08\u81ea\u7136\u901a\u8baf, 7\u7bc7\uff09\u3001JACS\uff08\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7, 52\u7bc7\uff09, Angew. Chem. Int. Ed.\uff08\u5fb7\u56fd\u5e94\u7528\u5316\u5b66, 22\u7bc7\uff09, Adv. Mater. (\u5148\u8fdb\u6750\u6599\uff0c5\u7bc7) \u7b49\u56fd\u9645\u77e5\u540d\u5b66\u672f\u671f\u520a\uff08IF >10\uff09\u4e0a\u3002\u8bba\u6587\u88ab\u5f15\u752831900\u4f59\u6b21\uff1bH\u56e0\u5b50\u4e3a79\u3002<\/p>\n

\uff082\uff09 \u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\u4ee5\u53ca\u76f8\u5173\u6587\u732e\u63a8\u8350<\/p>\n

\u6784\u9020\u591a\u7ea7\u5b54\u7f3a\u9677\u6750\u6599\uff1a<\/p>\n

\u201cCooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks\u201d Sun, L.-B.; Li, J.-R.; Park, J.; Zhou, H.-C. J. Am. Chem. Soc. 2012, <\/strong>134 (1), 126\u2013129.<\/em><\/p>\n

\u201cIntroduction of Functionalized Mesopores to Metal-Organic Frameworks via Metal-Ligand-Fragment Coassembly\u201d, Park, J.; Wang, Z.U.; Sun, L.-B.; Chen, Y.-P.; Zhou, H.-C., J. Am. Chem. Soc.<\/em>, 2012<\/strong>, 134 (49)<\/em>, 20110\u201320116.<\/p>\n

“Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs with Enhanced Tunability”, Yuan, S.; Qin, J.-S.; Zou, L.; Chen, Y.-P.; Wang, X.; Zhang, Q.; Zhou, H.-C., J. Am. Chem. Soc.,<\/em> 2016<\/strong>, DOI: 10.1021\/jacs.6b03263.<\/p>\n

\u201cConstruction of hierarchically porous metal\u2013organic frameworks through linker labilization\u201d Yuan, S.; Zou, L.; Qin, J.-S.; Li, J.; Huang, L.; Feng, L.; Wang, X.; Bosch, M.; Alsalme, A.; Cagin, T.; Zhou, H.-C. Nat. Commun.<\/em> 2017<\/strong>, 8<\/em>, 15356.<\/p>\n

\u591a\u7ec4\u5206MOF\u6750\u6599\u7684\u5408\u6210\u8bbe\u8ba1\uff1a<\/p>\n

\u201cSequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal\u2013Organic Frameworks\u201d, Yuan, S.; Lu, W.; Chen, Y.-P.; Zhang, Q.; Liu, T.-F.; Feng, D.; Wang, X.; Qin, J.; Zhou. H.-C., J. Am. Chem. Soc.<\/em>, 2015<\/strong>, 137<\/em>, 3177\u20133180.<\/p>\n

\u201cCooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks\u201d, Yuan, S.; Chen, Y.-P.; Qin, J.; Lu, W.; Wang, X; Zhang, Q.; Bosch, M.; Liu. T.-F.; Lian, X.; Zhou, H.\u2013C., Angew. Chem. Int. Ed.<\/em>, 2015<\/strong>, 54, 14696-14700.<\/p>\n

“An In Situ<\/em> One-Pot Synthetic Aproach towards Multivariate Zirconium MOFs”, Sun, Y.; Sun, L.; Feng, D.; Zhou, H.-C., Angew. Chem. Int. Ed.,<\/em> 2016<\/strong>, 55, 6471.<\/p>\n

“Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs”, Yuan, S.; Chen, Y.-P.; Qin, J.-S.; Lu, W.; Zou, L.; Zhang, Q.; Wang, X.; Sun, X.; Zhou, H.-C., J. Am. Chem. Soc.,<\/em> 2016<\/strong>, 138, 8912. “Stepwise Synthesis of Metal-Organic Frameworks”, Bosch, M.; Yuan, S.; Rutledge, W.; Zhou, H.-C., Acc. Chem. Res.<\/em>, 2017<\/strong>, 50<\/em> (4), 857-865.<\/p>\n

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